Phosphorene: Fabrication, properties, and applications

Kou, Liangzhi; Chen, Changfeng; Smith, Sean C.

doi:10.1021/acs.jpclett.5b01094

Title: Phosphorene: Fabrication, properties, and applications

Journal Article · Wed Jun 24 00:00:00 EDT 2015 · Journal of Physical Chemistry Letters

DOI: https://doi.org/10.1021/acs.jpclett.5b01094 · OSTI ID:1332445

Kou, Liangzhi ^[1]; Chen, Changfeng ^[2]; Smith, Sean C. ^[3]

Univ. of New South Wales, Sydney, NSW (Australia); UNLV
Univ. of Nevada, Las Vegas, NV (United States)
Univ. of New South Wales, Sydney, NSW (Australia)

Phosphorene, the single- or few-layer form of black phosphorus, was recently rediscovered as a two-dimensional layered material holding great promise for applications in electronics and optoelectronics. Research into its fundamental properties and device applications has since seen exponential growth. In this Perspective, we review recent progress in phosphorene research, touching upon topics on fabrication, properties, and applications; we also discuss challenges and future research directions. We highlight the intrinsically anisotropic electronic, transport, optoelectronic, thermoelectric, and mechanical properties of phosphorene resulting from its puckered structure in contrast to those of graphene and transition-metal dichalcogenides. The facile fabrication and novel properties of phosphorene have inspired design and demonstration of new nanodevices; however, further progress hinges on resolutions to technical obstructions like surface degradation effects and nonscalable fabrication techniques. We also briefly describe the latest developments of more sophisticated design concepts and implementation schemes that address some of the challenges in phosphorene research. As a result, it is expected that this fascinating material will continue to offer tremendous opportunities for research and development for the foreseeable future.

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Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0001982

OSTI ID:: 1332445

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 14 Vol. 6; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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A novel electrically controllable volatile memory device based on few-layer black phosphorus Zhang, Liwen; Yu, Zhizhou; Zhang, Lei Journal of Materials Chemistry C, Vol. 6, Issue 10 https://doi.org/10.1039/c7tc05083f	journal	January 2018
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Modifying the sensibility of nonmetal-doped phosphorene by local or global properties Yang, Na; Li, Li; Li, Jing Physical Chemistry Chemical Physics, Vol. 21, Issue 9 https://doi.org/10.1039/c8cp07851c	journal	January 2019
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Strain-tunable CO ₂ storage by black phosphorene and α-PC from combined first principles and molecular dynamics studies Song, Xiaohan; Liu, Yang; Yang, Yanmei Physical Chemistry Chemical Physics, Vol. 21, Issue 36 https://doi.org/10.1039/c9cp03676h	journal	January 2019
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Recent Advances in the Study of Phosphorene and its Nanostructures Sorkin, V.; Cai, Y.; Ong, Z. Critical Reviews in Solid State and Materials Sciences, Vol. 42, Issue 1 https://doi.org/10.1080/10408436.2016.1182469	journal	August 2016
Substitutionally doped phosphorene: electronic properties and gas sensing Suvansinpan, Nawat; Hussain, Fayyaz; Zhang, Gang Nanotechnology, Vol. 27, Issue 6 https://doi.org/10.1088/0957-4484/27/6/065708	journal	January 2016
Stability and magnetic properties of SnSe monolayer doped by transition metal atom (Mn, Fe, and Co): a first-principles study Tang, Chao; Li, Qinwen; Zhang, Chunxiao Journal of Physics D: Applied Physics, Vol. 51, Issue 24 https://doi.org/10.1088/1361-6463/aac3eb	journal	May 2018
Dwell time, Hartman effect and transport properties in a ferromagnetic phosphorene monolayer Hedayati Kh, Hamed; Faizabadi, Edris Journal of Physics: Condensed Matter, Vol. 30, Issue 8 https://doi.org/10.1088/1361-648x/aaa5e6	journal	February 2018
Tunable optical and excitonic properties of phosphorene via oxidation Sadki, S.; Drissi, L. B. Journal of Physics: Condensed Matter, Vol. 30, Issue 25 https://doi.org/10.1088/1361-648x/aac403	journal	June 2018
Controlling electron flow in anisotropic Dirac materials heterojunctions: a super-diverging lens Betancur-Ocampo, Y. Journal of Physics: Condensed Matter, Vol. 30, Issue 43 https://doi.org/10.1088/1361-648x/aae28a	journal	October 2018
Transport characteristics and dwell time in a bilayer phosphorene barrier Hedayati Kh, Hamed; Faizabadi, Edris Journal of Physics: Condensed Matter, Vol. 31, Issue 3 https://doi.org/10.1088/1361-648x/aaefbd	journal	December 2018
Nano-friction behavior of phosphorene Bai, Lichun; Liu, Bo; Srikanth, Narasimalu Nanotechnology, Vol. 28, Issue 35 https://doi.org/10.1088/1361-6528/aa7a2a	journal	July 2017
Electronic and magnetic properties of 3D transition-metal atom adsorbed arsenene Liu, Ming-Yang; Chen, Qing-Yuan; Huang, Yang Nanotechnology, Vol. 29, Issue 9 https://doi.org/10.1088/1361-6528/aaa684	journal	January 2018
Efficient band structure modulations in two-dimensional MnPSe ₃ /CrSiTe ₃ van der Waals heterostructures Pei, Qi; Wang, Xiaocha; Zou, Jijun Nanotechnology, Vol. 29, Issue 21 https://doi.org/10.1088/1361-6528/aab5ab	journal	March 2018
Effect of vacancies on the mechanical properties of phosphorene nanotubes Sorkin, V.; Zhang, Y. W. Nanotechnology, Vol. 29, Issue 23 https://doi.org/10.1088/1361-6528/aab749	journal	April 2018
HfO ₂ -passivated black phosphorus field effect transistor with long-termed stability and enhanced current on/off ratio Xing, Boran; Guan, Liao; Yu, Ying Nanotechnology, Vol. 30, Issue 34 https://doi.org/10.1088/1361-6528/ab1ffe	journal	June 2019
Black phosphorus @ molybdenum disulfide 2D nanocomposite with broad light absorption and high stability for methylene blue decomposition photocatalyst Jeong, Rak Hyun; Lee, Ji Won; Kim, Dong In Nanotechnology, Vol. 31, Issue 15 https://doi.org/10.1088/1361-6528/ab5e67	journal	January 2020
Electronic and optical properties of strained graphene and other strained 2D materials: a review Naumis, Gerardo G.; Barraza-Lopez, Salvador; Oliva-Leyva, Maurice Reports on Progress in Physics, Vol. 80, Issue 9 https://doi.org/10.1088/1361-6633/aa74ef	journal	August 2017
Two-dimensional SiP: an unexplored direct band-gap semiconductor Zhang, Shengli; Guo, Shiying; Huang, Yaxin 2D Materials, Vol. 4, Issue 1 https://doi.org/10.1088/2053-1583/4/1/015030	journal	December 2016
The rising star of 2D black phosphorus beyond graphene: synthesis, properties and electronic applications Chen, Pengfei; Li, Neng; Chen, Xingzhu 2D Materials, Vol. 5, Issue 1 https://doi.org/10.1088/2053-1583/aa8d37	journal	October 2017
Electric-field modulation of linear dichroism and Faraday rotation in few-layer phosphorene Li, L. L.; Partoens, B.; Xu, W. 2D Materials, Vol. 6, Issue 1 https://doi.org/10.1088/2053-1583/aaf47f	journal	December 2018
Ultra fast metal-free reduction catalyst of partial oxidized violet phosphorus synthesized via controlled mechanical energy Jeong, Rak Hyun; Kim, Dong In; Lee, Ji Won 2D Materials, Vol. 6, Issue 4 https://doi.org/10.1088/2053-1583/ab39c6	journal	September 2019
The electronic and transport properties of the phosphorene nanoribbons Jin, Junchao; Wang, Zhiyong; Dai, Xueqiong Materials Research Express, Vol. 6, Issue 9 https://doi.org/10.1088/2053-1591/ab33a7	journal	July 2019
Spin polarized electronic and optical properties of vacancy defects in armchair phosphorene nanoribbons Notash, Soroush; Fotoohi, Somayeh Materials Research Express, Vol. 6, Issue 11 https://doi.org/10.1088/2053-1591/ab47a7	journal	September 2019
How to ‘train’ your CVD to grow large-area 2D materials Narayanan, Vrinda; M. A., Gokul; Rahman, Atikur Materials Research Express, Vol. 6, Issue 12 https://doi.org/10.1088/2053-1591/ab5383	journal	November 2019
Adsorption of thiophene and SO _x molecules on Cr-doped and Ti-doped graphene nanosheets: a DFT study Yan, Ziqi; Bai, Yu; Sun, Lingjie Materials Research Express, Vol. 6, Issue 12 https://doi.org/10.1088/2053-1591/ab599d	journal	November 2019
Band alignment of two-dimensional semiconductors for designing heterostructures with momentum space matching Özçelik, V. Ongun; Azadani, Javad G.; Yang, Ce Physical Review B, Vol. 94, Issue 3 https://doi.org/10.1103/physrevb.94.035125	journal	July 2016
Quantum transport in defective phosphorene nanoribbons: Effects of atomic vacancies Li, L. L.; Peeters, F. M. Physical Review B, Vol. 97, Issue 7 https://doi.org/10.1103/physrevb.97.075414	journal	February 2018
Tunable auxetic properties in group-IV monochalcogenide monolayers Kong, Xian; Deng, Junkai; Li, Lou Physical Review B, Vol. 98, Issue 18 https://doi.org/10.1103/physrevb.98.184104	journal	November 2018
Thermotropic liquid crystal (5CB) on two-dimensional materials Brown, Paul A.; Fischer, Sean A.; Kołacz, Jakub Physical Review E, Vol. 100, Issue 6 https://doi.org/10.1103/physreve.100.062701	journal	December 2019
Ultralow-Frequency Collective Compression Mode and Strong Interlayer Coupling in Multilayer Black Phosphorus Dong, Shan; Zhang, Anmin; Liu, Kai Physical Review Letters, Vol. 116, Issue 8 https://doi.org/10.1103/physrevlett.116.087401	journal	February 2016
Discovery of Weyl Nodal Lines in a Single-Layer Ferromagnet Feng, Baojie; Zhang, Run-Wu; Feng, Ya Physical Review Letters, Vol. 123, Issue 11 https://doi.org/10.1103/physrevlett.123.116401	journal	September 2019
New two-dimensional phase of tin chalcogenides: Candidates for high-performance thermoelectric materials Dong, Baojuan; Wang, Zhenhai; Hung, Nguyen T. Physical Review Materials, Vol. 3, Issue 1 https://doi.org/10.1103/physrevmaterials.3.013405	journal	January 2019
Biodegradable Black Phosphorus-based Nanomaterials in Biomedicine: Theranostic Applications Wang, Zhen; Liu, Zhiming; Su, Chengkang Current Medicinal Chemistry, Vol. 26, Issue 10 https://doi.org/10.2174/0929867324666170920152529	journal	June 2019
First-Principles Study of Gas Molecule Adsorption on C-doped Zigzag Phosphorene Nanoribbons Yang, Shuai; Wang, Zhiyong; Dai, Xueqiong Coatings, Vol. 9, Issue 11 https://doi.org/10.3390/coatings9110763	journal	November 2019
Phosphorene Is the New Graphene in Biomedical Applications Tatullo, Marco; Genovese, Fabio; Aiello, Elisabetta Materials, Vol. 12, Issue 14 https://doi.org/10.3390/ma12142301	journal	July 2019
2D Materials for Gas Sensing Applications: A Review on Graphene Oxide, MoS2, WS2 and Phosphorene Donarelli, Maurizio; Ottaviano, Luca Sensors, Vol. 18, Issue 11 https://doi.org/10.3390/s18113638	journal	October 2018
Emerging Devices Based on Two-Dimensional Monolayer Materials for Energy Harvesting Fan, Feng Ru; Wu, Wenzhuo Research, Vol. 2019 https://doi.org/10.34133/2019/7367828	journal	November 2019
Two-dimensional silicon and carbon monochalcogenides with the structure of phosphorene Rocca, Dario; Abboud, Ali; Vaitheeswaran, Ganapathy Beilstein Journal of Nanotechnology, Vol. 8 https://doi.org/10.3762/bjnano.8.135	journal	January 2017
Covalent Functionalization and Passivation of Exfoliated Black Phosphorus via Aryl Diazonium Chemistry Ryder, Christopher R.; Wood, Joshua D.; Wells, Spencer A. arXiv https://doi.org/10.48550/arxiv.1605.01012	text	January 2016
Electric-field modulation of linear dichroism and Faraday rotation in few-layer phosphorene Li, L. L.; Partoens, B.; Xu, W. arXiv https://doi.org/10.48550/arxiv.1811.12072	text	January 2018

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