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Title: Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca 1-xSr xWO 4 and Sr 1-xBa xWO 4 nanocrystals

Here, a series of compositionally complex scheelite-structured nanocrystals of the formula A 1-xA’ xWO 4 (A = Ca, Sr, Ba) have been prepared under benign synthesis conditions using the vapor diffusion sol–gel method. Discrete nanocrystals with sub-20 nm mean diameters were obtained after kinetically controlled hydro- lysis and polycondensation at room temperature, followed by composition-dependent thermal aging at or below 60 °C. Rietveld analysis of X-ray diffraction data and Raman spectroscopy verified the synthesis of continuous and phase-pure nanocrystal solid solutions across the entire composition space for A 1-xA’ xWO 4, where 0 ≤ x ≤ 1. Elemental analysis by X-ray photoelectron and inductively coupled plasma- atomic emission spectroscopies demonstrated excellent agreement between the nominal and experi- mentally determined elemental stoichiometries, while energy dispersive X-ray spectroscopy illustrated good spatial elemental homogeneity within these nanocrystals synthesized under benign conditions.
Authors:
 [1] ;  [1] ;  [1] ;  [1]
  1. Univ. of Southern California, Los Angeles, CA (United States). Dept. of Chemistry
Publication Date:
Grant/Contract Number:
SC0006812
Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 44; Journal Issue: 33; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Research Org:
Univ. of Southern California, Los Angeles, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY
OSTI Identifier:
1338896

Culver, Sean P., Greaney, Matthew J., Tinoco, Antonio, and Brutchey, Richard L.. Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals. United States: N. p., Web. doi:10.1039/c5dt01722j.
Culver, Sean P., Greaney, Matthew J., Tinoco, Antonio, & Brutchey, Richard L.. Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals. United States. doi:10.1039/c5dt01722j.
Culver, Sean P., Greaney, Matthew J., Tinoco, Antonio, and Brutchey, Richard L.. 2015. "Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals". United States. doi:10.1039/c5dt01722j. https://www.osti.gov/servlets/purl/1338896.
@article{osti_1338896,
title = {Low-temperature synthesis of homogeneous solid solutions of scheelite-structured Ca1-xSrxWO4 and Sr1-xBaxWO4 nanocrystals},
author = {Culver, Sean P. and Greaney, Matthew J. and Tinoco, Antonio and Brutchey, Richard L.},
abstractNote = {Here, a series of compositionally complex scheelite-structured nanocrystals of the formula A1-xA’xWO4 (A = Ca, Sr, Ba) have been prepared under benign synthesis conditions using the vapor diffusion sol–gel method. Discrete nanocrystals with sub-20 nm mean diameters were obtained after kinetically controlled hydro- lysis and polycondensation at room temperature, followed by composition-dependent thermal aging at or below 60 °C. Rietveld analysis of X-ray diffraction data and Raman spectroscopy verified the synthesis of continuous and phase-pure nanocrystal solid solutions across the entire composition space for A1-xA’xWO4, where 0 ≤ x ≤ 1. Elemental analysis by X-ray photoelectron and inductively coupled plasma- atomic emission spectroscopies demonstrated excellent agreement between the nominal and experi- mentally determined elemental stoichiometries, while energy dispersive X-ray spectroscopy illustrated good spatial elemental homogeneity within these nanocrystals synthesized under benign conditions.},
doi = {10.1039/c5dt01722j},
journal = {Dalton Transactions},
number = 33,
volume = 44,
place = {United States},
year = {2015},
month = {7}
}