Single Pd Atoms on θ-Al2O3 (010) Surface do not Catalyze NO Oxidation
Abstract
New convenient wet chemistry synthetic routes have made it possible to explore catalytic activities of a variety of single supported atoms. The majority of single supported atoms have been synthesized on active supports which participate in oxidation reactions. The single supported atoms on inert substrates (e.g. alumina) are limited to Pt adatoms and Pd cations, and are generally active toward CO oxidation. In this manuscript, we show that single Pd atoms on -alumina show high CO oxidation activity; however, they exhibit no detectable NO oxidation under our experimental conditions. This led us to employ first principles modeling to explore multiple Langmuir-Hinshelwood-type pathways to explain high CO oxidation activity but lack of NO oxidation activity. For completeness, we have also examined Eley-Riedel pathways. We find that a pathway that involves carbonate or nitrate as an intermediate can explain the experimental results of CO and NO oxidation on single alumina supported Pd cations.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy & Transportation Science Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1349596
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Narula, Chaitanya K., Allard, Lawrence F., Moses-DeBusk, Melanie, Stocks, G. Malcom, and Wu, Zili. Single Pd Atoms on θ-Al2O3 (010) Surface do not Catalyze NO Oxidation. United States: N. p., 2017.
Web. doi:10.1038/s41598-017-00577-y.
Narula, Chaitanya K., Allard, Lawrence F., Moses-DeBusk, Melanie, Stocks, G. Malcom, & Wu, Zili. Single Pd Atoms on θ-Al2O3 (010) Surface do not Catalyze NO Oxidation. United States. https://doi.org/10.1038/s41598-017-00577-y
Narula, Chaitanya K., Allard, Lawrence F., Moses-DeBusk, Melanie, Stocks, G. Malcom, and Wu, Zili. Mon .
"Single Pd Atoms on θ-Al2O3 (010) Surface do not Catalyze NO Oxidation". United States. https://doi.org/10.1038/s41598-017-00577-y. https://www.osti.gov/servlets/purl/1349596.
@article{osti_1349596,
title = {Single Pd Atoms on θ-Al2O3 (010) Surface do not Catalyze NO Oxidation},
author = {Narula, Chaitanya K. and Allard, Lawrence F. and Moses-DeBusk, Melanie and Stocks, G. Malcom and Wu, Zili},
abstractNote = {New convenient wet chemistry synthetic routes have made it possible to explore catalytic activities of a variety of single supported atoms. The majority of single supported atoms have been synthesized on active supports which participate in oxidation reactions. The single supported atoms on inert substrates (e.g. alumina) are limited to Pt adatoms and Pd cations, and are generally active toward CO oxidation. In this manuscript, we show that single Pd atoms on -alumina show high CO oxidation activity; however, they exhibit no detectable NO oxidation under our experimental conditions. This led us to employ first principles modeling to explore multiple Langmuir-Hinshelwood-type pathways to explain high CO oxidation activity but lack of NO oxidation activity. For completeness, we have also examined Eley-Riedel pathways. We find that a pathway that involves carbonate or nitrate as an intermediate can explain the experimental results of CO and NO oxidation on single alumina supported Pd cations.},
doi = {10.1038/s41598-017-00577-y},
journal = {Scientific Reports},
number = 1,
volume = 7,
place = {United States},
year = {Mon Apr 03 00:00:00 EDT 2017},
month = {Mon Apr 03 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Preparation of highly effective ferric hydroxide supported noble metal catalysts for CO oxidations: From gold to palladium
journal, January 2009
- Qiao, B.; Liu, L.; Zhang, J.
- Journal of Catalysis, Vol. 261, Issue 2
Preparation of highly effective ferric hydroxide supported noble metal catalysts for CO oxidations: From gold to palladium
journal, January 2009
- Qiao, B.; Liu, L.; Zhang, J.
- Journal of Catalysis, Vol. 261, Issue 2
Mixed metal bis(μ-oxo) complexes with [CuM(μ-O) 2 ] n+ (M = Ni( iii ) or Pd( ii )) cores
journal, January 2004
- Aboelella, Nermeen W.; York, John T.; Reynolds, Anne M.
- Chem. Commun., Issue 15
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Structure Sensitivity of Alkynol Hydrogenation on Shape- and Size-Controlled Palladium Nanocrystals: Which Sites Are Most Active and Selective?
journal, August 2011
- Crespo-Quesada, Micaela; Yarulin, Artur; Jin, Mingshang
- Journal of the American Chemical Society, Vol. 133, Issue 32
High-Activity, Single-Site Mesoporous Pd/Al 2 O 3 Catalysts for Selective Aerobic Oxidation of Allylic Alcohols
journal, October 2007
- Hackett, Simon F. J.; Brydson, Rik M.; Gass, Mhairi H.
- Angewandte Chemie International Edition, Vol. 46, Issue 45
The mechanism of the catalytic action of platinum in the reactions 2Co + O2= 2Co2 and 2H2+ O2= 2H2O
journal, January 1922
- Langmuir, Irving
- Transactions of the Faraday Society, Vol. 17
In Situ FTIR Studies of the Selective Catalytic Reduction of NO by C3H6 over Pt/Al2O3
journal, June 1999
- Captain, Dinyar K.; Amiridis, Michael D.
- Journal of Catalysis, Vol. 184, Issue 2
CO Oxidation on a Single Pd Atom Supported on Magnesia
journal, June 2001
- Abbet, S.; Heiz, U.; Häkkinen, H.
- Physical Review Letters, Vol. 86, Issue 26
Design of a Highly Active Ir/Fe(OH) x Catalyst: Versatile Application of Pt-Group Metals for the Preferential Oxidation of Carbon Monoxide
journal, February 2012
- Lin, Jian; Qiao, Botao; Liu, Jingyue
- Angewandte Chemie International Edition, Vol. 51, Issue 12
Coupled theoretical and experimental analysis of surface coverage effects in Pt-catalyzed NO and O2 reaction to NO2 on Pt(111)
journal, July 2008
- Smeltz, A. D.; Getman, R. B.; Schneider, W. F.
- Catalysis Today, Vol. 136, Issue 1-2
The Power of Single-Atom Catalysis
journal, August 2015
- Liang, Suxia; Hao, Ce; Shi, Yantao
- ChemCatChem, Vol. 7, Issue 17
Palladium Complexes of 1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane: Synthesis, Crystal Structure and Use in the Suzuki and Sonogashira Reactions and the α-Arylation of Ketones
journal, July 2004
- Adjabeng, George; Brenstrum, Tim; Frampton, Christopher S.
- The Journal of Organic Chemistry, Vol. 69, Issue 15
In Situ FTIR Studies of the Selective Catalytic Reduction of NO by C3H6 over Pt/Al2O3
journal, June 1999
- Captain, Dinyar K.; Amiridis, Michael D.
- Journal of Catalysis, Vol. 184, Issue 2
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Reaction of NO and O2 to NO2 on Pt: Kinetics and catalyst deactivation
journal, July 2006
- Mulla, S.; Chen, N.; Cumaranatunge, L.
- Journal of Catalysis, Vol. 241, Issue 2
The mechanism of the catalytic action of platinum in the reactions 2Co + O2= 2Co2 and 2H2+ O2= 2H2O
journal, January 1922
- Langmuir, Irving
- Transactions of the Faraday Society, Vol. 17
Catalytic Oxidation of Carbon Monoxide on Monodispersed Platinum Clusters: Each Atom Counts
journal, April 1999
- Heiz, U.; Sanchez, A.; Abbet, S.
- Journal of the American Chemical Society, Vol. 121, Issue 13
Structure, Activity, and Stability of Atomically Dispersed Rh in Methane Steam Reforming
journal, March 2014
- Duarte, R. B.; Krumeich, F.; van Bokhoven, J. A.
- ACS Catalysis, Vol. 4, Issue 5
Structure, Activity, and Stability of Atomically Dispersed Rh in Methane Steam Reforming
journal, March 2014
- Duarte, R. B.; Krumeich, F.; van Bokhoven, J. A.
- ACS Catalysis, Vol. 4, Issue 5
Notes. Aqueous chemistry of platinum and palladium complexes. Synthesis and crystal structure of a palladium( II ) aqua complex with a cyclometallated ligand: [PdL(H 2 O)(ONO 2 )]ClO 4 ·H 2 O (L = 1-methyl-2,2′-bipyridin-3-ylium)
journal, January 1991
- Castan, Paule; Jaud, Joël; Wimmer, Smita
- J. Chem. Soc., Dalton Trans., Issue 4
Doping Effects in Cluster-Mediated Bond Activation
journal, June 2015
- Schwarz, Helmut
- Angewandte Chemie International Edition, Vol. 54, Issue 35
Catalytic Oxidation of Carbon Monoxide on Monodispersed Platinum Clusters: Each Atom Counts
journal, April 1999
- Heiz, U.; Sanchez, A.; Abbet, S.
- Journal of the American Chemical Society, Vol. 121, Issue 13
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013
- Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
- Accounts of Chemical Research, Vol. 46, Issue 8
Electronic Metal-Support Interactions in Single-Atom Catalysts
journal, March 2014
- Hu, Pingping; Huang, Zhiwei; Amghouz, Zakariae
- Angewandte Chemie International Edition, Vol. 53, Issue 13
Reaction of NO and O2 to NO2 on Pt: Kinetics and catalyst deactivation
journal, July 2006
- Mulla, S.; Chen, N.; Cumaranatunge, L.
- Journal of Catalysis, Vol. 241, Issue 2
Thermodynamics of Environment-Dependent Oxygen Chemisorption on Pt(111)
journal, June 2008
- Getman, Rachel B.; Xu, Ye; Schneider, William F.
- The Journal of Physical Chemistry C, Vol. 112, Issue 26
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Crystal structure refinement for trans-[Pd(NO3)2(H2O)2]
journal, November 2007
- Khranenko, S. P.; Baidina, I. A.; Gromilov, S. A.
- Journal of Structural Chemistry, Vol. 48, Issue 6
Doping Effects in Cluster-Mediated Bond Activation
journal, June 2015
- Schwarz, Helmut
- Angewandte Chemie International Edition, Vol. 54, Issue 35
Ab Initio Density Functional Calculations of Adsorption of Transition Metal Atoms on θ-Al 2 O 3 (010) Surface
journal, February 2012
- Narula, Chaitanya K.; Stocks, G. Malcolm
- The Journal of Physical Chemistry C, Vol. 116, Issue 9
NO Oxidation Catalysis on Pt Clusters: Elementary Steps, Structural Requirements, and Synergistic Effects of NO 2 Adsorption Sites
journal, July 2009
- Weiss, Brian M.; Iglesia, Enrique
- The Journal of Physical Chemistry C, Vol. 113, Issue 30
Coupled theoretical and experimental analysis of surface coverage effects in Pt-catalyzed NO and O2 reaction to NO2 on Pt(111)
journal, July 2008
- Smeltz, A. D.; Getman, R. B.; Schneider, W. F.
- Catalysis Today, Vol. 136, Issue 1-2
CO Oxidation on Supported Single Pt Atoms: Experimental and ab Initio Density Functional Studies of CO Interaction with Pt Atom on θ-Al 2 O 3 (010) Surface
journal, August 2013
- Moses-DeBusk, Melanie; Yoon, Mina; Allard, Lawrence F.
- Journal of the American Chemical Society, Vol. 135, Issue 34
Reactor and in situ FTIR studies of Pt/BaO/Al2O3 and Pd/BaO/Al2O3 NOx storage and reduction (NSR) catalysts
journal, February 2007
- Su, Y.; Kabin, K.; Harold, M.
- Applied Catalysis B: Environmental, Vol. 71, Issue 3-4
Catalytic CO Oxidation on Single Pt-Atom Doped Aluminum Oxide Clusters: Electronegativity-Ladder Effect
journal, June 2015
- Li, Xiao-Na; Yuan, Zhen; Meng, Jing-Heng
- The Journal of Physical Chemistry C, Vol. 119, Issue 27
Pure component spectral analysis of surface adsorbed species measured under real conditions. BTEM-DRIFTS study of CO and NO reaction over a Pd/γ-Al2O3 catalyst
journal, January 2008
- Chilukoti, Srilakshmi; Gao, Feng; Anderson, Bruce G.
- Physical Chemistry Chemical Physics, Vol. 10, Issue 36
Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina
journal, September 2014
- Peterson, Eric J.; DeLaRiva, Andrew T.; Lin, Sen
- Nature Communications, Vol. 5, Issue 1
Structure Sensitivity of Alkynol Hydrogenation on Shape- and Size-Controlled Palladium Nanocrystals: Which Sites Are Most Active and Selective?
journal, August 2011
- Crespo-Quesada, Micaela; Yarulin, Artur; Jin, Mingshang
- Journal of the American Chemical Society, Vol. 133, Issue 32
Mechanism and site requirements for NO oxidation on Pd catalysts
journal, May 2010
- Weiss, Brian M.; Iglesia, Enrique
- Journal of Catalysis, Vol. 272, Issue 1
Implications of coverage-dependent O adsorption for catalytic NO oxidation on the late transition metals
journal, January 2014
- Frey, Kurt; Schmidt, David J.; Wolverton, C.
- Catal. Sci. Technol., Vol. 4, Issue 12
Reversible work transition state theory: application to dissociative adsorption of hydrogen
journal, February 1995
- Mills, Gregory; Jónsson, Hannes; Schenter, Gregory K.
- Surface Science, Vol. 324, Issue 2-3
Catalysis by Design - Theoretical and Experimental Studies of Model Catalysts
conference, April 2007
- Narula, Chaitanya K.; Moses, Melanie J.; Xu, Ye
- SAE World Congress & Exhibition, SAE Technical Paper Series
Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C
journal, February 1987
- Haruta, Masatake; Kobayashi, Tetsuhiko; Sano, Hiroshi
- Chemistry Letters, Vol. 16, Issue 2
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
Molecular surface chemistry by metal single crystals and nanoparticles from vacuum to high pressure
journal, January 2008
- Somorjai, Gabor A.; Park, Jeong Y.
- Chemical Society Reviews, Vol. 37, Issue 10
Effect of alloy composition on dispersion stability and catalytic activity for NO oxidation over alumina-supported Pt–Pd catalysts
journal, April 2007
- Graham, G. W.; Jen, H. -W.; Ezekoye, O.
- Catalysis Letters, Vol. 116, Issue 1-2
Mechanism and site requirements for NO oxidation on Pd catalysts
journal, May 2010
- Weiss, Brian M.; Iglesia, Enrique
- Journal of Catalysis, Vol. 272, Issue 1
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008
- Herzing, A. A.; Kiely, C. J.; Carley, A. F.
- Science, Vol. 321, Issue 5894
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Nudged elastic band method for finding minimum energy paths of transitions
conference, November 2011
- JÓNsson, Hannes; Mills, Greg; Jacobsen, Karsten W.
- Proceedings of the International School of Physics, Classical and Quantum Dynamics in Condensed Phase Simulations
Quantified NOx adsorption on Pt/K/gamma-Al2O3 and the effects of CO2 and H2O
journal, June 2005
- Toops, Todd J.; Smith, D. Barton; Epling, William S.
- Applied Catalysis B: Environmental, Vol. 58, Issue 3-4
Effect of alloy composition on dispersion stability and catalytic activity for NO oxidation over alumina-supported Pt–Pd catalysts
journal, April 2007
- Graham, G. W.; Jen, H. -W.; Ezekoye, O.
- Catalysis Letters, Vol. 116, Issue 1-2
Fixation of Both O 2 and CO 2 from Air by a Crystalline Palladium Complex Bearing N- Heterocyclic Carbene Ligands
journal, May 2005
- Yamashita, Makoto; Goto, Kei; Kawashima, Takayuki
- Journal of the American Chemical Society, Vol. 127, Issue 20
Remarkable NO oxidation on single supported platinum atoms
journal, November 2014
- Narula, Chaitanya K.; Allard, Lawrence F.; Stocks, G. M.
- Scientific Reports, Vol. 4, Issue 1
Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters
journal, August 2008
- Turner, Mark; Golovko, Vladimir B.; Vaughan, Owain P. H.
- Nature, Vol. 454, Issue 7207
Thermodynamics of Environment-Dependent Oxygen Chemisorption on Pt(111)
journal, June 2008
- Getman, Rachel B.; Xu, Ye; Schneider, William F.
- The Journal of Physical Chemistry C, Vol. 112, Issue 26
Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C
journal, February 1987
- Haruta, Masatake; Kobayashi, Tetsuhiko; Sano, Hiroshi
- Chemistry Letters, Vol. 16, Issue 2
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003
- Fu, Q.
- Science, Vol. 301, Issue 5635
The Role of Surface Oxides in NOx Storage Reduction Catalysts
journal, June 2010
- Jelic, Jelena; Reuter, Karsten; Meyer, Randall
- ChemCatChem, Vol. 2, Issue 6
Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation
journal, September 1992
- Perdew, John P.; Chevary, J. A.; Vosko, S. H.
- Physical Review B, Vol. 46, Issue 11
Accurate and simple analytic representation of the electron-gas correlation energy
journal, June 1992
- Perdew, John P.; Wang, Yue
- Physical Review B, Vol. 45, Issue 23, p. 13244-13249
Crystal structure refinement for trans-[Pd(NO3)2(H2O)2]
journal, November 2007
- Khranenko, S. P.; Baidina, I. A.; Gromilov, S. A.
- Journal of Structural Chemistry, Vol. 48, Issue 6
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003
- Fu, Q.
- Science, Vol. 301, Issue 5635
Reversible work transition state theory: application to dissociative adsorption of hydrogen
journal, February 1995
- Mills, Gregory; Jónsson, Hannes; Schenter, Gregory K.
- Surface Science, Vol. 324, Issue 2-3
Catalytic CO Oxidation on Single Pt-Atom Doped Aluminum Oxide Clusters: Electronegativity-Ladder Effect
journal, June 2015
- Li, Xiao-Na; Yuan, Zhen; Meng, Jing-Heng
- The Journal of Physical Chemistry C, Vol. 119, Issue 27
Pure component spectral analysis of surface adsorbed species measured under real conditions. BTEM-DRIFTS study of CO and NO reaction over a Pd/γ-Al2O3 catalyst
journal, January 2008
- Chilukoti, Srilakshmi; Gao, Feng; Anderson, Bruce G.
- Physical Chemistry Chemical Physics, Vol. 10, Issue 36
Reactor and in situ FTIR studies of Pt/BaO/Al2O3 and Pd/BaO/Al2O3 NOx storage and reduction (NSR) catalysts
journal, February 2007
- Su, Y.; Kabin, K.; Harold, M.
- Applied Catalysis B: Environmental, Vol. 71, Issue 3-4
Characterization of Peroxo and Hydroperoxo Intermediates in the Aerobic Oxidation of N -Heterocyclic-Carbene-Coordinated Palladium(0)
journal, August 2004
- Konnick, Michael M.; Guzei, Ilia A.; Stahl, Shannon S.
- Journal of the American Chemical Society, Vol. 126, Issue 33
Palladium Complexes of 1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane: Synthesis, Crystal Structure and Use in the Suzuki and Sonogashira Reactions and the α-Arylation of Ketones.
journal, November 2004
- Adjabeng, George; Brenstrum, Tim; Frampton, Christopher S.
- ChemInform, Vol. 35, Issue 47
Remarkable NO oxidation on single supported platinum atoms
journal, November 2014
- Narula, Chaitanya K.; Allard, Lawrence F.; Stocks, G. M.
- Scientific Reports, Vol. 4, Issue 1
Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013
- Lin, Jian; Wang, Aiqin; Qiao, Botao
- Journal of the American Chemical Society, Vol. 135, Issue 41
Quantified NOx adsorption on Pt/K/gamma-Al2O3 and the effects of CO2 and H2O
journal, June 2005
- Toops, Todd J.; Smith, D. Barton; Epling, William S.
- Applied Catalysis B: Environmental, Vol. 58, Issue 3-4
NO Oxidation Catalysis on Pt Clusters: Elementary Steps, Structural Requirements, and Synergistic Effects of NO 2 Adsorption Sites
journal, July 2009
- Weiss, Brian M.; Iglesia, Enrique
- The Journal of Physical Chemistry C, Vol. 113, Issue 30
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008
- Herzing, A. A.; Kiely, C. J.; Carley, A. F.
- Science, Vol. 321, Issue 5894
Ab Initio Density Functional Calculations of Adsorption of Transition Metal Atoms on θ-Al 2 O 3 (010) Surface
journal, February 2012
- Narula, Chaitanya K.; Stocks, G. Malcolm
- The Journal of Physical Chemistry C, Vol. 116, Issue 9
High-Activity, Single-Site Mesoporous Pd/Al 2 O 3 Catalysts for Selective Aerobic Oxidation of Allylic Alcohols
journal, October 2007
- Hackett, Simon F. J.; Brydson, Rik M.; Gass, Mhairi H.
- Angewandte Chemie International Edition, Vol. 46, Issue 45
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Electronic Metal-Support Interactions in Single-Atom Catalysts
journal, March 2014
- Hu, Pingping; Huang, Zhiwei; Amghouz, Zakariae
- Angewandte Chemie International Edition, Vol. 53, Issue 13
The Power of Single-Atom Catalysis
journal, August 2015
- Liang, Suxia; Hao, Ce; Shi, Yantao
- ChemCatChem, Vol. 7, Issue 17
Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters
journal, August 2008
- Turner, Mark; Golovko, Vladimir B.; Vaughan, Owain P. H.
- Nature, Vol. 454, Issue 7207
Electronic Structure Controls Reactivity of Size-Selected Pd Clusters Adsorbed on TiO2 Surfaces
journal, November 2009
- Kaden, W. E.; Wu, T.; Kunkel, W. A.
- Science, Vol. 326, Issue 5954
Works referencing / citing this record:
Ab Initio Density Functional Calculations and Infra-Red Study of CO Interaction with Pd Atoms on θ-Al2O3 (010) Surface
journal, July 2017
- Narula, Chaitanya K.; Allard, Lawrence F.; Wu, Zili
- Scientific Reports, Vol. 7, Issue 1