Superhard BC3 in cubic diamond structure

Zhang, Miao; Liu, Hanyu; Li, Quan; Gao, Bo; Wang, Yanchao; Li, Hongdong; Chen, Changfeng; Ma, Yanming

doi:10.1103/PhysRevLett.114.015502

Title: Superhard ${BC}_{3}$ in cubic diamond structure

Journal Article · Mon Jan 05 23:00:00 EST 2015 · Physical Review Letters

DOI: https://doi.org/10.1103/PhysRevLett.114.015502 · OSTI ID:1332439

Zhang, Miao ^[1]; Liu, Hanyu ^[2]; Li, Quan ^[2]; Gao, Bo ^[2]; Wang, Yanchao ^[2]; Li, Hongdong ^[2]; Chen, Changfeng ^[3]; Ma, Yanming ^[2]

Jilin Univ., Changchun (China); Beihua Univ., Jilin (China); UNLV
Jilin Univ., Changchun (China)
Univ. of Nevada, Las Vegas, NV (United States)

We solve the crystal structure of recently synthesized cubic BC₃ using an unbiased swarm structure search, which identifies a highly symmetric BC₃ phase in the cubic diamond structure (d–BC3) that contains a distinct B-B bonding network along the body diagonals of a large 64-atom unit cell. Simulated x-ray diffraction and Raman peaks of d–BC₃ are in excellent agreement with experimental data. Calculated stress-strain relations of d–BC₃ demonstrate its intrinsic superhard nature and reveal intriguing sequential bond-breaking modes that produce superior ductility and extended elasticity, which are unique among superhard solids. Here, the present results establish the first boron carbide in the cubic diamond structure with remarkable properties, and these new findings also provide insights for exploring other covalent solids with complex bonding configurations.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0001982

OSTI ID:: 1332439

Journal Information:: Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 1 Vol. 114; ISSN 0031-9007; ISSN PRLTAO

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (59)

Superconductivity in Diamond. Ekimov, E. A.; Sidorov, V. A.; Bauer, E. D. ChemInform, Vol. 35, Issue 25 https://doi.org/10.1002/chin.200425022	journal	June 2004
CALYPSO: A method for crystal structure prediction Wang, Yanchao; Lv, Jian; Zhu, Li Computer Physics Communications, Vol. 183, Issue 10 https://doi.org/10.1016/j.cpc.2012.05.008	journal	October 2012
Synthesis of superhard materials Novikov, N. V. Journal of Materials Processing Technology, Vol. 161, Issue 1-2 https://doi.org/10.1016/j.jmatprotec.2004.07.071	journal	April 2005
Superhard and superconductive polymorphs of diamond-like BC3 Liu, Hanyu; Li, Quan; Zhu, Li Physics Letters A, Vol. 375, Issue 3 https://doi.org/10.1016/j.physleta.2010.12.034	journal	January 2011
Segregative Crystallization of Several Diamond-like Phases from the Graphitic BC2N without an Additive at 7.7 GPa Nakano, Satoshi; Akaishi, Minoru; Sasaki, Takayoshi Chemistry of Materials, Vol. 6, Issue 12 https://doi.org/10.1021/cm00048a011	journal	December 1994
Solid C60: a new form of carbon Krätschmer, W.; Lamb, Lowell D.; Fostiropoulos, K. Nature, Vol. 347, Issue 6291 https://doi.org/10.1038/347354a0	journal	September 1990
Helical microtubules of graphitic carbon Iijima, Sumio Nature, Vol. 354, Issue 6348 https://doi.org/10.1038/354056a0	journal	November 1991
NMR characterization of isomers of C78, C82 and C84 fullerenes Kikuchi, Koichi; Nakahara, Nobuo; Wakabayashi, Tomonari Nature, Vol. 357, Issue 6374 https://doi.org/10.1038/357142a0	journal	May 1992
Atomistic mechanisms governing elastic limit and incipient plasticity in crystals Li, Ju; Van Vliet, Krystyn J.; Zhu, Ting Nature, Vol. 418, Issue 6895 https://doi.org/10.1038/nature00865	journal	July 2002
Superconductivity in diamond Ekimov, E. A.; Sidorov, V. A.; Bauer, E. D. Nature, Vol. 428, Issue 6982 https://doi.org/10.1038/nature02449	journal	April 2004
Structure of phase III of solid hydrogen Pickard, Chris J.; Needs, Richard J. Nature Physics, Vol. 3, Issue 7 https://doi.org/10.1038/nphys625	journal	May 2007
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
Synthesis and characterization of a shock-synthesized cubic B–C–N solid solution of composition BC _2.5 N Komatsu, Tamikuni; Nomura, Masayuki; Kakudate, Youzou J. Mater. Chem., Vol. 6, Issue 11 https://doi.org/10.1039/jm9960601799	journal	January 1996
Synthesis of superhard cubic BC2N Solozhenko, Vladimir L.; Andrault, Denis; Fiquet, Guillaume Applied Physics Letters, Vol. 78, Issue 10 https://doi.org/10.1063/1.1337623	journal	March 2001
Predicting hardness of dense C3N4 polymorphs He, Julong; Guo, Licong; Guo, Xiaoju Applied Physics Letters, Vol. 88, Issue 10 https://doi.org/10.1063/1.2182109	journal	March 2006
Mechanical properties of superhard BC5 Lazar, P.; Podloucky, R. Applied Physics Letters, Vol. 94, Issue 25 https://doi.org/10.1063/1.3159627	journal	June 2009
Superhard and superconducting structures of BC5 Li, Quan; Wang, Hui; Tian, Yongjun Journal of Applied Physics, Vol. 108, Issue 2 https://doi.org/10.1063/1.3452374	journal	July 2010
Phase transition in BC _x system under high-pressure and high-temperature: Synthesis of cubic dense BC ₃ nanostructured phase Zinin, P. V.; Ming, L. C.; Ishii, H. A. Journal of Applied Physics, Vol. 111, Issue 11 https://doi.org/10.1063/1.4723275	journal	June 2012
Room-temperature structures of solid hydrogen at high pressures Liu, Hanyu; Zhu, Li; Cui, Wenwen The Journal of Chemical Physics, Vol. 137, Issue 7 https://doi.org/10.1063/1.4745186	journal	August 2012
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
Investigation of the relaxation process in the Cu 3 Au-alloy order-disorder phase transition near the transition point Hashimoto,, Takasu; Miyoshi,, Taisuke; Ohtsuka, Hideaki Physical Review B, Vol. 13, Issue 3 https://doi.org/10.1103/PhysRevB.13.1119	journal	February 1976
Electronic properties of random alloys: Special quasirandom structures Wei, S. -H.; Ferreira, L. G.; Bernard, James E. Physical Review B, Vol. 42, Issue 15 https://doi.org/10.1103/PhysRevB.42.9622	journal	November 1990
High-pressure synthesis, characterization, and equation of state of cubic C-BN solid solutions Knittle, E.; Kaner, R. B.; Jeanloz, R. Physical Review B, Vol. 51, Issue 18 https://doi.org/10.1103/PhysRevB.51.12149	journal	May 1995
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Connecting atomistic and experimental estimates of ideal strength Krenn, C. R.; Roundy, D.; Cohen, Marvin L. Physical Review B, Vol. 65, Issue 13 https://doi.org/10.1103/PhysRevB.65.134111	journal	March 2002
Structural deformation, strength, and instability of cubic BN compared to diamond: A first-principles study Zhang, Yi; Sun, Hong; Chen, Changfeng Physical Review B, Vol. 73, Issue 14 https://doi.org/10.1103/PhysRevB.73.144115	journal	April 2006
Prediction of a sandwichlike conducting superhard boron carbide: First-principles calculations Liu, Zhongyuan; He, Julong; Yang, Jun Physical Review B, Vol. 73, Issue 17 https://doi.org/10.1103/PhysRevB.73.172101	journal	May 2006
First-principles study of the lattice dynamics, thermodynamic properties and electron-phonon coupling of Y B 6 Xu, Ying; Zhang, Lijun; Cui, Tian Physical Review B, Vol. 76, Issue 21 https://doi.org/10.1103/PhysRevB.76.214103	journal	December 2007
Transition pathway of C O 2 crystals under high pressures Togo, Atsushi; Oba, Fumiyasu; Tanaka, Isao Physical Review B, Vol. 77, Issue 18 https://doi.org/10.1103/PhysRevB.77.184101	journal	May 2008
First-principles calculations of the ferroelastic transition between rutile-type and CaCl 2 -type SiO 2 at high pressures Togo, Atsushi; Oba, Fumiyasu; Tanaka, Isao Physical Review B, Vol. 78, Issue 13 https://doi.org/10.1103/PhysRevB.78.134106	journal	October 2008
Superhardness, stability, and metallicity of diamondlike BC 5 : Density functional calculations Liang, Yongcheng; Zhang, Wenqing; Zhao, Jianzhi Physical Review B, Vol. 80, Issue 11 https://doi.org/10.1103/PhysRevB.80.113401	journal	September 2009
Crystal structure prediction via particle-swarm optimization Wang, Yanchao; Lv, Jian; Zhu, Li Physical Review B, Vol. 82, Issue 9 https://doi.org/10.1103/PhysRevB.82.094116	journal	September 2010
Proton tunneling in phase IV of hydrogen and deuterium Howie, Ross T.; Scheler, Thomas; Guillaume, Christophe L. Physical Review B, Vol. 86, Issue 21 https://doi.org/10.1103/PhysRevB.86.214104	journal	December 2012
Crystal structures and metastability of carbon-boron compounds C 3 B and C 5 B Mikhaylushkin, Arkady S.; Zhang, Xiuwen; Zunger, Alex Physical Review B, Vol. 87, Issue 9 https://doi.org/10.1103/PhysRevB.87.094103	journal	March 2013
Ultimate Metastable Solubility of Boron in Diamond: Synthesis of Superhard Diamondlike BC 5 Solozhenko, Vladimir L.; Kurakevych, Oleksandr O.; Andrault, Denis Physical Review Letters, Vol. 102, Issue 1 https://doi.org/10.1103/PhysRevLett.102.015506	journal	January 2009
Harder than Diamond: Superior Indentation Strength of Wurtzite BN and Lonsdaleite Pan, Zicheng; Sun, Hong; Zhang, Yi Physical Review Letters, Vol. 102, Issue 5 https://doi.org/10.1103/PhysRevLett.102.055503	journal	February 2009
Soft Bond-Deformation Paths in Superhard γ -Boron Zhou, Wei; Sun, Hong; Chen, Changfeng Physical Review Letters, Vol. 105, Issue 21 https://doi.org/10.1103/PhysRevLett.105.215503	journal	November 2010
Predicted Novel High-Pressure Phases of Lithium Lv, Jian; Wang, Yanchao; Zhu, Li Physical Review Letters, Vol. 106, Issue 1 https://doi.org/10.1103/PhysRevLett.106.015503	journal	January 2011
Substitutional Alloy of Bi and Te at High Pressure Zhu, Li; Wang, Hui; Wang, Yanchao Physical Review Letters, Vol. 106, Issue 14 https://doi.org/10.1103/PhysRevLett.106.145501	journal	April 2011
Mixed Molecular and Atomic Phase of Dense Hydrogen Howie, Ross T.; Guillaume, Christophe L.; Scheler, Thomas Physical Review Letters, Vol. 108, Issue 12 https://doi.org/10.1103/PhysRevLett.108.125501	journal	March 2012
Global Structural Optimization of Tungsten Borides Li, Quan; Zhou, Dan; Zheng, Weitao Physical Review Letters, Vol. 110, Issue 13 https://doi.org/10.1103/PhysRevLett.110.136403	journal	March 2013
Order-Disorder Transformation at the {100} Surface of Cu 3 Au Sundaram, V. S.; Farrell, Brian; Alben, R. S. Physical Review Letters, Vol. 31, Issue 18 https://doi.org/10.1103/PhysRevLett.31.1136	journal	October 1973
Special quasirandom structures Zunger, Alex; Wei, S.-H.; Ferreira, L. G. Physical Review Letters, Vol. 65, Issue 3, p. 353-356 https://doi.org/10.1103/PhysRevLett.65.353	journal	July 1990
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
First-Principles Calculation of Vibrational Raman Spectra in Large Systems: Signature of Small Rings in Crystalline S i O 2 Lazzeri, Michele; Mauri, Francesco Physical Review Letters, Vol. 90, Issue 3 https://doi.org/10.1103/PhysRevLett.90.036401	journal	January 2003
Hardness of Covalent Crystals Gao, Faming; He, Julong; Wu, Erdong Physical Review Letters, Vol. 91, Issue 1 https://doi.org/10.1103/PhysRevLett.91.015502	journal	July 2003
Superhard Cubic B C 2 N Compared to Diamond Zhang, Yi; Sun, Hong; Chen, Changfeng Physical Review Letters, Vol. 93, Issue 19 https://doi.org/10.1103/PhysRevLett.93.195504	journal	November 2004
Atomistic Deformation Modes in Strong Covalent Solids Zhang, Yi; Sun, Hong; Chen, Changfeng Physical Review Letters, Vol. 94, Issue 14 https://doi.org/10.1103/PhysRevLett.94.145505	journal	April 2005
Colossal Shear-Strength Enhancement of Low-Density Cubic BC 2 N by Nanoindentation Pan, Zicheng; Sun, Hong; Chen, Changfeng Physical Review Letters, Vol. 98, Issue 13 https://doi.org/10.1103/PhysRevLett.98.135505	journal	March 2007
Order-Disorder Transformation at the {100} Surface of Cu 3 Au. Sundaram, V. S.; Farrell, Brian; Alben, R. S. Physical Review Letters, Vol. 31, Issue 21 https://doi.org/10.1103/physrevlett.31.1326	journal	November 1973
High Carrier Mobility in Single-Crystal Plasma-Deposited Diamond Isberg, Jan; Hammersberg, Johan; Johansson, Erik Science, Vol. 297, Issue 5587, p. 1670-1672 https://doi.org/10.1126/science.1074374	journal	September 2002
Bonding Changes in Compressed Superhard Graphite Mao, W. L. Science, Vol. 302, Issue 5644 https://doi.org/10.1126/science.1089713	journal	October 2003
Light-Transparent Phase Formed by Room-Temperature Compression of Graphite Yagi, W. U. A. T. Science, Vol. 252, Issue 5012 https://doi.org/10.1126/science.252.5012.1542	journal	June 1991
Electrochemical Behavior of Highly Conductive Boron-Doped Diamond Electrodes for Oxygen Reduction in Acid Solution Yano, T. Journal of The Electrochemical Society, Vol. 146, Issue 3 https://doi.org/10.1149/1.1391724	journal	January 1999
Superhard B–C–N materials synthesized in nanostructured bulks Zhao, Y.; He, D. W.; Daemen, L. L. Journal of Materials Research, Vol. 17, Issue 12 https://doi.org/10.1557/JMR.2002.0454	journal	December 2002
CALYPSO: a method for crystal structure prediction Wang, Yanchao; Lv, Jian; Zhu, Li arXiv https://doi.org/10.48550/arxiv.1205.2264	text	January 2012
Room-Temperature Structures of Solid Hydrogen at High Pressures Liu, Hanyu; Zhu, Li; Cui, Wenwen arXiv https://doi.org/10.48550/arxiv.1205.6092	text	January 2012
Superconductivity in diamond Ekimov, E. A.; Sidorov, V. A.; Bauer, E. D. arXiv https://doi.org/10.48550/arxiv.cond-mat/0404156	text	January 2004

Cited By (26)

Materials discovery at high pressures Zhang, Lijun; Wang, Yanchao; Lv, Jian Nature Reviews Materials, Vol. 2, Issue 4 https://doi.org/10.1038/natrevmats.2017.5	journal	February 2017
Predicting superhard materials via a machine learning informed evolutionary structure search Avery, Patrick; Wang, Xiaoyu; Oses, Corey npj Computational Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41524-019-0226-8	journal	September 2019
Ultrahard stitching of nanotwinned diamond and cubic boron nitride in C2-BN composite Liu, Xiaobing; Chen, Xin; Ma, Hong-An Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep30518	journal	July 2016
Magnetic moment collapse induced axial alternative compressibility of Cr2TiAlC2 at 420 GPa from first principle Ze-Jin, Yang; Rong-Feng, Linghu; Qing-He, Gao Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep34092	journal	September 2016
Superhard-driven search of the covalent network in the B ₃ NO system Li, Qian; Wang, Jianyun; Zhang, Miao RSC Advances, Vol. 5, Issue 45 https://doi.org/10.1039/c5ra02606g	journal	January 2015
Design of ternary alkaline-earth metal Sn( ii ) oxides with potential good p-type conductivity Li, Yuwei; Singh, David J.; Du, Mao-Hua Journal of Materials Chemistry C, Vol. 4, Issue 20 https://doi.org/10.1039/c6tc00996d	journal	January 2016
Phase diagram, stability and electronic properties of an Fe–P system under high pressure: a first principles study Zhao, Ziyuan; Liu, Lulu; Zhang, Shoutao RSC Advances, Vol. 7, Issue 26 https://doi.org/10.1039/c7ra01567d	journal	January 2017
Atomically thin NiB ₆ monolayer: a robust Dirac material Tang, Xiao; Sun, Weiguo; Lu, Cheng Physical Chemistry Chemical Physics, Vol. 21, Issue 2 https://doi.org/10.1039/c8cp05778h	journal	January 2019
Computational discovery and characterization of new B ₂ O phases Wang, Jianyun; Li, Quan; Pickard, Chris J. Physical Chemistry Chemical Physics, Vol. 21, Issue 5 https://doi.org/10.1039/c8cp07161f	journal	January 2019
Theoretical research on novel orthorhombic tungsten dinitride from first principles calculations Li, Qian; Wang, Jianyun; Liu, Hanyu RSC Advances, Vol. 8, Issue 17 https://doi.org/10.1039/c8ra01099d	journal	January 2018
Theoretical investigation of the valence states in Au via the Au–F compounds under high pressure Liu, Guangtao; Feng, Xiaolei; Wang, Linyan Physical Chemistry Chemical Physics, Vol. 21, Issue 32 https://doi.org/10.1039/c9cp02409c	journal	January 2019
Phase transition and electronic properties of skutterudite-type IrP ₃ under high pressure Ma, Xuejiao; Zhou, Dan; Yan, Yan Physical Chemistry Chemical Physics, Vol. 21, Issue 38 https://doi.org/10.1039/c9cp02422k	journal	January 2019
Ground-state structures, physical properties and phase diagram of carbon-rich nitride C ₅ N Wu, Qinghua; Hu, Qianku; Hou, Yiming Journal of Physics: Condensed Matter, Vol. 30, Issue 38 https://doi.org/10.1088/1361-648x/aada2c	journal	August 2018
Exploration of high-pressure structural transition and electronic properties of BaFe ₂ S ₃ Kong, Panlong; Wang, Jingjing; Jin, Yuanyuan Journal of Physics: Condensed Matter, Vol. 31, Issue 11 https://doi.org/10.1088/1361-648x/aaf8f8	journal	January 2019
Unravelling the structure and strength of the highest boride of tungsten WB 4.2 Gong, Weiguang; Liu, Chang; Song, Xianqi Physical Review B, Vol. 100, Issue 22 https://doi.org/10.1103/physrevb.100.220102	journal	December 2019
First-principles study of high-pressure phase stability and superconductivity of Bi 4 I 4 Deng, Shiyu; Song, Xianqi; Shao, Xuecheng Physical Review B, Vol. 100, Issue 22 https://doi.org/10.1103/physrevb.100.224108	journal	December 2019
Unraveling the structure and bonding evolution of the newly discovered iron oxide FeO 2 Lu, Cheng; Amsler, Maximilian; Chen, Changfeng Physical Review B, Vol. 98, Issue 5 https://doi.org/10.1103/physrevb.98.054102	journal	August 2018
CoB 6 monolayer: A robust two-dimensional ferromagnet Tang, Xiao; Sun, Weiguo; Gu, Yuantong Physical Review B, Vol. 99, Issue 4 https://doi.org/10.1103/physrevb.99.045445	journal	January 2019
Anomalous Stress Response of Ultrahard WB n Compounds Li, Quan; Zhou, Dan; Zheng, Weitao Physical Review Letters, Vol. 115, Issue 18 https://doi.org/10.1103/physrevlett.115.185502	journal	October 2015
Rare Helium-Bearing Compound FeO 2 He Stabilized at Deep-Earth Conditions Zhang, Jurong; Lv, Jian; Li, Hefei Physical Review Letters, Vol. 121, Issue 25 https://doi.org/10.1103/physrevlett.121.255703	journal	December 2018
Predicting copper gallium diselenide and band structure engineering through order-disordered transition Liu, Wenjie; Liang, Hanpu; Duan, Yifeng Physical Review Materials, Vol. 3, Issue 12 https://doi.org/10.1103/physrevmaterials.3.125405	journal	December 2019
Computational Discovery and Characterization of New B2O Phases Wang, Jianyun; Quan, Li; Pickard, Christopher Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.36069	text	January 2019
Crystal Structure and Mechanical Properties of ThBC2 Zhou, Xinchun; Zheng, Baobing Crystals, Vol. 9, Issue 8 https://doi.org/10.3390/cryst9080389	journal	July 2019
Detwinning Mechanism for Nanotwinned Cubic Boron Nitride with Unprecedented Strength: A First-Principles Study Yang, Bo; Peng, Xianghe; Sun, Sha Nanomaterials, Vol. 9, Issue 8 https://doi.org/10.3390/nano9081117	journal	August 2019
Design of ternary alkaline-earth metal Sn(II) oxides with potential good p-type conductivity Li, Yuwei; Singh, David J.; Du, Mao-Hua arXiv https://doi.org/10.48550/arxiv.1605.08252	text	January 2016
Predicting Superhard Materials via a Machine Learning Informed Evolutionary Structure Search Avery, Patrick; Wang, Xiaoyu; Proserpio, Davide M. arXiv https://doi.org/10.48550/arxiv.1906.05886	preprint	January 2019

Similar Records

Computational prediction of body-centered cubic carbon in an all-

s p^{3}

six-member ring configuration

Journal Article · Thu Jun 11 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1332443

Li, Zhen -Zhen; Lian, Chao -Sheng; Xu, Jing; +3 more

Phase transition in BC[subscript x] system under high-pressure and high-temperature: Synthesis of cubic dense BC[subscript 3] nanostructured phase

Journal Article · Wed Jul 11 00:00:00 EDT 2012 · Journal of Applied Physics · OSTI ID:1043080

Zinin, P V; Ming, L C; Ishii, H A; +3 more

Synthesis of bulk superhard semiconducting B-C material

Journal Article · Mon Aug 30 00:00:00 EDT 2004 · Applied Physics Letters · OSTI ID:20632757

Solozhenko, Vladimir L; Dubrovinskaia, Natalia A; Dubrovinsky, Leonid S

Related Subjects

36 MATERIALS SCIENCE

Title: Superhard BC 3 in cubic diamond structure

Citation Formats

References (59)

Cited By (26)

Similar Records

Related Subjects

Title: Superhard ${BC}_{3}$ in cubic diamond structure