Nano-scale synthesis of the complex silicate minerals forsterite and enstatite

Anovitz, Lawrence M.; Rondinone, Adam Justin; Sochalski-Kolbus, Lindsay; Rosenqvist, Jorgen; Cheshire, Michael C.

doi:10.1016/j.jcis.2017.01.052

Title: Nano-scale synthesis of the complex silicate minerals forsterite and enstatite

Journal Article · Wed Jan 18 04:00:00 UTC 2017 · Journal of Colloid and Interface Science

DOI: https://doi.org/10.1016/j.jcis.2017.01.052 · OSTI ID:1344274

Anovitz, Lawrence M. ^[1]; Rondinone, Adam Justin ^[1]; Sochalski-Kolbus, Lindsay ^[1]; Rosenqvist, Jorgen ^[2]; Cheshire, Michael C. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Gothenburg, Gothenburg (Sweden)

Olivine is a relatively common family of silicate minerals in many terrestrial and extraterrestrial environments, and is also useful as a refractory ceramic. A capability to synthesize fine particles of olivine will enable additional studies on surface reactivity under geologically relevant conditions. This paper presents a method for the synthesis of nanocrystalline samples of the magnesium end-member, forsterite (Mg₂SiO₄) in relatively large batches (15–20 g) using a sol-gel/surfactant approach. Magnesium methoxide and tetraethylorthosilicate (TEOS) are refluxed in a toluene/methanol mixture using dodecylamine as a surfactant and tert-butyl amine and water as hydrolysis agents. This material is then cleaned and dried, and fired at 800 °C. Post-firing reaction in hydrogen peroxide was used to remove residual organic surfactant. X-ray diffraction showed that a pure material resulted, with a BET surface area of up to 76.6 m²/g. Finally, the results of a preliminary attempt to use this approach to synthesize nano-scale orthopyroxene (MgSiO₃) are also reported.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1344274

Journal Information:: Journal of Colloid and Interface Science, Journal Name: Journal of Colloid and Interface Science Journal Issue: C Vol. 495; ISSN 0021-9797

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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54 ENVIRONMENTAL SCIENCES
58 GEOSCIENCES
clinopyroxene
enstatite
forsterite
nanosynthesis
olivine
orthopyroxene
pyroxene

Title: Nano-scale synthesis of the complex silicate minerals forsterite and enstatite

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References (74)

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