Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst
Abstract
Deposition of trimethylphosphate onto ceria followed by thermal treatment resulted in the formation of surface phosphates with retention of the ceria fluorite structure. The structural and chemical properties of the phosphate-functionalized ceria were studied using 31P solid-state NMR, XPS, zeta titration, ammonia thermal desorption, pyridine adsorption, and model reactions. The introduction of phosphates generated Brønsted acid sites and decreased the number of Lewis acid sites on the surface. The relative amount of Lewis and Brønsted acids can be controlled by the amount of trimethylphosphate used in the synthesis. Upon deposition of Pd, the multifunctional material showed enhanced activity for the hydrogenolysis of eugenol and guaiacol compared to Pd on the unmodified ceria support. As a result, this was attributed to the cooperativity between the Lewis acid sites, which activate the substrate for dearomatization, and the redox/Brønsted acid properties, which catalyze hydrogenolysis.
- Authors:
-
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1347404
- Report Number(s):
- IS-J-9220
Journal ID: ISSN 2050-7488; JMCAET
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 9; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Nelson, Nicholas C., Wang, Zhuoran, Naik, Pranjali, Manzano, J. Sebastian, Pruski, Marek, and Slowing, Igor I.. Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst. United States: N. p., 2017.
Web. doi:10.1039/C6TA08703E.
Nelson, Nicholas C., Wang, Zhuoran, Naik, Pranjali, Manzano, J. Sebastian, Pruski, Marek, & Slowing, Igor I.. Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst. United States. https://doi.org/10.1039/C6TA08703E
Nelson, Nicholas C., Wang, Zhuoran, Naik, Pranjali, Manzano, J. Sebastian, Pruski, Marek, and Slowing, Igor I.. Fri .
"Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst". United States. https://doi.org/10.1039/C6TA08703E. https://www.osti.gov/servlets/purl/1347404.
@article{osti_1347404,
title = {Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst},
author = {Nelson, Nicholas C. and Wang, Zhuoran and Naik, Pranjali and Manzano, J. Sebastian and Pruski, Marek and Slowing, Igor I.},
abstractNote = {Deposition of trimethylphosphate onto ceria followed by thermal treatment resulted in the formation of surface phosphates with retention of the ceria fluorite structure. The structural and chemical properties of the phosphate-functionalized ceria were studied using 31P solid-state NMR, XPS, zeta titration, ammonia thermal desorption, pyridine adsorption, and model reactions. The introduction of phosphates generated Brønsted acid sites and decreased the number of Lewis acid sites on the surface. The relative amount of Lewis and Brønsted acids can be controlled by the amount of trimethylphosphate used in the synthesis. Upon deposition of Pd, the multifunctional material showed enhanced activity for the hydrogenolysis of eugenol and guaiacol compared to Pd on the unmodified ceria support. As a result, this was attributed to the cooperativity between the Lewis acid sites, which activate the substrate for dearomatization, and the redox/Brønsted acid properties, which catalyze hydrogenolysis.},
doi = {10.1039/C6TA08703E},
journal = {Journal of Materials Chemistry. A},
number = 9,
volume = 5,
place = {United States},
year = {Fri Jan 06 00:00:00 EST 2017},
month = {Fri Jan 06 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
The Room Temperature Decomposition Mechanism of Dimethyl Methylphosphonate (DMMP) on Alumina-Supported Cerium Oxide − Participation of Nano-Sized Cerium Oxide Domains
journal, February 2004
- Mitchell, Mark B.; Sheinker, Viktor N.; Cox, Woodrow W.
- The Journal of Physical Chemistry B, Vol. 108, Issue 5
Thermally activated magnesium oxide surface chemistry. Adsorption and decomposition of phosphorus compounds
journal, September 1985
- Lin, Shaw Tao; Klabunde, Kenneth J.
- Langmuir, Vol. 1, Issue 5
Hydrodeoxygenation of Guaiacol over Ceria-Zirconia Catalysts
journal, June 2015
- Schimming, Sarah M.; LaMont, Onaje D.; König, Michael
- ChemSusChem, Vol. 8, Issue 12
Lignin Depolymerization and Conversion A Review of Thermochemical Methods
journal, November 2010
- Pandey, M. P.; Kim, C. S.
- Chemical Engineering & Technology, Vol. 34, Issue 1, p. 29-41
WO3/CeO2-ZrO2, a promising catalyst for selective catalytic reduction (SCR) of NOx with NH3 in diesel exhaust
journal, January 2008
- Li, Ye; Cheng, Hao; Li, Deyi
- Chemical Communications, Issue 12
Selective hydrogenation of nitroaromatics by ceria nanorods
journal, January 2013
- Zhu, Hai-Zhou; Lu, Yong-Ming; Fan, Feng-Jia
- Nanoscale, Vol. 5, Issue 16
STM and XPS study of CeO2(111) reduction by atomic hydrogen
journal, October 2014
- Shahed, Syed Mohammad Fakruddin; Hasegawa, Tomo; Sainoo, Yasuyuki
- Surface Science, Vol. 628
Catalytic Properties of Ceria and CeO 2 -Containing Materials
journal, November 1996
- Trovarelli, Alessandro
- Catalysis Reviews, Vol. 38, Issue 4
Polarity Control at Interfaces: Quantifying Pseudo-solvent Effects in Nano-confined Systems
journal, August 2016
- Singappuli-Arachchige, Dilini; Manzano, J. Sebastian; Sherman, Lindy M.
- ChemPhysChem, Vol. 17, Issue 19
Redox properties of water on the oxidized and reduced surfaces of CeO2
journal, February 2003
- Henderson, M. A.; Perkins, C. L.; Engelhard, M. H.
- Surface Science, Vol. 526, Issue 1-2
Multifunctional Phosphate-Based Inorganic–Organic Hybrid Nanoparticles
journal, June 2015
- Heck, Joachim G.; Napp, Joanna; Simonato, Sara
- Journal of the American Chemical Society, Vol. 137, Issue 23
Infrared Spectra and Characteristic Frequencies of Inorganic Ions
journal, August 1952
- Miller, F. A.; Wilkins, C. H.
- Analytical Chemistry, Vol. 24, Issue 8
Acidity Studies of Silica-Alumina Catalysts
journal, February 1959
- Holm, V. C. F.; Bailey, G. C.; Clark, Alfred
- The Journal of Physical Chemistry, Vol. 63, Issue 2
Solar Light Degradation of Trimethyl Phosphate and Triethyl Phosphate on Dry and Water-Precovered Hematite and Goethite Nanoparticles
journal, July 2012
- Mäkie, Peter; Persson, Per; Österlund, Lars
- The Journal of Physical Chemistry C, Vol. 116, Issue 28
Selective Hydrogenation of Phenol Catalyzed by Palladium on High-Surface-Area Ceria at Room Temperature and Ambient Pressure
journal, February 2015
- Nelson, Nicholas C.; Manzano, J. Sebastián; Sadow, Aaron D.
- ACS Catalysis, Vol. 5, Issue 4
Supported iron nanoparticles for the hydrodeoxygenation of microalgal oil to green diesel
journal, May 2014
- Kandel, Kapil; Anderegg, James W.; Nelson, Nicholas C.
- Journal of Catalysis, Vol. 314
Preparation and Characterization of Me 2 O 3 −CeO 2 (Me = B, Al, Ga, In) Mixed Oxide Catalysts. 2. Preparation by Sol−Gel Method
journal, February 2008
- Bonnetot, B.; Rakic, V.; Yuzhakova, T.
- Chemistry of Materials, Vol. 20, Issue 4
IR study of polycrystalline ceria properties in oxidised and reduced states
journal, April 1999
- Binet, Claude; Daturi, Marco; Lavalley, Jean-Claude
- Catalysis Today, Vol. 50, Issue 2
CHEMISTRY: Oxygen Vacancies and Catalysis on Ceria Surfaces
journal, July 2005
- Campbell, C. T.
- Science, Vol. 309, Issue 5735
Adsorption of Trimethyl Phosphate on Maghemite, Hematite, and Goethite Nanoparticles
journal, August 2011
- Mäkie, Peter; Westin, Gunnar; Persson, Per
- The Journal of Physical Chemistry A, Vol. 115, Issue 32
Composition of tungsten oxide bronzes active for hydrodeoxygenation
journal, November 2010
- Thibodeau, Timothy J.; Canney, Alexander S.; DeSisto, William J.
- Applied Catalysis A: General, Vol. 388, Issue 1-2
Transfer hydrogenation over sodium-modified ceria: Enrichment of redox sites active for alcohol dehydrogenation
journal, February 2017
- Nelson, Nicholas C.; Boote, Brett W.; Naik, Pranjali
- Journal of Catalysis, Vol. 346
Cerium phosphate in automotive exhaust catalyst poisoning
journal, June 2004
- Xu, L.; Guo, G.; Uy, D.
- Applied Catalysis B: Environmental, Vol. 50, Issue 2
The Isoelectric Points of Solid Oxides, Solid Hydroxides, and Aqueous Hydroxo Complex Systems
journal, April 1965
- Parks, George A.
- Chemical Reviews, Vol. 65, Issue 2
SIMPSON: A General Simulation Program for Solid-State NMR Spectroscopy
journal, December 2000
- Bak, Mads; Rasmussen, Jimmy T.; Nielsen, Niels Chr
- Journal of Magnetic Resonance, Vol. 147, Issue 2
EPR study of the photoassisted formation of radicals on CeO2 nanoparticles employed for toluene photooxidation
journal, July 2004
- Hernández-Alonso, Marı́a D.; Hungrı́a, Ana Belén; Martı́nez-Arias, Arturo
- Applied Catalysis B: Environmental, Vol. 50, Issue 3
Synthesis and Oxygen Storage Capacity of Two-Dimensional Ceria Nanocrystals
journal, April 2011
- Wang, Dianyuan; Kang, Yijin; Doan-Nguyen, Vicky
- Angewandte Chemie International Edition, Vol. 50, Issue 19
Aqueous-phase hydrodeoxygenation of bio-derived phenols to cycloalkanes
journal, May 2011
- Zhao, Chen; He, Jiayue; Lemonidou, Angeliki A.
- Journal of Catalysis, Vol. 280, Issue 1
WO 3 /CeO 2 Nanocomposite Powders: Synthesis, Characterization, and Reactivity
journal, July 2006
- Natile, Marta M.; Tomaello, Francesco; Glisenti, Antonella
- Chemistry of Materials, Vol. 18, Issue 14
Bifunctional Adsorbent-Catalytic Nanoparticles for the Refining of Renewable Feedstocks
journal, November 2013
- Kandel, Kapil; Frederickson, Conerd; Smith, Erica A.
- ACS Catalysis, Vol. 3, Issue 12
Lattice Defects and Oxygen Storage Capacity of Nanocrystalline Ceria and Ceria-Zirconia
journal, November 2000
- Mamontov, E.; Egami, T.; Brezny, R.
- The Journal of Physical Chemistry B, Vol. 104, Issue 47
Oxygen Mobility in CeO 2 and Ce x Zr (1 - x ) O 2 Compounds: Study by CO Transient Oxidation and 18 O/ 16 O Isotopic Exchange
journal, December 1999
- Madier, Y.; Descorme, C.; Le Govic, A. M.
- The Journal of Physical Chemistry B, Vol. 103, Issue 50
Synthesis, Characterization, and Photocatalytic Activity of Y-Doped CeO 2 Nanorods
journal, December 2013
- Liyanage, Anjalee D.; Perera, Sanjaya D.; Tan, Kui
- ACS Catalysis, Vol. 4, Issue 2
Alkali Metal Poisoning of a CeO 2 –WO 3 Catalyst Used in the Selective Catalytic Reduction of NO x with NH 3 : an Experimental and Theoretical Study
journal, February 2012
- Peng, Yue; Li, Junhua; Chen, Liang
- Environmental Science & Technology, Vol. 46, Issue 5
A case study: surface chemistry and surface structure of catalytic aluminas, as studied by vibrational spectroscopy of adsorbed species
journal, February 1996
- Morterra, Claudio; Magnacca, Giuliana
- Catalysis Today, Vol. 27, Issue 3-4
Spectroscopic Investigation of Surface-Dependent Acid–Base Property of Ceria Nanoshapes
journal, March 2015
- Wu, Zili; Mann, Amanda K. P.; Li, Meijun
- The Journal of Physical Chemistry C, Vol. 119, Issue 13
An infrared study of pyridine adsorbed on acidic solids. Characterization of surface acidity
journal, October 1963
- Parry, E.
- Journal of Catalysis, Vol. 2, Issue 5
Electron spectroscopy of single crystal and polycrystalline cerium oxide surfaces
journal, July 1998
- Mullins, D. R.; Overbury, S. H.; Huntley, D. R.
- Surface Science, Vol. 409, Issue 2
Effects of WOx modification on the activity, adsorption and redox properties of CeO2 catalyst for NOx reduction with ammonia
journal, July 2012
- Ma, Ziran; Weng, Duan; Wu, Xiaodong
- Journal of Environmental Sciences, Vol. 24, Issue 7
Imaging the Atomic Surface Structures of CeO 2 Nanoparticles
journal, December 2013
- Lin, Yuyuan; Wu, Zili; Wen, Jianguo
- Nano Letters, Vol. 14, Issue 1
Screening of Catalysts for Hydrodeoxygenation of Phenol as a Model Compound for Bio-oil
journal, July 2013
- Mortensen, Peter M.; Grunwaldt, Jan-Dierk; Jensen, Peter A.
- ACS Catalysis, Vol. 3, Issue 8
Surface characterization of acidic ceria–zirconia prepared by direct sulfation
journal, May 2010
- Azambre, B.; Zenboury, L.; Weber, J. V.
- Applied Surface Science, Vol. 256, Issue 14
Proton Distributions and Hydrogen Bonding in Crystalline and Glassy Hydrous Silicates and Related Inorganic Materials: Insights from High-Resolution Solid-State Nuclear Magnetic Resonance Spectroscopy
journal, December 2009
- Xue, Xianyu; Kanzaki, Masami
- Journal of the American Ceramic Society, Vol. 92, Issue 12
Chemical degradation of trimethyl phosphate as surrogate for organo-phosporus pesticides on nanostructured metal oxides
journal, January 2015
- Štengl, Václav; Henych, Jiří; Grygar, Tomáš
- Materials Research Bulletin, Vol. 61
Synthesis and characterization of mixed-morphology CePO4 nanoparticles
journal, March 2007
- Karpowich, L.; Wilcke, S.; Yu, Rong
- Journal of Solid State Chemistry, Vol. 180, Issue 3
Reactivity and stability investigation of supported molybdenum oxide catalysts for the hydrodeoxygenation (HDO) of m-cresol
journal, November 2015
- Shetty, Manish; Murugappan, Karthick; Prasomsri, Teerawit
- Journal of Catalysis, Vol. 331
Self-assembled hybrid metal oxide base catalysts prepared by simply mixing with organic modifiers
journal, October 2015
- Tamura, Masazumi; Kishi, Ryota; Nakagawa, Yoshinao
- Nature Communications, Vol. 6, Issue 1
Physical, chemical and electrochemical properties of pure and doped ceria
journal, April 2000
- Mogensen, M.
- Solid State Ionics, Vol. 129, Issue 1-4
Characterization and thermal behavior of amorphous cerium phosphate
journal, August 2003
- Masui, T.; Hirai, H.; Imanaka, N.
- physica status solidi (a), Vol. 198, Issue 2
Morphology control of ceria nanocrystals for catalytic conversion of CO2 with methanol
journal, January 2013
- Wang, Shengping; Zhao, Lifang; Wang, Wei
- Nanoscale, Vol. 5, Issue 12
Hydrodeoxygenation of Vicinal OH Groups over Heterogeneous Rhenium Catalyst Promoted by Palladium and Ceria Support
journal, December 2014
- Ota, Nobuhiko; Tamura, Masazumi; Nakagawa, Yoshinao
- Angewandte Chemie International Edition, Vol. 54, Issue 6
Adsorption of Trimethyl Phosphite at the Ge(100)-2 × 1 Surface by Nucleophilic Reaction
journal, December 2013
- Wong, Keith T.; Shong, Bonggeun; Sun, Weikang
- The Journal of Physical Chemistry C, Vol. 117, Issue 50
Catalytic roles of metals and supports on hydrodeoxygenation of lignin monomer guaiacol
journal, January 2012
- Lee, Cho Rim; Yoon, Ji Sun; Suh, Young-Woong
- Catalysis Communications, Vol. 17
A review of catalytic upgrading of bio-oil to engine fuels
journal, November 2011
- Mortensen, P. M.; Grunwaldt, J.-D.; Jensen, P. A.
- Applied Catalysis A: General, Vol. 407, Issue 1-2, p. 1-19
Ceria supported on sulfated zirconia as a superacid catalyst for selective catalytic reduction of NO with NH3
journal, March 2013
- Gao, Shan; Chen, Xiongbo; Wang, Haiqiang
- Journal of Colloid and Interface Science, Vol. 394
Adsorption and surface reactions of pyridine on pure and doped ceria catalysts as studied by infrared spectroscopy
journal, May 1989
- Zaki, M. I.; Hussein, G. A. M.; Mansour, S. A. A.
- Journal of Molecular Catalysis, Vol. 51, Issue 2
Exclusively selective oxidation of toluene to benzaldehyde on ceria nanocubes by molecular oxygen
journal, January 2010
- Lv, Jiangang; Shen, Yi; Peng, Luming
- Chemical Communications, Vol. 46, Issue 32
Role of P-containing species in phosphated CeO2 in the deterioration of its oxygen storage and release properties
journal, April 2006
- Lopezgranados, M.; Galisteo, F.; Lambrou, P.
- Journal of Catalysis, Vol. 239, Issue 2
Infrared studies of the surface acidity of oxides and zeolites using adsorbed probe molecules
journal, February 1996
- Lercher, Johannes A.; Gründling, Christian; Eder-Mirth, Gabriele
- Catalysis Today, Vol. 27, Issue 3-4
Exploring the Spatial Distribution and Transport Behavior of Charge Carriers in a Single Titania Nanowire
journal, June 2009
- Tachikawa, Takashi; Majima, Tetsuro
- Journal of the American Chemical Society, Vol. 131, Issue 24
The electronic structure of stoichiometric and reduced CeO2 surfaces: an XPS, UPS and HREELS study
journal, December 1994
- Pfau, A.; Schierbaum, K. D.
- Surface Science, Vol. 321, Issue 1-2
Bond Dissociation Energies of Organic Molecules
journal, April 2003
- Blanksby, Stephen J.; Ellison, G. Barney
- Accounts of Chemical Research, Vol. 36, Issue 4
Comprehensive IR study on acid/base properties of metal oxides
journal, August 2012
- Tamura, Masazumi; Shimizu, Ken-ichi; Satsuma, Atsushi
- Applied Catalysis A: General, Vol. 433-434
Effects of the CePO on the oxygen storage and release properties of CeO and CeZrO solid solution
journal, September 2004
- Larese, C.; Galisteo, F.; Granados, M.
- Journal of Catalysis, Vol. 226, Issue 2
Enhanced photocatalytic activity of Bi2WO6 with oxygen vacancies by zirconium doping
journal, November 2011
- Zhang, Zhijie; Wang, Wenzhong; Gao, Erping
- Journal of Hazardous Materials, Vol. 196
Enhanced oxygen vacancy formation in ceria (111) and (110) surfaces doped with divalent cations
journal, January 2011
- Nolan, Michael
- Journal of Materials Chemistry, Vol. 21, Issue 25
Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods, and Nanocubes
journal, December 2005
- Mai, Hao-Xin; Sun, Ling-Dong; Zhang, Ya-Wen
- The Journal of Physical Chemistry B, Vol. 109, Issue 51
Synergistic effect between ceria and tungsten oxide on WO3–CeO2–TiO2 catalysts for NH3-SCR reaction
journal, August 2012
- Chen, Lei; Weng, Duan; Si, Zhichun
- Progress in Natural Science: Materials International, Vol. 22, Issue 4
Synthesis, characterization and activity study of SO42−/CexZr1−xO2 solid superacid catalyst
journal, February 2006
- Reddy, Benjaram M.; Sreekanth, Pavani M.; Lakshmanan, Pandian
- Journal of Molecular Catalysis A: Chemical, Vol. 244, Issue 1-2
Molecular Metal Phosphonates
journal, June 2015
- Goura, Joydeb; Chandrasekhar, Vadapalli
- Chemical Reviews, Vol. 115, Issue 14
Forbidden transitions in the infra-red spectra of tetrahedral anions—III. Spectra-structure correlations in perchlorates, sulphates and phosphates of the formula MXO4
journal, November 1966
- Hezel, A.; Ross, S. D.
- Spectrochimica Acta, Vol. 22, Issue 11
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
journal, July 2013
- Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R.
- Science, Vol. 341, Issue 6147
Structure-dependent electronic properties of nanocrystalline cerium oxide films
journal, July 2003
- Patsalas, P.; Logothetidis, S.; Sygellou, L.
- Physical Review B, Vol. 68, Issue 3
Heterogeneous Ceria Catalyst with Water-Tolerant Lewis Acidic Sites for One-Pot Synthesis of 1,3-Diols via Prins Condensation and Hydrolysis Reactions
journal, January 2013
- Wang, Yehong; Wang, Feng; Song, Qi
- Journal of the American Chemical Society, Vol. 135, Issue 4
Cerium Oxide Slurries in CMP. Electrophoretic Mobility and Adsorption Investigations of Ceria/Silicate Interaction
journal, January 2004
- Suphantharida, Preuchsuda; Osseo-Asare, Kwadwo
- Journal of The Electrochemical Society, Vol. 151, Issue 10
Surface Modification of ZnO(0001)–Zn with Phosphonate-Based Self-Assembled Monolayers: Binding Modes, Orientation, and Work Function
journal, August 2014
- Timpel, Melanie; Nardi, Marco V.; Krause, Stefan
- Chemistry of Materials, Vol. 26, Issue 17
Surface Chemistry of Trimethyl Phosphate on α-Fe 2 O 3
journal, November 2011
- Henderson, Michael A.
- The Journal of Physical Chemistry C, Vol. 115, Issue 47
Effect of Sodium on the Catalytic Properties of VO x /CeO 2 Catalysts for Oxidative Dehydrogenation of Methanol
journal, March 2013
- Li, Yan; Wei, Zhehao; Sun, Junming
- The Journal of Physical Chemistry C, Vol. 117, Issue 11
The Vibrational Spectrum of Pyridine and the Thermodynamic Properties of Pyridine Vapors
journal, July 1944
- Kline, Charles H.; Turkevich, John
- The Journal of Chemical Physics, Vol. 12, Issue 7
Structure, composition and thermal properties of cerium oxide films on platinum {111}
journal, March 1995
- Hardacre, Christopher; Roe, Gerard M.; Lambert, Richard M.
- Surface Science, Vol. 326, Issue 1-2
The surface chemistry of cerium oxide
journal, March 2015
- Mullins, David R.
- Surface Science Reports, Vol. 70, Issue 1
Correlations between 31P n.m.r. chemical shifts and structural parameters in crystalline inorganic phosphates
journal, January 1986
- Cheetham, Anthony K.; Clayden, Nigel J.; Dobson, Christopher M.
- Journal of the Chemical Society, Chemical Communications, Issue 3
Controlled Synthesis and Self-Assembly of CeO 2 Nanocubes
journal, July 2006
- Yang, Songwang; Gao, Lian
- Journal of the American Chemical Society, Vol. 128, Issue 29
Dimethyl methylphosphonate decomposition on fully oxidized and partially reduced ceria thin films
journal, March 2010
- Chen, Donna A.; Ratliff, Jay S.; Hu, Xiaofeng
- Surface Science, Vol. 604, Issue 5-6
CeO2–Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction
journal, September 2012
- Stošić, Dušan; Bennici, Simona; Rakić, Vesna
- Catalysis Today, Vol. 192, Issue 1
Relationship between Oxygen Defects and the Photocatalytic Property of ZnO Nanocrystals in Nafion Membranes
journal, January 2009
- Wang, Jianchun; Liu, Ping; Fu, Xianzhi
- Langmuir, Vol. 25, Issue 2
Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment
journal, December 2012
- Paier, Joachim; Penschke, Christopher; Sauer, Joachim
- Chemical Reviews, Vol. 113, Issue 6
Electron Localization Determines Defect Formation on Ceria Substrates
journal, July 2005
- Esch, F.
- Science, Vol. 309, Issue 5735
XPS Study of the reduction of cerium dioxide
journal, May 1993
- Romeo, M.; Bak, K.; El Fallah, J.
- Surface and Interface Analysis, Vol. 20, Issue 6
Coupling Oxygen Ion Conduction to Photocatalysis in Mesoporous Nanorod-like Ceria Significantly Improves Photocatalytic Efficiency
journal, July 2011
- Li, Yuanzhi; Sun, Qian; Kong, Ming
- The Journal of Physical Chemistry C, Vol. 115, Issue 29
Structural studies of zinc polyphosphate glasses by nuclear magnetic resonance
journal, March 2000
- Wiench, J. W.; Pruski, M.; Tischendorf, B.
- Journal of Non-Crystalline Solids, Vol. 263-264
Mechanism of Hydrodeoxygenation of Acrolein on a Cluster Model of MoO 3
journal, July 2010
- Moberg, Daniel R.; Thibodeau, Timothy J.; Amar, François G.
- The Journal of Physical Chemistry C, Vol. 114, Issue 32
CeO 2 nanoplates with a hexagonal structure and their catalytic applications in highly selective hydrogenation of substituted nitroaromatics
journal, January 2012
- Zhang, Yu; Hou, Fei; Tan, Yiwei
- Chem. Commun., Vol. 48, Issue 18
The electronic structure of oxygen vacancy defects at the low index surfaces of ceria
journal, December 2005
- Nolan, Michael; Parker, Stephen C.; Watson, Graeme W.
- Surface Science, Vol. 595, Issue 1-3
Novel cerium–tungsten mixed oxide catalyst for the selective catalytic reduction of NOx with NH3
journal, January 2011
- Shan, Wenpo; Liu, Fudong; He, Hong
- Chemical Communications, Vol. 47, Issue 28
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
journal, April 2016
- Montini, Tiziano; Melchionna, Michele; Monai, Matteo
- Chemical Reviews, Vol. 116, Issue 10
Probing Defect Sites on CeO 2 Nanocrystals with Well-Defined Surface Planes by Raman Spectroscopy and O 2 Adsorption †
journal, November 2010
- Wu, Zili; Li, Meijun; Howe, Jane
- Langmuir, Vol. 26, Issue 21
Controlling the Surface Environment of Heterogeneous Catalysts Using Self-Assembled Monolayers
journal, February 2014
- Schoenbaum, Carolyn A.; Schwartz, Daniel K.; Medlin, J. Will
- Accounts of Chemical Research, Vol. 47, Issue 4
Broadband Multiple-Quantum NMR Spectroscopy
journal, October 1996
- Feike, M.; Demco, D. E.; Graf, R.
- Journal of Magnetic Resonance, Series A, Vol. 122, Issue 2
Hydrodeoxygenation of Lignin-Derived Phenols into Alkanes by Using Nanoparticle Catalysts Combined with Brønsted Acidic Ionic Liquids
journal, June 2010
- Yan, Ning; Yuan, Yuan; Dykeman, Ryan
- Angewandte Chemie International Edition, Vol. 49, Issue 32
Exposed Surfaces on Shape-Controlled Ceria Nanoparticles Revealed through AC-TEM and Water-Gas Shift Reactivity
journal, September 2013
- Agarwal, Shilpa; Lefferts, Leon; Mojet, Barbara L.
- ChemSusChem, Vol. 6, Issue 10
Directing reaction pathways by catalyst active-site selection using self-assembled monolayers
journal, September 2013
- Pang, Simon H.; Schoenbaum, Carolyn A.; Schwartz, Daniel K.
- Nature Communications, Vol. 4, Issue 1
Works referencing / citing this record:
Highly selective catalytic conversion of lignin-derived phenolic compounds to cycloalkanes over a hierarchically structured zeolite catalyst
journal, October 2018
- Xiang, Mei; Wu, Dongfang
- Journal of Materials Science, Vol. 54, Issue 4