Probing inter- and intrachain Zhang-Rice excitons in and determining their binding energy
Abstract
Cuprate materials, such as those hosting high-temperature superconductivity, represent a famous class of materials where the correlations between the strongly entangled charges and spins produce complex phase diagrams. Several years ago, the Zhang-Rice singlet was proposed as a natural quasiparticle in hole-doped cuprates. The occurrence and binding energy of this quasiparticle, consisting of a pair of bound holes with antiparallel spins on the same CuO4 plaquette, depends on the local electronic interactions, which are fundamental quantities for understanding the physics of the cuprates. Here, we employ state-of-the-art resonant inelastic x-ray scattering (RIXS) to probe the correlated physics of the CuO4 plaquettes in the quasi-one-dimensional chain cuprate Li2CuO2. By tuning the incoming photon energy to the O K edge, we populate bound states related to the Zhang-Rice quasiparticles in the RIXS process. Both intra- and interchain Zhang-Rice singlets are observed and their occurrence is shown to depend on the nearest-neighbor spin-spin correlations, which are readily probed in this experiment. Finally, we also extract the binding energy of the Zhang-Rice singlet and identify the Zhang-Rice triplet excitation in the RIXS spectra.
- Authors:
-
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology; Univ. of Zurich (Switzerland). Inst. of Physics
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology; Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II); Leibniz Inst. for Solid State and Materials Research (IFW), Dresden (Germany)
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology; Science and Technology Facilities Council (STFC), Harwell Campus, Oxford (United Kingdom). Diamond Light Source, Ltd.
- Leibniz Inst. for Solid State and Materials Research (IFW), Dresden (Germany)
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology
- Max-Planck Inst. for Chemical Physics of Solids, Dresden (Germany)
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy; Univ. of Tennessee, Knoxville, TN (United States). Joint Inst. for Advanced Materials
- Paris Lodron Univ. Salzburg, Salzburg (Austria)
- Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnologyv
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1341697
- Report Number(s):
- BNL-113444-2017-JA
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US1701544
- Grant/Contract Number:
- SC00112704; PZ00P2_154867; GE 1647/3-1; 200021L_141325
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 94; Journal Issue: 16; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Monney, Claude, Bisogni, Valentina, Zhou, Ke-Jin, Kraus, Roberto, Strocov, Vladimir N., Behr, Günter, Drechsler, Stefan-Ludwig, Rosner, Helge, Johnston, Steve, Geck, Jochen, and Schmitt, Thorsten. Probing inter- and intrachain Zhang-Rice excitons in Li2CuO2 and determining their binding energy. United States: N. p., 2016.
Web. doi:10.1103/PhysRevB.94.165118.
Monney, Claude, Bisogni, Valentina, Zhou, Ke-Jin, Kraus, Roberto, Strocov, Vladimir N., Behr, Günter, Drechsler, Stefan-Ludwig, Rosner, Helge, Johnston, Steve, Geck, Jochen, & Schmitt, Thorsten. Probing inter- and intrachain Zhang-Rice excitons in Li2CuO2 and determining their binding energy. United States. https://doi.org/10.1103/PhysRevB.94.165118
Monney, Claude, Bisogni, Valentina, Zhou, Ke-Jin, Kraus, Roberto, Strocov, Vladimir N., Behr, Günter, Drechsler, Stefan-Ludwig, Rosner, Helge, Johnston, Steve, Geck, Jochen, and Schmitt, Thorsten. Mon .
"Probing inter- and intrachain Zhang-Rice excitons in Li2CuO2 and determining their binding energy". United States. https://doi.org/10.1103/PhysRevB.94.165118. https://www.osti.gov/servlets/purl/1341697.
@article{osti_1341697,
title = {Probing inter- and intrachain Zhang-Rice excitons in Li2CuO2 and determining their binding energy},
author = {Monney, Claude and Bisogni, Valentina and Zhou, Ke-Jin and Kraus, Roberto and Strocov, Vladimir N. and Behr, Günter and Drechsler, Stefan-Ludwig and Rosner, Helge and Johnston, Steve and Geck, Jochen and Schmitt, Thorsten},
abstractNote = {Cuprate materials, such as those hosting high-temperature superconductivity, represent a famous class of materials where the correlations between the strongly entangled charges and spins produce complex phase diagrams. Several years ago, the Zhang-Rice singlet was proposed as a natural quasiparticle in hole-doped cuprates. The occurrence and binding energy of this quasiparticle, consisting of a pair of bound holes with antiparallel spins on the same CuO4 plaquette, depends on the local electronic interactions, which are fundamental quantities for understanding the physics of the cuprates. Here, we employ state-of-the-art resonant inelastic x-ray scattering (RIXS) to probe the correlated physics of the CuO4 plaquettes in the quasi-one-dimensional chain cuprate Li2CuO2. By tuning the incoming photon energy to the O K edge, we populate bound states related to the Zhang-Rice quasiparticles in the RIXS process. Both intra- and interchain Zhang-Rice singlets are observed and their occurrence is shown to depend on the nearest-neighbor spin-spin correlations, which are readily probed in this experiment. Finally, we also extract the binding energy of the Zhang-Rice singlet and identify the Zhang-Rice triplet excitation in the RIXS spectra.},
doi = {10.1103/PhysRevB.94.165118},
journal = {Physical Review B},
number = 16,
volume = 94,
place = {United States},
year = {Mon Oct 10 00:00:00 EDT 2016},
month = {Mon Oct 10 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Challenges in the crystal growth of Li2CuO2 and LiMnPO4
journal, March 2011
- Wizent, Nadja; Behr, Günter; Löser, Wolfgang
- Journal of Crystal Growth, Vol. 318, Issue 1
Extended Moment Formation and Second Neighbor Coupling in
journal, September 1998
- Weht, Ruben; Pickett, W. E.
- Physical Review Letters, Vol. 81, Issue 12
Doping evolution of the oxygen -edge x-ray absorption spectra of cuprate superconductors using a three-orbital Hubbard model
journal, April 2013
- Chen, C. -C.; Sentef, M.; Kung, Y. F.
- Physical Review B, Vol. 87, Issue 16
Zhang-Rice singlet-state formation by oxygen resonant x-ray emission in edge-sharing copper-oxide systems
journal, January 2001
- Okada, Kozo; Kotani, Akio
- Physical Review B, Vol. 63, Issue 4
Observation of multiple Zhang-Rice excitations in a correlated solid: Resonant inelastic X-ray scattering study of Li 2 CuO 2
journal, July 2007
- Learmonth, T.; McGuinness, C.; Glans, P. -A
- Europhysics Letters (EPL), Vol. 79, Issue 4
Highly dispersive spin excitations in the chain cuprate Li 2 CuO 2
journal, November 2009
- Lorenz, W. E. A.; Kuzian, R. O.; Drechsler, S. -L.
- EPL (Europhysics Letters), Vol. 88, Issue 3
Resonant Inelastic X-Ray Scattering at the Oxygen Resonance of NiO: Nonlocal Charge Transfer and Double-Singlet Excitations
journal, February 2006
- Duda, L. -C.; Schmitt, T.; Magnuson, M.
- Physical Review Letters, Vol. 96, Issue 6
Unoccupied electronic structure of
journal, November 1999
- Neudert, R.; Rosner, H.; Drechsler, S. -L.
- Physical Review B, Vol. 60, Issue 19
Die Kristallstruktur von Li2CuO2
journal, December 1970
- Hoppe, Rudolf; Rieck, Hilmar
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 379, Issue 2
Magnetic properties and exchange integrals of the frustrated chain cuprate linarite PbCuSO (OH)
journal, January 2012
- Wolter, A. U. B.; Lipps, F.; Schäpers, M.
- Physical Review B, Vol. 85, Issue 1
Crystal and magnetic structure of Li2CuO2
journal, May 1990
- Sapiña, F.; Rodríguez-Carvajal, J.; Sanchis, M. J.
- Solid State Communications, Vol. 74, Issue 8
Dynamics of a hole in a plaquette: Electron energy-loss spectroscopy of
journal, September 2000
- Atzkern, S.; Knupfer, M.; Golden, M. S.
- Physical Review B, Vol. 62, Issue 12
Temperature-dependent optical conductivity of undoped cuprates with weak exchange
journal, August 2008
- Málek, J.; Drechsler, S. -L.; Nitzsche, U.
- Physical Review B, Vol. 78, Issue 6
SAXES, a high resolution spectrometer for resonant x-ray emission in the 400–1600eV energy range
journal, November 2006
- Ghiringhelli, G.; Piazzalunga, A.; Dallera, C.
- Review of Scientific Instruments, Vol. 77, Issue 11
Determining the Short-Range Spin Correlations in the Spin-Chain and Compounds Using Resonant Inelastic X-Ray Scattering
journal, February 2013
- Monney, Claude; Bisogni, Valentina; Zhou, Ke-Jin
- Physical Review Letters, Vol. 110, Issue 8
Resonant inelastic x-ray scattering studies of elementary excitations
journal, June 2011
- Ament, Luuk J. P.; van Veenendaal, Michel; Devereaux, Thomas P.
- Reviews of Modern Physics, Vol. 83, Issue 2
Spin -Resolved Photoemission on Anti -Ferromagnets: Direct Observation of Zhang-Rice Singlets in CuO
journal, February 1997
- Tjeng, L. H.; Sinkovic, B.; Brookes, N. B.
- Physical Review Letters, Vol. 78, Issue 6
Copper-related information from the oxygen resonant x-ray emission in low-dimensional cuprates
journal, April 2002
- Okada, Kozo; Kotani, Akio
- Physical Review B, Vol. 65, Issue 14
Electronic structure and magnetic properties of : A spin- Heisenberg system close to a quantum critical point
journal, November 2009
- Schmitt, M.; Málek, J.; Drechsler, S. -L.
- Physical Review B, Vol. 80, Issue 20
Bandlike and excitonic states of oxygen in Observation using polarized resonant soft-x-ray emission spectroscopy
journal, February 2000
- Duda, L. -C.; Downes, J.; McGuinness, C.
- Physical Review B, Vol. 61, Issue 6
High-resolution soft X-ray beamline ADRESS at the Swiss Light Source for resonant inelastic X-ray scattering and angle-resolved photoelectron spectroscopies
journal, July 2010
- Strocov, V. N.; Schmitt, T.; Flechsig, U.
- Journal of Synchrotron Radiation, Vol. 17, Issue 5
Ab initio calculation of - excitations in quasi-one-dimensional Cu correlated materials
journal, December 2011
- Huang, Hsiao-Yu; Bogdanov, Nikolay A.; Siurakshina, Liudmila
- Physical Review B, Vol. 84, Issue 23
Accurate and simple analytic representation of the electron-gas correlation energy
journal, June 1992
- Perdew, John P.; Wang, Yue
- Physical Review B, Vol. 45, Issue 23, p. 13244-13249
Resonant inelastic x-ray scattering spectra for electrons in solids
journal, February 2001
- Kotani, Akio; Shin, Shik
- Reviews of Modern Physics, Vol. 73, Issue 1
Manifestation of Spin-Charge Separation in the Dynamic Dielectric Response of One-Dimensional
journal, July 1998
- Neudert, R.; Knupfer, M.; Golden, M. S.
- Physical Review Letters, Vol. 81, Issue 3
Charge and orbital excitations in
journal, April 2004
- Kim, Young-June; Hill, J. P.; Chou, F. C.
- Physical Review B, Vol. 69, Issue 15
Interchain interactions and magnetic properties of
journal, September 1999
- Mizuno, Y.; Tohyama, T.; Maekawa, S.
- Physical Review B, Vol. 60, Issue 9
Effective Hamiltonian for the superconducting Cu oxides
journal, March 1988
- Zhang, F. C.; Rice, T. M.
- Physical Review B, Vol. 37, Issue 7
Cu -edge resonant inelastic x-ray scattering in edge-sharing cuprates
journal, March 2008
- Vernay, F.; Moritz, B.; Elfimov, I. S.
- Physical Review B, Vol. 77, Issue 10
Apex oxygen and critical temperature in copper oxide superconductors: Universal correlation with the stability of local singlets
journal, February 1991
- Ohta, Y.; Tohyama, T.; Maekawa, S.
- Physical Review B, Vol. 43, Issue 4
Exciton Doublet in the Mott-Hubbard Insulator Identified by Spectral Ellipsometry
journal, October 2009
- Matiks, Y.; Horsch, P.; Kremer, R. K.
- Physical Review Letters, Vol. 103, Issue 18
Stability of the Zhang-Rice Singlet with Doping in Lanthanum Strontium Copper Oxide Across the Superconducting Dome and Above
journal, July 2015
- Brookes, N. B.; Ghiringhelli, G.; Charvet, A. -M.
- Physical Review Letters, Vol. 115, Issue 2
Electron-lattice interactions strongly renormalize the charge-transfer energy in the spin-chain cuprate Li2CuO2
journal, February 2016
- Johnston, Steve; Monney, Claude; Bisogni, Valentina
- Nature Communications, Vol. 7, Issue 1
Full-potential band-structure calculation of iron pyrite
journal, November 1999
- Opahle, I.; Koepernik, K.; Eschrig, H.
- Physical Review B, Vol. 60, Issue 20
Full-potential nonorthogonal local-orbital minimum-basis band-structure scheme
journal, January 1999
- Koepernik, Klaus; Eschrig, Helmut
- Physical Review B, Vol. 59, Issue 3
Works referencing / citing this record:
Signatures of a magnetic field-induced unconventional nematic liquid in the frustrated and anisotropic spin-chain cuprate LiCuSbO4
journal, July 2017
- Grafe, H. -J.; Nishimoto, S.; Iakovleva, M.
- Scientific Reports, Vol. 7, Issue 1
Signatures of a magnetic field-induced unconventional nematic liquid in the frustrated and anisotropic spin-chain cuprate LiCuSbO4
other, January 2017
- Grafe, H. -J.; Nishimoto, S.; Iakovleva, M.
- London : Nature Publishing Group