Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes

Li, Xinle; Van Zeeland, Ryan; Maligal-Ganesh, Raghu V.; Pei, Yuchen; Power, Gregory; Stanley, Levi; Huang, Wenyu

doi:10.1021/acscatal.6b01753

Title: Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes

Journal Article · Tue Aug 09 04:00:00 UTC 2016 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.6b01753 · OSTI ID:1337683

Li, Xinle ^[1]; Van Zeeland, Ryan ^[2]; Maligal-Ganesh, Raghu V. ^[1]; Pei, Yuchen ^[1]; Power, Gregory ^[2]; Stanley, Levi ^[2]; Huang, Wenyu ^[1]

Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States)
Iowa State Univ., Ames, IA (United States)

A series of mixed-linker bipyridyl metal–organic framework (MOF)-supported palladium(II) catalysts were used to elucidate the electronic and steric effects of linker substitution on the activity of these catalysts in the context of Suzuki–Miyaura cross-coupling reactions. m-6,6'-Me₂bpy-MOF-PdCl₂ exhibited 110- and 496-fold enhancements in activity compared to nonfunctionalized m-bpy-MOF-PdCl₂ and m-4,4'-Me₂bpy-MOF-PdCl₂, respectively. Furthermore, this result clearly demonstrates that the stereoelectronic properties of metal-binding linker units are critical to the activity of single-site organometallic catalysts in MOFs and highlights the importance of linker engineering in the design and development of efficient MOF catalysts.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1337683

Report Number(s):: IS-J--9087

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 9 Vol. 6; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Suzuki−Miyaura cross-coupling
bipyridyl linker
heterogeneous catalysis
isoreticular metal−organic frameworks
single-site catalyst
structure−activity relationship

Title: Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes

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