Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis

Bu, Lingzheng; Zhang, Nan; Guo, Shaojun; Zhang, Xu; Li, Jing; Yao, Jianlin; Wu, Tao; Lu, Gang; Ma, Jing-Yuan; Su, Dong; Huang, Xiaoqing

doi:10.1126/science.aah6133

Title: Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis

Journal Article · Thu Dec 15 23:00:00 EST 2016 · Science

DOI: https://doi.org/10.1126/science.aah6133 · OSTI ID:1336209

Bu, Lingzheng ^[1]; Zhang, Nan ^[1]; Guo, Shaojun ^[2]; Zhang, Xu ^[3]; Li, Jing ^[4]; Yao, Jianlin ^[1]; Wu, Tao ^[1]; Lu, Gang ^[3]; Ma, Jing-Yuan ^[5]; Su, Dong ^[4]; Huang, Xiaoqing ^[1]

Soochow Univ., Jiangsu (China). College of Chemistry, Chemical Engineering and Materials Science
Peking Univ., Beijing (China). College of Engineering, Dept. of Materials Science and Engineering and Dept. of Energy and Resources Engineering; Peking Univ., Beijing (China). College of Engineering, Beijing Innovation Center for Engineering Science and Advanced Technology (BIC-ESAT); Peking Univ., Beijing (China). College of Engineering, Key Lab. of Theory and Technology of Advanced Batteries Materials
California State Univ. (CalState), Northridge, CA (United States). Dept. of Physics and Astronomy
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Chinese Academy of Sciences (CAS), Shanghai (China). Shanghai Synchrotron Radiation Facility, Shanghai Inst. of Applied Physics

Compressive surface strains have been necessary to boost oxygen reduction reaction (ORR) activity in core/shell M/Pt catalysts (where M can be Ni, Co, Fe). We report a class of PtPb/Pt core/shell nanoplate catalysts that exhibit large biaxial tensile strains. The stable Pt (110) facets of the nanoplates have high ORR specific and mass activities that reach 7.8 milliampere per centimeter square and 4.3 ampere per milligram of platinum at 0.9 volts versus the reversible hydrogen electrode (RHE), respectively. Density functional theory calculations revealed that the edge-Pt and top (bottom)-Pt (110) facets undergo large tensile strains that help optimize the Pt-O bond strength. The intermetallic core and uniform 4 layers of Pt shell of the PtPb/Pt nanoplates appear to underlie the high endurance of these catalysts, which can undergo 50,000 voltage cycles with negligible activity decay and no apparent structure and composition changes.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1336209

Report Number(s):: BNL--113227-2016-JA; KC0403020

Journal Information:: Science, Journal Name: Science Journal Issue: 6318 Vol. 354; ISSN 0036-8075

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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A Simple Mechanical Method to Modulate the Electrochemical Electrosorption Processes at Metal Surfaces Yuan, Aiting; Zhang, Haixia; Deng, Qibo Molecules, Vol. 24, Issue 20 https://doi.org/10.3390/molecules24203662	journal	October 2019
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Tunable Electrochemistry of Electrosynthesized Copper Metal-Organic Frameworks Ji, Liudi; Wang, Juan; Wu, Kangbing Advanced Functional Materials, Vol. 28, Issue 13 https://doi.org/10.1002/adfm.201706961	journal	January 2018
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Replicating the Defect Structures on Ultrathin Rh Nanowires with Pt to Achieve Superior Electrocatalytic Activity toward Ethanol Oxidation Liu, Kai; Wang, Wei; Guo, Penghui Advanced Functional Materials, Vol. 29, Issue 2 https://doi.org/10.1002/adfm.201806300	journal	November 2018
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Oxygen Vacancies Dominated NiS ₂ /CoS ₂ Interface Porous Nanowires for Portable Zn-Air Batteries Driven Water Splitting Devices Yin, Jie; Li, Yuxuan; Lv, Fan Advanced Materials, Vol. 29, Issue 47 https://doi.org/10.1002/adma.201704681	journal	November 2017
Lithium Electrochemical Tuning for Electrocatalysis Lu, Zhiyi; Jiang, Kun; Chen, Guangxu Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201800978	journal	September 2018
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Metal‐Based Nanocatalysts via a Universal Design on Cellular Structure Zhao, Yajing; Min, Xin; Ding, Zhengping Advanced Science, Vol. 7, Issue 3 https://doi.org/10.1002/advs.201902051	journal	November 2019
Tuning Surface Structure of Pd ₃ Pb/Pt _n Pb Nanocrystals for Boosting the Methanol Oxidation Reaction Wu, Xingqiao; Jiang, Yi; Yan, Yucong Advanced Science, Vol. 6, Issue 24 https://doi.org/10.1002/advs.201902249	journal	October 2019
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Efficient Bifunctional Polyalcohol Oxidation and Oxygen Reduction Electrocatalysts Enabled by Ultrathin PtPdM (M = Ni, Fe, Co) Nanosheets Lai, Jianping; Lin, Fei; Tang, Yonghua Advanced Energy Materials, Vol. 9, Issue 8 https://doi.org/10.1002/aenm.201800684	journal	January 2019
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Reversible loss of core–shell structure for Ni–Au bimetallic nanoparticles during CO2 hydrogenation Zhang, Xiaoben; Han, Shaobo; Zhu, Beien Nature Catalysis, Vol. 3, Issue 4 https://doi.org/10.1038/s41929-020-0440-2	journal	March 2020
Gallic acid-assisted synthesis of Pd uniformly anchored on porous N-rGO as efficient electrocatalyst for microbial fuel cells Wu, Xiao-Tong; Li, Jie-Cheng; Pan, Qiu-Ren Dalton Transactions, Vol. 47, Issue 5 https://doi.org/10.1039/c7dt04063f	journal	January 2018
Strain-induced Stranski–Krastanov growth of Pd@Pt core–shell hexapods and octapods as electrocatalysts for methanol oxidation Xiong, Yalin; Ma, Yanling; Li, Junjie Nanoscale, Vol. 9, Issue 31 https://doi.org/10.1039/c7nr02638b	journal	January 2017
Ag ₃ PO ₄ electrocatalyst for oxygen reduction reaction: enhancement from positive charge Qin, Yong; Li, Fan; Tu, Peng RSC Advances, Vol. 8, Issue 10 https://doi.org/10.1039/c7ra12643c	journal	January 2018
Bridged-multi-octahedral cobalt oxide nanocrystals with a Co-terminated surface as an oxygen evolution and reduction electrocatalyst Yiliguma, Yiliguma; Wang, Zhijie; Xu, Wenhao Journal of Materials Chemistry A, Vol. 5, Issue 16 https://doi.org/10.1039/c7ta01013c	journal	January 2017
Hierarchically 3D porous films electrochemically constructed on gas–liquid–solid three-phase interface for energy application Wang, Mingyong; Yu, Xiangtao; Wang, Zhi Journal of Materials Chemistry A, Vol. 5, Issue 20 https://doi.org/10.1039/c7ta02519j	journal	January 2017
Ordered mesoporous FeN x -doped carbon: a class of highly active and stable catalysts in acids, bases and polymer electrolyte membrane fuel cells Jiang, Rongzhong; Tran, Dat T.; McClure, Joshua P. Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c7ta10555j	journal	January 2018
Dynamic charge acceptance and hydrogen evolution of a new MXene additive in advanced lead-acid batteries via a rapid screening three-electrode method Kang, Shuai; Shang, Mingwei; Spence, Matthew A. Chemical Communications, Vol. 54, Issue 28 https://doi.org/10.1039/c8cc00086g	journal	January 2018
Unconventional morphologies of CoO nanocrystals via controlled oxidation of cobalt oleate precursors Yiliguma, Yiliguma; Xu, Wenhao; Wang, Zhijie Chemical Communications, Vol. 54, Issue 31 https://doi.org/10.1039/c8cc01060a	journal	January 2018
Shell thickness controlled core–shell Fe ₃ O ₄ @CoO nanocrystals as efficient bifunctional catalysts for the oxygen reduction and evolution reactions Zhou, Lingshan; Deng, Binglu; Jiang, Zhongqing Chemical Communications, Vol. 55, Issue 4 https://doi.org/10.1039/c8cc09140d	journal	January 2019
Intermetallic Pd ₃ Pb square nanoplates as highly efficient electrocatalysts for oxygen reduction reaction Luo, Sai; Tang, Min; Wu, Xingqiao CrystEngComm, Vol. 21, Issue 2 https://doi.org/10.1039/c8ce01490f	journal	January 2019
Intrinsic effects of strain on low-index surfaces of platinum: roles of the five 5d orbitals Zheng, Xingqun; Li, Li; Li, Jing Physical Chemistry Chemical Physics, Vol. 21, Issue 6 https://doi.org/10.1039/c8cp07556e	journal	January 2019
DNA metallization: principles, methods, structures, and applications Chen, Zhaowei; Liu, Chaoqun; Cao, Fangfang Chemical Society Reviews, Vol. 47, Issue 11 https://doi.org/10.1039/c8cs00011e	journal	January 2018
Multimetallic nanosheets: synthesis and applications in fuel cells Zeb Gul Sial, Muhammad Aurang; Ud Din, Muhammad Aizaz; Wang, Xun Chemical Society Reviews, Vol. 47, Issue 16 https://doi.org/10.1039/c8cs00113h	journal	January 2018
Hollow nanoparticles as emerging electrocatalysts for renewable energy conversion reactions Park, Jongsik; Kwon, Taehyun; Kim, Jun Chemical Society Reviews, Vol. 47, Issue 22 https://doi.org/10.1039/c8cs00336j	journal	January 2018
Strain engineering of metal-based nanomaterials for energy electrocatalysis Xia, Zhonghong; Guo, Shaojun Chemical Society Reviews, Vol. 48, Issue 12 https://doi.org/10.1039/c8cs00846a	journal	January 2019
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Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER Jiang, Hao; Gu, Jinxing; Zheng, Xusheng Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/c8ee03276a	journal	January 2019
‘Painting’ nanostructured metals—playing with liquid metal Wang, Zhenbin; Wang, Ying; Gao, Hui Nanoscale Horizons, Vol. 3, Issue 4 https://doi.org/10.1039/c8nh00045j	journal	January 2018
Realizing the extraction of carbon from WC for in situ formation of W/WC heterostructures with efficient photoelectrochemical hydrogen evolution Kou, Zongkui; Wang, Tingting; Pu, Zonghua Nanoscale Horizons, Vol. 4, Issue 1 https://doi.org/10.1039/c8nh00275d	journal	January 2019
Hemi-core@frame AuCu@IrNi nanocrystals as active and durable bifunctional catalysts for the water splitting reaction in acidic media Park, Jongsik; Choi, Songa; Oh, Aram Nanoscale Horizons, Vol. 4, Issue 3 https://doi.org/10.1039/c8nh00520f	journal	January 2019
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Open-air spray plasma deposited UV-absorbing nanocomposite coatings Ding, Yichuan; Dong, Siming; Hilt, Florian Nanoscale, Vol. 10, Issue 30 https://doi.org/10.1039/c8nr04095h	journal	January 2018
A self-supported nanoporous PtGa film as an efficient multifunctional electrocatalyst for energy conversion Wang, Ying; Wang, Zhenbin; Zhang, Jie Nanoscale, Vol. 10, Issue 36 https://doi.org/10.1039/c8nr04741c	journal	January 2018
Porous platinum–silver bimetallic alloys: surface composition and strain tunability toward enhanced electrocatalysis Zhang, Erhuan; Ma, Fenfen; Liu, Jia Nanoscale, Vol. 10, Issue 46 https://doi.org/10.1039/c8nr06192k	journal	January 2018
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3D PtAu nanoframe superstructure as a high-performance carbon-free electrocatalyst Yoo, Sungjae; Cho, Sanghyun; Kim, Dajeong Nanoscale, Vol. 11, Issue 6 https://doi.org/10.1039/c8nr08231f	journal	January 2019
Direct fabrication of bi-metallic PdRu nanorod assemblies for electrochemical ammonia synthesis Wang, Hongjing; Li, Yinghao; Yang, Dandan Nanoscale, Vol. 11, Issue 12 https://doi.org/10.1039/c8nr10398d	journal	January 2019
Cu nanocrystal enhancement of C ₃ N ₄ /Cu hetero-structures and new applications in photo-electronic catalysis: hydrazine oxidation and redox reactions of organic molecules Ji, Muwei; Huang, Jintao; Zhang, Kai Inorganic Chemistry Frontiers, Vol. 5, Issue 10 https://doi.org/10.1039/c8qi00594j	journal	January 2018
Porous Pt ₃ Ni with enhanced activity and durability towards oxygen reduction reaction Mi, Shuying; Cheng, Na; Jiang, Hao RSC Advances, Vol. 8, Issue 28 https://doi.org/10.1039/c8ra02219d	journal	January 2018
Enhanced electrocatalytic performance of platinum nanoparticles on thiolated polyaniline-multiwalled carbon nanotubes for methanol oxidation Su, Zhaohong; Li, Chaorong; Cheng, Yongbing RSC Advances, Vol. 8, Issue 59 https://doi.org/10.1039/c8ra06246c	journal	January 2018
Synthesis of ultrathin wrinkle-free PdCu alloy nanosheets for modulating d-band electrons for efficient methanol oxidation Fan, Jinchang; Yu, Shansheng; Qi, Kun Journal of Materials Chemistry A, Vol. 6, Issue 18 https://doi.org/10.1039/c8ta01912f	journal	January 2018
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TePbPt alloy nanotube as electrocatalyst with enhanced performance towards methanol oxidation reaction Yang, Long; Li, Guoqiang; Ge, Junjie Journal of Materials Chemistry A, Vol. 6, Issue 35 https://doi.org/10.1039/c8ta04132f	journal	January 2018
Interfacial proton enrichment enhances proton-coupled electrocatalytic reactions Zhao, Yue; Ding, Yu; Qiao, Bin Journal of Materials Chemistry A, Vol. 6, Issue 36 https://doi.org/10.1039/c8ta06856a	journal	January 2018
Hyperbranched PdRu nanospine assemblies: an efficient electrocatalyst for formic acid oxidation Wang, Hongjing; Li, Yinghao; Li, Chunjie Journal of Materials Chemistry A, Vol. 6, Issue 36 https://doi.org/10.1039/c8ta06908e	journal	January 2018
One-pot synthesis of bi-metallic PdRu tripods as an efficient catalyst for electrocatalytic nitrogen reduction to ammonia Wang, Hongjing; Li, Yinghao; Li, Chunjie Journal of Materials Chemistry A, Vol. 7, Issue 2 https://doi.org/10.1039/c8ta09482a	journal	January 2019
Ordered platinum–bismuth intermetallic clusters with Pt-skin for a highly efficient electrochemical ethanol oxidation reaction Zhang, Bin-Wei; Lai, Wei-Hong; Sheng, Tian Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta09553a	journal	January 2019
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Lattice-strained palladium nanoparticles as active catalysts for the oxygen reduction reaction Lin, Jing-Yang; Xi, Cong; Li, Zhe Chemical Communications, Vol. 55, Issue 21 https://doi.org/10.1039/c9cc00447e	journal	January 2019
Regulating locations of active sites: a novel strategy to greatly improve the stability of PtAu electrocatalysts Xu, Suying; Hou, Wenjie; Jiang, Rui Chemical Communications, Vol. 55, Issue 90 https://doi.org/10.1039/c9cc07275f	journal	January 2019
Ligand-protected atomically precise gold nanoclusters as model catalysts for oxidation reactions Tian, Shubo; Cao, Yitao; Chen, Tiankai Chemical Communications, Vol. 56, Issue 8 https://doi.org/10.1039/c9cc08215h	journal	January 2020
Effects of a graphene substrate on the structure and properties of atomically thin metal sheets Zhou, Gang Physical Chemistry Chemical Physics, Vol. 22, Issue 2 https://doi.org/10.1039/c9cp05466a	journal	January 2020
Anisotropic nanomaterials for shape-dependent physicochemical and biomedical applications Yang, Lijiao; Zhou, Zijian; Song, Jibin Chemical Society Reviews, Vol. 48, Issue 19 https://doi.org/10.1039/c9cs00011a	journal	January 2019
Recent advancements in Pt-nanostructure-based electrocatalysts for the oxygen reduction reaction Mahata, Arup; Nair, Akhil S.; Pathak, Biswarup Catalysis Science & Technology, Vol. 9, Issue 18 https://doi.org/10.1039/c9cy00895k	journal	January 2019
Precious metal nanocrystals for renewable energy electrocatalysis: structural design and controlled synthesis Luo, Mingchuan; Yang, Yong; Guo, Shaojun Dalton Transactions, Vol. 49, Issue 2 https://doi.org/10.1039/c9dt04351a	journal	January 2020
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Pd@Rh core–shell nanocrystals with well-defined facets and their enhanced catalytic performance towards CO oxidation Choi, Sang-Il; Young, Allison; Lee, Sujin R. Nanoscale Horizons, Vol. 4, Issue 5 https://doi.org/10.1039/c9nh00360f	journal	January 2019
Trimetallic PtPdCo mesoporous nanopolyhedra with hollow cavities Xu, You; Li, Yinghao; Qian, Xiaoqian Nanoscale, Vol. 11, Issue 11 https://doi.org/10.1039/c9nr00598f	journal	January 2019
Deviations from Vegard's law and evolution of the electrocatalytic activity and stability of Pt-based nanoalloys inside fuel cells by in operando X-ray spectroscopy and total scattering Petkov, Valeri; Maswadeh, Yazan; Vargas, Jorge A. Nanoscale, Vol. 11, Issue 12 https://doi.org/10.1039/c9nr01069f	journal	January 2019
The rational design of sandwich-like MnO ₂ –Pd–CeO ₂ hollow spheres with enhanced activity and stability for CO oxidation Zhang, Jian; Li, Tong; Wang, Chang-An Nanoscale, Vol. 11, Issue 14 https://doi.org/10.1039/c9nr01737b	journal	January 2019
Galvanic replacement of liquid metal galinstan with Pt for the synthesis of electrocatalytically active nanomaterials Oloye, Olawale; Tang, Cheng; Du, Aijun Nanoscale, Vol. 11, Issue 19 https://doi.org/10.1039/c9nr02458a	journal	January 2019
Locally-ordered PtNiPb ternary nano-pompons as efficient bifunctional oxygen reduction and methanol oxidation catalysts Cheng, Na; Zhang, Ling; Jiang, Hao Nanoscale, Vol. 11, Issue 36 https://doi.org/10.1039/c9nr04053f	journal	January 2019
Monodisperse nanoparticles for catalysis and nanomedicine Muzzio, Michelle; Li, Junrui; Yin, Zhouyang Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr06080d	journal	January 2019
Multifunctional inorganic nanomaterials for energy applications Wang, Huilin; Liang, Xitong; Wang, Jiutian Nanoscale, Vol. 12, Issue 1 https://doi.org/10.1039/c9nr07008g	journal	January 2020
Tuning the electronic structure of PtRu bimetallic nanoparticles for promoting the hydrogen oxidation reaction in alkaline media Long, Chang; Wang, Kun; Shi, Yanan Inorganic Chemistry Frontiers, Vol. 6, Issue 10 https://doi.org/10.1039/c9qi00942f	journal	January 2019
One-pot synthesis of hollow hydrangea Au nanoparticles as a dual catalyst with SERS activity for in situ monitoring of a reduction reaction Qin, Yazhou; Lu, Yuxiang; Pan, Wufan RSC Advances, Vol. 9, Issue 18 https://doi.org/10.1039/c9ra00733d	journal	January 2019
A dinuclear cobalt cluster as electrocatalyst for oxygen reduction reaction Li, Yun-Wu; Zhang, Wen-Jie; Li, Chun-Xia RSC Advances, Vol. 9, Issue 72 https://doi.org/10.1039/c9ra08068f	journal	January 2019
Optimal coordination-site exposure engineering in porous platinum for outstanding oxygen reduction performance Cheng, Han; Liu, Si; Hao, Zikai Chemical Science, Vol. 10, Issue 21 https://doi.org/10.1039/c9sc01078e	journal	January 2019
Pt-rare earth metal alloy/metal oxide catalysts for oxygen reduction and alcohol oxidation reactions: an overview Peera, Shaik Gouse; Lee, Tae Gwan; Sahu, Akhila Kumar Sustainable Energy & Fuels, Vol. 3, Issue 8 https://doi.org/10.1039/c9se00082h	journal	January 2019
Tuning the surface segregation composition of a PdCo alloy by the atmosphere for increasing electrocatalytic activity Li, Tongtong; Wang, Rong; Yang, Minghe Sustainable Energy & Fuels, Vol. 4, Issue 1 https://doi.org/10.1039/c9se00620f	journal	January 2020
Sub-nanometer Pt cluster decoration enhances the oxygen reduction reaction performances of NiO _x supported Pd nano-islands Bhalothia, Dinesh; Dai, Sheng; Wang, Sheng-Po Sustainable Energy & Fuels, Vol. 4, Issue 2 https://doi.org/10.1039/c9se00884e	journal	January 2020
Nanoporous high-entropy alloys for highly stable and efficient catalysts Qiu, Hua-Jun; Fang, Gang; Wen, Yuren Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/c9ta00505f	journal	January 2019
Facile synthesis of polyacrylonitrile-based N/S-codoped porous carbon as an efficient oxygen reduction electrocatalyst for zinc–air batteries Li, Guodong; Pei, Lei; Wu, Yu Journal of Materials Chemistry A, Vol. 7, Issue 18 https://doi.org/10.1039/c9ta02256b	journal	January 2019
Atomically dispersed Fe–N _x active sites within hierarchical mesoporous carbon as efficient electrocatalysts for the oxygen reduction reaction Gu, Wenling; Wu, Maochun; Sun, Jing Journal of Materials Chemistry A, Vol. 7, Issue 35 https://doi.org/10.1039/c9ta06128b	journal	January 2019
Advanced engineering of core/shell nanostructures for electrochemical carbon dioxide reduction Shao, Qi; Wang, Pengtang; Liu, Shangheng Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta07016h	journal	January 2019
Shape-controlled Pd nanocrystal–polyaniline heteronanostructures with modulated polyaniline thickness for efficient electrochemical ethanol oxidation Kim, Heon Chul; Kim, Yena; Bando, Yoshio Journal of Materials Chemistry A, Vol. 7, Issue 38 https://doi.org/10.1039/c9ta08349a	journal	January 2019
Hydroxyl group modification improves the electrocatalytic ORR and OER activity of graphene supported single and bi-metal atomic catalysts (Ni, Co, and Fe) Zhao, Xiaomei; Liu, Xia; Huang, Baoyu Journal of Materials Chemistry A, Vol. 7, Issue 42 https://doi.org/10.1039/c9ta08661g	journal	January 2019
Catalyst design by scanning probe block copolymer lithography Huang, Liliang; Chen, Peng-Cheng; Liu, Mohan Proceedings of the National Academy of Sciences, Vol. 115, Issue 15 https://doi.org/10.1073/pnas.1800884115	journal	March 2018
Recent progress in the synthesis and applications of 2D metal nanosheets Pei, Yuantao; Huang, Liang; Wang, Junkai Nanotechnology, Vol. 30, Issue 22 https://doi.org/10.1088/1361-6528/ab0642	journal	March 2019
All-metallic nanorattles consisting of a Pt core and a mesoporous PtPd shell for enhanced electrocatalysis Wang, Hongjing; Yin, Shuli; Li, Chunjie Nanotechnology, Vol. 30, Issue 47 https://doi.org/10.1088/1361-6528/ab3c94	journal	September 2019
Integration mesoporous surface and hollow cavity into PtPdRh nano-octahedra for enhanced oxygen reduction electrocatalysis Deng, Kai; Xu, You; Li, Yinghao Nanotechnology, Vol. 31, Issue 2 https://doi.org/10.1088/1361-6528/ab46d8	journal	October 2019
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Oxygen Reduction Reaction Catalyzed by Noble Metal Clusters Tang, Zhenghua; Wu, Wen; Wang, Kai Catalysts, Vol. 8, Issue 2 https://doi.org/10.3390/catal8020065	journal	February 2018
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