Characterization of Ordering in A-Site Deficient Perovskite Ca 1– x La 2 x /3 TiO 3 Using STEM/EELS

Danaie, Mohsen; Kepaptsoglou, Demie; Ramasse, Quentin M.; Ophus, Colin; Whittle, Karl R.; Lawson, Sebastian M.; Pedrazzini, Stella; Young, Neil P.; Bagot, Paul A. J.; Edmondson, Philip D.

doi:10.1021/acs.inorgchem.6b02087

Title: Characterization of Ordering in A-Site Deficient Perovskite Ca _{1– x} La _{2 x /3} TiO ₃ Using STEM/EELS

Authors:

Danaie, Mohsen ^[1]; Kepaptsoglou, Demie ^[2]; Ramasse, Quentin M. ^[2]; Ophus, Colin ^[3]; Whittle, Karl R. ^[4]; Lawson, Sebastian M. ^[5]; Pedrazzini, Stella ^[1]; Young, Neil P. ^[1]; Bagot, Paul A. J. ^[1]; Edmondson, Philip D. ^[6]

University of Oxford, Department of Materials, Parks Road, Oxford OX1 3PH, U.K.
SuperSTEM Laboratory, SciTech Daresbury Campus, Keckwick Ln, Warrington WA4 4AD, U.K.
National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, 67 Cyclotron Road, Berkeley, California 94720, United States
University of Sheffield, Department of Materials Science & Engineering, Immobilisation Science Laboratory, Mappin Street, Sheffield S1 3JD, U.K., School of Engineering, University of Liverpool, Brownlow Hill, Liverpool L69 3GH, U.K.
University of Sheffield, Department of Materials Science & Engineering, Immobilisation Science Laboratory, Mappin Street, Sheffield S1 3JD, U.K.
Materials Science & Technology Division, Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, Tennessee 37831, United States

Publication Date:: Thu Sep 15 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Fusion Energy Sciences (FES)

OSTI Identifier:: 1328524

Alternate Identifier(s):: OSTI ID: 1329131; OSTI ID: 1440000

Grant/Contract Number:: AC02-05CH11231; AC05-00OR22725

Resource Type:: Published Article

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Name: Inorganic Chemistry Journal Volume: 55 Journal Issue: 19; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Danaie, Mohsen, Kepaptsoglou, Demie, Ramasse, Quentin M., Ophus, Colin, Whittle, Karl R., Lawson, Sebastian M., Pedrazzini, Stella, Young, Neil P., Bagot, Paul A. J., and Edmondson, Philip D. Characterization of Ordering in A-Site Deficient Perovskite Ca 1– x La 2 x /3 TiO 3 Using STEM/EELS.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.inorgchem.6b02087.

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                    Danaie, Mohsen, Kepaptsoglou, Demie, Ramasse, Quentin M., Ophus, Colin, Whittle, Karl R., Lawson, Sebastian M., Pedrazzini, Stella, Young, Neil P., Bagot, Paul A. J., & Edmondson, Philip D. Characterization of Ordering in A-Site Deficient Perovskite Ca 1– x La 2 x /3 TiO 3 Using STEM/EELS.  United States.  https://doi.org/10.1021/acs.inorgchem.6b02087

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                    Danaie, Mohsen, Kepaptsoglou, Demie, Ramasse, Quentin M., Ophus, Colin, Whittle, Karl R., Lawson, Sebastian M., Pedrazzini, Stella, Young, Neil P., Bagot, Paul A. J., and Edmondson, Philip D. Thu .  
"Characterization of Ordering in A-Site Deficient Perovskite Ca 1– x La 2 x /3 TiO 3 Using STEM/EELS".  United States.  https://doi.org/10.1021/acs.inorgchem.6b02087.

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@article{osti_1328524,

  title        = {Characterization of Ordering in A-Site Deficient Perovskite Ca 1– x La 2 x /3 TiO 3 Using STEM/EELS},

  author       = {Danaie, Mohsen and Kepaptsoglou, Demie and Ramasse, Quentin M. and Ophus, Colin and Whittle, Karl R. and Lawson, Sebastian M. and Pedrazzini, Stella and Young, Neil P. and Bagot, Paul A. J. and Edmondson, Philip D.},

  abstractNote = {},

  doi          = {10.1021/acs.inorgchem.6b02087},

  journal      = {Inorganic Chemistry},

  number       = 19,

  volume       = 55,

  place        = {United States},

  year         = {Thu Sep 15 00:00:00 EDT 2016},

  month        = {Thu Sep 15 00:00:00 EDT 2016}

}

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Title: Characterization of Ordering in A-Site Deficient Perovskite Ca 1– x La 2 x /3 TiO 3 Using STEM/EELS

Citation Formats

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High-Pressure Synthesis of A -Site Ordered Double Perovskite CaMnTi 2 O 6 and Ferroelectricity Driven by Coupling of A -Site Ordering and the Second-Order Jahn–Teller Effect journal, April 2014

Lanthanum doped calcium titanates: synthesis, crystal structure, thermal expansion and transport properties journal, May 2003

Ion Mobility Pathways of the Li + Conductor Li 0.125 La 0.625 TiO 3 by Ab Initio Simulations journal, June 2008

Inversion of defect interactions due to ordering in Sr 1 − 3 x ∕ 2 La x TiO 3 perovskites: An atomistic simulation study journal, December 2006

Electron diffraction of tilted perovskites journal, July 2005

Structures and phase transition in the layered perovskite La 0.6 Sr 0.1 TiO 3 : a new orthorhombic structure solved from high-resolution diffraction in combination with group theoretical analysis journal, June 2003

Dielectric properties of a-site deficient perovskite-type lanthanum-calcium-titanium oxide solid solution system [] journal, March 1995

Cation ordering in A-site-deficient Li-ion conducting perovskites La (1−x)/3 Li x NbO 3 journal, January 2015

Practical aspects of atomic resolution imaging and analysis in STEM journal, June 1999

Suppression of strain coupling in perovskite La 0.6 Sr 0.1 Ti O 3 by cation disorder journal, August 2007

Unravelling the complex nanostructure of La 0.5−x Li 0.5−x Sr 2x TiO 3 Li ionic conductors journal, January 2016

Twin boundaries in perovskite journal, April 1985

X-ray study of the deficient perovskite journal, February 1974

In situ radiation damage studies of LaxSr1−3x∕2TiO3 perovskites journal, April 2008

Direct Mapping of Octahedral Tilts in Perovskite Oxide Materials Using Bright Field Scanning Transmission Electron Microscopy journal, July 2012

On the structure of Perovskite from the Burgumer Alp, Pfitschthal, Tyrol journal, November 1908

Chessboard/Diamond Nanostructures and the A -site Deficient, Li 1/2–3 x Nd 1/2+ x TiO 3 , Defect Perovskite Solid Solution journal, January 2013

Phase separation, cation ordering and nano-structural complexities in Nd2/3−xLi3xTiO3 with x=0.14 journal, December 2008

Simple ways of determining perovskite structures journal, November 1975

Advanced Computing in Electron Microscopy book, January 2010

Direct Observation of Ferrielectricity at Ferroelastic Domain Boundaries in CaTiO 3 by Electron Microscopy journal, December 2011

Crystal structures and crystal chemistry of the RETiO3 perovskites: RE = La, Nd, Sm, Gd, Y journal, October 1979

Cation ordering in perovskites journal, January 2010

Direct experimental determination of the atomic structure at internal interfaces journal, July 1996

The Lanthanum-Titanium-Oxygen System journal, December 1955

Cation ordering in complex oxides journal, October 1999

Crystal Structure and Microstructure of Some La 2/ 3 - x Li 3 x TiO 3 Oxides: An Example of the Complementary Use of Electron Diffraction and Microscopy and Synchrotron X-ray Diffraction To Study Complex Materials journal, March 2004

Structural studies on A -cation-deficient perovskite-related phases. II. Microdomain formation in ThNb 4 O 12 journal, November 1982

High ionic conductivity in lithium lanthanum titanate journal, June 1993

On the Origin of Nanochessboard Superlattices in A-Site-Deficient Ca-Stabilized Nd 2/3 TiO 3 journal, January 2015

The Crystal Structure of LaAlO 3 -Stabilized La 2/3 TiO 3 Ceramics: An HRTEM Investigation journal, September 2009

A-site deficient perovskite-type compounds in the ternary CaTiO3-LaCrO3-La2/3TiO3 system journal, August 2006

Immobilisation of high level nuclear reactor wastes in SYNROC journal, March 1979

Octahedral Tilt Propagation Controlled by A-Site Cation Size at Perovskite Oxide Heterointerfaces journal, April 2014

Title: Characterization of Ordering in A-Site Deficient Perovskite Ca _{1– x} La _{2 x /3} TiO ₃ Using STEM/EELS

Correcting nonlinear drift distortion of scanning probe and scanning transmission electron microscopies from image pairs with orthogonal scan directions
journal, March 2016

Direct Observation of A-Site Vacancies and a Twin Boundary Structure in La _2/3 TiO ₃ -Based Ceramics Using HAADF/STEM
journal, January 2010

A review of focused ion beam milling techniques for TEM specimen preparation
journal, June 1999

Observation of structural units at symmetric [001] tilt boundaries in SrTiO3
journal, January 1995

A high resolution neutron diffraction study of the perovskite LaTiO3
journal, February 1986

Nano-chessboard superlattices formed by spontaneous phase separation in oxides
journal, June 2007

Reversible Cation/Anion Extraction from K ₂ La ₂ Ti ₃ O ₁₀ : Formation of New Layered Titanates, KLa ₂ Ti ₃ O _9.5 and La ₂ Ti ₃ O ₉
journal, October 2006

Effect of small crystal tilt on atomic-resolution high-angle annular dark field STEM imaging
journal, August 2002

Electron diffraction of ABX ₃ perovskites with both layered ordering of A cations and tilting of BX ₆ octahedra
journal, June 2009

Structures and phase diagram for the system CaTiO3–La2/3TiO3
journal, March 2007

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

The structure of the A -cation-deficient perovskite UNb ₄ O ₁₂
journal, February 1985

Domain boundary engineering
journal, June 2009

Space group and crystal structure of the Perovskite CaTiO3 from 296 to 1720K
journal, September 2005

The System La ₂ O ₃ - TiO ₅ ; Phase Equilibria and Electrical Properties
journal, September 1962

A-site cation ordering in AA′BB′O6 perovskites
journal, April 2006

Direct mapping of Li-enabled octahedral tilt ordering and associated strain in nanostructured perovskites
journal, August 2015

Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State
journal, February 2008

Crystal structures and phase transition in the system SrTiO3–La2/3TiO3
journal, August 2004

Structural and Microstructural Studies of the Series La2/3−xLi3x□1/3−2xTiO3
journal, December 1996

Microstructure Characterization of the (1− x )La _2/3 TiO ₃ · x LaAlO ₃ System
journal, August 2003

Structural distortions in families of perovskite-like crystals
journal, October 2001

High-Pressure Synthesis of A -Site Ordered Double Perovskite CaMnTi ₂ O ₆ and Ferroelectricity Driven by Coupling of A -Site Ordering and the Second-Order Jahn–Teller Effect
journal, April 2014

Lanthanum doped calcium titanates: synthesis, crystal structure, thermal expansion and transport properties
journal, May 2003

Ion Mobility Pathways of the Li ⁺ Conductor Li _0.125 La _0.625 TiO ₃ by Ab Initio Simulations
journal, June 2008

Inversion of defect interactions due to ordering in ${Sr}_{1 - 3 x ∕ 2} {La}_{x} {TiO}_{3}$ perovskites: An atomistic simulation study
journal, December 2006

Electron diffraction of tilted perovskites
journal, July 2005

Structures and phase transition in the layered perovskite La _0.6 Sr _0.1 TiO ₃ : a new orthorhombic structure solved from high-resolution diffraction in combination with group theoretical analysis
journal, June 2003

Dielectric properties of a-site deficient perovskite-type lanthanum-calcium-titanium oxide solid solution system []
journal, March 1995

Cation ordering in A-site-deficient Li-ion conducting perovskites La _(1−x)/3 Li _x NbO ₃
journal, January 2015

Practical aspects of atomic resolution imaging and analysis in STEM
journal, June 1999

Suppression of strain coupling in perovskite ${La}_{0.6} {Sr}_{0.1} Ti O_{3}$ by cation disorder
journal, August 2007

Unravelling the complex nanostructure of La _0.5−x Li _0.5−x Sr _2x TiO ₃ Li ionic conductors
journal, January 2016

Twin boundaries in perovskite
journal, April 1985

X-ray study of the deficient perovskite
journal, February 1974

In situ radiation damage studies of LaxSr1−3x∕2TiO3 perovskites
journal, April 2008

Direct Mapping of Octahedral Tilts in Perovskite Oxide Materials Using Bright Field Scanning Transmission Electron Microscopy
journal, July 2012

On the structure of Perovskite from the Burgumer Alp, Pfitschthal, Tyrol
journal, November 1908

Chessboard/Diamond Nanostructures and the A -site Deficient, Li _{1/2–3 x} Nd _{1/2+ x} TiO ₃ , Defect Perovskite Solid Solution
journal, January 2013

Phase separation, cation ordering and nano-structural complexities in Nd2/3−xLi3xTiO3 with x=0.14
journal, December 2008

Simple ways of determining perovskite structures
journal, November 1975

Advanced Computing in Electron Microscopy
book, January 2010

Direct Observation of Ferrielectricity at Ferroelastic Domain Boundaries in CaTiO ₃ by Electron Microscopy
journal, December 2011

Crystal structures and crystal chemistry of the RETiO3 perovskites: RE = La, Nd, Sm, Gd, Y
journal, October 1979

Cation ordering in perovskites
journal, January 2010

Direct experimental determination of the atomic structure at internal interfaces
journal, July 1996

The Lanthanum-Titanium-Oxygen System
journal, December 1955

Cation ordering in complex oxides
journal, October 1999

Crystal Structure and Microstructure of Some La _2/ ₃ _- _x Li ₃ _x TiO ₃ Oxides: An Example of the Complementary Use of Electron Diffraction and Microscopy and Synchrotron X-ray Diffraction To Study Complex Materials
journal, March 2004

Structural studies on A -cation-deficient perovskite-related phases. II. Microdomain formation in ThNb ₄ O ₁₂
journal, November 1982

High ionic conductivity in lithium lanthanum titanate
journal, June 1993

On the Origin of Nanochessboard Superlattices in A-Site-Deficient Ca-Stabilized Nd _2/3 TiO ₃
journal, January 2015

The Crystal Structure of LaAlO ₃ -Stabilized La _2/3 TiO ₃ Ceramics: An HRTEM Investigation
journal, September 2009

A-site deficient perovskite-type compounds in the ternary CaTiO3-LaCrO3-La2/3TiO3 system
journal, August 2006

Immobilisation of high level nuclear reactor wastes in SYNROC
journal, March 1979

Octahedral Tilt Propagation Controlled by A-Site Cation Size at Perovskite Oxide Heterointerfaces
journal, April 2014