Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications
Abstract
The electrolyte is an indispensable component in all electrochemical energy storage and conversion devices with batteries being a prime example. While most research efforts have been pursued on the materials side, the progress for the electrolyte is slow due to the decomposition of salts and solvents at low potentials, not to mention their complicated interactions with the electrode materials. The general properties of bulk electrolytes such as ionic conductivity, viscosity, and stability all affect the cell performance. However, for a specific electrochemical cell in which the cathode, anode, and electrolyte are optimized, it is the interface between the solid electrode and the liquid electrolyte, generally referred to as the solid electrolyte interphase (SEI), that dictates the rate of ion flow in the system. The commonly used electrolyte is within the range of 1–1.2 m based on the prior optimization experience, leaving the high concentration region insufficiently recognized. Recently, electrolytes with increased concentration (>1.0 m ) have received intensive attention due to quite a few interesting discoveries in cells containing concentrated electrolytes. The formation mechanism and the nature of the SEI layers derived from concentrated electrolytes could be fundamentally distinct from those of the traditional SEI and thus enable unusual functionsmore »
- Authors:
-
- Energy and Environment Directorate Pacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA
- Chemistry &, Biochemistry Department University of Arkansas Fayetteville AR 72701 USA
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1349307
- Alternate Identifier(s):
- OSTI ID: 1349308; OSTI ID: 1378046
- Report Number(s):
- PNNL-SA-123526
Journal ID: ISSN 2198-3844; 1700032
- Grant/Contract Number:
- DE‐AC02‐05CH11231; 18769; AC05-76RL01830
- Resource Type:
- Published Article
- Journal Name:
- Advanced Science
- Additional Journal Information:
- Journal Name: Advanced Science Journal Volume: 4 Journal Issue: 8; Journal ID: ISSN 2198-3844
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; batteries; concentrated electrolytes; interfacial stability; solvation structures; solid electrolyte interphase (SEI)
Citation Formats
Zheng, Jianming, Lochala, Joshua A., Kwok, Alexander, Deng, Zhiqun Daniel, and Xiao, Jie. Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications. Germany: N. p., 2017.
Web. doi:10.1002/advs.201700032.
Zheng, Jianming, Lochala, Joshua A., Kwok, Alexander, Deng, Zhiqun Daniel, & Xiao, Jie. Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications. Germany. https://doi.org/10.1002/advs.201700032
Zheng, Jianming, Lochala, Joshua A., Kwok, Alexander, Deng, Zhiqun Daniel, and Xiao, Jie. Fri .
"Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications". Germany. https://doi.org/10.1002/advs.201700032.
@article{osti_1349307,
title = {Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications},
author = {Zheng, Jianming and Lochala, Joshua A. and Kwok, Alexander and Deng, Zhiqun Daniel and Xiao, Jie},
abstractNote = {The electrolyte is an indispensable component in all electrochemical energy storage and conversion devices with batteries being a prime example. While most research efforts have been pursued on the materials side, the progress for the electrolyte is slow due to the decomposition of salts and solvents at low potentials, not to mention their complicated interactions with the electrode materials. The general properties of bulk electrolytes such as ionic conductivity, viscosity, and stability all affect the cell performance. However, for a specific electrochemical cell in which the cathode, anode, and electrolyte are optimized, it is the interface between the solid electrode and the liquid electrolyte, generally referred to as the solid electrolyte interphase (SEI), that dictates the rate of ion flow in the system. The commonly used electrolyte is within the range of 1–1.2 m based on the prior optimization experience, leaving the high concentration region insufficiently recognized. Recently, electrolytes with increased concentration (>1.0 m ) have received intensive attention due to quite a few interesting discoveries in cells containing concentrated electrolytes. The formation mechanism and the nature of the SEI layers derived from concentrated electrolytes could be fundamentally distinct from those of the traditional SEI and thus enable unusual functions that cannot be realized using regular electrolytes. In this article, we provide an overview on the recent progress of high concentration electrolytes in different battery chemistries. The experimentally observed phenomena and their underlying fundamental mechanisms are discussed. New insights and perspectives are proposed to inspire more revolutionary solutions to address the interfacial challenges.},
doi = {10.1002/advs.201700032},
journal = {Advanced Science},
number = 8,
volume = 4,
place = {Germany},
year = {Fri Mar 31 00:00:00 EDT 2017},
month = {Fri Mar 31 00:00:00 EDT 2017}
}
https://doi.org/10.1002/advs.201700032
Web of Science
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