A new lithium-rich anti-spinel in Li–O–Br system
Abstract
In spinel-type materials currently known, the divalent anions are arranged in a closed-pack lattice and cations of various valences occupy some or all of the tetrahedral and octahedral sites. We report here the first discovery of an ‘‘electronically inverted’’ antispinel. Furthermore, the new material, crystallized in a defect spinel structure, was obtained from the dehydration of Li5Br(OH)4 under moderate pressure and temperature conditions.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Univ. of Nevada, Las Vegas, NV (United States)
- Publication Date:
- Research Org.:
- Univ. of Nevada, Las Vegas, NV (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1332530
- Grant/Contract Number:
- NA0001982
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 51; Journal Issue: 47; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Zhang, J., Zhu, J., Wang, L., and Zhao, Y. A new lithium-rich anti-spinel in Li–O–Br system. United States: N. p., 2015.
Web. doi:10.1039/c5cc01109d.
Zhang, J., Zhu, J., Wang, L., & Zhao, Y. A new lithium-rich anti-spinel in Li–O–Br system. United States. https://doi.org/10.1039/c5cc01109d
Zhang, J., Zhu, J., Wang, L., and Zhao, Y. Mon .
"A new lithium-rich anti-spinel in Li–O–Br system". United States. https://doi.org/10.1039/c5cc01109d. https://www.osti.gov/servlets/purl/1332530.
@article{osti_1332530,
title = {A new lithium-rich anti-spinel in Li–O–Br system},
author = {Zhang, J. and Zhu, J. and Wang, L. and Zhao, Y.},
abstractNote = {In spinel-type materials currently known, the divalent anions are arranged in a closed-pack lattice and cations of various valences occupy some or all of the tetrahedral and octahedral sites. We report here the first discovery of an ‘‘electronically inverted’’ antispinel. Furthermore, the new material, crystallized in a defect spinel structure, was obtained from the dehydration of Li5Br(OH)4 under moderate pressure and temperature conditions.},
doi = {10.1039/c5cc01109d},
journal = {ChemComm},
number = 47,
volume = 51,
place = {United States},
year = {Mon May 11 00:00:00 EDT 2015},
month = {Mon May 11 00:00:00 EDT 2015}
}
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Works referenced in this record:
Size, Shape, and Internal Atomic Ordering of Nanocrystals by Atomic Pair Distribution Functions: A Comparative Study of γ-Fe 2 O 3 Nanosized Spheres and Tetrapods
journal, October 2009
- Petkov, Valeri; Cozzoli, P. Davide; Buonsanti, Raffaella
- Journal of the American Chemical Society, Vol. 131, Issue 40
Idealizing γ-Al 2 O 3 : In Situ Determination of Nonstoichiometric Spinel Defect Structure
journal, July 2010
- Miller, Michelene E.; Misture, Scott T.
- The Journal of Physical Chemistry C, Vol. 114, Issue 30
High pressure-high temperature synthesis of lithium-rich Li3O(Cl, Br) and Li3−xCax/2OCl anti-perovskite halides
journal, October 2014
- Zhang, Jianzhong; Han, Jiantao; Zhu, Jinlong
- Inorganic Chemistry Communications, Vol. 48
Superionic Conductivity in Lithium-Rich Anti-Perovskites
journal, August 2012
- Zhao, Yusheng; Daemen, Luke L.
- Journal of the American Chemical Society, Vol. 134, Issue 36
Ab initio study of the stabilities of and mechanism of superionic transport in lithium-rich antiperovskites
journal, April 2013
- Zhang, Yi; Zhao, Yusheng; Chen, Changfeng
- Physical Review B, Vol. 87, Issue 13
Phase Stability and Transport Mechanisms in Antiperovskite Li 3 OCl and Li 3 OBr Superionic Conductors
journal, November 2013
- Emly, Alexandra; Kioupakis, Emmanouil; Van der Ven, Anton
- Chemistry of Materials, Vol. 25, Issue 23
New A2+Mo4+O3 oxides with defect spinel structure
journal, February 1980
- Manthiram, A.; Gopalakrishnan, J.
- Materials Research Bulletin, Vol. 15, Issue 2
Insights into the Mechanism Related to the Phase Transition from γ-Fe 2 O 3 to α-Fe 2 O 3 Nanoparticles Induced by Thermal Treatment and Laser Irradiation
journal, October 2012
- El Mendili, Yassine; Bardeau, Jean-François; Randrianantoandro, Nirina
- The Journal of Physical Chemistry C, Vol. 116, Issue 44
Mechanically Induced Phase Transformation of γ-Al 2 O 3 into α-Al 2 O 3 . Access to Structurally Disordered γ-Al 2 O 3 with a Controllable Amount of Pentacoordinated Al Sites
journal, October 2011
- Düvel, A.; Romanova, E.; Sharifi, M.
- The Journal of Physical Chemistry C, Vol. 115, Issue 46
Vibrational spectroscopy at high pressures. 58. An IR study of phase transitions in the hexaamminenickel(II) halides
journal, September 1991
- Adams, David M.; Haines, Julian
- The Journal of Physical Chemistry, Vol. 95, Issue 18
High-pressure phase transition in lithium deuteroxide: a neutron powder diffraction and vibrational spectroscopic study
journal, October 1992
- Adams, David M.; Christy, Andrew G.; Haines, Julian
- The Journal of Physical Chemistry, Vol. 96, Issue 20
Lithium hydroxide, LiOH, at elevated densities
journal, July 2014
- Hermann, Andreas; Ashcroft, N. W.; Hoffmann, Roald
- The Journal of Chemical Physics, Vol. 141, Issue 2
Works referencing / citing this record:
Ion Conductivity Enhancement in Anti-Spinel Li 3 OBr with Intrinsic Vacancies
journal, November 2018
- Hussain, Fiaz; Li, Pai; Li, Zhenyu
- Advanced Theory and Simulations, Vol. 2, Issue 3
Insights into Grain Boundary in Lithium-Rich Anti-Perovskite as Solid Electrolytes
journal, January 2018
- Chen, Bingbing; Xu, Chaoqun; Zhou, Jianqiu
- Journal of The Electrochemical Society, Vol. 165, Issue 16