Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics
Abstract
In this paper, we develop a general thermodynamic framework to investigate multicaloric effects in multiferroic materials. This is applied to the study of both magnetostructural and magnetoelectric multiferroics. Landau models with appropriate interplay between the corresponding ferroic properties (order parameters) are proposed for metamagnetic shape-memory and ferrotoroidic materials, which, respectively, belong to the two classes of multiferroics. For each ferroic property, caloric effects are quantified by the isothermal entropy change induced by the application of the corresponding thermodynamically conjugated field. The multicaloric effect is obtained as a function of the two relevant applied fields in each class of multiferroics. It is further shown that multicaloric effects comprise the corresponding contributions from caloric effects associated with each ferroic property and the cross-contribution arising from the interplay between these ferroic properties. Finally, this article is part of the themed issue ‘Taking the temperature of phase transitions in cool materials’.
- Authors:
-
[1];
- Univ. of Barcelona (Spain). Faculty of Physics. Dept. of Structure and Constituents of Matter
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Theoretical Division
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of Barcelona (Spain)
- Sponsoring Org.:
- USDOE; Interministerial Commission of Science and Technology (CICyT) (Spain)
- OSTI Identifier:
- 1338758
- Report Number(s):
- LA-UR-16-20640
Journal ID: ISSN 1364-503X
- Grant/Contract Number:
- AC52-06NA25396; MAT2013-40590-P
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences
- Additional Journal Information:
- Journal Volume: 374; Journal Issue: 2074; Journal ID: ISSN 1364-503X
- Publisher:
- Royal Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; caloric effects; multiferroics; magnetoelectric; magnetostructural; thermodynamics; solid-state physics
Citation Formats
Planes, Antoni, Castán, Teresa, and Saxena, Avadh. Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics. United States: N. p., 2016.
Web. doi:10.1098/rsta.2015.0304.
Planes, Antoni, Castán, Teresa, & Saxena, Avadh. Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics. United States. https://doi.org/10.1098/rsta.2015.0304
Planes, Antoni, Castán, Teresa, and Saxena, Avadh. Mon .
"Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics". United States. https://doi.org/10.1098/rsta.2015.0304. https://www.osti.gov/servlets/purl/1338758.
@article{osti_1338758,
title = {Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics},
author = {Planes, Antoni and Castán, Teresa and Saxena, Avadh},
abstractNote = {In this paper, we develop a general thermodynamic framework to investigate multicaloric effects in multiferroic materials. This is applied to the study of both magnetostructural and magnetoelectric multiferroics. Landau models with appropriate interplay between the corresponding ferroic properties (order parameters) are proposed for metamagnetic shape-memory and ferrotoroidic materials, which, respectively, belong to the two classes of multiferroics. For each ferroic property, caloric effects are quantified by the isothermal entropy change induced by the application of the corresponding thermodynamically conjugated field. The multicaloric effect is obtained as a function of the two relevant applied fields in each class of multiferroics. It is further shown that multicaloric effects comprise the corresponding contributions from caloric effects associated with each ferroic property and the cross-contribution arising from the interplay between these ferroic properties. Finally, this article is part of the themed issue ‘Taking the temperature of phase transitions in cool materials’.},
doi = {10.1098/rsta.2015.0304},
journal = {Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences},
number = 2074,
volume = 374,
place = {United States},
year = {Mon Jul 11 00:00:00 EDT 2016},
month = {Mon Jul 11 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 23 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Large entropy change associated with the elastocaloric effect in polycrystalline Ni-Mn-Sb-Co magnetic shape memory alloys
journal, December 2014
- Millán-Solsona, Rubén; Stern-Taulats, Enric; Vives, Eduard
- Applied Physics Letters, Vol. 105, Issue 24
Multiple Metamagnetic Transitions in the Magnetic Refrigerant
journal, October 2008
- Lyubina, Julia; Nenkov, Konstantin; Schultz, Ludwig
- Physical Review Letters, Vol. 101, Issue 17
Effects of hydrostatic pressure on the magnetism and martensitic transition of Ni–Mn–In magnetic superelastic alloys
journal, January 2008
- Mañosa, Lluís; Moya, Xavier; Planes, Antoni
- Applied Physics Letters, Vol. 92, Issue 1
Magnetic symmetry of low-dimensional multiferroics and ferroelastics
journal, May 2011
- Saxena, Avadh; Lookman, Turab
- Phase Transitions, Vol. 84, Issue 5-6
Multicaloric effect in Pb(Mn1/3Nb2/3)O3-32PbTiO3 single crystals: Modes of measurement
journal, September 2015
- Chauhan, Aditya; Patel, Satyanarayan; Vaish, Rahul
- Acta Materialia, Vol. 97
Thermodynamics of ferrotoroidic materials: Toroidocaloric effect
journal, April 2012
- Castán, Teresa; Planes, Antoni; Saxena, Avadh
- Physical Review B, Vol. 85, Issue 14
Toroid moments in electrodynamics and solid-state physics
journal, March 1990
- Dubovik, V. M.; Tugushev, V. V.
- Physics Reports, Vol. 187, Issue 4
Electric Field Control of the Magnetocaloric Effect
journal, December 2014
- Gong, Yuan-Yuan; Wang, Dun-Hui; Cao, Qing-Qi
- Advanced Materials, Vol. 27, Issue 5
Giant and reversible extrinsic magnetocaloric effects in La0.7Ca0.3MnO3 films due to strain
journal, October 2012
- Moya, X.; Hueso, L. E.; Maccherozzi, F.
- Nature Materials, Vol. 12, Issue 1
Magnetocaloric effect and its relation to shape-memory properties in ferromagnetic Heusler alloys
journal, May 2009
- Planes, Antoni; Mañosa, Lluís; Acet, Mehmet
- Journal of Physics: Condensed Matter, Vol. 21, Issue 23
Pressure-tuned magnetocaloric effect in Mn Cr CoGe
journal, July 2011
- Caron, L.; Trung, N. T.; Brück, E.
- Physical Review B, Vol. 84, Issue 2
Multicaloric effect in Pb(Mn1/3Nb2/3)O3-32PbTiO3 single crystals
journal, May 2015
- Chauhan, Aditya; Patel, Satyanarayan; Vaish, Rahul
- Acta Materialia, Vol. 89
Thermodynamics of multicaloric effects in multiferroics
journal, April 2014
- Planes, A.; Castán, T.; Saxena, A.
- Philosophical Magazine, Vol. 94, Issue 17
Theoretical description of magnetocaloric effect in the shape memory alloy exhibiting metamagnetic behavior
journal, January 2016
- L'vov, Victor A.; Kosogor, Anna; Barandiaran, Jose M.
- Journal of Applied Physics, Vol. 119, Issue 1
Inverse barocaloric effect in the giant magnetocaloric La–Fe–Si–Co compound
journal, September 2011
- Mañosa, Lluís; González-Alonso, David; Planes, Antoni
- Nature Communications, Vol. 2, Issue 1
Multiferroicity: the coupling between magnetic and polarization orders
journal, July 2009
- Wang, K. F.; Liu, J. -M.; Ren, Z. F.
- Advances in Physics, Vol. 58, Issue 4
Barocaloric and magnetocaloric effects in
journal, June 2014
- Stern-Taulats, Enric; Planes, Antoni; Lloveras, Pol
- Physical Review B, Vol. 89, Issue 21
Controlling toroidal moments by crossed electric and magnetic fields
journal, July 2013
- Baum, M.; Schmalzl, K.; Steffens, P.
- Physical Review B, Vol. 88, Issue 2
The toroidal moment in condensed-matter physics and its relation to the magnetoelectric effect
journal, October 2008
- Spaldin, Nicola A.; Fiebig, Manfred; Mostovoy, Maxim
- Journal of Physics: Condensed Matter, Vol. 20, Issue 43
Monte Carlo study of the influence of antiferromagnetic exchange interactions on the phase transitions of ferromagnetic alloys
journal, November 2008
- Buchelnikov, V. D.; Entel, P.; Taskaev, S. V.
- Physical Review B, Vol. 78, Issue 18
Caloric effects induced by magnetic and mechanical fields in a Ni Mn Ga Co magnetic shape memory alloy
journal, May 2011
- Castillo-Villa, P. O.; Soto-Parra, D. E.; Matutes-Aquino, J. A.
- Physical Review B, Vol. 83, Issue 17
Recent Progress and Future Perspectives in Magnetic and Metamagnetic Shape-Memory Heusler Alloys
journal, January 2013
- Planes, Antoni; Mañosa, Lluís; Acet, Mehmet
- Materials Science Forum, Vol. 738-739
Elastocaloric effect in ferroelectric ceramics
journal, April 2015
- Chauhan, Aditya; Patel, Satyanarayan; Vaish, Rahul
- Applied Physics Letters, Vol. 106, Issue 17
Observation of ferrotoroidic domains
journal, October 2007
- Van Aken, Bas B.; Rivera, Jean-Pierre; Schmid, Hans
- Nature, Vol. 449, Issue 7163
Caloric materials near ferroic phase transitions
journal, April 2014
- Moya, X.; Kar-Narayan, S.; Mathur, N. D.
- Nature Materials, Vol. 13, Issue 5
Giant barocaloric effects at low pressure in ferrielectric ammonium sulphate
journal, November 2015
- Lloveras, P.; Stern-Taulats, E.; Barrio, M.
- Nature Communications, Vol. 6, Issue 1
Giant elastocaloric effect in ferroelectric Ba Sr TiO alloys from first-principles
journal, September 2012
- Lisenkov, S.; Ponomareva, I.
- Physical Review B, Vol. 86, Issue 10
Monte Carlo simulations of the magnetocaloric effect in magnetic Ni–Mn– X ( X = Ga, In) Heusler alloys
journal, January 2011
- Buchelnikov, V. D.; Sokolovskiy, V. V.; Taskaev, S. V.
- Journal of Physics D: Applied Physics, Vol. 44, Issue 6
Anisotropy-enhanced giant reversible rotating magnetocaloric effect in HoMn 2 O 5 single crystals
journal, June 2014
- Balli, M.; Jandl, S.; Fournier, P.
- Applied Physics Letters, Vol. 104, Issue 23
Thermally Mediated Mechanism to Enhance Magnetoelectric Coupling in Multiferroics
journal, May 2015
- Chang, C. -M.; Mani, B. K.; Lisenkov, S.
- Physical Review Letters, Vol. 114, Issue 17
Entropy change linked to the martensitic transformation in metamagnetic shape memory alloys
journal, April 2012
- Recarte, V.; Pérez-Landazábal, J. I.; Sánchez-Alarcos, V.
- Acta Materialia, Vol. 60, Issue 6-7
Entropy change and effect of magnetic field on martensitic transformation in a metamagnetic Ni–Co–Mn–In shape memory alloy
journal, May 2009
- Kustov, S.; Corró, M. L.; Pons, J.
- Applied Physics Letters, Vol. 94, Issue 19
Barocaloric effect in the magnetocaloric prototype Gd5Si2Ge2
journal, August 2012
- Yuce, Suheyla; Barrio, Maria; Emre, Baris
- Applied Physics Letters, Vol. 101, Issue 7
Multicaloric effect in bi-layer multiferroic composites
journal, November 2015
- Vopson, M. M.; Zhou, D.; Caruntu, G.
- Applied Physics Letters, Vol. 107, Issue 18
Giant Rotating Magnetocaloric Effect in the Region of Spin-Reorientation Transition in the Single Crystal
journal, September 2010
- Nikitin, S. A.; Skokov, K. P.; Koshkid’ko, Yu. S.
- Physical Review Letters, Vol. 105, Issue 13
The effect of heat treatments on Ni43Mn42Co4Sn11 meta-magnetic shape memory alloys for magnetic refrigeration
journal, August 2014
- Bruno, Nickolaus M.; Yegin, Cengiz; Karaman, Ibrahim
- Acta Materialia, Vol. 74
Pressure induced magnetic and magnetocaloric properties in NiCoMnSb Heusler alloy
journal, September 2009
- Nayak, Ajaya K.; Suresh, K. G.; Nigam, A. K.
- Journal of Applied Physics, Vol. 106, Issue 5
The magnetic and magnetocaloric properties of Gd5Ge2Si2 compound under hydrostatic pressure
journal, May 2005
- Carvalho, A. Magnus G.; Alves, Cleber S.; de Campos, Ariana
- Journal of Applied Physics, Vol. 97, Issue 10
Primary ferrotoroidicity in antiferromagnets
journal, September 2015
- Tolédano, P.; Ackermann, M.; Bohatý, L.
- Physical Review B, Vol. 92, Issue 9
Hydrostatic pressure-induced modifications of structural transitions lead to large enhancements of magnetocaloric effects in MnNiSi-based systems
journal, January 2015
- Samanta, Tapas; Lepkowski, Daniel L.; Saleheen, Ahmad Us
- Physical Review B, Vol. 91, Issue 2
Martensitic and Magnetic Transformation Behaviors in Heusler-Type NiMnIn and NiCoMnIn Metamagnetic Shape Memory Alloys
journal, April 2007
- Ito, W.; Imano, Y.; Kainuma, R.
- Metallurgical and Materials Transactions A, Vol. 38, Issue 4
Giant Magnetocaloric Effect in
journal, June 1997
- Pecharsky, V. K.; Gschneidner, Jr., K. A.
- Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497
Giant solid-state barocaloric effect in the Ni–Mn–In magnetic shape-memory alloy
journal, April 2010
- Mañosa, Lluís; González-Alonso, David; Planes, Antoni
- Nature Materials, Vol. 9, Issue 6
Giant barocaloric effect enhanced by the frustration of the antiferromagnetic phase in Mn3GaN
journal, October 2014
- Matsunami, Daichi; Fujita, Asaya; Takenaka, Koshi
- Nature Materials, Vol. 14, Issue 1
Classifying multiferroics: Mechanisms and effects
journal, March 2009
- Khomskii, Daniel
- Physics, Vol. 2
Advanced materials for solid-state refrigeration
journal, January 2013
- Mañosa, Lluís; Planes, Antoni; Acet, Mehmet
- Journal of Materials Chemistry A, Vol. 1, Issue 16
Towards a microscopic theory of toroidal moments in bulk periodic crystals
journal, December 2007
- Ederer, Claude; Spaldin, Nicola A.
- Physical Review B, Vol. 76, Issue 21
General analysis of magnetic refrigeration and its optimization using a new concept: maximization of refrigerant capacity
journal, December 1985
- Wood, M. E.; Potter, W. H.
- Cryogenics, Vol. 25, Issue 12
Direct measurements of inverse magnetocaloric effects in metamagnetic shape-memory alloy NiCoMnIn
journal, December 2014
- Kihara, T.; Xu, X.; Ito, W.
- Physical Review B, Vol. 90, Issue 21
Pressure-Induced Colossal Magnetocaloric Effect in MnAs
journal, November 2004
- Gama, Sergio; Coelho, Adelino A.; de Campos, Ariana
- Physical Review Letters, Vol. 93, Issue 23
Electric-field control of magnetic order above room temperature
journal, January 2014
- Cherifi, R. O.; Ivanovskaya, V.; Phillips, L. C.
- Nature Materials, Vol. 13, Issue 4
Works referencing / citing this record:
Materials with Giant Mechanocaloric Effects: Cooling by Strength
journal, December 2016
- Mañosa, Lluís; Planes, Antoni
- Advanced Materials, Vol. 29, Issue 11
Making a Cool Choice: The Materials Library of Magnetic Refrigeration
journal, July 2019
- Gottschall, Tino; Skokov, Konstantin P.; Fries, Maximilian
- Advanced Energy Materials, Vol. 9, Issue 34
Energy Applications of Magnetocaloric Materials
journal, March 2020
- Kitanovski, Andrej
- Advanced Energy Materials, Vol. 10, Issue 10
Novel mechanocaloric materials for solid-state cooling applications
journal, December 2019
- Cazorla, Claudio
- Applied Physics Reviews, Vol. 6, Issue 4
Giant multicaloric response of bulk
journal, March 2017
- Stern-Taulats, Enric; Castán, Teresa; Planes, Antoni
- Physical Review B, Vol. 95, Issue 10
Reversible low-field magnetocaloric effect in Ni-Mn-In-based Heusler alloys
journal, August 2019
- Liu, Jun; You, Xinmin; Huang, Bowei
- Physical Review Materials, Vol. 3, Issue 8
Multicaloric materials and effects
journal, April 2018
- Stern-Taulats, Enric; Castán, Teresa; Mañosa, Lluís
- MRS Bulletin, Vol. 43, Issue 4
Multicaloric materials and effects
text, January 2018
- Stern-Taulats, E.; Castán, T.; Mañosa, L.
- Apollo - University of Cambridge Repository
Novel Mechanocaloric Materials for Solid-State Cooling Applications
preprint, January 2019
- Cazorla, Claudio
- arXiv
Novel mechanocaloric materials for solid-state cooling applications
journal, December 2019
- Cazorla, Claudio
- Applied Physics Reviews, Vol. 6, Issue 4