Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst

Nelson, Nicholas C.; Wang, Zhuoran; Naik, Pranjali; Manzano, J. Sebastian; Pruski, Marek; Slowing, Igor I.

doi:10.1039/C6TA08703E

Title: Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst

Journal Article · Fri Jan 06 04:00:00 UTC 2017 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/C6TA08703E · OSTI ID:1347404

Nelson, Nicholas C. ^[1]; Wang, Zhuoran ^[1]; Naik, Pranjali ^[1]; Manzano, J. Sebastian ^[1];

^[1];

^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)

Deposition of trimethylphosphate onto ceria followed by thermal treatment resulted in the formation of surface phosphates with retention of the ceria fluorite structure. The structural and chemical properties of the phosphate-functionalized ceria were studied using ³¹P solid-state NMR, XPS, zeta titration, ammonia thermal desorption, pyridine adsorption, and model reactions. The introduction of phosphates generated Brønsted acid sites and decreased the number of Lewis acid sites on the surface. The relative amount of Lewis and Brønsted acids can be controlled by the amount of trimethylphosphate used in the synthesis. Upon deposition of Pd, the multifunctional material showed enhanced activity for the hydrogenolysis of eugenol and guaiacol compared to Pd on the unmodified ceria support. As a result, this was attributed to the cooperativity between the Lewis acid sites, which activate the substrate for dearomatization, and the redox/Brønsted acid properties, which catalyze hydrogenolysis.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1347404

Report Number(s):: IS-J--9220

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 9 Vol. 5; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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CHEMISTRY: Oxygen Vacancies and Catalysis on Ceria Surfaces Campbell, C. T. Science, Vol. 309, Issue 5735 https://doi.org/10.1126/science.1113955	journal	July 2005
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Catalysis by Ceria and Related Materials Trovarelli, Alessandro Catalytic Science Series https://doi.org/10.1142/p249	book	January 2002
Cerium Oxide Slurries in CMP. Electrophoretic Mobility and Adsorption Investigations of Ceria/Silicate Interaction Suphantharida, Preuchsuda; Osseo-Asare, Kwadwo Journal of The Electrochemical Society, Vol. 151, Issue 10 https://doi.org/10.1149/1.1785793	journal	January 2004
Chemical Properties of Material Surfaces Kosmulski, Marek Surfactant Science https://doi.org/10.1201/9780585418049	book	July 2001

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Highly selective catalytic conversion of lignin-derived phenolic compounds to cycloalkanes over a hierarchically structured zeolite catalyst Xiang, Mei; Wu, Dongfang Journal of Materials Science, Vol. 54, Issue 4 https://doi.org/10.1007/s10853-018-3057-y	journal	October 2018

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