ZrB2-HfB2 solid solutions as electrode materials for hydrogen reaction in acidic and basic solutions
Abstract
Spark plasma sintered transition metal diborides such as HfB2, ZrB2 and their solid solutions were investigated as electrode materials for electrochemical hydrogen evolutions reactions (HER) in 1 M H2SO4 and 1 M NaOH electrolytes. HfB2 and ZrB2 formed complete solid solutions when mixed in 1:1, 1:4, and 4:1 ratios and they were stable in both electrolytes. The HER kinetics of the diborides were slower in the basic solution than in the acidic solutions. The Tafel slopes in 1 M H2SO4 were in the range of 0.15 - 0.18 V/decade except for pure HfB2 which showed a Tafel slope of 0.38 V/decade. In 1 M NaOH the Tafel slopes were in the range of 0.12 - 0.27 V/decade. The composition of HfxZr1-xB2 solid solutions with x = 0.2 - 0.8, influenced the exchange current densities, overpotentials and Tafel slopes of the HER. As a result, the EIS data were fitted with a porous film equivalent circuit model in order to better understand the HER behavior. In addition, modeling calculations, using density functional theory approach, were carried out to estimate the density of states and band structure of the boride solid solutions.
- Authors:
-
- Univ. of Idaho, Moscow, ID (United States)
- Publication Date:
- Research Org.:
- Univ. of Idaho, Moscow, ID (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1331595
- Alternate Identifier(s):
- OSTI ID: 1411449
- Grant/Contract Number:
- FE0022988
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Materials Letters
- Additional Journal Information:
- Journal Name: Materials Letters; Journal ID: ISSN 0167-577X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; electroceramics; energy storage and conversion; solar energy materials; borides; ceramic composites
Citation Formats
Sitler, Steven J., Raja, Krishnan S., and Charit, Indrajit. ZrB2-HfB2 solid solutions as electrode materials for hydrogen reaction in acidic and basic solutions. United States: N. p., 2016.
Web. doi:10.1016/j.matlet.2016.10.122.
Sitler, Steven J., Raja, Krishnan S., & Charit, Indrajit. ZrB2-HfB2 solid solutions as electrode materials for hydrogen reaction in acidic and basic solutions. United States. https://doi.org/10.1016/j.matlet.2016.10.122
Sitler, Steven J., Raja, Krishnan S., and Charit, Indrajit. Wed .
"ZrB2-HfB2 solid solutions as electrode materials for hydrogen reaction in acidic and basic solutions". United States. https://doi.org/10.1016/j.matlet.2016.10.122. https://www.osti.gov/servlets/purl/1331595.
@article{osti_1331595,
title = {ZrB2-HfB2 solid solutions as electrode materials for hydrogen reaction in acidic and basic solutions},
author = {Sitler, Steven J. and Raja, Krishnan S. and Charit, Indrajit},
abstractNote = {Spark plasma sintered transition metal diborides such as HfB2, ZrB2 and their solid solutions were investigated as electrode materials for electrochemical hydrogen evolutions reactions (HER) in 1 M H2SO4 and 1 M NaOH electrolytes. HfB2 and ZrB2 formed complete solid solutions when mixed in 1:1, 1:4, and 4:1 ratios and they were stable in both electrolytes. The HER kinetics of the diborides were slower in the basic solution than in the acidic solutions. The Tafel slopes in 1 M H2SO4 were in the range of 0.15 - 0.18 V/decade except for pure HfB2 which showed a Tafel slope of 0.38 V/decade. In 1 M NaOH the Tafel slopes were in the range of 0.12 - 0.27 V/decade. The composition of HfxZr1-xB2 solid solutions with x = 0.2 - 0.8, influenced the exchange current densities, overpotentials and Tafel slopes of the HER. As a result, the EIS data were fitted with a porous film equivalent circuit model in order to better understand the HER behavior. In addition, modeling calculations, using density functional theory approach, were carried out to estimate the density of states and band structure of the boride solid solutions.},
doi = {10.1016/j.matlet.2016.10.122},
journal = {Materials Letters},
number = ,
volume = ,
place = {United States},
year = {Wed Nov 09 00:00:00 EST 2016},
month = {Wed Nov 09 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Recent advances in heterogeneous electrocatalysts for the hydrogen evolution reaction
journal, January 2015
- Zeng, Min; Li, Yanguang
- Journal of Materials Chemistry A, Vol. 3, Issue 29
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
journal, November 2012
- Vrubel, Heron; Hu, Xile
- Angewandte Chemie International Edition, Vol. 51, Issue 51
Cobalt-Boride: An efficient and robust electrocatalyst for Hydrogen Evolution Reaction
journal, April 2015
- Gupta, Suraj; Patel, Nainesh; Miotello, Antonio
- Journal of Power Sources, Vol. 279
Amorphous Cobalt Boride (Co 2 B) as a Highly Efficient Nonprecious Catalyst for Electrochemical Water Splitting: Oxygen and Hydrogen Evolution
journal, January 2016
- Masa, Justus; Weide, Philipp; Peeters, Daniel
- Advanced Energy Materials, Vol. 6, Issue 6
Electrocatalytic properties of amorphous nickel boride electrodes for hydrogen evolution reaction in alkaline solution
journal, July 1992
- Los, Przemyslaw; Lasia, Andrzej
- Journal of Electroanalytical Chemistry, Vol. 333, Issue 1-2
Nanostructured Amorphous Nickel Boride for High-Efficiency Electrocatalytic Hydrogen Evolution over a Broad pH Range
journal, January 2016
- Zeng, Min; Wang, Hao; Zhao, Chong
- ChemCatChem, Vol. 8, Issue 4
Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives
journal, June 2013
- Carenco, Sophie; Portehault, David; Boissière, Cédric
- Chemical Reviews, Vol. 113, Issue 10, p. 7981-8065
Layered titanium diboride: towards exfoliation and electrochemical applications
journal, January 2015
- Lim, Chee Shan; Sofer, Zdeněk; Mazánek, Vlastimil
- Nanoscale, Vol. 7, Issue 29
Solid solution ranges of zirconium diboride with other refractory diborides: HfB2, TiB2, TaB2, NbB2, VB2 and CrB2
journal, May 2009
- Otani, S.; Aizawa, T.; Kieda, N.
- Journal of Alloys and Compounds, Vol. 475, Issue 1-2
On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution
journal, October 2001
- Krstajić, N.; Popović, M.; Grgur, B.
- Journal of Electroanalytical Chemistry, Vol. 512, Issue 1-2
Impedance plane display of a reaction with an adsorbed intermediate
journal, September 1972
- Armstrong, R. D.; Henderson, M.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 1
Phase stability and electronic structure of and and of Sc-stabilized cubic precipitates
journal, June 1990
- Xu, J. -H.; Freeman, A. J.
- Physical Review B, Vol. 41, Issue 18
Electronic structure and equation of state of TiB 2
journal, November 1992
- Tian, De-Cheng; Wang, Xiao-Bing
- Journal of Physics: Condensed Matter, Vol. 4, Issue 45
Ab Initio Computations of Electronic, Mechanical, and Thermal Properties of ZrB 2 and HfB 2
journal, July 2011
- Lawson, John W.; Bauschlicher, Charles W.; Daw, Murray S.
- Journal of the American Ceramic Society, Vol. 94, Issue 10
Selected properties of Pt(111) modified surfaces: A DFT study
journal, November 2015
- Pinto, Leandro M. C.; Maia, Gilberto
- Electrochemistry Communications, Vol. 60
Electronic structure, bonding, and ground-state properties of AlB_{2}-type transition-metal diborides
journal, January 2001
- Vajeeston, P.; Ravindran, P.; Ravi, C.
- Physical Review B, Vol. 63, Issue 4
Works referencing / citing this record:
Molten salt synthesis, characterization, and formation mechanism of superfine (Hf x Zr 1‐ x )B 2 solid‐solution powders
journal, December 2018
- Liu, Da; Wen, Tongqi; Ye, Beilin
- Journal of the American Ceramic Society, Vol. 102, Issue 6