Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis

Bu, Lingzheng; Zhang, Nan; Guo, Shaojun; Zhang, Xu; Li, Jing; Yao, Jianlin; Wu, Tao; Lu, Gang; Ma, Jing-Yuan; Su, Dong; Huang, Xiaoqing

doi:10.1126/science.aah6133

Title: Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis

Abstract

Compressive surface strains have been necessary to boost oxygen reduction reaction (ORR) activity in core/shell M/Pt catalysts (where M can be Ni, Co, Fe). We report a class of PtPb/Pt core/shell nanoplate catalysts that exhibit large biaxial tensile strains. The stable Pt (110) facets of the nanoplates have high ORR specific and mass activities that reach 7.8 milliampere per centimeter square and 4.3 ampere per milligram of platinum at 0.9 volts versus the reversible hydrogen electrode (RHE), respectively. Density functional theory calculations revealed that the edge-Pt and top (bottom)-Pt (110) facets undergo large tensile strains that help optimize the Pt-O bond strength. The intermetallic core and uniform 4 layers of Pt shell of the PtPb/Pt nanoplates appear to underlie the high endurance of these catalysts, which can undergo 50,000 voltage cycles with negligible activity decay and no apparent structure and composition changes.

Authors:

Bu, Lingzheng ^[1]; Zhang, Nan ^[1]; Guo, Shaojun ^[2]; Zhang, Xu ^[3]; Li, Jing ^[4]; Yao, Jianlin ^[1]; Wu, Tao ^[1]; Lu, Gang ^[3]; Ma, Jing-Yuan ^[5]; Su, Dong ^[4]; Huang, Xiaoqing ^[1]

Soochow Univ., Jiangsu (China). College of Chemistry, Chemical Engineering and Materials Science
Peking Univ., Beijing (China). College of Engineering, Dept. of Materials Science and Engineering and Dept. of Energy and Resources Engineering; Peking Univ., Beijing (China). College of Engineering, Beijing Innovation Center for Engineering Science and Advanced Technology (BIC-ESAT); Peking Univ., Beijing (China). College of Engineering, Key Lab. of Theory and Technology of Advanced Batteries Materials
California State Univ. (CalState), Northridge, CA (United States). Dept. of Physics and Astronomy
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Chinese Academy of Sciences (CAS), Shanghai (China). Shanghai Synchrotron Radiation Facility, Shanghai Inst. of Applied Physics

Publication Date:: Fri Dec 16 00:00:00 EST 2016

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1336209

Report Number(s):: BNL-113227-2016-JA
Journal ID: ISSN 0036-8075; R&D Project: 16060; 16060; KC0403020

Grant/Contract Number:: SC0012704; W911NF-11-1-0353

Resource Type:: Accepted Manuscript

Journal Name:: Science

Additional Journal Information:: Journal Volume: 354; Journal Issue: 6318; Journal ID: ISSN 0036-8075

Publisher:: AAAS

Country of Publication:: United States

Language:: English

Subject:: 29 ENERGY PLANNING, POLICY, AND ECONOMY; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; PtPb/Pt; Core/Shell Nanoplate; Oxygen Reduction; Center for Functional Nanomaterials

Citation Formats


                    Bu, Lingzheng, Zhang, Nan, Guo, Shaojun, Zhang, Xu, Li, Jing, Yao, Jianlin, Wu, Tao, Lu, Gang, Ma, Jing-Yuan, Su, Dong, and Huang, Xiaoqing. Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis.  United States: N. p., 2016. 
Web.  doi:10.1126/science.aah6133.

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                    Bu, Lingzheng, Zhang, Nan, Guo, Shaojun, Zhang, Xu, Li, Jing, Yao, Jianlin, Wu, Tao, Lu, Gang, Ma, Jing-Yuan, Su, Dong, & Huang, Xiaoqing. Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis.  United States.  https://doi.org/10.1126/science.aah6133

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                    Bu, Lingzheng, Zhang, Nan, Guo, Shaojun, Zhang, Xu, Li, Jing, Yao, Jianlin, Wu, Tao, Lu, Gang, Ma, Jing-Yuan, Su, Dong, and Huang, Xiaoqing. Fri .  
"Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis".  United States.  https://doi.org/10.1126/science.aah6133.  https://www.osti.gov/servlets/purl/1336209.

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@article{osti_1336209,

  title        = {Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis},

  author       = {Bu, Lingzheng and Zhang, Nan and Guo, Shaojun and Zhang, Xu and Li, Jing and Yao, Jianlin and Wu, Tao and Lu, Gang and Ma, Jing-Yuan and Su, Dong and Huang, Xiaoqing},

  abstractNote = {Compressive surface strains have been necessary to boost oxygen reduction reaction (ORR) activity in core/shell M/Pt catalysts (where M can be Ni, Co, Fe). We report a class of PtPb/Pt core/shell nanoplate catalysts that exhibit large biaxial tensile strains. The stable Pt (110) facets of the nanoplates have high ORR specific and mass activities that reach 7.8 milliampere per centimeter square and 4.3 ampere per milligram of platinum at 0.9 volts versus the reversible hydrogen electrode (RHE), respectively. Density functional theory calculations revealed that the edge-Pt and top (bottom)-Pt (110) facets undergo large tensile strains that help optimize the Pt-O bond strength. The intermetallic core and uniform 4 layers of Pt shell of the PtPb/Pt nanoplates appear to underlie the high endurance of these catalysts, which can undergo 50,000 voltage cycles with negligible activity decay and no apparent structure and composition changes.},

  doi          = {10.1126/science.aah6133},

  journal      = {Science},

  number       = 6318,

  volume       = 354,

  place        = {United States},

  year         = {Fri Dec 16 00:00:00 EST 2016},

  month        = {Fri Dec 16 00:00:00 EST 2016}

}

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journal, October 2018

Song, Xing; Luo, Shuiping; Fan, Xiaokun
Frontiers in Chemistry, Vol. 6
DOI: 10.3389/fchem.2018.00468

A Simple Mechanical Method to Modulate the Electrochemical Electrosorption Processes at Metal Surfaces
journal, October 2019

Yuan, Aiting; Zhang, Haixia; Deng, Qibo
Molecules, Vol. 24, Issue 20
DOI: 10.3390/molecules24203662

Recent Advances in Isolated Single-Atom Catalysts for Zinc Air Batteries: A Focus Review
journal, October 2019

Zhang, Weimin; Liu, Yuqing; Zhang, Lipeng
Nanomaterials, Vol. 9, Issue 10
DOI: 10.3390/nano9101402

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Title: Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis

Abstract

Citation Formats

Shape-Selective Synthesis and Facet-Dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt−Pd Tetrahedrons and Cubes journal, March 2011

Projector augmented-wave method journal, December 1994

Mass-selected nanoparticles of PtxY as model catalysts for oxygen electroreduction journal, July 2014

Facile Synthesis of PdPt@Pt Nanorings Supported on Reduced Graphene Oxide with Enhanced Electrocatalytic Properties journal, June 2014

Hierarchical Pt/Pt x Pb Core/Shell Nanowires as Efficient Catalysts for Electrooxidation of Liquid Fuels journal, June 2016

Synthesis, Shape Control, and Methanol Electro-oxidation Properties of Pt–Zn Alloy and Pt 3 Zn Intermetallic Nanocrystals journal, May 2012

Ab initiomolecular dynamics for liquid metals journal, January 1993

Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation journal, April 2009

Promoted C–C bond cleavage over intermetallic TaPt 3 catalyst toward low-temperature energy extraction from ethanol journal, January 2015

On the kinetics of oxygen reduction on platinum stepped surfaces in acidic media journal, March 2004

Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters journal, December 2012

Palladium–platinum core-shell icosahedra with substantially enhanced activity and durability towards oxygen reduction journal, July 2015

Methanol electrooxidation on well-characterized platinum-ruthenium bulk alloys journal, November 1993

Synthesis of Ultrathin FePtPd Nanowires and Their Use as Catalysts for Methanol Oxidation Reaction journal, October 2011

Surface Composition Tuning of Au–Pt Bimetallic Nanoparticles for Enhanced Carbon Monoxide and Methanol Electro-oxidation journal, May 2013

Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets journal, July 2015

Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts journal, October 2012

Crystalline Control of {111} Bounded Pt 3 Cu Nanocrystals: Multiply-Twinned Pt 3 Cu Icosahedra with Enhanced Electrocatalytic Properties journal, June 2015

Magnetosomes could be protective shields against metal stress in magnetotactic bacteria journal, July 2020

Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction journal, January 2015

Ultrathin Pt–Cu Nanosheets and Nanocones journal, November 2013

Computational Design of Core/Shell Nanoparticles for Oxygen Reduction Reactions journal, December 2013

Structural effects in electrocatalysis: oxygen reduction on platinum low index single-crystal surfaces in perchloric acid solutions journal, October 1994

Catalysts by Platonic design journal, July 2015

The influence of different co-catalysts in Pt-based ternary and quaternary electro-catalysts on the electro-oxidation of methanol and ethanol in acid media journal, March 2012

FePt and CoPt Nanowires as Efficient Catalysts for the Oxygen Reduction Reaction journal, February 2013

Microfluidic Synthesis Enables Dense and Uniform Loading of Surfactant-Free PtSn Nanocrystals on Carbon Supports for Enhanced Ethanol Oxidation journal, March 2016

Alternative energy technologies journal, November 2001

Design and Synthesis of Bimetallic Electrocatalyst with Multilayered Pt-Skin Surfaces journal, September 2011

Synthesis of Structurally Ordered Pt 3 Ti and Pt 3 V Nanoparticles as Methanol Oxidation Catalysts journal, July 2014

Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts journal, April 2010

Synthesis of Ni@PbPt supported on graphene by galvanic displacement reaction for improving ethanol electro-oxidation journal, January 2013

Mechanical work makes important contributions to surface chemistry at steps journal, February 2015

Mesostructured Intermetallic Compounds of Platinum and Non-Transition Metals for Enhanced Electrocatalysis of Oxygen Reduction Reaction journal, November 2014

Synthesis, Characterization, and Electrocatalytic Activity of PtBi and PtPb Nanoparticles Prepared by Borohydride Reduction in Methanol journal, July 2006

High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction journal, June 2015

Microwave synthesis and electrochemical performance of a PtPb alloy catalyst for methanol and formic acid oxidation journal, February 2012

Ethanol and Methanol Oxidation Activity of PtPb, PtBi, and PtBi2 Intermetallic Compounds in Alkaline Media journal, January 2012

Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis journal, June 2013

Roles of Pb and MnO x in PtPb/MnO x -CNTs catalyst for methanol electro-oxidation journal, January 2012

Generalized Gradient Approximation Made Simple journal, October 1996

Microfluidic Synthesis Enables Dense and Uniform Loading of Surfactant-Free PtSn Nanocrystals on Carbon Supports for Enhanced Ethanol Oxidation journal, March 2016

Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces journal, February 2014

Enhancing by Weakening: Electrooxidation of Methanol on Pt3Co and Pt Nanocubes journal, August 2010

A Strategy for Designing a Concave Pt-Ni Alloy through Controllable Chemical Etching journal, November 2012

Solution-Based Evolution and Enhanced Methanol Oxidation Activity of Monodisperse Platinum-Copper Nanocubes journal, May 2009

What Are Batteries, Fuel Cells, and Supercapacitors? journal, October 2004

Platinum-Based Nanostructured Materials: Synthesis, Properties, and Applications journal, June 2010

Recent Developments in Shape-Controlled Synthesis of Silver Nanocrystals journal, September 2012

Scalable Bromide-Triggered Synthesis of Pd@Pt Core–Shell Ultrathin Nanowires with Enhanced Electrocatalytic Performance toward Oxygen Reduction Reaction journal, June 2015

Physical and electrochemical characterizations of PtPb/C catalyst prepared by pyrolysis of platinum(II) and lead(II) acetylacetonate journal, September 2008

Effect of Strain on the Reactivity of Metal Surfaces journal, September 1998

Fabrication of a novel PtPbBi/C catalyst for ethanol electro-oxidation in alkaline medium journal, November 2012

Enhanced Activity for Oxygen Reduction Reaction on “Pt 3 Co” Nanoparticles: Direct Evidence of Percolated and Sandwich-Segregation Structures journal, October 2008

Epitaxial Growth of Twinned Au–Pt Core–Shell Star-Shaped Decahedra as Highly Durable Electrocatalysts journal, November 2015

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Octahedral PtNi Nanoparticle Catalysts Exceptional Oxygen Reduction Activity by Tuning the Alloy Particle Surface Composition journal, October 2012

One-pot solvothermal synthesis of ordered intermetallic Pt2In3 as stable and efficient electrocatalyst towards direct alcohol fuel cell application journal, October 2016

Towards the computational design of solid catalysts journal, April 2009

Pd-Pt Bimetallic Nanodendrites with High Activity for Oxygen Reduction journal, May 2009

IFEFFIT : interactive XAFS analysis and FEFF fitting journal, March 2001

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts journal, September 2009

Synthesis and Characterization of Ordered Intermetallic PtPb Nanorods journal, July 2007

Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure journal, April 2006

Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs journal, March 2005

Synthetic Control of FePtM Nanorods (M = Cu, Ni) To Enhance the Oxygen Reduction Reaction journal, May 2013

High-Yield Seedless Synthesis of Triangular Gold Nanoplates through Oxidative Etching journal, November 2014

A Strategy for Designing a Concave Pt-Ni Alloy through Controllable Chemical Etching journal, November 2012

Promotional Effects of Ir Addition in Carbon-Supported Pt 5 Rh Electrocatalysts for the Electrooxidation of Ethanol at Room Temperature journal, July 2011

Enhancing by Weakening: Electrooxidation of Methanol on Pt3Co and Pt Nanocubes journal, August 2010

Three-dimensional hierarchical porous platinum–copper alloy networks with enhanced catalytic activity towards methanol and ethanol electro-oxidation journal, November 2015

Facile route for the preparation of ordered intermetallic Pt3Pb–PtPb core–shell nanoparticles and its enhanced activity for alkaline methanol and ethanol oxidation journal, January 2015

Intermetallics as Novel Supports for Pt Monolayer O 2 Reduction Electrocatalysts: Potential for Significantly Improving Properties journal, January 2010

Special points for Brillouin-zone integrations journal, June 1976

Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt 3 Ni Nanopolyhedra journal, February 2010

Morphology and Phase Controlled Construction of Pt–Ni Nanostructures for Efficient Electrocatalysis journal, March 2016

Just a Dream—or Future Reality? journal, April 2009

Shape-Selective Synthesis and Facet-Dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt−Pd Tetrahedrons and Cubes
journal, March 2011

Projector augmented-wave method
journal, December 1994

Mass-selected nanoparticles of PtxY as model catalysts for oxygen electroreduction
journal, July 2014

Facile Synthesis of PdPt@Pt Nanorings Supported on Reduced Graphene Oxide with Enhanced Electrocatalytic Properties
journal, June 2014

Hierarchical Pt/Pt _x Pb Core/Shell Nanowires as Efficient Catalysts for Electrooxidation of Liquid Fuels
journal, June 2016

Synthesis, Shape Control, and Methanol Electro-oxidation Properties of Pt–Zn Alloy and Pt ₃ Zn Intermetallic Nanocrystals
journal, May 2012

Ab initiomolecular dynamics for liquid metals
journal, January 1993

Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation
journal, April 2009

Promoted C–C bond cleavage over intermetallic TaPt ₃ catalyst toward low-temperature energy extraction from ethanol
journal, January 2015

On the kinetics of oxygen reduction on platinum stepped surfaces in acidic media
journal, March 2004

Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters
journal, December 2012

Palladium–platinum core-shell icosahedra with substantially enhanced activity and durability towards oxygen reduction
journal, July 2015

Methanol electrooxidation on well-characterized platinum-ruthenium bulk alloys
journal, November 1993

Synthesis of Ultrathin FePtPd Nanowires and Their Use as Catalysts for Methanol Oxidation Reaction
journal, October 2011

Surface Composition Tuning of Au–Pt Bimetallic Nanoparticles for Enhanced Carbon Monoxide and Methanol Electro-oxidation
journal, May 2013

Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets
journal, July 2015

Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012

Crystalline Control of {111} Bounded Pt ₃ Cu Nanocrystals: Multiply-Twinned Pt ₃ Cu Icosahedra with Enhanced Electrocatalytic Properties
journal, June 2015

Magnetosomes could be protective shields against metal stress in magnetotactic bacteria
journal, July 2020

Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction
journal, January 2015

Ultrathin Pt–Cu Nanosheets and Nanocones
journal, November 2013

Computational Design of Core/Shell Nanoparticles for Oxygen Reduction Reactions
journal, December 2013

Structural effects in electrocatalysis: oxygen reduction on platinum low index single-crystal surfaces in perchloric acid solutions
journal, October 1994

Catalysts by Platonic design
journal, July 2015

The influence of different co-catalysts in Pt-based ternary and quaternary electro-catalysts on the electro-oxidation of methanol and ethanol in acid media
journal, March 2012

FePt and CoPt Nanowires as Efficient Catalysts for the Oxygen Reduction Reaction
journal, February 2013

Microfluidic Synthesis Enables Dense and Uniform Loading of Surfactant-Free PtSn Nanocrystals on Carbon Supports for Enhanced Ethanol Oxidation
journal, March 2016

Alternative energy technologies
journal, November 2001

Design and Synthesis of Bimetallic Electrocatalyst with Multilayered Pt-Skin Surfaces
journal, September 2011

Synthesis of Structurally Ordered Pt ₃ Ti and Pt ₃ V Nanoparticles as Methanol Oxidation Catalysts
journal, July 2014

Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
journal, April 2010

Synthesis of Ni@PbPt supported on graphene by galvanic displacement reaction for improving ethanol electro-oxidation
journal, January 2013

Mechanical work makes important contributions to surface chemistry at steps
journal, February 2015

Mesostructured Intermetallic Compounds of Platinum and Non-Transition Metals for Enhanced Electrocatalysis of Oxygen Reduction Reaction
journal, November 2014

Synthesis, Characterization, and Electrocatalytic Activity of PtBi and PtPb Nanoparticles Prepared by Borohydride Reduction in Methanol
journal, July 2006

High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction
journal, June 2015

Microwave synthesis and electrochemical performance of a PtPb alloy catalyst for methanol and formic acid oxidation
journal, February 2012

Ethanol and Methanol Oxidation Activity of PtPb, PtBi, and PtBi2 Intermetallic Compounds in Alkaline Media
journal, January 2012

Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis
journal, June 2013

Roles of Pb and MnO x in PtPb/MnO x -CNTs catalyst for methanol electro-oxidation
journal, January 2012

Generalized Gradient Approximation Made Simple
journal, October 1996

Microfluidic Synthesis Enables Dense and Uniform Loading of Surfactant-Free PtSn Nanocrystals on Carbon Supports for Enhanced Ethanol Oxidation
journal, March 2016

Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014

Enhancing by Weakening: Electrooxidation of Methanol on Pt3Co and Pt Nanocubes
journal, August 2010

A Strategy for Designing a Concave Pt-Ni Alloy through Controllable Chemical Etching
journal, November 2012

Solution-Based Evolution and Enhanced Methanol Oxidation Activity of Monodisperse Platinum-Copper Nanocubes
journal, May 2009

What Are Batteries, Fuel Cells, and Supercapacitors?
journal, October 2004

Platinum-Based Nanostructured Materials: Synthesis, Properties, and Applications
journal, June 2010

Recent Developments in Shape-Controlled Synthesis of Silver Nanocrystals
journal, September 2012

Scalable Bromide-Triggered Synthesis of Pd@Pt Core–Shell Ultrathin Nanowires with Enhanced Electrocatalytic Performance toward Oxygen Reduction Reaction
journal, June 2015

Physical and electrochemical characterizations of PtPb/C catalyst prepared by pyrolysis of platinum(II) and lead(II) acetylacetonate
journal, September 2008

Effect of Strain on the Reactivity of Metal Surfaces
journal, September 1998

Fabrication of a novel PtPbBi/C catalyst for ethanol electro-oxidation in alkaline medium
journal, November 2012

Enhanced Activity for Oxygen Reduction Reaction on “Pt ₃ Co” Nanoparticles: Direct Evidence of Percolated and Sandwich-Segregation Structures
journal, October 2008

Epitaxial Growth of Twinned Au–Pt Core–Shell Star-Shaped Decahedra as Highly Durable Electrocatalysts
journal, November 2015

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Octahedral PtNi Nanoparticle Catalysts Exceptional Oxygen Reduction Activity by Tuning the Alloy Particle Surface Composition
journal, October 2012

One-pot solvothermal synthesis of ordered intermetallic Pt2In3 as stable and efficient electrocatalyst towards direct alcohol fuel cell application
journal, October 2016

Towards the computational design of solid catalysts
journal, April 2009

Pd-Pt Bimetallic Nanodendrites with High Activity for Oxygen Reduction
journal, May 2009

IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
journal, September 2009

Synthesis and Characterization of Ordered Intermetallic PtPb Nanorods
journal, July 2007

Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure
journal, April 2006

Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs
journal, March 2005

Synthetic Control of FePtM Nanorods (M = Cu, Ni) To Enhance the Oxygen Reduction Reaction
journal, May 2013

High-Yield Seedless Synthesis of Triangular Gold Nanoplates through Oxidative Etching
journal, November 2014

A Strategy for Designing a Concave Pt-Ni Alloy through Controllable Chemical Etching
journal, November 2012

Promotional Effects of Ir Addition in Carbon-Supported Pt ₅ Rh Electrocatalysts for the Electrooxidation of Ethanol at Room Temperature
journal, July 2011

Enhancing by Weakening: Electrooxidation of Methanol on Pt3Co and Pt Nanocubes
journal, August 2010

Three-dimensional hierarchical porous platinum–copper alloy networks with enhanced catalytic activity towards methanol and ethanol electro-oxidation
journal, November 2015

Facile route for the preparation of ordered intermetallic Pt3Pb–PtPb core–shell nanoparticles and its enhanced activity for alkaline methanol and ethanol oxidation
journal, January 2015

Intermetallics as Novel Supports for Pt Monolayer O ₂ Reduction Electrocatalysts: Potential for Significantly Improving Properties
journal, January 2010

Special points for Brillouin-zone integrations
journal, June 1976

Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt ₃ Ni Nanopolyhedra
journal, February 2010

Morphology and Phase Controlled Construction of Pt–Ni Nanostructures for Efficient Electrocatalysis
journal, March 2016

Just a Dream—or Future Reality?
journal, April 2009

Highly dispersive Pt atoms on the surface of RuNi nanoparticles with remarkably enhanced catalytic performance for ethanol oxidation
journal, January 2011

Ethanol Electro-oxidation on Novel Electrocatalyst PtVSnO 2 /C in Acidic Media
journal, October 2014

Pt—Si Bifunctional Surfaces for CO and Methanol Electro-Oxidation
journal, April 2015