Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Cluster Model Studies of Anion and Molecular Specificities via Electrospray Ionization Photoelectron Spectroscopy

Abstract

Ion specificity, a widely observed macroscopic phenomenon in condensed phases and at interfaces, is essentially a fundamental chemical physical issue. We have been investigating such effects using cluster models in an “atom-by-atom” and “molecule-by-molecule” fashion not possible with condensed-phase methods. We use electrospray ionization (ESI) to generate molecular and ionic clusters to simulate key molecular entities involved in local binding regions, and characterize them employing negative ion photoelectron spectroscopy (NIPES). Inter- and intramolecular interactions and binding configurations are directly obtained as functions of cluster size and composition, providing insightful molecular-level description and characterization over the local active sites that play crucial roles in determining solution chemistry and condensed phase phenomena. Finally, the topics covered in this article are relevant to a wide scope of research fields ranging from ion specific effects in electrolyte solutions, ion selectivity/recognition in normal functioning of life, to molecular specificity in aerosol particle formation, as well as in rational material design and synthesis.

Authors:
ORCiD logo [1]
+ Show Author Affiliations
  1. Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, MS K8-88, Richland, Washington 99352, United States
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1341469
Alternate Identifier(s):
OSTI ID: 1346289
Report Number(s):
PNNL-SA-121345
Journal ID: ISSN 1089-5639
Grant/Contract Number:  
AC05-76RL01830
Resource Type:
Published Article
Journal Name:
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
Additional Journal Information:
Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Volume: 121 Journal Issue: 7; Journal ID: ISSN 1089-5639
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Environmental Molecular Sciences Laboratory

Citation Formats

Wang, Xue-Bin. Cluster Model Studies of Anion and Molecular Specificities via Electrospray Ionization Photoelectron Spectroscopy. United States: N. p., 2017. Web. doi:10.1021/acs.jpca.6b09784.
Copy to clipboard
Wang, Xue-Bin. Cluster Model Studies of Anion and Molecular Specificities via Electrospray Ionization Photoelectron Spectroscopy. United States. https://doi.org/10.1021/acs.jpca.6b09784
Copy to clipboard
Wang, Xue-Bin. Mon . "Cluster Model Studies of Anion and Molecular Specificities via Electrospray Ionization Photoelectron Spectroscopy". United States. https://doi.org/10.1021/acs.jpca.6b09784.
Copy to clipboard
@article{osti_1341469,
title = {Cluster Model Studies of Anion and Molecular Specificities via Electrospray Ionization Photoelectron Spectroscopy},
author = {Wang, Xue-Bin},
abstractNote = {Ion specificity, a widely observed macroscopic phenomenon in condensed phases and at interfaces, is essentially a fundamental chemical physical issue. We have been investigating such effects using cluster models in an “atom-by-atom” and “molecule-by-molecule” fashion not possible with condensed-phase methods. We use electrospray ionization (ESI) to generate molecular and ionic clusters to simulate key molecular entities involved in local binding regions, and characterize them employing negative ion photoelectron spectroscopy (NIPES). Inter- and intramolecular interactions and binding configurations are directly obtained as functions of cluster size and composition, providing insightful molecular-level description and characterization over the local active sites that play crucial roles in determining solution chemistry and condensed phase phenomena. Finally, the topics covered in this article are relevant to a wide scope of research fields ranging from ion specific effects in electrolyte solutions, ion selectivity/recognition in normal functioning of life, to molecular specificity in aerosol particle formation, as well as in rational material design and synthesis.},
doi = {10.1021/acs.jpca.6b09784},
journal = {Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory},
number = 7,
volume = 121,
place = {United States},
year = {Mon Jan 30 00:00:00 EST 2017},
month = {Mon Jan 30 00:00:00 EST 2017}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.jpca.6b09784
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 41 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Study of Ion Specific Interactions of Alkali Cations with Dicarboxylate Dianions
journal, February 2012

  • Murdachaew, Garold; Valiev, Marat; Kathmann, Shawn M.
  • The Journal of Physical Chemistry A, Vol. 116, Issue 9
  • DOI: 10.1021/jp3012848

Nucleation and Growth of Nanoparticles in the Atmosphere
journal, November 2011

  • Zhang, Renyi; Khalizov, Alexei; Wang, Lin
  • Chemical Reviews, Vol. 112, Issue 3
  • DOI: 10.1021/cr2001756

Stepwise hydration of the cyanide anion: A temperature-controlled photoelectron spectroscopy and ab initio computational study of CN−(H2O)n, n=2–5
journal, March 2010

  • Wang, Xue-Bin; Kowalski, Karol; Wang, Lai-Sheng
  • The Journal of Chemical Physics, Vol. 132, Issue 12
  • DOI: 10.1063/1.3360306

Bulk versus Interfacial Aqueous Solvation of Dicarboxylate Dianions
journal, September 2004

  • Minofar, Babak; Mucha, Martin; Jungwirth, Pavel
  • Journal of the American Chemical Society, Vol. 126, Issue 37
  • DOI: 10.1021/ja047493i

Is Iodate a Strongly Hydrated Cation?
journal, October 2011

  • Baer, Marcel D.; Pham, Van-Thai; Fulton, John L.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 20
  • DOI: 10.1021/jz2011435

The present state of affairs with Hofmeister effects
journal, August 2004

  • Kunz, W.; Lo Nostro, P.; Ninham, B. W.
  • Current Opinion in Colloid & Interface Science, Vol. 9, Issue 1-2
  • DOI: 10.1016/j.cocis.2004.05.004

Vibrational Spectroscopy of Microhydrated Conjugate Base Anions
journal, June 2011

  • Asmis, Knut R.; Neumark, Daniel M.
  • Accounts of Chemical Research, Vol. 45, Issue 1
  • DOI: 10.1021/ar2000748

Vibrational Spectra and Fragmentation Pathways of Size-Selected, D 2 -Tagged Ammonium/Methylammonium Bisulfate Clusters
journal, August 2013

  • Johnson, Christopher J.; Johnson, Mark A.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 50
  • DOI: 10.1021/jp404244y

Sulfate Ion Patterns Water at Long Distance
journal, June 2010

  • O’Brien, Jeremy T.; Prell, James S.; Bush, Matthew F.
  • Journal of the American Chemical Society, Vol. 132, Issue 24
  • DOI: 10.1021/ja1024113

Theoretical Study of the Hydration of Atmospheric Nucleation Precursors with Acetic Acid
journal, August 2014

  • Zhu, Yu-Peng; Liu, Yi-Rong; Huang, Teng
  • The Journal of Physical Chemistry A, Vol. 118, Issue 36
  • DOI: 10.1021/jp506226z

An ab initio approach to understanding the specific ion effect
journal, January 2013

  • Baer, Marcel D.; Mundy, Christopher J.
  • Faraday Discuss., Vol. 160
  • DOI: 10.1039/C2FD20113E

Characterization of a Saturated and Flexible Aliphatic Polyol Anion Receptor
journal, October 2012

  • Shokri, Alireza; Schmidt, Jacob; Wang, Xue-Bin
  • Journal of the American Chemical Society, Vol. 134, Issue 41
  • DOI: 10.1021/ja3075456

Ozonolysis of α-pinene and β-pinene: Kinetics and mechanism
journal, March 2005

  • Zhang, Dan; Zhang, Renyi
  • The Journal of Chemical Physics, Vol. 122, Issue 11
  • DOI: 10.1063/1.1862616

Observation of Weak CH⋅⋅⋅O Hydrogen Bonding to Unactivated Alkanes
journal, August 2005

  • Wang, Xue-Bin; Woo, Hin-Koon; Kiran, Boggavarapu
  • Angewandte Chemie International Edition, Vol. 44, Issue 31
  • DOI: 10.1002/anie.200501349

Photoelectron Spectroscopy of Cold Hydrated Sulfate Clusters, SO 4 2− (H 2 O) n ( n = 4−7): Temperature-Dependent Isomer Populations
journal, May 2009

  • Wang, Xue-Bin; Sergeeva, Alina P.; Yang, Jie
  • The Journal of Physical Chemistry A, Vol. 113, Issue 19
  • DOI: 10.1021/jp900682g

Anion–arene adducts: C–H hydrogen bonding, anion–π interaction, and carbon bonding motifs
journal, January 2008

  • Hay, Benjamin P.; Bryantsev, Vyacheslav S.
  • Chemical Communications, Issue 21
  • DOI: 10.1039/b800055g

Flexible Acyclic Polyol-Chloride Anion Complexes and Their Characterization by Photoelectron Spectroscopy and Variable Temperature Binding Constant Determinations
journal, March 2016

  • Shokri, Alireza; Wang, Xue-Bin; Wang, Yanping
  • The Journal of Physical Chemistry A, Vol. 120, Issue 10
  • DOI: 10.1021/acs.jpca.5b12286

Formation and properties of hydrogen-bonded complexes of common organic oxalic acid with atmospheric nucleation precursors
journal, July 2010

Multivariate analysis of homogeneous nucleation rate measurements. Nucleation in the p-toluic acid/sulfuric acid/water system
journal, February 2008

  • McGraw, Robert; Zhang, Renyi
  • The Journal of Chemical Physics, Vol. 128, Issue 6
  • DOI: 10.1063/1.2830030

Direct Observations of Atmospheric Aerosol Nucleation
journal, February 2013

Fatty acids in the marine atmosphere: Factors governing their concentrations and evaluation of organic films on sea-salt particles: FATTY ACIDS IN THE MARINE ATMOSPHERE
journal, September 2002

  • Mochida, Michihiro; Kitamori, Yasuyuki; Kawamura, Kimitaka
  • Journal of Geophysical Research: Atmospheres, Vol. 107, Issue D17
  • DOI: 10.1029/2001JD001278

The Ionic Hydrogen Bond
journal, January 2005

  • Meot-Ner (Mautner), Michael
  • Chemical Reviews, Vol. 105, Issue 1
  • DOI: 10.1021/cr9411785

Infrared Spectroscopy of Hydrated Bisulfate Anion Clusters: HSO 4 ¯(H 2 O) 1–16
journal, August 2011

  • Yacovitch, Tara I.; Wende, Torsten; Jiang, Ling
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 17
  • DOI: 10.1021/jz200917f

Photoelectron spectroscopic study of the hydrated nucleoside anions: Uridine−(H2O)n=0–2, cytidine−(H2O)n=0–2, and thymidine−(H2O)n=0,1
journal, October 2010

  • Li, Xiang; Wang, Haopeng; Bowen, Kit H.
  • The Journal of Chemical Physics, Vol. 133, Issue 14
  • DOI: 10.1063/1.3487735

Theory of the hydrogen bond
journal, June 1972

  • Kollman, Peter A.; Allen, Leland C.
  • Chemical Reviews, Vol. 72, Issue 3
  • DOI: 10.1021/cr60277a004

Ion Pairing: From Water Clusters to the Aqueous Bulk
journal, August 2014

  • Jungwirth, Pavel
  • The Journal of Physical Chemistry B, Vol. 118, Issue 35
  • DOI: 10.1021/jp507964q

The effect of halide and iodate anions on the hydrogen-bonding network of water in aqueous nanodrops
journal, January 2016

  • Chakrabarty, Satrajit; Williams, Evan R.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 36
  • DOI: 10.1039/C6CP05033F

How Anion Chaotrope Changes the Local Structure of Water: Insights from Photoelectron Spectroscopy and Theoretical Modeling of SCN – Water Clusters
journal, September 2015

  • Valiev, Marat; Deng, Shihu H. M.; Wang, Xue-Bin
  • The Journal of Physical Chemistry B, Vol. 120, Issue 8
  • DOI: 10.1021/acs.jpcb.5b07257

Spectroscopy and structure of solvated alkali-metal ions
journal, July 1997

Strong hydrogen bonding between atmospheric nucleation precursors and common organics
journal, February 2007

Frontiers in the spectroscopy of mass-selected molecular ions
journal, December 2000

Interaction between Common Organic Acids and Trace Nucleation Species in the Earth’s Atmosphere
journal, January 2010

  • Xu, Yisheng; Nadykto, Alexey B.; Yu, Fangqun
  • The Journal of Physical Chemistry A, Vol. 114, Issue 1
  • DOI: 10.1021/jp9068575

CHEMISTRY: Getting Specific About Specific Ion Effects
journal, February 2008

Evidence for Water Rings in the Hexahydrated Sulfate Dianion from IR Spectroscopy
journal, February 2007

  • Bush, Matthew F.; Saykally, Richard J.; Williams, Evan R.
  • Journal of the American Chemical Society, Vol. 129, Issue 8
  • DOI: 10.1021/ja068357b

Cluster Ion Thermal Decomposition (I):  Experimental Kinetics Study and ab Initio Calculations for HSO 4 - (H 2 SO 4 ) x (HNO 3 ) y
journal, December 2001

  • Curtius, Joachim; Froyd, Karl D.; Lovejoy, Edward R.
  • The Journal of Physical Chemistry A, Vol. 105, Issue 48
  • DOI: 10.1021/jp0124950

Communication: Vibrational spectroscopy of atmospherically relevant acid cluster anions: Bisulfate versus nitrate core structures
journal, June 2012

  • Yacovitch, Tara I.; Heine, Nadja; Brieger, Claudia
  • The Journal of Chemical Physics, Vol. 136, Issue 24
  • DOI: 10.1063/1.4732148

Negative Ion Photoelectron Spectroscopy Confirms the Prediction that (CO) 5 and (CO) 6 Each Has a Singlet Ground State
journal, March 2013

  • Bao, Xiaoguang; Hrovat, David A.; Borden, Weston Thatcher
  • Journal of the American Chemical Society, Vol. 135, Issue 11
  • DOI: 10.1021/ja4005128

Seasonal changes in the distribution of dicarboxylic acids in the urban atmosphere
journal, September 1993

  • Kawamura, Kimitaka; Ikushima, Kouichi
  • Environmental Science & Technology, Vol. 27, Issue 10
  • DOI: 10.1021/es00047a033

Q and Soret Band Photoexcitation of Isolated Palladium Porphyrin Tetraanions Leads to Delayed Emission of Nonthermal Electrons over Microsecond Time Scales
journal, March 2016

  • Jäger, Patrick; Brendle, Katrina; Schwarz, Ulrike
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 7
  • DOI: 10.1021/acs.jpclett.6b00407

The Negative Ion Photoelectron Spectrum of meta -Benzoquinone Radical Anion (MBQ •– ): A Joint Experimental and Computational Study
journal, February 2014

  • Chen, Bo; Hrovat, David A.; Deng, S. H. M.
  • Journal of the American Chemical Society, Vol. 136, Issue 9
  • DOI: 10.1021/ja412433t

On the formation of anions: frequency-, angle-, and time-resolved photoelectron imaging of the menadione radical anion
journal, January 2015

  • Bull, James N.; West, Christopher W.; Verlet, Jan R. R.
  • Chemical Science, Vol. 6, Issue 2
  • DOI: 10.1039/C4SC03491K

Multiply Charged Anions in the Gas Phase
journal, January 2002

  • Dreuw, Andreas; Cederbaum, Lorenz S.
  • Chemical Reviews, Vol. 102, Issue 1
  • DOI: 10.1021/cr0104227

Photodetachment photoelectron spectroscopy of multiply charged anions using electrospray ionization
journal, April 1999

  • Wang, Lai-Sheng; Ding, Chuan-Fan; Wang, Xue-Bin
  • Review of Scientific Instruments, Vol. 70, Issue 4
  • DOI: 10.1063/1.1149694

Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Precursors
journal, January 2009

  • Zhao, Jun; Khalizov, Alexei; Zhang, Renyi
  • The Journal of Physical Chemistry A, Vol. 113, Issue 4
  • DOI: 10.1021/jp806693r

Determinants of K + vs Na + Selectivity in Potassium Channels
journal, June 2009

  • Dudev, Todor; Lim, Carmay
  • Journal of the American Chemical Society, Vol. 131, Issue 23
  • DOI: 10.1021/ja900168k

Chemical Characterization of Individual, Airborne Sub-10-nm Particles and Molecules
journal, March 2006

  • Wang, Shenyi; Zordan, Christopher A.; Johnston, Murray V.
  • Analytical Chemistry, Vol. 78, Issue 6
  • DOI: 10.1021/ac052243l

Photoelectron Spectroscopy of Multiply Charged Anions
journal, May 2009

Fragmentation Energetics of Clusters Relevant to Atmospheric New Particle Formation
journal, February 2013

  • Bzdek, Bryan R.; DePalma, Joseph W.; Ridge, Douglas P.
  • Journal of the American Chemical Society, Vol. 135, Issue 8
  • DOI: 10.1021/ja3124509

Probing the early stages of solvation of cis-pinate dianions by water, acetonitrile, and methanol: a photoelectron spectroscopy and theoretical study
journal, January 2016

  • Hou, Gao-Lei; Kong, Xiang-Tao; Valiev, Marat
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 5
  • DOI: 10.1039/C5CP05974G

Anion−π Interactions in Supramolecular Architectures
journal, June 2012

  • Chifotides, Helen T.; Dunbar, Kim R.
  • Accounts of Chemical Research, Vol. 46, Issue 4
  • DOI: 10.1021/ar300251k

Probing Free Multiply Charged Anions Using Photodetachment Photoelectron Spectroscopy
journal, March 2000

  • Wang, Lai-Sheng; Wang, Xue-Bin
  • The Journal of Physical Chemistry A, Vol. 104, Issue 10
  • DOI: 10.1021/jp9940093

Probing the Low-Lying Electronic States of Cyclobutanetetraone (C 4 O 4 ) and Its Radical Anion: A Low-Temperature Anion Photoelectron Spectroscopic Approach
journal, January 2012

  • Guo, Jin-Chang; Hou, Gao-Lei; Li, Si-Dian
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 3
  • DOI: 10.1021/jz201593z

Charge Separation in Molecular Clusters:  Dissolution of a Salt in a Salt−(Solvent) n Cluster
journal, November 2000

  • Dedonder-Lardeux, Claude; Grégoire, Gilles; Jouvet, Christophe
  • Chemical Reviews, Vol. 100, Issue 11
  • DOI: 10.1021/cr990059s

Atmospheric New Particle Formation Enhanced by Organic Acids
journal, June 2004

Deprotonated Dicarboxylic Acid Homodimers: Hydrogen Bonds and Atmospheric Implications
journal, April 2016

  • Hou, Gao-Lei; Valiev, Marat; Wang, Xue-Bin
  • The Journal of Physical Chemistry A, Vol. 120, Issue 15
  • DOI: 10.1021/acs.jpca.6b01166

Factors Governing the Na + vs K + Selectivity in Sodium Ion Channels
journal, February 2010

  • Dudev, Todor; Lim, Carmay
  • Journal of the American Chemical Society, Vol. 132, Issue 7
  • DOI: 10.1021/ja909280g

Elucidating severe urban haze formation in China
journal, November 2014

  • Guo, Song; Hu, Min; Zamora, Misti L.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 49
  • DOI: 10.1073/pnas.1419604111

Communication: Solute anisotropy effects in hydrated anion and neutral clusters
journal, January 2013

  • Wen, Hui; Hou, Gao-Lei; Kathmann, Shawn M.
  • The Journal of Chemical Physics, Vol. 138, Issue 3
  • DOI: 10.1063/1.4776766

Molecular Mechanisms of Ion-Specific Effects on Proteins
journal, June 2012

  • Rembert, Kelvin B.; Paterová, Jana; Heyda, Jan
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja301297g

Bulk-Like Features in the Photoemission Spectra of Hydrated Doubly Charged Anion Clusters
journal, November 2001

Development of a low-temperature photoelectron spectroscopy instrument using an electrospray ion source and a cryogenically controlled ion trap
journal, July 2008

  • Wang, Xue-Bin; Wang, Lai-Sheng
  • Review of Scientific Instruments, Vol. 79, Issue 7
  • DOI: 10.1063/1.2957610

Gas to particle distribution of low molecular weight dicarboxylic acids at two different sites in central Europe (Austria)
journal, August 2005

Infrared spectroscopy of hydrated sulfate dianions
journal, September 2006

  • Zhou, Jia; Santambrogio, Gabriele; Brümmer, Mathias
  • The Journal of Chemical Physics, Vol. 125, Issue 11
  • DOI: 10.1063/1.2351675

Dynamics of Hydrogen Bromide Dissolution in the Ground and Excited States
journal, October 2002

A Preorganized Hydrogen Bond Network and Its Effect on Anion Stability
journal, July 2014

  • Samet, Masoud; Wang, Xue-Bin; Kass, Steven R.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 31
  • DOI: 10.1021/jp505308v

Photoelectron spectroscopy and theoretical studies of anion–π interactions: binding strength and anion specificity
journal, January 2015

  • Zhang, Jian; Zhou, Bin; Sun, Zhen-Rong
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 5
  • DOI: 10.1039/C4CP04687K

Isomer-Selected Photoelectron Spectroscopy of Isolated DNA Oligonucleotides: Phosphate and Nucleobase Deprotonation at High Negative Charge States
journal, April 2012

  • Vonderach, Matthias; Ehrler, Oli T.; Matheis, Katerina
  • Journal of the American Chemical Society, Vol. 134, Issue 18
  • DOI: 10.1021/ja300619j

Time-resolved study of solvent-induced recombination in photodissociated IBr−(CO2)n clusters
journal, October 2006

  • Dribinski, Vladimir; Barbera, Jack; Martin, Joshua P.
  • The Journal of Chemical Physics, Vol. 125, Issue 13
  • DOI: 10.1063/1.2217741

Photoelectron spectroscopy of Cl − , Br − , and I − solvated in water clusters
journal, December 1994

  • Markovich, Gil; Pollack, Stuart; Giniger, Rina
  • The Journal of Chemical Physics, Vol. 101, Issue 11
  • DOI: 10.1063/1.467965

Theoretical Study on the Structure and Stabilities of Molecular Clusters of Oxalic Acid with Water
journal, November 2012

  • Weber, Kevin H.; Morales, Francisco J.; Tao, Fu-Ming
  • The Journal of Physical Chemistry A, Vol. 116, Issue 47
  • DOI: 10.1021/jp308499f

Formation of Urban Fine Particulate Matter
journal, February 2015

Cluster Ion Thermal Decomposition (II):  Master Equation Modeling in the Low-Pressure Limit and Fall-Off Regions. Bond Energies for HSO 4 - (H 2 SO 4 ) x (HNO 3 ) y
journal, November 2001

  • Lovejoy, Edward R.; Curtius, Joachim
  • The Journal of Physical Chemistry A, Vol. 105, Issue 48
  • DOI: 10.1021/jp012496s

Observation of a Remarkable Temperature Effect in the Hydrogen Bonding Structure and Dynamics of the CN − (H 2 O) Cluster
journal, July 2009

  • Wang, Xue-Bin; Werhahn, Jasper C.; Wang, Lai-Sheng
  • The Journal of Physical Chemistry A, Vol. 113, Issue 35
  • DOI: 10.1021/jp9034002

Anion−π Interactions: Generality, Binding Strength, and Structure
journal, December 2012

  • Wang, De-Xian; Wang, Mei-Xiang
  • Journal of the American Chemical Society, Vol. 135, Issue 2
  • DOI: 10.1021/ja310834w

Interactions between macromolecules and ions: the Hofmeister series
journal, December 2006

Hofmeister series and specific interactions of charged headgroups with aqueous ions
journal, February 2009

  • Vlachy, Nina; Jagoda-Cwiklik, Barbara; Vácha, Robert
  • Advances in Colloid and Interface Science, Vol. 146, Issue 1-2
  • DOI: 10.1016/j.cis.2008.09.010

Theoretical Investigation of Interaction of Dicarboxylic Acids with Common Aerosol Nucleation Precursors
journal, May 2012

  • Xu, Wen; Zhang, Renyi
  • The Journal of Physical Chemistry A, Vol. 116, Issue 18
  • DOI: 10.1021/jp301964u

Proton mobility and stability of water clusters containing the bisulfate anion, HSO4−(H2O)n
journal, January 2011

  • Zatula, Alexey S.; Andersson, Patrik Urban; Ryding, Mauritz Johan
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 29
  • DOI: 10.1039/c1cp21070j

Perspective: Electrospray photoelectron spectroscopy: From multiply-charged anions to ultracold anions
journal, July 2015

  • Wang, Lai-Sheng
  • The Journal of Chemical Physics, Vol. 143, Issue 4
  • DOI: 10.1063/1.4927086

M OLECULAR A SPECTS OF H ALIDE I ON H YDRATION : The Cluster Approach
journal, October 2003

Gas-Phase Femtosecond Particle Spectroscopy: A Bottom-Up Approach to Nucleotide Dynamics
journal, May 2016

Microsolvation of LiI and CsI in Water: Anion Photoelectron Spectroscopy and ab initio Calculations
journal, March 2013

  • Li, Ren-Zhong; Liu, Cheng-Wen; Gao, Yi Qin
  • Journal of the American Chemical Society, Vol. 135, Issue 13
  • DOI: 10.1021/ja4006942

Observation of Entropic Effect on Conformation Changes of Complex Systems under Well-Controlled Temperature Conditions
journal, January 2008

  • Wang, Xue-Bin; Yang, Jie; Wang, Lai-Sheng
  • The Journal of Physical Chemistry A, Vol. 112, Issue 2
  • DOI: 10.1021/jp711205z

Ozonolysis of α -pinene at atmospherically relevant concentrations: Temperature dependence of aerosol mass fractions (yields)
journal, January 2007

  • Pathak, Ravi K.; Stanier, Charles O.; Donahue, Neil M.
  • Journal of Geophysical Research, Vol. 112, Issue D3
  • DOI: 10.1029/2006JD007436

Beyond Hofmeister
journal, March 2014

  • Jungwirth, Pavel; Cremer, Paul S.
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1899

Microscopic hydration of the fluoride anion
journal, January 1999

  • Cabarcos, Orlando M.; Weinheimer, Corey J.; Lisy, James M.
  • The Journal of Chemical Physics, Vol. 110, Issue 1
  • DOI: 10.1063/1.478075

Getting to the Critical Nucleus of Aerosol Formation
journal, June 2010

Probing the intrinsic features and environmental stabilization of multiply charged anions
journal, January 2006

  • Boxford, William E.; Dessent, Caroline E. H.
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 44
  • DOI: 10.1039/b609123g

Molecular understanding of sulphuric acid–amine particle nucleation in the atmosphere
journal, October 2013

  • Almeida, João; Schobesberger, Siegfried; Kürten, Andreas
  • Nature, Vol. 502, Issue 7471
  • DOI: 10.1038/nature12663

Hydrogen Bonding in Biological Structures
book, January 1991

Photoelectron spectra of the hydrated iodine anion from molecular dynamics simulations
journal, August 1993

  • Dang, Liem X.; Garrett, Bruce C.
  • The Journal of Chemical Physics, Vol. 99, Issue 4
  • DOI: 10.1063/1.465203

Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds
journal, January 2012

  • Shokri, Alireza; Schmidt, Jacob; Wang, Xue-Bin
  • Journal of the American Chemical Society, Vol. 134, Issue 4
  • DOI: 10.1021/ja2081907

Formation of nanoparticles of blue haze enhanced by anthropogenic pollution
journal, October 2009

  • Zhang, R.; Wang, L.; Khalizov, A. F.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 42
  • DOI: 10.1073/pnas.0910125106

Negative Ion Photoelectron Spectroscopy Reveals Thermodynamic Advantage of Organic Acids in Facilitating Formation of Bisulfate Ion Clusters: Atmospheric Implications
journal, February 2013

  • Hou, Gao-Lei; Lin, Wei; Deng, S. H. M.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 5
  • DOI: 10.1021/jz400108y
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: