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Title: Local twin domains and tip-voltage-induced domain switching of monoclinic M C phase in Pb ( M g 1 / 3 N b 2 / 3 ) O 3 - 0.34 PbTi O 3 single crystal revealed by piezoresponse force microscopy

Abstract

Here, the monoclinic (M) phases in high-performance relaxor-based ferroelectric single crystals have been recognized to be a vital structural factor for the outstanding piezoelectric property. However, due to the complexity of the structure in M phases, the understanding about it is still limited. In this paper, the local twin domains and tip-voltage-induced domain switching of the MC phase in Pb(Mg1/3Nb2/3)O3 - 0.34PbTiO3 (PMN-0.34PT) single crystal have been intensively investigated by piezoresponse force microscopy (PFM). By theoretically analyzing the experimental patterns of domain walls on the (001)C face, the specific MC twin domains in the initial annealed state of a selected area have been clarified, and the polarization orientation of the MC phase in this sample is determined to be at an angle of 29 degrees to the < 001 > C directions. In addition, based on the evolution of domains and the motion of domain walls under the step-increased PFM tip dc voltage (Vdc), the switching process and features of different types of MC domain variants are visually revealed

Authors:
 [1];  [1];  [2];  [1];  [1];  [2];  [2];  [1];  [3];  [2];  [4]
  1. Harbin Institute of Technology, Harbin (China)
  2. Univ. of Science and Technology of China, Anhui (China)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Harbin Institute of Technology, Harbin (China); The Pennsylvania State Univ., University Park, PA (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Key Basic Research Program of China; National Natural Science Foundation of China (NNSFC)
OSTI Identifier:
1339416
Alternate Identifier(s):
OSTI ID: 1310844
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 94; Journal Issue: 5; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats

Wang, Ruixue, Yang, Bin, Luo, Zhenlin, Sun, Enwei, Sun, Yuan, Xu, Han, Zhao, Jiangtao, Zheng, Limei, Zhou, Hua, Gao, Chen, and Cao, Wenwu. Local twin domains and tip-voltage-induced domain switching of monoclinic MC phase in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by piezoresponse force microscopy. United States: N. p., 2016. Web. doi:10.1103/PhysRevB.94.054115.
Wang, Ruixue, Yang, Bin, Luo, Zhenlin, Sun, Enwei, Sun, Yuan, Xu, Han, Zhao, Jiangtao, Zheng, Limei, Zhou, Hua, Gao, Chen, & Cao, Wenwu. Local twin domains and tip-voltage-induced domain switching of monoclinic MC phase in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by piezoresponse force microscopy. United States. doi:10.1103/PhysRevB.94.054115.
Wang, Ruixue, Yang, Bin, Luo, Zhenlin, Sun, Enwei, Sun, Yuan, Xu, Han, Zhao, Jiangtao, Zheng, Limei, Zhou, Hua, Gao, Chen, and Cao, Wenwu. Mon . "Local twin domains and tip-voltage-induced domain switching of monoclinic MC phase in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by piezoresponse force microscopy". United States. doi:10.1103/PhysRevB.94.054115. https://www.osti.gov/servlets/purl/1339416.
@article{osti_1339416,
title = {Local twin domains and tip-voltage-induced domain switching of monoclinic MC phase in Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 single crystal revealed by piezoresponse force microscopy},
author = {Wang, Ruixue and Yang, Bin and Luo, Zhenlin and Sun, Enwei and Sun, Yuan and Xu, Han and Zhao, Jiangtao and Zheng, Limei and Zhou, Hua and Gao, Chen and Cao, Wenwu},
abstractNote = {Here, the monoclinic (M) phases in high-performance relaxor-based ferroelectric single crystals have been recognized to be a vital structural factor for the outstanding piezoelectric property. However, due to the complexity of the structure in M phases, the understanding about it is still limited. In this paper, the local twin domains and tip-voltage-induced domain switching of the MC phase in Pb(Mg1/3Nb2/3)O3 - 0.34PbTiO3 (PMN-0.34PT) single crystal have been intensively investigated by piezoresponse force microscopy (PFM). By theoretically analyzing the experimental patterns of domain walls on the (001)C face, the specific MC twin domains in the initial annealed state of a selected area have been clarified, and the polarization orientation of the MC phase in this sample is determined to be at an angle of 29 degrees to the < 001 > C directions. In addition, based on the evolution of domains and the motion of domain walls under the step-increased PFM tip dc voltage (Vdc), the switching process and features of different types of MC domain variants are visually revealed},
doi = {10.1103/PhysRevB.94.054115},
journal = {Physical Review B},
number = 5,
volume = 94,
place = {United States},
year = {2016},
month = {8}
}

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Works referenced in this record:

Monoclinic phases arising across thermal inter-ferroelectric phase transitions
journal, July 2014


Monoclinic phase in the relaxor-based piezoelectric/ferroelectric P b ( M g 1 / 3 Nb 2 / 3 ) O 3 P b T i O 3 system
journal, October 2001


Growth, characterization and properties of relaxor ferroelectric PMN-PT single crystals
journal, May 1999


Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics
journal, January 2000

  • Fu, Huaxiang; Cohen, Ronald E.
  • Nature, Vol. 403, Issue 6767
  • DOI: 10.1038/35002022

Comments on Origins of Enhanced Piezoelectric Properties in Ferroelectrics
journal, August 2009

  • Damjanovic, D.; Damjanovic, Dragan; Damjanovic, Dragan
  • IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 56, Issue 8
  • DOI: 10.1109/TUFFC.2009.1222

Mesoscale Domains and Nature of the Relaxor State by Piezoresponse Force Microscopy
journal, July 2013


Monoclinic structure of unpoled morphotropic high piezoelectric PMN-PT and PZN-PT compounds
journal, January 2002


Periodic elastic nanodomains in ultrathin tetragonal-like BiFeO 3 films
journal, August 2013


Pattern Transfer and Electric-Field-Induced Magnetic Domain Formation in Multiferroic Heterostructures
journal, May 2011

  • Lahtinen, Tuomas H. E.; Tuomi, Jussi O.; van Dijken, Sebastiaan
  • Advanced Materials, Vol. 23, Issue 28
  • DOI: 10.1002/adma.201100426

Ferroelastic domain switching dynamics under electrical and mechanical excitations
journal, May 2014

  • Gao, Peng; Britson, Jason; Nelson, Christopher T.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4801

Monodomain versus polydomain piezoelectric response of 0.67Pb(Mg1/3Nb2/3)O3–0.33PbTiO3 single crystals along nonpolar directions
journal, July 2003

  • Damjanovic, Dragan; Budimir, Marko; Davis, Matthew
  • Applied Physics Letters, Vol. 83, Issue 3
  • DOI: 10.1063/1.1592880

Elastic, piezoelectric, and dielectric properties of multidomain 0.67Pb(Mg1/3Nb2/3)O3–0.33PbTiO3 single crystals
journal, October 2001

  • Zhang, Rui; Jiang, Bei; Cao, Wenwu
  • Journal of Applied Physics, Vol. 90, Issue 7
  • DOI: 10.1063/1.1390494

Adaptive ferroelectric state at morphotropic phase boundary: Coexisting tetragonal and rhombohedral phases
journal, June 2014


Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals
journal, August 1997

  • Park, Seung-Eek; Shrout, Thomas R.
  • Journal of Applied Physics, Vol. 82, Issue 4
  • DOI: 10.1063/1.365983

Non-volatile ferroelastic switching of the Verwey transition and resistivity of epitaxial Fe3O4/PMN-PT (011)
journal, May 2013

  • Liu, Ming; Hoffman, Jason; Wang, Jing
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep01876

Applying uniform reversible strain to epitaxial oxide films
journal, April 2010

  • Biegalski, M. D.; Dörr, K.; Kim, D. H.
  • Applied Physics Letters, Vol. 96, Issue 15
  • DOI: 10.1063/1.3374323

Relaxor-based ferroelectric single crystals: Growth, domain engineering, characterization and applications
journal, August 2014


Origin of morphotropic phase boundaries in ferroelectrics
journal, January 2008

  • Ahart, Muhtar; Somayazulu, Maddury; Cohen, R. E.
  • Nature, Vol. 451, Issue 7178
  • DOI: 10.1038/nature06459

Probing Ferroelectrics Using Optical Second Harmonic Generation
journal, August 2011


High performance ferroelectric relaxor-PbTiO 3 single crystals: Status and perspective
journal, February 2012

  • Zhang, Shujun; Li, Fei
  • Journal of Applied Physics, Vol. 111, Issue 3
  • DOI: 10.1063/1.3679521

Probing Ferroelectric Domain Engineering in BiFeO 3 Thin Films by Second Harmonic Generation
journal, July 2015

  • Trassin, Morgan; Luca, Gabriele De; Manz, Sebastian
  • Advanced Materials, Vol. 27, Issue 33
  • DOI: 10.1002/adma.201501636

Enhanced piezoelectric properties of barium titanate single crystals with different engineered-domain sizes
journal, July 2005

  • Wada, Satoshi; Yako, Koichi; Kakemoto, Hirofumi
  • Journal of Applied Physics, Vol. 98, Issue 1
  • DOI: 10.1063/1.1957130

Rotator and extender ferroelectrics: Importance of the shear coefficient to the piezoelectric properties of domain-engineered crystals and ceramics
journal, March 2007

  • Davis, Matthew; Budimir, Marko; Damjanovic, Dragan
  • Journal of Applied Physics, Vol. 101, Issue 5
  • DOI: 10.1063/1.2653925

A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
journal, April 1999

  • Noheda, B.; Cox, D. E.; Shirane, G.
  • Applied Physics Letters, Vol. 74, Issue 14
  • DOI: 10.1063/1.123756

The giant piezoelectric effect: electric field induced monoclinic phase or piezoelectric distortion of the rhombohedral parent?
journal, May 2003


Enhanced electromechanical response of ferroelectrics due to charged domain walls
journal, January 2012

  • Sluka, Tomas; Tagantsev, Alexander K.; Damjanovic, Dragan
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1751

Domain-wall orientations in ferroelastics
journal, December 1975


Phase instability induced by polar nanoregions in a relaxor ferroelectric system
journal, May 2008

  • Xu, Guangyong; Wen, Jinsheng; Stock, C.
  • Nature Materials, Vol. 7, Issue 7
  • DOI: 10.1038/nmat2196

Adaptive ferroelectric states in systems with low domain wall energy: Tetragonal microdomains
journal, September 2003

  • Jin, Y. M.; Wang, Y. U.; Khachaturyan, A. G.
  • Journal of Applied Physics, Vol. 94, Issue 5
  • DOI: 10.1063/1.1599632

Coexistence of MA and MC phases in Pb(Mg1∕3Nb2∕3)0.68Ti0.32O3 single crystals
journal, February 2006

  • Bao, Peng; Yan, Feng; Lu, Xiaomei
  • Applied Physics Letters, Vol. 88, Issue 9
  • DOI: 10.1063/1.2177370

Origin of the High Piezoelectric Response in PbZr 1 x Ti x O 3
journal, June 2000


Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries
journal, November 2003


Formation of monoclinic nanodomains at the morphotropic phase boundary of ferroelectric systems
journal, December 2013


Phase diagram of the ferroelectric relaxor ( 1 x ) PbMg 1 / 3 Nb 2 / 3 O 3 x PbTiO 3
journal, August 2002


Probing the domain structure of BiFeO 3 epitaxial films with three-dimensional reciprocal space mapping
journal, May 2014

  • Luo, Z. L.; Huang, H.; Zhou, H.
  • Applied Physics Letters, Vol. 104, Issue 18
  • DOI: 10.1063/1.4875579

Monoclinic and triclinic phases in higher-order Devonshire theory
journal, January 2001


Electric-field control of magnetism via strain transfer across ferromagnetic/ferroelectric interfaces
journal, November 2015


Monoclinic nanodomains in morphotropic phase boundary Pb(Mg 1/3 Nb 2/3 )O 3 –PbTiO 3
journal, February 2014

  • Sato, Y.; Hirayama, T.; Ikuhara, Y.
  • Applied Physics Letters, Vol. 104, Issue 8
  • DOI: 10.1063/1.4866791

The missing boundary in the phase diagram of PbZr1−xTixO3
journal, October 2014

  • Zhang, N.; Yokota, H.; Glazer, A. M.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6231

Theory of tetragonal twin structures in ferroelectric perovskites with a first-order phase transition
journal, July 1991


Electric field dependence of piezoelectric properties for rhombohedral 0.955Pb(Zn1/3Nb2/3)O3– 0.045PbTiO3 single crystals
journal, March 1999

  • Liu, Shi-Fang; Park, Seung-Eek; Shrout, Thomas R.
  • Journal of Applied Physics, Vol. 85, Issue 5
  • DOI: 10.1063/1.369599

Thermotropic phase boundaries in classic ferroelectrics
journal, January 2014

  • Lummen, Tom T. A.; Gu, Yijia; Wang, Jianjun
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4172