Quantitative 13C NMR characterization of fast pyrolysis oils
Abstract
Quantitative 13C NMR analysis of model catalytic fast pyrolysis (CFP) oils following literature procedures showed poor agreement for aromatic hydrocarbons between NMR measured concentrations and actual composition. Furthermore, modifying integration regions based on DEPT analysis for aromatic carbons resulted in better agreement. Solvent effects were also investigated for hydrotreated CFP oil.
- Authors:
-
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office
- OSTI Identifier:
- 1332485
- Report Number(s):
- NREL/JA-5100-67305
Journal ID: ISSN 2046-2069; RSCACL
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- RSC Advances
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 104; Journal ID: ISSN 2046-2069
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; pyrolysis; NMR; 13C; catalytic fast pyrolysis
Citation Formats
Happs, Renee M., Lisa, Kristina, and Ferrell, III, Jack R. Quantitative 13C NMR characterization of fast pyrolysis oils. United States: N. p., 2016.
Web. doi:10.1039/C6RA24044E.
Happs, Renee M., Lisa, Kristina, & Ferrell, III, Jack R. Quantitative 13C NMR characterization of fast pyrolysis oils. United States. https://doi.org/10.1039/C6RA24044E
Happs, Renee M., Lisa, Kristina, and Ferrell, III, Jack R. Thu .
"Quantitative 13C NMR characterization of fast pyrolysis oils". United States. https://doi.org/10.1039/C6RA24044E. https://www.osti.gov/servlets/purl/1332485.
@article{osti_1332485,
title = {Quantitative 13C NMR characterization of fast pyrolysis oils},
author = {Happs, Renee M. and Lisa, Kristina and Ferrell, III, Jack R.},
abstractNote = {Quantitative 13C NMR analysis of model catalytic fast pyrolysis (CFP) oils following literature procedures showed poor agreement for aromatic hydrocarbons between NMR measured concentrations and actual composition. Furthermore, modifying integration regions based on DEPT analysis for aromatic carbons resulted in better agreement. Solvent effects were also investigated for hydrotreated CFP oil.},
doi = {10.1039/C6RA24044E},
journal = {RSC Advances},
number = 104,
volume = 6,
place = {United States},
year = {Thu Oct 20 00:00:00 EDT 2016},
month = {Thu Oct 20 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 18 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part II: Comparative catalyst performance and reaction pathways
journal, December 1995
- Adjaye, J. D.; Bakhshi, N. N.
- Fuel Processing Technology, Vol. 45, Issue 3
Recent advances in heterogeneous catalysts for bio-oil upgrading via “ex situ catalytic fast pyrolysis”: catalyst development through the study of model compounds
journal, January 2014
- Ruddy, Daniel A.; Schaidle, Joshua A.; Ferrell III, Jack R.
- Green Chem., Vol. 16, Issue 2
Review of fast pyrolysis of biomass and product upgrading
journal, March 2012
- Bridgwater, A. V.
- Biomass and Bioenergy, Vol. 38, p. 68-94
A review and perspective of recent bio-oil hydrotreating research
journal, January 2014
- Zacher, Alan H.; Olarte, Mariefel V.; Santosa, Daniel M.
- Green Chem., Vol. 16, Issue 2
Characterizing Biomass Fast Pyrolysis Oils by 13 C NMR and Chemometric Analysis
journal, November 2011
- Strahan, Gary D.; Mullen, Charles A.; Boateng, Akwasi A.
- Energy & Fuels, Vol. 25, Issue 11
Chemical Shifts and Lifetimes for Nuclear Magnetic Resonance (NMR) Analysis of Biofuels
journal, September 2010
- Joseph, Jincy; Baker, Cirila; Mukkamala, Saikrishna
- Energy & Fuels, Vol. 24, Issue 9
A perspective on oxygenated species in the refinery integration of pyrolysis oil
journal, January 2014
- Talmadge, Michael S.; Baldwin, Robert M.; Biddy, Mary J.
- Green Chem., Vol. 16, Issue 2
Advanced biofuels from pyrolysis oil…Opportunities for cost reduction
journal, February 2013
- Arbogast, S.; Bellman, D.; Paynter, J. D.
- Fuel Processing Technology, Vol. 106
Bio-oil Stabilization and Upgrading by Hot Gas Filtration
journal, May 2013
- Baldwin, Robert M.; Feik, Calvin J.
- Energy & Fuels, Vol. 27, Issue 6
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
journal, May 2006
- Mohan, Dinesh; Pittman,, Charles U.; Steele, Philip H.
- Energy & Fuels, Vol. 20, Issue 3, p. 848-889
NMR Characterization of Pyrolysis Oils from Kraft Lignin
journal, May 2011
- Ben, Haoxi; Ragauskas, Arthur J.
- Energy & Fuels, Vol. 25, Issue 5
Catalytic pyrolysis of biomass for biofuels production
journal, January 2010
- French, Richard; Czernik, Stefan
- Fuel Processing Technology, Vol. 91, Issue 1
In Situ and ex Situ Catalytic Pyrolysis of Pine in a Bench-Scale Fluidized Bed Reactor System
journal, December 2015
- Iisa, Kristiina; French, Richard J.; Orton, Kellene A.
- Energy & Fuels, Vol. 30, Issue 3
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
journal, May 2010
- Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H.
- Organometallics, Vol. 29, Issue 9
Conceptual Process Design and Techno-Economic Assessment of Ex Situ Catalytic Fast Pyrolysis of Biomass: A Fixed Bed Reactor Implementation Scenario for Future Feasibility
journal, October 2015
- Dutta, Abhijit; Schaidle, Joshua A.; Humbird, David
- Topics in Catalysis, Vol. 59, Issue 1
Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part I: Conversion over various catalysts
journal, December 1995
- Adjaye, J. D.; Bakhshi, N. N.
- Fuel Processing Technology, Vol. 45, Issue 3
Standardization of chemical analytical techniques for pyrolysis bio-oil: history, challenges, and current status of methods: Bio-oil Analytical Standardization
journal, July 2016
- Ferrell, Jack R.; Olarte, Mariefel V.; Christensen, Earl D.
- Biofuels, Bioproducts and Biorefining, Vol. 10, Issue 5
Overview of Applications of Biomass Fast Pyrolysis Oil
journal, March 2004
- Czernik, S.; Bridgwater, A. V.
- Energy & Fuels, Vol. 18, Issue 2, p. 590-598
Aromatic Production from Catalytic Fast Pyrolysis of Biomass-Derived Feedstocks
journal, January 2009
- Carlson, Torren R.; Tompsett, Geoffrey A.; Conner, William C.
- Topics in Catalysis, Vol. 52, Issue 3
Works referencing / citing this record:
Hybridization of ZSM‐5 with Spinel Oxides for Biomass Vapour Upgrading
journal, January 2020
- Atanda, Luqman; Batalha, Nuno; Stark, Terra
- ChemCatChem, Vol. 12, Issue 5
Molecular weight distribution of raw and catalytic fast pyrolysis oils: comparison of analytical methodologies
journal, January 2020
- Harman-Ware, Anne E.; Orton, Kellene; Deng, Chris
- RSC Advances, Vol. 10, Issue 7