Stable metal–organic framework-supported niobium catalysts

Ahn, Sol; Thornburg, Nicholas E.; Li, Zhanyong; Wang, Timothy C.; Gallington, Leighanne C.; Chapman, Karena W.; Notestein, Justin M.; Hupp, Joseph T.; Farha, Omar K.

doi:10.1021/acs.inorgchem.6b02103

Title: Stable metal–organic framework-supported niobium catalysts

Journal Article · Mon Oct 31 04:00:00 UTC 2016 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.6b02103 · OSTI ID:1332973

Ahn, Sol ^[1]; Thornburg, Nicholas E. ^[1]; Li, Zhanyong ^[1]; Wang, Timothy C. ^[1]; Gallington, Leighanne C. ^[2]; Chapman, Karena W. ^[2]; Notestein, Justin M. ^[1]; Hupp, Joseph T. ^[1]; Farha, Omar K. ^[3]

Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)

In this study by developing structurally well-defined, supported oxide catalysts remains a significant challenge. Here, we report the grafting of Nb(V) oxide sites onto the nodes of the Zr-based metal organic framework (MOF) NU-1000 as a stable, well-defined catalyst support. Nb(V) oxide was deposited with loadings up to 1.6 mmol/g via two post-synthetic methods: atomic layer deposition in a MOF (AIM), and solution-phase grafting in a MOF (SIM). Difference envelope density (DED) measurements indicated that the two synthetic methods resulted in different local structures of the Nb(V) ions within NU-1000. Despite their high Nb(V) loadings, which were equivalent to >60% surface coverage, nearly all Nb(V) sites of the MOF-supported catalysts were active sites for alkene epoxidation, as confirmed by phenylphosphonic acid titration. The MOF-supported catalysts were more selective than the control Nb-ZrO₂ catalyst for cyclohexene epoxidation with aqueous H₂O₂, and were far more active on a gravimetric basis.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357; SC0012702

OSTI ID:: 1332973

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 22 Vol. 55; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
active site titration
atomic layer deposition
epoxidation
heterogeneous catalysis
metal-organic framework
niobium
supported catalyst

Title: Stable metal–organic framework-supported niobium catalysts

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