Stable metal–organic framework-supported niobium catalysts

Ahn, Sol; Thornburg, Nicholas E.; Li, Zhanyong; Wang, Timothy C.; Gallington, Leighanne C.; Chapman, Karena W.; Notestein, Justin M.; Hupp, Joseph T.; Farha, Omar K.

doi:10.1021/acs.inorgchem.6b02103

Title: Stable metal–organic framework-supported niobium catalysts

Journal Article · Mon Oct 31 00:00:00 EDT 2016 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.6b02103 · OSTI ID:1332973

Ahn, Sol ^[1]; Thornburg, Nicholas E. ^[1]; Li, Zhanyong ^[1]; Wang, Timothy C. ^[1]; Gallington, Leighanne C. ^[2]; Chapman, Karena W. ^[2]; Notestein, Justin M. ^[1]; Hupp, Joseph T. ^[1]; Farha, Omar K. ^[3]

Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)

In this study by developing structurally well-defined, supported oxide catalysts remains a significant challenge. Here, we report the grafting of Nb(V) oxide sites onto the nodes of the Zr-based metal organic framework (MOF) NU-1000 as a stable, well-defined catalyst support. Nb(V) oxide was deposited with loadings up to 1.6 mmol/g via two post-synthetic methods: atomic layer deposition in a MOF (AIM), and solution-phase grafting in a MOF (SIM). Difference envelope density (DED) measurements indicated that the two synthetic methods resulted in different local structures of the Nb(V) ions within NU-1000. Despite their high Nb(V) loadings, which were equivalent to >60% surface coverage, nearly all Nb(V) sites of the MOF-supported catalysts were active sites for alkene epoxidation, as confirmed by phenylphosphonic acid titration. The MOF-supported catalysts were more selective than the control Nb-ZrO₂ catalyst for cyclohexene epoxidation with aqueous H₂O₂, and were far more active on a gravimetric basis.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357; SC0012702

OSTI ID:: 1332973

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 22 Vol. 55; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (67)

Single-Site Heterogeneous Catalysts Thomas, John Meurig; Raja, Robert; Lewis, Dewi W. Angewandte Chemie International Edition, Vol. 44, Issue 40, p. 6456-6482 https://doi.org/10.1002/anie.200462473	journal	October 2005
Counting Active Sites on Titanium Oxide-Silica Catalysts for Hydrogen Peroxide Activation through In Situ Poisoning with Phenylphosphonic Acid Eaton, Todd R.; Boston, Andrew M.; Thompson, Anthony B. ChemCatChem, Vol. 6, Issue 11 https://doi.org/10.1002/cctc.201402611	journal	October 2014
Adding to the Arsenal of Zirconium-Based Metal-Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation : Adding to the Arsenal of Zirconium-Based Metal-Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation Liu, Tian-Fu; Vermeulen, Nicolaas A.; Howarth, Ashlee J. European Journal of Inorganic Chemistry, Vol. 2016, Issue 27 https://doi.org/10.1002/ejic.201600627	journal	July 2016
Epoxidation with hydrogen peroxide of unsaturated fatty acid methyl esters over Nb(V)-silica catalysts Tiozzo, Cristina; Bisio, Chiara; Carniato, Fabio European Journal of Lipid Science and Technology, Vol. 115, Issue 1 https://doi.org/10.1002/ejlt.201200217	journal	October 2012
Structural and Reactivity Properties of NbMCM-41: Comparison with That of Highly Dispersed Nb2O5/SiO2 Catalysts Gao, Xingtao; Wachs, Israel E.; Wong, Michael S. Journal of Catalysis, Vol. 203, Issue 1 https://doi.org/10.1006/jcat.2001.3313	journal	October 2001
Synthesis of Supported Catalysts by Atomic Layer Deposition Stair, Peter C. Topics in Catalysis, Vol. 55, Issue 1-2 https://doi.org/10.1007/s11244-012-9776-4	journal	February 2012
Chemistry of zirconia and its use in chromatography Nawrocki, J.; Rigney, M.; McCormick, A. Journal of Chromatography A, Vol. 657, Issue 2 https://doi.org/10.1016/0021-9673(93)80284-F	journal	December 1993
Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction Le Bail, A.; Duroy, H.; Fourquet, J. L. Materials Research Bulletin, Vol. 23, Issue 3 https://doi.org/10.1016/0025-5408(88)90019-0	journal	March 1988
Synthetic and mechanistic aspects of metal-catalysed epoxidations with hydroperoxides Sheldon, R. A. Journal of Molecular Catalysis, Vol. 7, Issue 1 https://doi.org/10.1016/0304-5102(80)85010-3	journal	January 1980
Application of niobium oxides as catalysts Tanabe, Kozo Catalysis Today, Vol. 8, Issue 1 https://doi.org/10.1016/0920-5861(90)87003-L	journal	October 1990
The molecular structures and reactivity of supported niobium oxide catalysts Jehng, Jih-Mirn; Wachs, Israel E. Catalysis Today, Vol. 8, Issue 1 https://doi.org/10.1016/0920-5861(90)87006-O	journal	October 1990
Redox properties of niobium oxide catalysts Wachs, I. E.; Jehng, J. -M.; Deo, G. Catalysis Today, Vol. 28, Issue 1-2 https://doi.org/10.1016/0920-5861(95)00229-4	journal	April 1996
Epoxidation of cyclohexene on Nb-containing meso- and macroporous materials Nowak, Izabela; Kilos, Beata; Ziolek, Maria Catalysis Today, Vol. 78, Issue 1-4 https://doi.org/10.1016/S0920-5861(02)00332-2	journal	February 2003
Optimization of cyclohexene epoxidation with dilute hydrogen peroxide and silica-supported titanium catalysts Fraile, José M.; Garcı́a, José I.; Mayoral, José A. Applied Catalysis A: General, Vol. 245, Issue 2 https://doi.org/10.1016/S0926-860X(02)00643-9	journal	June 2003
Gel derived niobium–silicon mixed oxides: Characterization and catalytic activity for cyclooctene epoxidation Aronne, Antonio; Turco, Maria; Bagnasco, Giovanni Applied Catalysis A: General, Vol. 347, Issue 2 https://doi.org/10.1016/j.apcata.2008.06.011	journal	September 2008
Kinetic study of cyclooctene epoxidation with aqueous hydrogen peroxide over silica-supported calixarene–Ta(V) Morlanes, Natalia; Notestein, Justin M. Applied Catalysis A: General, Vol. 387, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.07.063	journal	October 2010
Frontiers in mesoporous molecular sieves containing niobium: From model materials to catalysts Nowak, Izabela Catalysis Today, Vol. 192, Issue 1 https://doi.org/10.1016/j.cattod.2012.05.048	journal	September 2012
Influence of preparation methods and structure of niobium oxide-based catalysts in the epoxidation reaction Turco, Rosa; Aronne, Antonio; Carniti, Paolo Catalysis Today, Vol. 254 https://doi.org/10.1016/j.cattod.2014.11.033	journal	October 2015
Catalytic sites in silica-supported titanium catalysts: silsesquioxane complexes as models Fraile, J.; Garcia, J.; Mayoral, J. Journal of Catalysis, Vol. 233, Issue 1 https://doi.org/10.1016/j.jcat.2005.04.018	journal	July 2005
Grafted Ta–calixarenes: Tunable, selective catalysts for direct olefin epoxidation with aqueous hydrogen peroxide Morlanés, Natalia; Notestein, Justin M. Journal of Catalysis, Vol. 275, Issue 2 https://doi.org/10.1016/j.jcat.2010.07.010	journal	October 2010
Niobium metallocenes deposited onto mesoporous silica via dry impregnation as catalysts for selective epoxidation of alkenes Gallo, Alessandro; Tiozzo, Cristina; Psaro, Rinaldo Journal of Catalysis, Vol. 298 https://doi.org/10.1016/j.jcat.2012.11.015	journal	February 2013
Selective catalytic oxidations of cyclohexene, thioether and geraniol with hydrogen peroxide. Sensitivity to the structure of mesoporous niobosilicates Feliczak-Guzik, Agnieszka; Wawrzyńczak, Agata; Nowak, Izabela Microporous and Mesoporous Materials, Vol. 202 https://doi.org/10.1016/j.micromeso.2014.09.051	journal	January 2015
Metal–Organic Framework Thin Films as Platforms for Atomic Layer Deposition of Cobalt Ions To Enable Electrocatalytic Water Oxidation Kung, Chung-Wei; Mondloch, Joseph E.; Wang, Timothy C. ACS Applied Materials & Interfaces, Vol. 7, Issue 51 https://doi.org/10.1021/acsami.5b06901	journal	December 2015
Periodic Trends in Highly Dispersed Groups IV and V Supported Metal Oxide Catalysts for Alkene Epoxidation with H ₂ O ₂ Thornburg, Nicholas E.; Thompson, Anthony B.; Notestein, Justin M. ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b01105	journal	August 2015
Synthesis−Structure–Function Relationships of Silica-Supported Niobium(V) Catalysts for Alkene Epoxidation with H ₂ O ₂ Thornburg, Nicholas E.; Nauert, Scott L.; Thompson, Anthony B. ACS Catalysis, Vol. 6, Issue 9 https://doi.org/10.1021/acscatal.6b01796	journal	August 2016
Atomically Precise Growth of Catalytically Active Cobalt Sulfide on Flat Surfaces and within a Metal–Organic Framework via Atomic Layer Deposition Peters, Aaron W.; Li, Zhanyong; Farha, Omar K. ACS Nano, Vol. 9, Issue 8 https://doi.org/10.1021/acsnano.5b03429	journal	July 2015
Study of Guest Molecules in Metal–Organic Frameworks by Powder X-ray Diffraction: Analysis of Difference Envelope Density Yakovenko, Andrey A.; Wei, Zhangwen; Wriedt, Mario Crystal Growth & Design, Vol. 14, Issue 11 https://doi.org/10.1021/cg500525g	journal	October 2014
Size-Selective Synthesis and Stabilization of Small Silver Nanoparticles on TiO ₂ Partially Masked by SiO ₂ Bo, Zhenyu; Eaton, Todd R.; Gallagher, James R. Chemistry of Materials, Vol. 27, Issue 4 https://doi.org/10.1021/cm504243f	journal	January 2015
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Niobium Compounds: Preparation, Characterization, and Application in Heterogeneous Catalysis Nowak, Izabela; Ziolek, Maria Chemical Reviews, Vol. 99, Issue 12 https://doi.org/10.1021/cr9800208	journal	December 1999
MOF Functionalization via Solvent-Assisted Ligand Incorporation: Phosphonates vs Carboxylates Deria, Pravas; Bury, Wojciech; Hod, Idan Inorganic Chemistry, Vol. 54, Issue 5 https://doi.org/10.1021/ic502639v	journal	February 2015
Grafted Metallocalixarenes as Single-Site Surface Organometallic Catalysts Notestein, Justin M.; Iglesia, Enrique; Katz, Alexander Journal of the American Chemical Society, Vol. 126, Issue 50 https://doi.org/10.1021/ja0470259	journal	December 2004
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption Wu, Hui; Chua, Yong Shen; Krungleviciute, Vaiva Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja404514r	journal	May 2013
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence Jiang, Hai-Long; Feng, Dawei; Wang, Kecheng Journal of the American Chemical Society, Vol. 135, Issue 37 https://doi.org/10.1021/ja406844r	journal	September 2013
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO₂ Adsorption Studies Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804 https://doi.org/10.1021/ja408959g	journal	October 2013
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381 https://doi.org/10.1021/ja500330a	journal	March 2014
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Cooperative Effect of Monopodal Silica-Supported Niobium Complex Pairs Enhancing Catalytic Cyclic Carbonate Production D’Elia, Valerio; Dong, Hailin; Rossini, Aaron J. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b02872	journal	June 2015
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes Yang, Dong; Odoh, Samuel O.; Wang, Timothy C. Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396 https://doi.org/10.1021/jacs.5b02956	journal	June 2015
Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b11350	journal	December 2015
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B. Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b12515	journal	February 2016
Defining the Proton Topology of the Zr₆-Based Metal–Organic Framework NU-1000 Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723 https://doi.org/10.1021/jz501899j	journal	October 2014
A Sinter-Resistant Catalytic System Fabricated by Maneuvering the Selectivity of SiO ₂ Deposition onto the TiO ₂ Surface versus the Pt Nanoparticle Surface Lu, Ping; Campbell, Charles T.; Xia, Younan Nano Letters, Vol. 13, Issue 10 https://doi.org/10.1021/nl4029973	journal	September 2013
Chemical, thermal and mechanical stabilities of metal–organic frameworks Howarth, Ashlee J.; Liu, Yangyang; Li, Peng Nature Reviews Materials, Vol. 1, Issue 3 https://doi.org/10.1038/natrevmats.2015.18	journal	February 2016
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian Nature, Vol. 519, Issue 7543 https://doi.org/10.1038/nature14327	journal	March 2015
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim Nature Chemistry, Vol. 2, Issue 11, p. 944-948 https://doi.org/10.1038/nchem.834	journal	September 2010
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2 Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10942	journal	March 2016
Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000 Wang, Timothy C.; Vermeulen, Nicolaas A.; Kim, In Soo Nature Protocols, Vol. 11, Issue 1 https://doi.org/10.1038/nprot.2016.001	journal	December 2015
Are Zr ₆ -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse Mondloch, Joseph E.; Katz, Michael J.; Planas, Nora Chemical Communications, Vol. 50, Issue 64 https://doi.org/10.1039/C4CC02401J	journal	January 2014
Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant Li, Peng; Klet, Rachel C.; Moon, Su-Young Chem. Commun., Vol. 51, Issue 54 https://doi.org/10.1039/C5CC03398E	journal	January 2015
Review: monoclinic zirconia, its surface sites and their interaction with carbon monoxide Kouva, Sonja; Honkala, Karoliina; Lefferts, Leon Catalysis Science & Technology, Vol. 5, Issue 7 https://doi.org/10.1039/C5CY00330J	journal	January 2015
Evaluation of Brønsted acidity and proton topology in Zr- and Hf-based metal–organic frameworks using potentiometric acid–base titration Klet, Rachel C.; Liu, Yangyang; Wang, Timothy C. Journal of Materials Chemistry A, Vol. 4, Issue 4 https://doi.org/10.1039/C5TA07687K	journal	January 2016
A metal–organic framework immobilised iridium pincer complex Rimoldi, Martino; Nakamura, Akitake; Vermeulen, Nicolaas A. Chemical Science, Vol. 7, Issue 8 https://doi.org/10.1039/C6SC01376G	journal	January 2016
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Enantioselective catalysis with homochiral metal–organic frameworks Ma, Liqing; Abney, Carter; Lin, Wenbin Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256 https://doi.org/10.1039/b807083k	journal	January 2009
Niobium–silica catalysts for the selective epoxidation of cyclic alkenes: the generation of the active site by grafting niobocene dichloride Tiozzo, Cristina; Bisio, Chiara; Carniato, Fabio Physical Chemistry Chemical Physics, Vol. 15, Issue 32 https://doi.org/10.1039/c3cp51570b	journal	January 2013
A new metal–organic framework with ultra-high surface area Grünker, Ronny; Bon, Volodymyr; Müller, Philipp Chemical Communications, Vol. 50, Issue 26 https://doi.org/10.1039/c4cc00113c	journal	January 2014
Electronic spectroscopy of the niobium dimer molecule: Experimental and theoretical results James, Andrew M.; Kowalczyk, Pawel; Fournier, René The Journal of Chemical Physics, Vol. 99, Issue 11 https://doi.org/10.1063/1.465627	journal	December 1993
Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66 Jakobsen, Søren; Gianolio, Diego; Wragg, David S. Physical Review B, Vol. 86, Issue 12 https://doi.org/10.1103/PhysRevB.86.125429	journal	September 2012
Generation and applications of structure envelopes for porous metal–organic frameworks Yakovenko, Andrey A.; Reibenspies, Joseph H.; Bhuvanesh, Nattamai Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889812050935	journal	February 2013
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Ultrahigh Porosity in Metal-Organic Frameworks Furukawa, H.; Ko, N.; Go, Y. B. Science, Vol. 329, Issue 5990, p. 424-428 https://doi.org/10.1126/science.1192160	journal	July 2010
Atomically Dispersed Supported Metal Catalysts Flytzani-Stephanopoulos, Maria; Gates, Bruce C. Annual Review of Chemical and Biomolecular Engineering, Vol. 3, Issue 1 https://doi.org/10.1146/annurev-chembioeng-062011-080939	journal	July 2012
Kinetics of Heterogeneous Catalytic Reactions Boudart, Michel; Djega-Mariadassou, G. https://doi.org/10.1515/9781400853335	book	January 1984
Crystallographic Computing System JANA2006: General features Petříček, Václav; Dušek, Michal; Palatinus, Lukáš Zeitschrift für Kristallographie - Crystalline Materials, Vol. 229, Issue 5 https://doi.org/10.1515/zkri-2014-1737	journal	January 2014

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
active site titration
atomic layer deposition
epoxidation
heterogeneous catalysis
metal-organic framework
niobium
supported catalyst

Title: Stable metal–organic framework-supported niobium catalysts

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