Evolution from the plasmon to exciton state in ligand-protected atomically precise gold nanoparticles

Zhou, Meng; Zeng, Chenjie; Chen, Yuxiang; Zhao, Shuo; Sfeir, Matthew Y.; Zhu, Manzhou; Jin, Rongchao

doi:10.1038/ncomms13240

Title: Evolution from the plasmon to exciton state in ligand-protected atomically precise gold nanoparticles

Journal Article · Mon Oct 24 04:00:00 UTC 2016 · Nature Communications

DOI: https://doi.org/10.1038/ncomms13240 · OSTI ID:1347376

Zhou, Meng ^[1]; Zeng, Chenjie ^[1]; Chen, Yuxiang ^[1]; Zhao, Shuo ^[1]; Sfeir, Matthew Y. ^[2]; Zhu, Manzhou ^[3]; Jin, Rongchao ^[1]

Carnegie Mellon Univ., Pittsburgh, PA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Anhui Univ., Anhui (China)

The evolution from the metallic (or plasmonic) to molecular state in metal nanoparticles constitutes a central question in nanoscience research because of its importance in revealing the origin of metallic bonding and offering fundamental insights into the birth of surface plasmon resonance. Previous research has not been able to probe the transition due to the unavailability of atomically precise nanoparticles in the 1–3 nm size regime. Herein, we investigate the transition by performing ultrafast spectroscopic studies on atomically precise thiolate-protected Au₂₅, Au₃₈, Au₁₄₄, Au₃₃₃, Au_~520 and Au_~940 nanoparticles. Our results clearly map out three distinct states: metallic (size larger than Au333, that is, larger than 2.3 nm), transition regime (between Au₃₃₃ and Au₁₄₄, that is, 2.3–1.7 nm) and non-metallic or excitonic state (smaller than Au₁₄₄, that is, smaller than 1.7 nm). As a result, the transition also impacts the catalytic properties as demonstrated in both carbon monoxide oxidation and electrocatalytic oxidation of alcohol.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1347376

Report Number(s):: BNL--113660-2017-JA; KC0403020

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 7; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Plasmon-induced efficient hot carrier generation in graphene on gold ultrathin film with periodic array of holes: Ultrafast pump-probe spectroscopy Prakash, Gyan; Srivastava, Rajesh Kumar; Gupta, Satyendra Nath The Journal of Chemical Physics, Vol. 151, Issue 23 https://doi.org/10.1063/1.5117882	journal	December 2019
Plasmon charge transfer dynamics in layered Au–ZnO nanocomposites Gogurla, Narendar; Chowdhury, Rup K.; Battacharya, Sayantan Journal of Applied Physics, Vol. 127, Issue 5 https://doi.org/10.1063/1.5134892	journal	February 2020
Electron localization in rod-shaped triicosahedral gold nanocluster Zhou, Meng; Jin, Renxi; Sfeir, Matthew Y. Proceedings of the National Academy of Sciences, Vol. 114, Issue 24 https://doi.org/10.1073/pnas.1704699114	journal	May 2017
Lifetime dynamics of plasmons in the few-atom limit Chapkin, Kyle D.; Bursi, Luca; Stec, Grant J. Proceedings of the National Academy of Sciences, Vol. 115, Issue 37 https://doi.org/10.1073/pnas.1805357115	journal	August 2018
Anomalous phonon relaxation in Au ₃₃₃ (SR) ₇₉ nanoparticles with nascent plasmons Higaki, Tatsuya; Zhou, Meng; He, Guiying Proceedings of the National Academy of Sciences, Vol. 116, Issue 27 https://doi.org/10.1073/pnas.1904337116	journal	June 2019
Surface plasmon resonance in gold nanoparticles: a review Amendola, Vincenzo; Pilot, Roberto; Frasconi, Marco Journal of Physics: Condensed Matter, Vol. 29, Issue 20 https://doi.org/10.1088/1361-648x/aa60f3	journal	April 2017
Gold Nanoclusters: Bridging Gold Complexes and Plasmonic Nanoparticles in Photophysical Properties Zhou, Meng; Zeng, Chenjie; Li, Qi Nanomaterials, Vol. 9, Issue 7 https://doi.org/10.3390/nano9070933	journal	June 2019
Carrier dynamics in ultrathin gold nanowires: Role of Auger processes Prakash, Gyan; Kundu, Subhajit; Roy, Ahin arXiv https://doi.org/10.48550/arxiv.1909.01551	preprint	January 2019

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