Quantitative 13C NMR characterization of fast pyrolysis oils

Happs, Renee M.; Lisa, Kristina; Ferrell, III, Jack R.

doi:10.1039/C6RA24044E

Title: Quantitative ¹³C NMR characterization of fast pyrolysis oils

Journal Article · Thu Oct 20 04:00:00 UTC 2016 · RSC Advances

DOI: https://doi.org/10.1039/C6RA24044E · OSTI ID:1332485

Happs, Renee M. ^[1]; Lisa, Kristina ^[1]; Ferrell, III, Jack R. ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)

Quantitative ¹³C NMR analysis of model catalytic fast pyrolysis (CFP) oils following literature procedures showed poor agreement for aromatic hydrocarbons between NMR measured concentrations and actual composition. Furthermore, modifying integration regions based on DEPT analysis for aromatic carbons resulted in better agreement. Solvent effects were also investigated for hydrotreated CFP oil.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: NREL (National Renewable Energy Laboratory (NREL), Golden, CO (United States))

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Bioenergy Technologies Office (EE-3B)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1332485

Report Number(s):: NREL/JA--5100-67305

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 104 Vol. 6; ISSN 2046-2069; ISSN RSCACL

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (20)

Standardization of chemical analytical techniques for pyrolysis bio-oil: history, challenges, and current status of methods: Bio-oil Analytical Standardization Ferrell, Jack R.; Olarte, Mariefel V.; Christensen, Earl D. Biofuels, Bioproducts and Biorefining, Vol. 10, Issue 5 https://doi.org/10.1002/bbb.1661	journal	July 2016
Aromatic Production from Catalytic Fast Pyrolysis of Biomass-Derived Feedstocks Carlson, Torren R.; Tompsett, Geoffrey A.; Conner, William C. Topics in Catalysis, Vol. 52, Issue 3 https://doi.org/10.1007/s11244-008-9160-6	journal	January 2009
Conceptual Process Design and Techno-Economic Assessment of Ex Situ Catalytic Fast Pyrolysis of Biomass: A Fixed Bed Reactor Implementation Scenario for Future Feasibility Dutta, Abhijit; Schaidle, Joshua A.; Humbird, David Topics in Catalysis, Vol. 59, Issue 1 https://doi.org/10.1007/s11244-015-0500-z	journal	October 2015
Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part I: Conversion over various catalysts Adjaye, J. D.; Bakhshi, N. N. Fuel Processing Technology, Vol. 45, Issue 3 https://doi.org/10.1016/0378-3820(95)00034-5	journal	December 1995
Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part II: Comparative catalyst performance and reaction pathways Adjaye, J. D.; Bakhshi, N. N. Fuel Processing Technology, Vol. 45, Issue 3 https://doi.org/10.1016/0378-3820(95)00040-E	journal	December 1995
Review of fast pyrolysis of biomass and product upgrading Bridgwater, A. V. Biomass and Bioenergy, Vol. 38, p. 68-94 https://doi.org/10.1016/j.biombioe.2011.01.048	journal	March 2012
Catalytic pyrolysis of biomass for biofuels production French, Richard; Czernik, Stefan Fuel Processing Technology, Vol. 91, Issue 1 https://doi.org/10.1016/j.fuproc.2009.08.011	journal	January 2010
Advanced biofuels from pyrolysis oil…Opportunities for cost reduction Arbogast, S.; Bellman, D.; Paynter, J. D. Fuel Processing Technology, Vol. 106 https://doi.org/10.1016/j.fuproc.2012.09.022	journal	February 2013
In Situ and ex Situ Catalytic Pyrolysis of Pine in a Bench-Scale Fluidized Bed Reactor System Iisa, Kristiina; French, Richard J.; Orton, Kellene A. Energy & Fuels, Vol. 30, Issue 3 https://doi.org/10.1021/acs.energyfuels.5b02165	journal	December 2015
Overview of Applications of Biomass Fast Pyrolysis Oil Czernik, S.; Bridgwater, A. V. Energy & Fuels, Vol. 18, Issue 2, p. 590-598 https://doi.org/10.1021/ef034067u	journal	March 2004
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review Mohan, Dinesh; Pittman,, Charles U.; Steele, Philip H. Energy & Fuels, Vol. 20, Issue 3, p. 848-889 https://doi.org/10.1021/ef0502397	journal	May 2006
Chemical Shifts and Lifetimes for Nuclear Magnetic Resonance (NMR) Analysis of Biofuels Joseph, Jincy; Baker, Cirila; Mukkamala, Saikrishna Energy & Fuels, Vol. 24, Issue 9 https://doi.org/10.1021/ef100504d	journal	September 2010
NMR Characterization of Pyrolysis Oils from Kraft Lignin Ben, Haoxi; Ragauskas, Arthur J. Energy & Fuels, Vol. 25, Issue 5 https://doi.org/10.1021/ef2001162	journal	May 2011
Characterizing Biomass Fast Pyrolysis Oils by ¹³ C NMR and Chemometric Analysis Strahan, Gary D.; Mullen, Charles A.; Boateng, Akwasi A. Energy & Fuels, Vol. 25, Issue 11 https://doi.org/10.1021/ef2013166	journal	November 2011
Bio-oil Stabilization and Upgrading by Hot Gas Filtration Baldwin, Robert M.; Feik, Calvin J. Energy & Fuels, Vol. 27, Issue 6 https://doi.org/10.1021/ef400177t	journal	May 2013
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H. Organometallics, Vol. 29, Issue 9 https://doi.org/10.1021/om100106e	journal	May 2010
Recent advances in heterogeneous catalysts for bio-oil upgrading via “ex situ catalytic fast pyrolysis”: catalyst development through the study of model compounds Ruddy, Daniel A.; Schaidle, Joshua A.; Ferrell III, Jack R. Green Chem., Vol. 16, Issue 2 https://doi.org/10.1039/C3GC41354C	journal	January 2014
A review and perspective of recent bio-oil hydrotreating research Zacher, Alan H.; Olarte, Mariefel V.; Santosa, Daniel M. Green Chem., Vol. 16, Issue 2 https://doi.org/10.1039/C3GC41382A	journal	January 2014
A perspective on oxygenated species in the refinery integration of pyrolysis oil Talmadge, Michael S.; Baldwin, Robert M.; Biddy, Mary J. Green Chem., Vol. 16, Issue 2 https://doi.org/10.1039/C3GC41951G	journal	January 2014
In-depth investigation on quantitative characterization of pyrolysis oil by ³¹ P NMR Ben, Haoxi; Ferrell III, Jack R. RSC Advances, Vol. 6, Issue 21 https://doi.org/10.1039/C5RA23939G	journal	January 2016

Cited By (3)

Hybridization of ZSM‐5 with Spinel Oxides for Biomass Vapour Upgrading Atanda, Luqman; Batalha, Nuno; Stark, Terra ChemCatChem, Vol. 12, Issue 5 https://doi.org/10.1002/cctc.201902023	journal	January 2020
Driving towards cost-competitive biofuels through catalytic fast pyrolysis by rethinking catalyst selection and reactor configuration Griffin, Michael B.; Iisa, Kristiina; Wang, Huamin Energy & Environmental Science, Vol. 11, Issue 10 https://doi.org/10.1039/c8ee01872c	journal	January 2018
Molecular weight distribution of raw and catalytic fast pyrolysis oils: comparison of analytical methodologies Harman-Ware, Anne E.; Orton, Kellene; Deng, Chris RSC Advances, Vol. 10, Issue 7 https://doi.org/10.1039/c9ra09726k	journal	January 2020

Similar Records

Hydrotreating of Model Mixtures and Catalytic Fast Pyrolysis Oils over Pd/C

Journal Article · Fri Nov 16 04:00:00 UTC 2018 · Energy and Fuels · OSTI ID:1494732

French, Richard J.; Orton, Kellene A.; Iisa, Kristiina

Characterization of Catalytic Fast Pyrolysis Oils: The Importance of Solvent Selection for Analytical Method Development

Journal Article · Sun Feb 25 04:00:00 UTC 2018 · Journal of Analytical and Applied Pyrolysis · OSTI ID:1429977

Ferrell, Jack R; Ware, Anne E

Production of low-oxygen bio-oil via ex situ catalytic fast pyrolysis and hydrotreating

Journal Article · Thu Jun 29 04:00:00 UTC 2017 · Fuel · OSTI ID:1371529

Iisa, Kristiina; French, Richard J.; Orton, Kellene A.; +2 more

Related Subjects

09 BIOMASS FUELS
13C
NMR
catalytic fast pyrolysis
pyrolysis

Title: Quantitative 13C NMR characterization of fast pyrolysis oils

Citation Formats

References (20)

Cited By (3)

Similar Records

Related Subjects

Title: Quantitative ¹³C NMR characterization of fast pyrolysis oils