Kinetically Controlled Synthesis of Pt-Based One-Dimensional Hierarchically Porous Nanostructures with Large Mesopores as Highly Efficient ORR Catalysts
Abstract
Rational design and construction of Pt-based porous nanostructures with large mesopores have triggered significant considerations because of their high surface area and more efficient mass transport. Hydrochloric acid-induced kinetic reduction of metal precursors in the presence of soft template F-127 and hard template tellurium nanowires has been successfully demonstrated to construct one-dimensional hierarchical porous PtCu alloy nanostructures with large mesopores. Furthermore, the electrochemical experiments demonstrated that the resultant PtCu hierarchically porous nanostructures with optimized composition exhibit enhanced electrocatalytic performance for oxygen reduction reaction.
- Authors:
-
[3];
[4]
- Washington State Univ., Pullman, WA (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Shandong Univ., Jinan (China)
- Washington State Univ., Pullman, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1339828
- Report Number(s):
- PNNL-SA-117387
Journal ID: ISSN 1944-8244; 48920; KP1704020
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 51; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Environmental Molecular Sciences Laboratory; porous nanostructures; one-dimensional nanomaterials; kinetically controlled synthesis; Pt alloys; oxygen reduction reaction; redox reactions; nanostructures; platinum; genetics; precursors
Citation Formats
Fu, Shaofang, Zhu, Chengzhou, Song, Junhua, Engelhard, Mark H., Xia, Haibing, Du, Dan, and Lin, Yuehe. Kinetically Controlled Synthesis of Pt-Based One-Dimensional Hierarchically Porous Nanostructures with Large Mesopores as Highly Efficient ORR Catalysts. United States: N. p., 2016.
Web. doi:10.1021/acsami.6b11537.
Fu, Shaofang, Zhu, Chengzhou, Song, Junhua, Engelhard, Mark H., Xia, Haibing, Du, Dan, & Lin, Yuehe. Kinetically Controlled Synthesis of Pt-Based One-Dimensional Hierarchically Porous Nanostructures with Large Mesopores as Highly Efficient ORR Catalysts. United States. https://doi.org/10.1021/acsami.6b11537
Fu, Shaofang, Zhu, Chengzhou, Song, Junhua, Engelhard, Mark H., Xia, Haibing, Du, Dan, and Lin, Yuehe. Thu .
"Kinetically Controlled Synthesis of Pt-Based One-Dimensional Hierarchically Porous Nanostructures with Large Mesopores as Highly Efficient ORR Catalysts". United States. https://doi.org/10.1021/acsami.6b11537. https://www.osti.gov/servlets/purl/1339828.
@article{osti_1339828,
title = {Kinetically Controlled Synthesis of Pt-Based One-Dimensional Hierarchically Porous Nanostructures with Large Mesopores as Highly Efficient ORR Catalysts},
author = {Fu, Shaofang and Zhu, Chengzhou and Song, Junhua and Engelhard, Mark H. and Xia, Haibing and Du, Dan and Lin, Yuehe},
abstractNote = {Rational design and construction of Pt-based porous nanostructures with large mesopores have triggered significant considerations because of their high surface area and more efficient mass transport. Hydrochloric acid-induced kinetic reduction of metal precursors in the presence of soft template F-127 and hard template tellurium nanowires has been successfully demonstrated to construct one-dimensional hierarchical porous PtCu alloy nanostructures with large mesopores. Furthermore, the electrochemical experiments demonstrated that the resultant PtCu hierarchically porous nanostructures with optimized composition exhibit enhanced electrocatalytic performance for oxygen reduction reaction.},
doi = {10.1021/acsami.6b11537},
journal = {ACS Applied Materials and Interfaces},
number = 51,
volume = 8,
place = {United States},
year = {Thu Dec 01 00:00:00 EST 2016},
month = {Thu Dec 01 00:00:00 EST 2016}
}
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