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Title: A new lithium-rich anti-spinel in Li–O–Br system

In spinel-type materials currently known, the divalent anions are arranged in a closed-pack lattice and cations of various valences occupy some or all of the tetrahedral and octahedral sites. We report here the first discovery of an ‘‘electronically inverted’’ antispinel. Furthermore, the new material, crystallized in a defect spinel structure, was obtained from the dehydration of Li 5Br(OH) 4 under moderate pressure and temperature conditions.
Authors:
 [1] ;  [2] ;  [2] ;  [2]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Univ. of Nevada, Las Vegas, NV (United States)
Publication Date:
Grant/Contract Number:
NA0001982
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 51; Journal Issue: 47; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Univ. of Nevada, Las Vegas, NV (United States)
Sponsoring Org:
USDOE National Nuclear Security Administration (NNSA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1332530

Zhang, J., Zhu, J., Wang, L., and Zhao, Y.. A new lithium-rich anti-spinel in Li–O–Br system. United States: N. p., Web. doi:10.1039/c5cc01109d.
Zhang, J., Zhu, J., Wang, L., & Zhao, Y.. A new lithium-rich anti-spinel in Li–O–Br system. United States. doi:10.1039/c5cc01109d.
Zhang, J., Zhu, J., Wang, L., and Zhao, Y.. 2015. "A new lithium-rich anti-spinel in Li–O–Br system". United States. doi:10.1039/c5cc01109d. https://www.osti.gov/servlets/purl/1332530.
@article{osti_1332530,
title = {A new lithium-rich anti-spinel in Li–O–Br system},
author = {Zhang, J. and Zhu, J. and Wang, L. and Zhao, Y.},
abstractNote = {In spinel-type materials currently known, the divalent anions are arranged in a closed-pack lattice and cations of various valences occupy some or all of the tetrahedral and octahedral sites. We report here the first discovery of an ‘‘electronically inverted’’ antispinel. Furthermore, the new material, crystallized in a defect spinel structure, was obtained from the dehydration of Li5Br(OH)4 under moderate pressure and temperature conditions.},
doi = {10.1039/c5cc01109d},
journal = {ChemComm},
number = 47,
volume = 51,
place = {United States},
year = {2015},
month = {5}
}