Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries
Abstract
A fluorine-doped antiperovskite Li-ion conducto Li2(OH)X (X=Cl, Br) is shown to be a promising candidat for a solid electrolyte in an all-solid-state Li-ion rechargeabl battery. Substitution of F¯ for OH¯ transforms orthorhombi Li2OHCl to a room-temperature cubic phase, which show electrochemical stability to 9 V versus Li+/Li and two orders o magnitude higher Li-ion conductivity than that of orthorhombi Li2OHCl. As a result, an all-solid-state Li/LiFePO4 with F-dope Li2OHCl as the solid electrolyte showed good cyclability an a high coulombic efficiency over 40 charge/discharge cycles
- Authors:
-
[4];
[4];
- Univ. of Texas at Austin, Austin, TX (United States)
- Univ. of Texas at Austin, Austin, TX (United States); Hefei Univ. of Technology, Anhui (People's Republic of China)
- Univ. of Nevada, Las Vegas, NV (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of Nevada, Las Vegas, NV (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1414136
- Alternate Identifier(s):
- OSTI ID: 1332392; OSTI ID: 1400457
- Report Number(s):
- LA-UR-17-20628
Journal ID: ISSN 1433-7851
- Grant/Contract Number:
- AC52-06NA25396; NA0001982
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 55; Journal Issue: 34; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Energy Sciences; all-solid-state battery; antiperovskite; lithium-ion battery; solid electrolyte
Citation Formats
Li, Yutao, Zhou, Weidong, Xin, Sen, Li, Shuai, Zhu, Jinlong, Lu, Xujie, Cui, Zhiming, Jia, Quanxi, Zhou, Jianshi, Zhao, Yusheng, and Goodenough, John B. Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries. United States: N. p., 2016.
Web. doi:10.1002/anie.201604554.
Li, Yutao, Zhou, Weidong, Xin, Sen, Li, Shuai, Zhu, Jinlong, Lu, Xujie, Cui, Zhiming, Jia, Quanxi, Zhou, Jianshi, Zhao, Yusheng, & Goodenough, John B. Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries. United States. https://doi.org/10.1002/anie.201604554
Li, Yutao, Zhou, Weidong, Xin, Sen, Li, Shuai, Zhu, Jinlong, Lu, Xujie, Cui, Zhiming, Jia, Quanxi, Zhou, Jianshi, Zhao, Yusheng, and Goodenough, John B. Thu .
"Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries". United States. https://doi.org/10.1002/anie.201604554. https://www.osti.gov/servlets/purl/1414136.
@article{osti_1414136,
title = {Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries},
author = {Li, Yutao and Zhou, Weidong and Xin, Sen and Li, Shuai and Zhu, Jinlong and Lu, Xujie and Cui, Zhiming and Jia, Quanxi and Zhou, Jianshi and Zhao, Yusheng and Goodenough, John B.},
abstractNote = {A fluorine-doped antiperovskite Li-ion conducto Li2(OH)X (X=Cl, Br) is shown to be a promising candidat for a solid electrolyte in an all-solid-state Li-ion rechargeabl battery. Substitution of F¯ for OH¯ transforms orthorhombi Li2OHCl to a room-temperature cubic phase, which show electrochemical stability to 9 V versus Li+/Li and two orders o magnitude higher Li-ion conductivity than that of orthorhombi Li2OHCl. As a result, an all-solid-state Li/LiFePO4 with F-dope Li2OHCl as the solid electrolyte showed good cyclability an a high coulombic efficiency over 40 charge/discharge cycles},
doi = {10.1002/anie.201604554},
journal = {Angewandte Chemie (International Edition)},
number = 34,
volume = 55,
place = {United States},
year = {Thu Jun 30 00:00:00 EDT 2016},
month = {Thu Jun 30 00:00:00 EDT 2016}
}
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