Revisiting formic acid decomposition on metallic powder catalysts: Exploding the HCOOH decomposition volcano curve
- Authors:
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1324336
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Surface Science
- Additional Journal Information:
- Journal Name: Surface Science Journal Volume: 650 Journal Issue: C; Journal ID: ISSN 0039-6028
- Publisher:
- Elsevier
- Country of Publication:
- Netherlands
- Language:
- English
Citation Formats
Tang, Yadan, Roberts, Charles A., Perkins, Ryan T., and Wachs, Israel E. Revisiting formic acid decomposition on metallic powder catalysts: Exploding the HCOOH decomposition volcano curve. Netherlands: N. p., 2016.
Web. doi:10.1016/j.susc.2015.12.032.
Tang, Yadan, Roberts, Charles A., Perkins, Ryan T., & Wachs, Israel E. Revisiting formic acid decomposition on metallic powder catalysts: Exploding the HCOOH decomposition volcano curve. Netherlands. https://doi.org/10.1016/j.susc.2015.12.032
Tang, Yadan, Roberts, Charles A., Perkins, Ryan T., and Wachs, Israel E. Mon .
"Revisiting formic acid decomposition on metallic powder catalysts: Exploding the HCOOH decomposition volcano curve". Netherlands. https://doi.org/10.1016/j.susc.2015.12.032.
@article{osti_1324336,
title = {Revisiting formic acid decomposition on metallic powder catalysts: Exploding the HCOOH decomposition volcano curve},
author = {Tang, Yadan and Roberts, Charles A. and Perkins, Ryan T. and Wachs, Israel E.},
abstractNote = {},
doi = {10.1016/j.susc.2015.12.032},
journal = {Surface Science},
number = C,
volume = 650,
place = {Netherlands},
year = {Mon Aug 01 00:00:00 EDT 2016},
month = {Mon Aug 01 00:00:00 EDT 2016}
}
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https://doi.org/10.1016/j.susc.2015.12.032
https://doi.org/10.1016/j.susc.2015.12.032
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Cited by: 38 works
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Works referenced in this record:
Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support
journal, April 2011
- Solymosi, F.; Koós, Á.; Liliom, N.
- Journal of Catalysis, Vol. 279, Issue 1
Reactions of formic acid and formaldehyde on Rh(111) and Rh(111)-(2 × 2)O surfaces
journal, May 1991
- Houtman, Carl; Barteau, Mark A.
- Surface Science, Vol. 248, Issue 1-2
The interaction of formic acid with transition metal surfaces, studied in ultrahigh vacuum
journal, May 1994
- Columbia, M. R.; Thiel, P. A.
- Journal of Electroanalytical Chemistry, Vol. 369, Issue 1-2
Linear free energy relationships for C1-oxygenate decomposition on transition metal surfaces
journal, January 1991
- Barteau, Mark A.
- Catalysis Letters, Vol. 8, Issue 2-4
The adsorption and decomposition of formaldehyde and formic acid on the clean and modified Fe (100) surface
journal, February 1996
- Hung, Wei-Hsiu; Bernasek, Steven L.
- Surface Science, Vol. 346, Issue 1-3
Adsorption and reaction of HCOOH on K-promoted Pd(100) surfaces
journal, December 1991
- Solymosi, Frigyes; Kovács, Imre
- Surface Science, Vol. 259, Issue 1-2
Hydrogen from formic acid decomposition over Pd and Au catalysts
journal, September 2010
- Bulushev, Dmitri A.; Beloshapkin, Sergey; Ross, Julian R. H.
- Catalysis Today, Vol. 154, Issue 1-2
The kinetics and mechanism of catalytic reactions by molecular beam relaxation spectroscopy: HCOOH decomposition
journal, June 1977
- Wachs, Israel E.; Madix, Robert J.
- Surface Science, Vol. 65, Issue 1
Trends in Formic Acid Decomposition on Model Transition Metal Surfaces: A Density Functional Theory study
journal, November 2014
- Herron, Jeffrey A.; Scaranto, Jessica; Ferrin, Peter
- ACS Catalysis, Vol. 4, Issue 12
MBRS measurements of overlayer effects on surface lifetimes and reaction probabilities
journal, February 1980
- Wachs, I.
- Journal of Catalysis, Vol. 61, Issue 2
A vibrational study of formic acid interaction with clean and oxygen-covered silver (110) surfaces
journal, April 1981
- Sexton, Brett A.; Madix, Robert J.
- Surface Science, Vol. 105, Issue 1
Reaction Kinetics and Mechanism on Metal Single Crystal Surfaces
book, January 1980
- Madix, Robert J.
- Advances in Catalysis
The temperature and coverage dependences of adsorbed formic acid and its conversion to formate on platinum(111)
journal, February 1992
- Columbia, M. R.; Crabtree, A. M.; Thiel, P. A.
- Journal of the American Chemical Society, Vol. 114, Issue 4
Decomposition of formic acid on copper, nickel, and copper-nickel alloys II. Catalytic and temperature-programmed decomposition of formic acid on Cu/SiO2, Cu/Al2O3, and Cu powder
journal, May 1983
- Iglesia, E.
- Journal of Catalysis, Vol. 81, Issue 1
Quantitative determination of the number of active surface sites and the turnover frequencies for methanol oxidation over metal oxide catalysts
journal, November 2000
- Briand, Laura E.; Farneth, William E.; Wachs, Israel E.
- Catalysis Today, Vol. 62, Issue 2-3
Selectivity Control in Gold-Mediated Esterification of Methanol
journal, May 2009
- Xu, Bingjun; Liu, Xiaoying; Haubrich, Jan
- Angewandte Chemie International Edition, Vol. 48, Issue 23, p. 4206-4209
Electronic factors in catalysis: the volcano curve and the effect of promotion in catalytic ammonia synthesis
journal, December 2001
- Dahl, Søren; Logadottir, Ashildur; Jacobsen, Claus J. H.
- Applied Catalysis A: General, Vol. 222, Issue 1-2
Theoretical Analysis of Transition-Metal Catalysts for Formic Acid Decomposition
journal, March 2014
- Yoo, Jong Suk; Abild-Pedersen, Frank; Nørskov, Jens K.
- ACS Catalysis, Vol. 4, Issue 4
Adsorption and decomposition of formic acid on Ni{110}
journal, March 1995
- Haq, S.; Love, J. G.; Sanders, H. E.
- Surface Science, Vol. 325, Issue 3
A spectroscopic study of the adsorption and reactions of methanol, formaldehyde and methyl formate on clean and oxygenated Cu(110) surfaces
journal, June 1985
- Sexton, B. A.; Hughes, A. E.; Avery, N. R.
- Surface Science, Vol. 155, Issue 1
Volcano-Curves for Dehydrogenation of 2-Propanol and Hydrogenation of Nitrobenzene by SiO 2 -Supported Metal Nanoparticles Catalysts As Described in Terms of a d-Band Model
journal, August 2012
- Tamura, Masazumi; Kon, Kenichi; Satsuma, Atsushi
- ACS Catalysis, Vol. 2, Issue 9
Potassium-promoted synthesis of surface formate and reactions of formic acid on Co{100}
journal, March 1996
- Toomes, R. L.; King, D. A.
- Surface Science, Vol. 349, Issue 1
Using first principles to predict bimetallic catalysts for the ammonia decomposition reaction
journal, April 2010
- Hansgen, Danielle A.; Vlachos, Dionisios G.; Chen, Jingguang G.
- Nature Chemistry, Vol. 2, Issue 6
Diagnosis of the nature of carboxylate coordination from the direction of shifts of carbonoxygen stretching frequencies
journal, October 1985
- Deacon, G. B.; Huber, F.; Phillips, R. J.
- Inorganica Chimica Acta, Vol. 104, Issue 1
Active oxygen on Group VIII metals: activation of formic acid and formaldehyde on Pd(100)
journal, January 1988
- Jorgensen, Scott W.; Madix, Robert J.
- Journal of the American Chemical Society, Vol. 110, Issue 2
Formic acid desorption from graphitized Ni(110)
journal, February 1976
- McCarty, J. G.; Madix, R. J.
- Surface Science, Vol. 54, Issue 2