Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals

Culver, Sean P.; Greaney, Matthew J.; Tinoco, Antonio; Brutchey, Richard L.

doi:10.1039/c5dt01722j

Title: Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca_1-xSr_xWO₄ and Sr_1-xBa_xWO₄ nanocrystals

Abstract

Here, a series of compositionally complex scheelite-structured nanocrystals of the formula A_1-xA’_xWO₄ (A = Ca, Sr, Ba) have been prepared under benign synthesis conditions using the vapor diffusion sol–gel method. Discrete nanocrystals with sub-20 nm mean diameters were obtained after kinetically controlled hydro- lysis and polycondensation at room temperature, followed by composition-dependent thermal aging at or below 60 °C. Rietveld analysis of X-ray diffraction data and Raman spectroscopy verified the synthesis of continuous and phase-pure nanocrystal solid solutions across the entire composition space for A_1-xA’_xWO₄, where 0 ≤ x ≤ 1. Elemental analysis by X-ray photoelectron and inductively coupled plasma- atomic emission spectroscopies demonstrated excellent agreement between the nominal and experi- mentally determined elemental stoichiometries, while energy dispersive X-ray spectroscopy illustrated good spatial elemental homogeneity within these nanocrystals synthesized under benign conditions.

Authors:

Culver, Sean P. ^[1]; Greaney, Matthew J. ^[1]; Tinoco, Antonio ^[1]; Brutchey, Richard L. ^[1]

Univ. of Southern California, Los Angeles, CA (United States). Dept. of Chemistry

Publication Date:: Fri Jul 24 00:00:00 EDT 2015

Research Org.:: Univ. of Southern California, Los Angeles, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1338896

Grant/Contract Number:: SC0006812

Resource Type:: Accepted Manuscript

Journal Name:: Dalton Transactions

Additional Journal Information:: Journal Volume: 44; Journal Issue: 33; Journal ID: ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats


                    Culver, Sean P., Greaney, Matthew J., Tinoco, Antonio, and Brutchey, Richard L. Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals.  United States: N. p., 2015. 
Web.  doi:10.1039/c5dt01722j.

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                    Culver, Sean P., Greaney, Matthew J., Tinoco, Antonio, & Brutchey, Richard L. Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals.  United States.  https://doi.org/10.1039/c5dt01722j

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                    Culver, Sean P., Greaney, Matthew J., Tinoco, Antonio, and Brutchey, Richard L. Fri .  
"Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals".  United States.  https://doi.org/10.1039/c5dt01722j.  https://www.osti.gov/servlets/purl/1338896.

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@article{osti_1338896,

  title        = {Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals},

  author       = {Culver, Sean P. and Greaney, Matthew J. and Tinoco, Antonio and Brutchey, Richard L.},

  abstractNote = {Here, a series of compositionally complex scheelite-structured nanocrystals of the formula A1-xA’xWO4 (A = Ca, Sr, Ba) have been prepared under benign synthesis conditions using the vapor diffusion sol–gel method. Discrete nanocrystals with sub-20 nm mean diameters were obtained after kinetically controlled hydro- lysis and polycondensation at room temperature, followed by composition-dependent thermal aging at or below 60 °C. Rietveld analysis of X-ray diffraction data and Raman spectroscopy verified the synthesis of continuous and phase-pure nanocrystal solid solutions across the entire composition space for A1-xA’xWO4, where 0 ≤ x ≤ 1. Elemental analysis by X-ray photoelectron and inductively coupled plasma- atomic emission spectroscopies demonstrated excellent agreement between the nominal and experi- mentally determined elemental stoichiometries, while energy dispersive X-ray spectroscopy illustrated good spatial elemental homogeneity within these nanocrystals synthesized under benign conditions.},

  doi          = {10.1039/c5dt01722j},

  journal      = {Dalton Transactions},

  number       = 33,

  volume       = 44,

  place        = {United States},

  year         = {Fri Jul 24 00:00:00 EDT 2015},

  month        = {Fri Jul 24 00:00:00 EDT 2015}

}

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Works referencing / citing this record:

Lanthanide-activated scheelite nanocrystal phosphors prepared by the low-temperature vapor diffusion sol–gel method
journal, January 2016

Culver, Sean P.; Brutchey, Richard L.
Dalton Transactions, Vol. 45, Issue 45
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Title: Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals

Abstract

Citation Formats

Carbon-Coated Nanophase CaMoO 4 as Anode Material for Li Ion Batteries journal, February 2004

Synthesis and Optimum Luminescence of CaWO 4 -Based Red Phosphors with Codoping of Eu 3+ and Na + journal, October 2008

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Ultraviolet emission from ABO4-type niobates, tantalates and tungstates journal, October 1990

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Polymer-Directed Synthesis of Penniform BaWO 4 Nanostructures in Reverse Micelles journal, March 2003

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Understanding the origin of photoluminescence in disordered Ca0.60Sr0.40WO4: An experimental and first-principles study journal, April 2007

Photoluminescence in the CaxSr1−xWO4 system at room temperature journal, August 2008

Growth and properties of various scheelite type mixed crystal systems journal, June 1980

Tailoring the Mechanism of the Amorphous-to-Crystalline Phase Transition of PbTiO 3 via Kinetically Controlled Hydrolysis journal, September 2011

A profile refinement method for nuclear and magnetic structures journal, June 1969

Rietveld refinement of Debye–Scherrer synchrotron X-ray data from Al 2 O 3 journal, April 1987

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

Analysis of solid solutions stability in scheelite-type molybdates and tungstates journal, October 2011

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Title: Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca_1-xSr_xWO₄ and Sr_1-xBa_xWO₄ nanocrystals

Carbon-Coated Nanophase CaMoO ₄ as Anode Material for Li Ion Batteries
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Synthesis and Optimum Luminescence of CaWO ₄ -Based Red Phosphors with Codoping of Eu ³⁺ and Na ⁺
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Luminescence of CaWO4, CaMoO4, and ZnWO4 scintillating crystals under different excitations
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Photophysical and Photocatalytic Properties of Molybdates and Tungstates with a Scheelite Structure
journal, September 2004

Oxide ion conduction in the Sm-substituted PbWO4 phases
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Ultraviolet emission from ABO4-type niobates, tantalates and tungstates
journal, October 1990

Microwave-hydrothermal preparation of alkaline-earth-metal tungstates
journal, June 2010

Metathetic room temperature preparation and characterization of scheelite-type ABO4 (A = Ca, Sr, Ba, Pb; B = Mo, W) powders
journal, February 2004

Polymer-Directed Synthesis of Penniform BaWO ₄ Nanostructures in Reverse Micelles
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General, Room-Temperature Method for the Synthesis of Isolated as Well as Arrays of Single-Crystalline ABO ₄ -Type Nanorods
journal, November 2004

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journal, January 2014

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journal, October 2006

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journal, January 2010

Local structural distortion of BaZr _x Ti _1−x O ₃ nanocrystals synthesized at room temperature
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journal, August 2012

Low-Temperature Synthesis of AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
journal, October 2013

Structural Disorder in AMoO ₄ (A = Ca, Sr, Ba) Scheelite Nanocrystals
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Luminescence of solid solutions CaWO4− PbWO4 activated by samarium
journal, March 1964

Understanding the origin of photoluminescence in disordered Ca0.60Sr0.40WO4: An experimental and first-principles study
journal, April 2007

Photoluminescence in the CaxSr1−xWO4 system at room temperature
journal, August 2008

Growth and properties of various scheelite type mixed crystal systems
journal, June 1980

Tailoring the Mechanism of the Amorphous-to-Crystalline Phase Transition of PbTiO ₃ via Kinetically Controlled Hydrolysis
journal, September 2011

A profile refinement method for nuclear and magnetic structures
journal, June 1969

Rietveld refinement of Debye–Scherrer synchrotron X-ray data from Al ₂ O ₃
journal, April 1987

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Analysis of solid solutions stability in scheelite-type molybdates and tungstates
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Lattice dynamics study of scheelite tungstates under high pressure I. $Ba W O_{4}$
journal, October 2006

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journal, January 2016