A self-forming composite electrolyte for solid-state sodium battery with ultra-long cycle life

Zhang, Zhizhen; Yang, Xiao -Qing; Zhang, Qinghua; Shi, Jinan; Chu, Yong S.; Yu, Xiqian; Xu, Kaiqi; Ge, Mingyuan; Yan, Hanfei; Li, Wenjun; Gu, Lin; Hu, Yong -Sheng; Li, Hong; Chen, Liquan; Huang, Xuejie

doi:10.1002/aenm.201601196

Title: A self-forming composite electrolyte for solid-state sodium battery with ultra-long cycle life

Journal Article · Mon Oct 31 04:00:00 UTC 2016 · Advanced Energy Materials (Online)

DOI: https://doi.org/10.1002/aenm.201601196 · OSTI ID:1326759

Zhang, Zhizhen ^[1]; Yang, Xiao -Qing ^[2]; Zhang, Qinghua ^[3]; Shi, Jinan ^[3]; Chu, Yong S. ^[2]; Yu, Xiqian ^[2]; Xu, Kaiqi ^[1]; Ge, Mingyuan ^[2]; Yan, Hanfei ^[2]; Li, Wenjun ^[1]; Gu, Lin ^[3]; Hu, Yong -Sheng ^[1]; Li, Hong ^[1]; Chen, Liquan ^[1]; Huang, Xuejie ^[1]

Univ. of Chinese Academy of Sciences, Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Chinese Academy of Sciences (CAS), Beijing (China)

Replacing organic liquid electrolyte with inorganic solid electrolytes (SE) can potentially address the inherent safety problems in conventional rechargeable batteries. Furthermore, all-solid-state batteries have been plagues by the relatively low ionic conductivity of solid electrolytes and large charge-transfer resistance resulted from solid-solid interfaces between electrode materials and solid electrolytes. Here we report a new design strategy for improving the ionic conductivity of solid electrolyte by self-forming a composite material. An optimized Na⁺ ion conducting composite electrolyte derived from the NASICON structure was successfully synthesized, yielding ultra-high ionic conductivity of 3.4 mS cm^–1 at 25°C and 14 ms cm^–1 at 80°C.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI ID:: 1326759

Report Number(s):: BNL--112661-2016-JA; VT1201000

Journal Information:: Advanced Energy Materials (Online), Journal Name: Advanced Energy Materials (Online); ISSN 1614-6840

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (36)

A Battery Made from a Single Material Han, Fudong; Gao, Tao; Zhu, Yujie Advanced Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adma.201500180	journal	April 2015
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721 https://doi.org/10.1002/aenm.201200026	journal	May 2012
Superior Electrochemical Performance and Storage Mechanism of Na ₃ V ₂ (PO ₄ ) ₃ Cathode for Room-Temperature Sodium-Ion Batteries Jian, Zelang; Han, Wenze; Lu, Xia Advanced Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1002/aenm.201200558	journal	October 2012
Dielectric Modification of 5V-Class Cathodes for High-Voltage All-Solid-State Lithium Batteries Yada, Chihiro; Ohmori, Akihiro; Ide, Kazuto Advanced Energy Materials, Vol. 4, Issue 9 https://doi.org/10.1002/aenm.201301416	journal	March 2014
Excellent Compatibility of Solvate Ionic Liquids with Sulfide Solid Electrolytes: Toward Favorable Ionic Contacts in Bulk-Type All-Solid-State Lithium-Ion Batteries Oh, Dae Yang; Nam, Young Jin; Park, Kern Ho Advanced Energy Materials, Vol. 5, Issue 22 https://doi.org/10.1002/aenm.201500865	journal	August 2015
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage Kundu, Dipan; Talaie, Elahe; Duffort, Victor Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410376	journal	February 2015
Rechargeable batteries: challenges old and new Goodenough, John B. Journal of Solid State Electrochemistry, Vol. 16, Issue 6 https://doi.org/10.1007/s10008-012-1751-2	journal	May 2012
Crystal structures and crystal chemistry in the system Na1+xZr2SixP3−xO12 Hong, H. Y-P. Materials Research Bulletin, Vol. 11, Issue 2 https://doi.org/10.1016/0025-5408(76)90073-8	journal	February 1976
Fast Na+-ion transport in skeleton structures Goodenough, J. B.; Hong, H. Y-P.; Kafalas, J. A. Materials Research Bulletin, Vol. 11, Issue 2 https://doi.org/10.1016/0025-5408(76)90077-5	journal	February 1976
Phase transition in nasicon (Na3Zr2Si2PO12) von Alpen, U.; Bell, M. F.; Wichelhaus, W. Materials Research Bulletin, Vol. 14, Issue 10 https://doi.org/10.1016/0025-5408(79)90010-2	journal	October 1979
Phase transformation in Na1+xSixZr2P3−xO12 compounds Boilot, J. P.; Salanié, J. P.; Desplanches, G. Materials Research Bulletin, Vol. 14, Issue 11 https://doi.org/10.1016/0025-5408(79)90091-6	journal	November 1979
Composition and conduction mechanism of the NASICON structure X-ray diffraction study on two crystals at different temperatures Kohler, Heinz; Schulz, Heinz; Melnikov, Oleg Materials Research Bulletin, Vol. 18, Issue 9 https://doi.org/10.1016/0025-5408(83)90158-7	journal	September 1983
Crystal structure of the true nasicon: Na3Zr2Si2PO12 Boilot, J. P.; Collin, G.; Colomban, Ph. Materials Research Bulletin, Vol. 22, Issue 5 https://doi.org/10.1016/0025-5408(87)90116-4	journal	May 1987
Ionic conduction in space charge regions Maier, Joachim Progress in Solid State Chemistry, Vol. 23, Issue 3 https://doi.org/10.1016/0079-6786(95)00004-E	journal	January 1995
Neutron powder diffraction study and ionic conductivity of Na2Zr2SiP2O12 and Na3Zr2Si2PO12 Baur, W.; Dygas, J.; Whitmore, D. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90290-0	journal	January 1986
Conductivity measurements on nasicon and nasicon-modified materials Bohnke, O. Solid State Ionics, Vol. 122, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00062-4	journal	July 1999
N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13–TFSI) – novel electrolyte base for Li battery Sakaebe, Hikari; Matsumoto, Hajime Electrochemistry Communications, Vol. 5, Issue 7 https://doi.org/10.1016/S1388-2481(03)00137-1	journal	July 2003
Novel technique to form electrode–electrolyte nanointerface in all-solid-state rechargeable lithium batteries Hayashi, Akitoshi; Nishio, Yusuke; Kitaura, Hirokazu Electrochemistry Communications, Vol. 10, Issue 12 https://doi.org/10.1016/j.elecom.2008.09.026	journal	December 2008
Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries Jian, Zelang; Zhao, Liang; Pan, Huilin Electrochemistry Communications, Vol. 14, Issue 1 https://doi.org/10.1016/j.elecom.2011.11.009	journal	January 2012
Fast cycling of Li/LiCoO2 cell with low-viscosity ionic liquids based on bis(fluorosulfonyl)imide [FSI]− Matsumoto, Hajime; Sakaebe, Hikari; Tatsumi, Kuniaki Journal of Power Sources, Vol. 160, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.02.018	journal	October 2006
LiFePO4 and graphite electrodes with ionic liquids based on bis(fluorosulfonyl)imide (FSI)− for Li-ion batteries Guerfi, A.; Duchesne, S.; Kobayashi, Y. Journal of Power Sources, Vol. 175, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.09.030	journal	January 2008
Composite effect in superionically conducting lithium aluminium germanium phosphate based glass-ceramic Thokchom, Joykumar S.; Kumar, Binod Journal of Power Sources, Vol. 185, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.07.009	journal	October 2008
All-solid-state lithium secondary batteries using LiCoO₂ particles with pulsed laser deposition coatings of Li₂S–P₂S₅ solid electrolytes Sakuda, Atsushi; Hayashi, Akitoshi; Ohtomo, Takamasa Journal of Power Sources, Vol. 196, Issue 16, p. 6735-6741 https://doi.org/10.1016/j.jpowsour.2010.10.103	journal	August 2011
NaFSA–C1C3pyrFSA ionic liquids for sodium secondary battery operating over a wide temperature range Ding, Changsheng; Nohira, Toshiyuki; Kuroda, Keisuke Journal of Power Sources, Vol. 238 https://doi.org/10.1016/j.jpowsour.2013.03.089	journal	September 2013
Synthesis of NASICONA Molecular Precursor-Based Approach Porkodi, P.; Yegnaraman, V.; Kamaraj, P. Chemistry of Materials, Vol. 20, Issue 20 https://doi.org/10.1021/cm800208k	journal	October 2008
Interfacial Nanoarchitectonics for Solid-State Lithium Batteries Takada, Kazunori Langmuir, Vol. 29, Issue 24 https://doi.org/10.1021/la3045253	journal	December 2012
Batteries: Getting solid Hu, Yong-Sheng Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.42	journal	April 2016
11 nm hard X-ray focus from a large-aperture multilayer Laue lens Huang, Xiaojing; Yan, Hanfei; Nazaretski, Evgeny Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep03562	journal	December 2013
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems Palomares, Verónica; Serras, Paula; Villaluenga, Irune Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee02781j	journal	January 2012
High-capacity Li2S–nanocarbon composite electrode for all-solid-state rechargeable lithium batteries Nagao, Motohiro; Hayashi, Akitoshi; Tatsumisago, Masahiro Journal of Materials Chemistry, Vol. 22, Issue 19 https://doi.org/10.1039/c2jm16802b	journal	January 2012
High temperature sodium batteries: status, challenges and future trends Hueso, Karina B.; Armand, Michel; Rojo, Teófilo Energy & Environmental Science, Vol. 6, Issue 3 https://doi.org/10.1039/c3ee24086j	journal	January 2013
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Pushing the limits: an instrument for hard X-ray imaging below 20 nm Nazaretski, E.; Lauer, K.; Yan, H. Journal of Synchrotron Radiation, Vol. 22, Issue 2 https://doi.org/10.1107/S1600577514025715	journal	January 2015
Conduction Characteristics of the Lithium Iodide-Aluminum Oxide Solid Electrolytes Liang, C. C. Journal of The Electrochemical Society, Vol. 120, Issue 10, p. 1289-1292 https://doi.org/10.1149/1.2403248	journal	October 1973
Space-Charge-Mediated Superionic Transport in Lithium Ion Conducting Glass–Ceramics Kumar, B.; Thomas, D.; Kumar, J. Journal of The Electrochemical Society, Vol. 156, Issue 7 https://doi.org/10.1149/1.3122903	journal	January 2009
Electrochemical and Thermal Properties of NASICON Structured Na ₃ V ₂ (PO ₄ ) ₃ as a Sodium Rechargeable Battery Cathode: A Combined Experimental and Theoretical Study Lim, Soo Yeon; Kim, Heejin; Shakoor, R. A. Journal of The Electrochemical Society, Vol. 159, Issue 9 https://doi.org/10.1149/2.015209jes	journal	January 2012

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25 ENERGY STORAGE
National Synchrotron Light Source
ionic liquid
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solid electrolyte
solid-state batteries
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Title: A self-forming composite electrolyte for solid-state sodium battery with ultra-long cycle life

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