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Title: Nuclear forensic analysis of a non-traditional actinide sample

Abstract

Nuclear forensic publications, performance tests, and research and development efforts typically target the bulk global inventory of intentionally safeguarded materials, such as plutonium (Pu) and uranium (U). Other materials, such as neptunium (Np), pose a nuclear security risk as well. Trafficking leading to recovery of an interdicted Np sample is a realistic concern especially for materials originating in countries that reprocesses fuel. Using complementary forensic methods, potential signatures for an unknown Np oxide sample were investigated. Measurement results were assessed against published Np processes to present hypotheses as to the original intended use, method of production, and origin for this Np oxide.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
DHS; USDOE
OSTI Identifier:
1341859
Report Number(s):
LA-UR-16-21338
Journal ID: ISSN 0039-9140
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Talanta
Additional Journal Information:
Journal Volume: 159; Journal Issue: C; Journal ID: ISSN 0039-9140
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL PROTECTION; 36 MATERIALS SCIENCE; Np; neptunium oxide; nuclear forensics; chronometry

Citation Formats

Doyle, Jamie L., Kuhn, Kevin John, Byerly, Benjamin, Colletti, Lisa Michelle, Fulwyler, James Brent, Garduno, Katherine, Keller, Russell, Lujan, Elmer J. W., Martinez, Alexander, Myers, Steve Charles, Porterfield, Donivan R., Spencer, Khalil J., Stanley, Floyd E., Townsend, Lisa Ellen, Thomas, Mariam, Walker, Laurie F., Xu, Ning, and Tandon, Lav. Nuclear forensic analysis of a non-traditional actinide sample. United States: N. p., 2016. Web. https://doi.org/10.1016/j.talanta.2016.06.028.
Doyle, Jamie L., Kuhn, Kevin John, Byerly, Benjamin, Colletti, Lisa Michelle, Fulwyler, James Brent, Garduno, Katherine, Keller, Russell, Lujan, Elmer J. W., Martinez, Alexander, Myers, Steve Charles, Porterfield, Donivan R., Spencer, Khalil J., Stanley, Floyd E., Townsend, Lisa Ellen, Thomas, Mariam, Walker, Laurie F., Xu, Ning, & Tandon, Lav. Nuclear forensic analysis of a non-traditional actinide sample. United States. https://doi.org/10.1016/j.talanta.2016.06.028
Doyle, Jamie L., Kuhn, Kevin John, Byerly, Benjamin, Colletti, Lisa Michelle, Fulwyler, James Brent, Garduno, Katherine, Keller, Russell, Lujan, Elmer J. W., Martinez, Alexander, Myers, Steve Charles, Porterfield, Donivan R., Spencer, Khalil J., Stanley, Floyd E., Townsend, Lisa Ellen, Thomas, Mariam, Walker, Laurie F., Xu, Ning, and Tandon, Lav. Wed . "Nuclear forensic analysis of a non-traditional actinide sample". United States. https://doi.org/10.1016/j.talanta.2016.06.028. https://www.osti.gov/servlets/purl/1341859.
@article{osti_1341859,
title = {Nuclear forensic analysis of a non-traditional actinide sample},
author = {Doyle, Jamie L. and Kuhn, Kevin John and Byerly, Benjamin and Colletti, Lisa Michelle and Fulwyler, James Brent and Garduno, Katherine and Keller, Russell and Lujan, Elmer J. W. and Martinez, Alexander and Myers, Steve Charles and Porterfield, Donivan R. and Spencer, Khalil J. and Stanley, Floyd E. and Townsend, Lisa Ellen and Thomas, Mariam and Walker, Laurie F. and Xu, Ning and Tandon, Lav},
abstractNote = {Nuclear forensic publications, performance tests, and research and development efforts typically target the bulk global inventory of intentionally safeguarded materials, such as plutonium (Pu) and uranium (U). Other materials, such as neptunium (Np), pose a nuclear security risk as well. Trafficking leading to recovery of an interdicted Np sample is a realistic concern especially for materials originating in countries that reprocesses fuel. Using complementary forensic methods, potential signatures for an unknown Np oxide sample were investigated. Measurement results were assessed against published Np processes to present hypotheses as to the original intended use, method of production, and origin for this Np oxide.},
doi = {10.1016/j.talanta.2016.06.028},
journal = {Talanta},
number = C,
volume = 159,
place = {United States},
year = {2016},
month = {6}
}

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Works referenced in this record:

Security: Expand nuclear forensics
journal, November 2013


The state of nuclear forensics
journal, January 2013

  • Kristo, Michael J.; Tumey, Scott J.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 294
  • DOI: 10.1016/j.nimb.2012.07.047

Nuclear forensic investigations with a focus on plutonium
journal, October 2007


An Evaluation of Safeguards Approaches for Neptunium
journal, March 2001

  • Burr, Tom; Stanbro, William D.; Charlton, William
  • Journal of Nuclear Science and Technology, Vol. 38, Issue 3
  • DOI: 10.1080/18811248.2001.9715023

Nuclear forensic investigations: Two case studies
journal, January 2006


A brief introduction to analytical methods in nuclear forensics
journal, July 2012

  • Stanley, Floyd E.; Stalcup, A. M.; Spitz, H. B.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 295, Issue 2
  • DOI: 10.1007/s10967-012-1927-3

Documentation of a model action plan to deter illicit nuclear trafficking
journal, May 2008

  • Smith, D. K.; Kristo, M. J.; Niemeyer, S.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 276, Issue 2
  • DOI: 10.1007/s10967-008-0520-2

Nuclear forensic science—From cradle to maturity
journal, October 2007


Refinement of Pu parent–daughter isotopic and concentration analysis for forensic (dating) purposes
journal, August 2009

  • Spencer, Khalil J.; Tandon, Lav; Gallimore, Dave
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 282, Issue 2
  • DOI: 10.1007/s10967-009-0287-0

Nuclear, chemical, and physical characterization of nuclear materials
journal, May 2008

  • Tandon, L.; Hastings, E.; Banar, J.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 276, Issue 2
  • DOI: 10.1007/s10967-008-0528-7

Dissolution and assay of neptunium oxide
journal, July 2012

  • Xu, N.; Tandon, L.; Gallimore, D.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 296, Issue 1
  • DOI: 10.1007/s10967-012-1947-z

High accuracy plutonium mass determination by controlled-potential coulometry
journal, April 2014

  • Ruas, Alexandre; Leguay, Nicolas; Sueur, Romain
  • Radiochimica Acta, Vol. 102, Issue 8
  • DOI: 10.1515/ract-2013-2213

Determination of neptunium using controlled potential coulometry
journal, August 1991

  • Kasar, U. M.; Joshi, A. R.; Patil, S. K.
  • Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 150, Issue 2
  • DOI: 10.1007/BF02035324

High-precision isotopic analyses of uranium and plutonium by total sample volatilization and signal integration
journal, January 1991

  • Callis, E. L.; Abernathey, R. M.
  • International Journal of Mass Spectrometry and Ion Processes, Vol. 103, Issue 2-3
  • DOI: 10.1016/0168-1176(91)80081-W

Production of 235 Np, 236 Pu and 237 Pu via nuclear reactions on 235,236,238 U and 237 Np targets
journal, October 2003


Some observations on the preparation of neptunium oxides
journal, February 1958


Nuclear Forensics of a Non-Traditional Sample: Neptunium
journal, May 2016

  • Doyle, Jamie L.; Schwartz, Daniel; Tandon, Lav
  • MRS Advances, Vol. 1, Issue 44
  • DOI: 10.1557/adv.2016.353

Neptunium concentration profiles in the Purex process
journal, June 1998


Corrosion of Type 304L Stainless Steel in Concentrated Plutonium Nitrate Solution
journal, January 1985


Production of Plutonium-238 with Minimum Plutonium-236 Contamination
journal, January 1972

  • Lindsey, W. J.; Roggenkamp, P. L.; Woods, W. K.
  • Nuclear Technology, Vol. 13, Issue 1
  • DOI: 10.13182/NT72-A31069

Isotopic composition of plutonium-238 from Americium-241 and reactor crosssections of actinide nuclides
journal, August 1972


Design characteristics and fabrication of radioisotope heat sources for space missions
journal, January 2001


Separation of Pu-238 and Pu-242 from Irradiated Am-241
journal, January 1973


NASA’s Program for Radioisotope Power System Research and Development
conference, January 2005

  • Schmidt, George R.
  • SPACE TECHNOLOGY AND APPLICATIONS INT.FORUM-STAIF 2005: Conf.Thermophys in Micrograv;Conf Comm/Civil Next Gen.Space Transp; 22nd Symp Space Nucl.Powr Propuls.;Conf.Human/Robotic Techn.Nat'l Vision Space Expl.; 3rd Symp Space Colon.; 2nd Symp.New Frontiers, AIP Conference Proceedings
  • DOI: 10.1063/1.1867159

Technology and fabrication of plutonium-238 radionuclide heat sources
conference, January 1996

  • Malikh, Y. A.; Aldoshin, A. I.; Danilkin, E. A.
  • Space technology and applications international forum: 1st conference on commercial development of space; 1st conference on next generation launch systems; 2nd spacecraft thermal control symposium; 13th symposium on space nuclear power and propulsion, AIP Conference Proceedings
  • DOI: 10.1063/1.50076

Radioactive Contamination at Chelyabinsk-65, Russia
journal, November 1993


    Works referencing / citing this record:

    Determination of natural uranium by various analytical techniques in soils of Zacatecas State (Mexico)
    journal, January 2019

    • Escareño-Juárez, Edmundo; Pardo, Rafael; Gascó-Leonarte, Catalina
    • Journal of Radioanalytical and Nuclear Chemistry, Vol. 319, Issue 3
    • DOI: 10.1007/s10967-019-06428-6