Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2Sr2MgOsO6

Morrow, Ryan; Taylor, Alice E.; Singh, D. J.; Xiong, Jie; Rodan, Steven; Wolter, A. U.  B.; Wurmehl, Sabine; Büchner, Bernd; Stone, M. B.; Kolesnikov, A. I.; Aczel, Adam A.; Christianson, A. D.; Woodward, Patrick M.

doi:10.1038/srep32462

Title: Spin-orbit coupling control of anisotropy, ground state and frustration in 5d₂Sr₂MgOsO₆

Abstract

The influence of spin-orbit coupling (SOC) on the physical properties of the 5d² system Sr₂MgOsO₆ is probed via a combination of magnetometry, specific heat measurements, elastic and inelastic neutron scattering, and density functional theory calculations. Although a significant degree of frustration is expected, we find that Sr₂MgOsO₆ orders in a type I antiferromagnetic structure at the remarkably high temperature of 108 K. The measurements presented allow for the first accurate quantification of the size of the magnetic moment in a 5d² system of 0.60(2) μ_B a significantly reduced moment from the expected value for such a system. Furthermore, significant anisotropy is identified via a spin excitation gap, and we confirm by first principles calculations that SOC not only provides the magnetocrystalline anisotropy, but also plays a crucial role in determining both the ground state magnetic order and the moment size in this compound. In conclusion, through comparison to Sr₂ScOsO₆, it is demonstrated that SOC-induced anisotropy has the ability to relieve frustration in 5d² systems relative to their 5d³ counterparts, providing an explanation of the high TN found in Sr₂MgOsO₆.

Authors:

Morrow, Ryan ^[1]; Taylor, Alice E. ^[2]; Singh, D. J. ^[3]; Xiong, Jie ^[1]; Rodan, Steven ^[4]; Wolter, A. U. B. ^[4]; Wurmehl, Sabine ^[5]; Büchner, Bernd ^[5]; Stone, M. B. ^[2]; Kolesnikov, A. I. ^[2]; Aczel, Adam A. ^[2]; Christianson, A. D. ^[6]; Woodward, Patrick M. ^[1]

The Ohio State Univ., Columbus, OH (United States). Dept of Chemistry and Biochemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
Univ. of Missouri, Columbia, MO (United States). Dept. of Physics and Astronomy
Leibniz Inst. for Solid State and Materials Research (IFW), Dresden (Germany)
Leibniz Inst. for Solid State and Materials Research (IFW), Dresden (Germany); Dresden Univ. of Technology (Germany). Inst. for Solid State Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy

Publication Date:: Tue Aug 30 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS); Energy Frontier Research Centers (EFRC) (United States). Solid-State Solar-Thermal Energy Conversion Center (S3TEC)

Sponsoring Org.:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); Deutsche Forschungsgemeinschaft DFG

OSTI Identifier:: 1319201

Grant/Contract Number:: AC05-00OR22725; SC0001299; FG02- 09ER46577; DMR-1420451; WU595/5-1; DMR-1107637; WU 595/3-3

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 6; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Morrow, Ryan, Taylor, Alice E., Singh, D. J., Xiong, Jie, Rodan, Steven, Wolter, A. U.  B., Wurmehl, Sabine, Büchner, Bernd, Stone, M. B., Kolesnikov, A. I., Aczel, Adam A., Christianson, A. D., and Woodward, Patrick M. Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2Sr2MgOsO6.  United States: N. p., 2016. 
Web.  doi:10.1038/srep32462.

Copy to clipboard


                    Morrow, Ryan, Taylor, Alice E., Singh, D. J., Xiong, Jie, Rodan, Steven, Wolter, A. U.  B., Wurmehl, Sabine, Büchner, Bernd, Stone, M. B., Kolesnikov, A. I., Aczel, Adam A., Christianson, A. D., & Woodward, Patrick M. Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2Sr2MgOsO6.  United States.  https://doi.org/10.1038/srep32462

Copy to clipboard


                    Morrow, Ryan, Taylor, Alice E., Singh, D. J., Xiong, Jie, Rodan, Steven, Wolter, A. U.  B., Wurmehl, Sabine, Büchner, Bernd, Stone, M. B., Kolesnikov, A. I., Aczel, Adam A., Christianson, A. D., and Woodward, Patrick M. Tue .  
"Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2Sr2MgOsO6".  United States.  https://doi.org/10.1038/srep32462.  https://www.osti.gov/servlets/purl/1319201.

Copy to clipboard


                    
@article{osti_1319201,

  title        = {Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2Sr2MgOsO6},

  author       = {Morrow, Ryan and Taylor, Alice E. and Singh, D. J. and Xiong, Jie and Rodan, Steven and Wolter, A. U.  B. and Wurmehl, Sabine and Büchner, Bernd and Stone, M. B. and Kolesnikov, A. I. and Aczel, Adam A. and Christianson, A. D. and Woodward, Patrick M.},

  abstractNote = {The influence of spin-orbit coupling (SOC) on the physical properties of the 5d2 system Sr2MgOsO6 is probed via a combination of magnetometry, specific heat measurements, elastic and inelastic neutron scattering, and density functional theory calculations. Although a significant degree of frustration is expected, we find that Sr2MgOsO6 orders in a type I antiferromagnetic structure at the remarkably high temperature of 108 K. The measurements presented allow for the first accurate quantification of the size of the magnetic moment in a 5d2 system of 0.60(2) μB a significantly reduced moment from the expected value for such a system. Furthermore, significant anisotropy is identified via a spin excitation gap, and we confirm by first principles calculations that SOC not only provides the magnetocrystalline anisotropy, but also plays a crucial role in determining both the ground state magnetic order and the moment size in this compound. In conclusion, through comparison to Sr2ScOsO6, it is demonstrated that SOC-induced anisotropy has the ability to relieve frustration in 5d2 systems relative to their 5d3 counterparts, providing an explanation of the high TN found in Sr2MgOsO6.},

  doi          = {10.1038/srep32462},

  journal      = {Scientific Reports},

  number       = ,

  volume       = 6,

  place        = {United States},

  year         = {Tue Aug 30 00:00:00 EDT 2016},

  month        = {Tue Aug 30 00:00:00 EDT 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1038/srep32462

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 21 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Strongly Geometrically Frustrated Magnets
journal, August 1994

Ramirez, A. P.
Annual Review of Materials Science, Vol. 24, Issue 1
DOI: 10.1146/annurev.ms.24.080194.002321

Spin liquids in frustrated magnets
journal, March 2010

Balents, Leon
Nature, Vol. 464, Issue 7286
DOI: 10.1038/nature08917

A2B′B″O6 perovskites: A review
journal, May 2015

Vasala, Sami; Karppinen, Maarit
Progress in Solid State Chemistry, Vol. 43, Issue 1-2
DOI: 10.1016/j.progsolidstchem.2014.08.001

Correlated Quantum Phenomena in the Strong Spin-Orbit Regime
journal, March 2014

Witczak-Krempa, William; Chen, Gang; Kim, Yong Baek
Annual Review of Condensed Matter Physics, Vol. 5, Issue 1
DOI: 10.1146/annurev-conmatphys-020911-125138

Exotic phases induced by strong spin-orbit coupling in ordered double perovskites
journal, November 2010

Chen, Gang; Pereira, Rodrigo; Balents, Leon
Physical Review B, Vol. 82, Issue 17
DOI: 10.1103/PhysRevB.82.174440

Spin-orbit coupling in $d^{2}$ ordered double perovskites
journal, September 2011

Chen, Gang; Balents, Leon
Physical Review B, Vol. 84, Issue 9
DOI: 10.1103/PhysRevB.84.094420

Spin-orbit coupled $j_{eff} = 1 / 2$ iridium moments on the geometrically frustrated fcc lattice
journal, July 2015

Cook, A. M.; Matern, S.; Hickey, C.
Physical Review B, Vol. 92, Issue 2
DOI: 10.1103/PhysRevB.92.020417

Magnetic order and electronic structure of the $5 d^{3}$ double perovskite ${Sr}_{2} {ScOsO}_{6}$
journal, March 2015

Taylor, A. E.; Morrow, R.; Singh, D. J.
Physical Review B, Vol. 91, Issue 10
DOI: 10.1103/PhysRevB.91.100406

High antiferromagnetic transition temperature of the honeycomb compound ${SrRu}_{2} O_{6}$
journal, September 2015

Tian, W.; Svoboda, C.; Ochi, M.
Physical Review B, Vol. 92, Issue 10
DOI: 10.1103/PhysRevB.92.100404

Frustrated fcc antiferromagnet ${Ba}_{2} {YOsO}_{6}$ : Structural characterization, magnetic properties, and neutron scattering studies
journal, February 2015

Kermarrec, E.; Marjerrison, C. A.; Thompson, C. M.
Physical Review B, Vol. 91, Issue 7
DOI: 10.1103/PhysRevB.91.075133

Magnetically Frustrated Double Perovskites: Synthesis, Structural Properties, and Magnetic Order of Sr ₂ B OsO ₆ ( B = Y, In, Sc) : Magnetically Frustrated Double Perovskites Sr
journal, February 2015

Paul, Avijit Kumar; Sarapulova, Angelina; Adler, Peter
Zeitschrift für anorganische und allgemeine Chemie, Vol. 641, Issue 2
DOI: 10.1002/zaac.201400590

Coupled Nd and $B^{'}$ spin ordering in the double perovskites Nd $_{2}$ Na $B^{'}$ O $_{6}$ ( $B^{'} = Ru$ , Os)
journal, July 2013

Aczel, A. A.; Bugaris, D. E.; Yeon, J.
Physical Review B, Vol. 88, Issue 1
DOI: 10.1103/PhysRevB.88.014413

Magnetic properties of the $S = \frac{3}{2}$ geometrically frustrated double perovskites ${La}_{2} {LiRuO}_{6}$ and ${Ba}_{2} {YRuO}_{6}$
journal, October 2009

Aharen, Tomoko; Greedan, John E.; Ning, Fanlong
Physical Review B, Vol. 80, Issue 13
DOI: 10.1103/PhysRevB.80.134423

Frustration by competing interactions in the highly distorted double perovskites La $_{2}$ Na $B^{'}$ O $_{6}$ ( $B^{'} = Ru$ , Os)
journal, January 2013

Aczel, A. A.; Bugaris, D. E.; Li, L.
Physical Review B, Vol. 87, Issue 1
DOI: 10.1103/PhysRevB.87.014435

Exotic Magnetism on the Quasi-fcc Lattices of the $d^{3}$ Double Perovskites ${La}_{2} Na B^{'} O_{6}$ ( $B^{'} = Ru$ , Os)
journal, March 2014

Aczel, A. A.; Baker, P. J.; Bugaris, D. E.
Physical Review Letters, Vol. 112, Issue 11
DOI: 10.1103/PhysRevLett.112.117603

Magnetism in $S = \frac{1}{2}$ double perovskites with strong spin-orbit interactions
journal, November 2014

Ishizuka, Hiroaki; Balents, Leon
Physical Review B, Vol. 90, Issue 18
DOI: 10.1103/PhysRevB.90.184422

Crystal growth of Ba2MOsO6 (MLi, Na) from reactive hydroxide fluxes
journal, March 2002

Stitzer, Katharine E.; Smith, Mark D.; zur Loye, Hans-Conrad
Solid State Sciences, Vol. 4, Issue 3
DOI: 10.1016/S1293-2558(01)01257-2

Ferromagnetism in the Mott Insulator ${Ba}_{2} {NaOsO}_{6}$
journal, July 2007

Erickson, A. S.; Misra, S.; Miller, G. J.
Physical Review Letters, Vol. 99, Issue 1
DOI: 10.1103/PhysRevLett.99.016404

Frustration-driven spin freezing in the $S = \frac{1}{2}$ fcc perovskite ${Sr}_{2} {MgReO}_{6}$
journal, October 2003

Wiebe, C. R.; Greedan, J. E.; Kyriakou, P. P.
Physical Review B, Vol. 68, Issue 13
DOI: 10.1103/PhysRevB.68.134410

Magnetic properties of the geometrically frustrated $S = \frac{1}{2}$ antiferromagnets, ${La}_{2} {LiMoO}_{6}$ and ${Ba}_{2} {YMoO}_{6}$ , with the B-site ordered double perovskite structure: Evidence for a collective spin-singlet ground state
journal, June 2010

Aharen, Tomoko; Greedan, John E.; Bridges, Craig A.
Physical Review B, Vol. 81, Issue 22
DOI: 10.1103/PhysRevB.81.224409

Triplet and in-gap magnetic states in the ground state of the quantum frustrated fcc antiferromagnet Ba $_{2}$ YMoO $_{6}$
journal, September 2011

Carlo, J. P.; Clancy, J. P.; Aharen, T.
Physical Review B, Vol. 84, Issue 10
DOI: 10.1103/PhysRevB.84.100404

Novel Magnetism of ${Ir}^{5 +} (5 d^{4})$ Ions in the Double Perovskite ${Sr}_{2} {YIrO}_{6}$
journal, February 2014

Cao, G.; Qi, T. F.; Li, L.
Physical Review Letters, Vol. 112, Issue 5
DOI: 10.1103/PhysRevLett.112.056402

Structural and Magnetic Properties of the Iridium Double Perovskites Ba _{2– x} Sr _x YIrO ₆
journal, October 2015

Ranjbar, Ben; Reynolds, Emily; Kayser, Paula
Inorganic Chemistry, Vol. 54, Issue 21
DOI: 10.1021/acs.inorgchem.5b01905

Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds
journal, June 2015

Laguna-Marco, M. A.; Kayser, P.; Alonso, J. A.
Physical Review B, Vol. 91, Issue 21
DOI: 10.1103/PhysRevB.91.214433

${Ba}_{2} {YIrO}_{6}$ : A cubic double perovskite material with ${Ir}^{5 +}$ ions
journal, January 2016

Dey, T.; Maljuk, A.; Efremov, D. V.
Physical Review B, Vol. 93, Issue 1
DOI: 10.1103/PhysRevB.93.014434

Compounds of Osmium and Rhenium with the Ordered Perovskite Structure
journal, May 1962

Sleight, Arthur W.; Longo, John; Ward, Roland
Inorganic Chemistry, Vol. 1, Issue 2
DOI: 10.1021/ic50002a010

Sr ₂ MgOsO ₆ : A Frustrated Os ⁶⁺ (5d ² ) Double Perovskite with Strong Antiferromagnetic Interactions : Sr
journal, March 2015

Sarapulova, Angelina; Adler, Peter; Schnelle, Walter
Zeitschrift für anorganische und allgemeine Chemie, Vol. 641, Issue 5
DOI: 10.1002/zaac.201500151

High-Pressure Synthesis, Crystal Structures, and Magnetic Properties of 5d Double-Perovskite Oxides Ca ₂ MgOsO ₆ and Sr ₂ MgOsO ₆
journal, March 2015

Yuan, Yahua; Feng, Hai L.; Ghimire, Madhav Prasad
Inorganic Chemistry, Vol. 54, Issue 7
DOI: 10.1021/ic503086a

Structural and magnetic properties of the $5 d^{2}$ double perovskites ${Sr}_{2} B {ReO}_{6}$ ( $B = Y$ , In)
journal, June 2016

Aczel, A. A.; Zhao, Z.; Calder, S.
Physical Review B, Vol. 93, Issue 21
DOI: 10.1103/PhysRevB.93.214407

Structure and magnetic properties of the $S = 1$ geometrically frustrated double perovskites ${La}_{2} {LiReO}_{6}$ and ${Ba}_{2} {YReO}_{6}$
journal, February 2010

Aharen, Tomoko; Greedan, John E.; Bridges, Craig A.
Physical Review B, Vol. 81, Issue 6
DOI: 10.1103/PhysRevB.81.064436

Anisotropic thermal expansion behavior in tetragonal Sr2MgWO6
journal, March 2006

Achary, S. N.; Chakraborty, K. R.; Patwe, S. J.
Materials Research Bulletin, Vol. 41, Issue 3
DOI: 10.1016/j.materresbull.2005.07.025

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Toby, Brian H.
Journal of Applied Crystallography, Vol. 34, Issue 2
DOI: 10.1107/S0021889801002242

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Rodríguez-Carvajal, Juan
Physica B: Condensed Matter, Vol. 192, Issue 1-2
DOI: 10.1016/0921-4526(93)90108-I

Radial integrals for the magnetic form factor of 5 d transition elements
journal, August 2011

Kobayashi, Kohjiro; Nagao, Tatsuya; Ito, Masahisa
Acta Crystallographica Section A Foundations of Crystallography, Vol. 67, Issue 5
DOI: 10.1107/S010876731102633X

Spin-orbit coupling controlled ground state in ${Sr}_{2} {ScOsO}_{6}$
journal, June 2016

Taylor, A. E.; Morrow, R.; Fishman, R. S.
Physical Review B, Vol. 93, Issue 22
DOI: 10.1103/PhysRevB.93.220408

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

Independent Ordering of Two Interpenetrating Magnetic Sublattices in the Double Perovskite Sr ₂ CoOsO ₆
journal, December 2013

Morrow, Ryan; Mishra, Rohan; Restrepo, Oscar D.
Journal of the American Chemical Society, Vol. 135, Issue 50
DOI: 10.1021/ja407342w

Lattice-Site-Specific Spin Dynamics in Double Perovskite ${Sr}_{2} {CoOsO}_{6}$
journal, April 2014

Yan, Binghai; Paul, Avijit Kumar; Kanungo, Sudipta
Physical Review Letters, Vol. 112, Issue 14
DOI: 10.1103/PhysRevLett.112.147202

Probing the Links between Structure and Magnetism in Sr _{2– x} Ca _x FeOsO ₆ Double Perovskites
journal, July 2014

Morrow, Ryan; Freeland, John W.; Woodward, Patrick M.
Inorganic Chemistry, Vol. 53, Issue 15
DOI: 10.1021/ic5006715

Lattice Instability and Competing Spin Structures in the Double Perovskite Insulator ${Sr}_{2} {FeOsO}_{6}$
journal, October 2013

Paul, Avijit Kumar; Reehuis, Manfred; Ksenofontov, Vadim
Physical Review Letters, Vol. 111, Issue 16
DOI: 10.1103/PhysRevLett.111.167205

Synthesis, Structure, and Magnetic Properties of Sr₂NiOsO₆ and Ca₂NiOsO₆: Two New Osmium-Containing Double Perovskites
journal, November 2005

Macquart, René; Kim, Seung-Joo; Gemmill, William R.
Inorganic Chemistry, Vol. 44, Issue 26
DOI: 10.1021/ic051045+

The classification of tilted octahedra in perovskites
journal, November 1972

Glazer, A. M.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 11
DOI: 10.1107/S0567740872007976

Effects of chemical pressure on the magnetic ground states of the osmate double perovskites $SrCaCoOs O_{6}$ and $C a_{2} CoOs O_{6}$
journal, September 2015

Morrow, Ryan; Yan, Jiaqiang; McGuire, Michael A.
Physical Review B, Vol. 92, Issue 9
DOI: 10.1103/PhysRevB.92.094435

Flux growth and characterization of Sr2NiWO6 single crystals
journal, July 2015

Blum, C. G. F.; Holcombe, A.; Gellesch, M.
Journal of Crystal Growth, Vol. 421
DOI: 10.1016/j.jcrysgro.2015.04.004

Spin gap and the nature of the 4 $d^{3}$ magnetic ground state in the frustrated fcc antiferromagnet Ba $_{2}$ YRuO $_{6}$
journal, July 2013

Carlo, J. P.; Clancy, J. P.; Fritsch, K.
Physical Review B, Vol. 88, Issue 2
DOI: 10.1103/PhysRevB.88.024418

Structural phase transition and magnetic properties of double perovskites Ba2CaMO6 (M=W, Re, Os)
journal, March 2006

Yamamura, Kazuhiro; Wakeshima, Makoto; Hinatsu, Yukio
Journal of Solid State Chemistry, Vol. 179, Issue 3
DOI: 10.1016/j.jssc.2005.10.003

High-pressure crystal growth and electromagnetic properties of 5d double-perovskite Ca3OsO6
journal, May 2013

Feng, Hai Luke; Shi, Youguo; Guo, Yanfeng
Journal of Solid State Chemistry, Vol. 201
DOI: 10.1016/j.jssc.2013.02.037

Effect of frustrations on magnetism in the Ru double perovskite ${Sr}_{2} {YRuO}_{6}$
journal, July 2003

Kuz’min, E. V.; Ovchinnikov, S. G.; Singh, D. J.
Physical Review B, Vol. 68, Issue 2
DOI: 10.1103/PhysRevB.68.024409

Strongly Geometrically Frustrated Magnets
journal, January 1994

Ramirez, A.
Annual Review of Materials Research, Vol. 24, Issue 1
DOI: 10.1146/annurev.matsci.24.1.453

Synthesis, Structure, and Magnetic Properties of Sr2NiOsO6 and Ca2NiOsO6: Two New Osmium-Containing Double Perovskites.
journal, March 2006

Macquart, Rene; Kim, Seung-Joo; Gemmill, William R.
ChemInform, Vol. 37, Issue 12
DOI: 10.1002/chin.200612027

Correlated quantum phenomena in the strong spin-orbit regime
text, January 2013

Witczak-Krempa, William; Chen, Gang; Kim, Yong Baek
arXiv
DOI: 10.48550/arxiv.1305.2193

Structural phase transition and magnetic properties of double perovskites Ba2CaMO6 (M=W, Re, Os)
journal, March 2006

Yamamura, Kazuhiro; Wakeshima, Makoto; Hinatsu, Yukio
Journal of Solid State Chemistry, Vol. 179, Issue 3
DOI: 10.1016/j.jssc.2005.10.003

Anisotropic thermal expansion behavior in tetragonal Sr2MgWO6
journal, March 2006

Achary, S. N.; Chakraborty, K. R.; Patwe, S. J.
Materials Research Bulletin, Vol. 41, Issue 3
DOI: 10.1016/j.materresbull.2005.07.025

High-Pressure Synthesis, Crystal Structures, and Magnetic Properties of 5d Double-Perovskite Oxides Ca ₂ MgOsO ₆ and Sr ₂ MgOsO ₆
journal, March 2015

Yuan, Yahua; Feng, Hai L.; Ghimire, Madhav Prasad
Inorganic Chemistry, Vol. 54, Issue 7
DOI: 10.1021/ic503086a

Independent Ordering of Two Interpenetrating Magnetic Sublattices in the Double Perovskite Sr ₂ CoOsO ₆
journal, December 2013

Morrow, Ryan; Mishra, Rohan; Restrepo, Oscar D.
Journal of the American Chemical Society, Vol. 135, Issue 50
DOI: 10.1021/ja407342w

Spin liquids in frustrated magnets
journal, March 2010

Balents, Leon
Nature, Vol. 464, Issue 7286
DOI: 10.1038/nature08917

Long-range magnetic order in the 5 d ² double perovskite Ba ₂ CaOsO ₆ : comparison with spin-disordered Ba ₂ YReO ₆
journal, July 2014

Thompson, C. M.; Carlo, J. P.; Flacau, R.
Journal of Physics: Condensed Matter, Vol. 26, Issue 30
DOI: 10.1088/0953-8984/26/30/306003

Magnetism in S=1/2 Double-Perovskites with Strong Spin-Orbit Interactions
text, January 2014

Ishizuka, Hiroaki; Balents, Leon
arXiv
DOI: 10.48550/arxiv.1408.6785

Works referencing / citing this record:

Magnetic ground states in the three $O s^{6 +}$ $(5 d^{2})$ double perovskites $B a_{2} M Os O_{6}$ $(M = Mg, Zn, and Cd)$ from Néel order to its suppression
journal, October 2016

Marjerrison, C. A.; Thompson, C. M.; Sharma, A. Z.
Physical Review B, Vol. 94, Issue 13
DOI: 10.1103/physrevb.94.134429

Octupolar order in d-orbital Mott insulators
text, January 2019

Paramekanti, Arun; Maharaj, Dalini D.; Gaulin, Bruce D.
arXiv
DOI: 10.48550/arxiv.1909.03089

Similar Records in DOE PAGES and OSTI.GOV collections:

The frustrated fcc antiferromagnet Ba₂ YOsO₆: Structural characterization, magnetic properties and neutron scattering studies

Journal Article Kermarrec, E. ; Marjerrison, Casey A. ; Thompson, C. M. ; ... - Physical Review. B, Condensed Matter and Materials Physics

Here we report the crystal structure, magnetization, and neutron scattering measurements on the double perovskite Ba₂ YOsO₆. The Fmmore »« less
Cited by 65
https://doi.org/10.1103/PhysRevB.91.075133

Full Text Available
Spin-orbit coupling controlled ground state in ${Sr}_{2} {ScOsO}_{6}$

Journal Article Taylor, A. E. ; Morrow, R. ; Fishman, R. S. ; ... - Physical Review B

In this paper, we report neutron scattering experiments which reveal a large spin gap in the magnetic excitation spectrum of weakly-monoclinic double perovskite Sr₂ScOsO₆. The spin gap is demonstrative of appreciable spin-orbit-induced anisotropy, despite nominally orbitally-quenched 5d³Os⁵⁺ ions. The system is successfully modeled including nearest neighbor interactions in a Heisenberg Hamiltonian with exchange anisotropy. We find that the presence of the spin-orbit-induced anisotropy is essential for the realization of the type I antiferromagnetic ground state. Finally, this demonstrates that physics beyond the LS or JJ coupling limits plays an active role in determining the collective properties of 4d³ and 5d³more »« less
Cited by 34
https://doi.org/10.1103/PhysRevB.93.220408

Full Text Available
The Impact of Structural Distortions on the Magnetism of Double Perovskites Containing 5d¹ Transition-Metal Ions

Journal Article da Cruz Pinha Barbosa, Victor ; Xiong, Jie ; Tran, Phuong Minh ; ... - Chemistry of Materials

Five double perovskites, each containing a transition-metal ion with a 5d¹ configuration, have been studied to better understand the surprising diversity of magnetic ground states seen in these isoelectronic compounds. Ba₂ZnReO₆ adopts the cubic double perovskite structure and magnetically orders below 16 K, with a canted ferromagnetic structure and a saturated magnetization of ~0.24 μ_B/Re. X-ray magnetic circular dichroism indicates a substantial orbital moment of approximately 0.4 μ_B/Re that opposes the spin moment. The structures of Ba₂NaOsO₆ (canted ferromagnet, T_C = 7 K) and Ba₂LiOsO₆ (antiferromagnet, T_N = 8 K) are reinvestigated using time-of-flight neutron powder diffraction and found tomore »« less
https://doi.org/10.1021/acs.chemmater.1c03456

Full Text Available
Quantum liquid from strange frustration in the trimer magnet Ba4Ir3O10

Journal Article Cao, Gang ; Zheng, Hao ; Zhao, Hengdi ; ... - npj Quantum Materials

Abstract Quantum spin systems such as magnetic insulators usually show magnetic order, but such classical states can give way to quantum liquids with exotic entanglement through two known mechanisms of frustration: geometric frustration in lattices with triangle motifs, and spin-orbit-coupling frustration in the exactly solvable quantum liquid of Kitaev’s honeycomb lattice. Here we present the experimental observation of a new kind of frustrated quantum liquid arising in an unlikely place: the magnetic insulator Ba ₄ Ir ₃ O ₁₀ where Ir ₃ O ₁₂ trimers form an unfrustrated square lattice. The crystal structure shows no apparent spin chains. Experimentally wemore »« less
https://doi.org/10.1038/s41535-020-0232-6
Magnetic order and electronic structure of 5d³ double perovskite Sr₂ScOsO₆

Journal Article Taylor, A. E. ; Morrow, R. ; Singh, D. J. ; ... - Physical Review. B, Condensed Matter and Materials Physics

The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr₂ScOsO₆ are reported. Using both neutron and x-ray powder diffraction we find that the crystal structure is monoclinic P21/n from 3.5 to 300 K. Magnetization measurements indicate an antiferromagnetic transition at TN=92 K, one of the highest transition temperatures of any double perovskite hosting only one magnetic ion. Type I antiferromagnetic order is determined by neutron powder diffraction, with an Os moment of only 1.6(1) muB, close to half the spin-only value for a crystal field split 5d electron state with t2g^3 ground state. Density functional calculationsmore »« less
Cited by 56
https://doi.org/10.1103/PhysRevB.91.100406

Full Text Available

Similar Records

Title: Spin-orbit coupling control of anisotropy, ground state and frustration in 5d2Sr2MgOsO6

Abstract

Citation Formats

Strongly Geometrically Frustrated Magnets journal, August 1994

Spin liquids in frustrated magnets journal, March 2010

A2B′B″O6 perovskites: A review journal, May 2015

Correlated Quantum Phenomena in the Strong Spin-Orbit Regime journal, March 2014

Exotic phases induced by strong spin-orbit coupling in ordered double perovskites journal, November 2010

Spin-orbit coupling in d 2 ordered double perovskites journal, September 2011

Spin-orbit coupled j eff = 1 / 2 iridium moments on the geometrically frustrated fcc lattice journal, July 2015

Magnetic order and electronic structure of the 5 d 3 double perovskite Sr 2 ScOsO 6 journal, March 2015

High antiferromagnetic transition temperature of the honeycomb compound SrRu 2 O 6 journal, September 2015

Frustrated fcc antiferromagnet Ba 2 YOsO 6 : Structural characterization, magnetic properties, and neutron scattering studies journal, February 2015

Magnetically Frustrated Double Perovskites: Synthesis, Structural Properties, and Magnetic Order of Sr 2 B OsO 6 ( B = Y, In, Sc) : Magnetically Frustrated Double Perovskites Sr journal, February 2015

Coupled Nd and B ′ spin ordering in the double perovskites Nd 2 Na B ′ O 6 ( B ′ = Ru , Os) journal, July 2013

Magnetic properties of the S = 3 2 geometrically frustrated double perovskites La 2 LiRuO 6 and Ba 2 YRuO 6 journal, October 2009

Frustration by competing interactions in the highly distorted double perovskites La 2 Na B ′ O 6 ( B ′ = Ru , Os) journal, January 2013

Exotic Magnetism on the Quasi-fcc Lattices of the d 3 Double Perovskites La 2 Na B ′ O 6 ( B ′ = Ru , Os) journal, March 2014

Magnetism in S = 1 2 double perovskites with strong spin-orbit interactions journal, November 2014

Crystal growth of Ba2MOsO6 (MLi, Na) from reactive hydroxide fluxes journal, March 2002

Ferromagnetism in the Mott Insulator Ba 2 NaOsO 6 journal, July 2007

Frustration-driven spin freezing in the S = 1 2 fcc perovskite Sr 2 MgReO 6 journal, October 2003

Magnetic properties of the geometrically frustrated S = 1 2 antiferromagnets, La 2 LiMoO 6 and Ba 2 YMoO 6 , with the B-site ordered double perovskite structure: Evidence for a collective spin-singlet ground state journal, June 2010

Triplet and in-gap magnetic states in the ground state of the quantum frustrated fcc antiferromagnet Ba 2 YMoO 6 journal, September 2011

Novel Magnetism of Ir 5 + ( 5 d 4 ) Ions in the Double Perovskite Sr 2 YIrO 6 journal, February 2014

Structural and Magnetic Properties of the Iridium Double Perovskites Ba 2– x Sr x YIrO 6 journal, October 2015

Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds journal, June 2015

Ba 2 YIrO 6 : A cubic double perovskite material with Ir 5 + ions journal, January 2016

Compounds of Osmium and Rhenium with the Ordered Perovskite Structure journal, May 1962

Sr 2 MgOsO 6 : A Frustrated Os 6+ (5d 2 ) Double Perovskite with Strong Antiferromagnetic Interactions : Sr journal, March 2015

High-Pressure Synthesis, Crystal Structures, and Magnetic Properties of 5d Double-Perovskite Oxides Ca 2 MgOsO 6 and Sr 2 MgOsO 6 journal, March 2015

Structural and magnetic properties of the 5 d 2 double perovskites Sr 2 B ReO 6 ( B = Y , In) journal, June 2016

Structure and magnetic properties of the S = 1 geometrically frustrated double perovskites La 2 LiReO 6 and Ba 2 YReO 6 journal, February 2010

Anisotropic thermal expansion behavior in tetragonal Sr2MgWO6 journal, March 2006

EXPGUI , a graphical user interface for GSAS journal, April 2001

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

Radial integrals for the magnetic form factor of 5 d transition elements journal, August 2011

Spin-orbit coupling controlled ground state in Sr 2 ScOsO 6 journal, June 2016

Generalized Gradient Approximation Made Simple journal, October 1996

Independent Ordering of Two Interpenetrating Magnetic Sublattices in the Double Perovskite Sr 2 CoOsO 6 journal, December 2013

Lattice-Site-Specific Spin Dynamics in Double Perovskite Sr 2 CoOsO 6 journal, April 2014

Probing the Links between Structure and Magnetism in Sr 2– x Ca x FeOsO 6 Double Perovskites journal, July 2014

Lattice Instability and Competing Spin Structures in the Double Perovskite Insulator Sr 2 FeOsO 6 journal, October 2013

Synthesis, Structure, and Magnetic Properties of Sr2NiOsO6 and Ca2NiOsO6: Two New Osmium-Containing Double Perovskites journal, November 2005

The classification of tilted octahedra in perovskites journal, November 1972

Effects of chemical pressure on the magnetic ground states of the osmate double perovskites SrCaCoOs O 6 and C a 2 CoOs O 6 journal, September 2015

Flux growth and characterization of Sr2NiWO6 single crystals journal, July 2015

Spin gap and the nature of the 4 d 3 magnetic ground state in the frustrated fcc antiferromagnet Ba 2 YRuO 6 journal, July 2013

Structural phase transition and magnetic properties of double perovskites Ba2CaMO6 (M=W, Re, Os) journal, March 2006

High-pressure crystal growth and electromagnetic properties of 5d double-perovskite Ca3OsO6 journal, May 2013

Effect of frustrations on magnetism in the Ru double perovskite Sr 2 YRuO 6 journal, July 2003

Strongly Geometrically Frustrated Magnets journal, January 1994

Synthesis, Structure, and Magnetic Properties of Sr2NiOsO6 and Ca2NiOsO6: Two New Osmium-Containing Double Perovskites. journal, March 2006

Correlated quantum phenomena in the strong spin-orbit regime text, January 2013

Structural phase transition and magnetic properties of double perovskites Ba2CaMO6 (M=W, Re, Os) journal, March 2006

Anisotropic thermal expansion behavior in tetragonal Sr2MgWO6 journal, March 2006

High-Pressure Synthesis, Crystal Structures, and Magnetic Properties of 5d Double-Perovskite Oxides Ca 2 MgOsO 6 and Sr 2 MgOsO 6 journal, March 2015

Independent Ordering of Two Interpenetrating Magnetic Sublattices in the Double Perovskite Sr 2 CoOsO 6 journal, December 2013

Spin liquids in frustrated magnets journal, March 2010

Long-range magnetic order in the 5 d 2 double perovskite Ba 2 CaOsO 6 : comparison with spin-disordered Ba 2 YReO 6 journal, July 2014

Magnetism in S=1/2 Double-Perovskites with Strong Spin-Orbit Interactions text, January 2014

Magnetic ground states in the three O s 6 + ( 5 d 2 ) double perovskites B a 2 M Os O 6 ( M = Mg , Zn , and Cd ) from Néel order to its suppression journal, October 2016

Octupolar order in d-orbital Mott insulators text, January 2019

Title: Spin-orbit coupling control of anisotropy, ground state and frustration in 5d₂Sr₂MgOsO₆

Strongly Geometrically Frustrated Magnets
journal, August 1994

Spin liquids in frustrated magnets
journal, March 2010

A2B′B″O6 perovskites: A review
journal, May 2015

Correlated Quantum Phenomena in the Strong Spin-Orbit Regime
journal, March 2014

Exotic phases induced by strong spin-orbit coupling in ordered double perovskites
journal, November 2010

Spin-orbit coupling in $d^{2}$ ordered double perovskites
journal, September 2011

Spin-orbit coupled $j_{eff} = 1 / 2$ iridium moments on the geometrically frustrated fcc lattice
journal, July 2015

Magnetic order and electronic structure of the $5 d^{3}$ double perovskite ${Sr}_{2} {ScOsO}_{6}$
journal, March 2015

High antiferromagnetic transition temperature of the honeycomb compound ${SrRu}_{2} O_{6}$
journal, September 2015

Frustrated fcc antiferromagnet ${Ba}_{2} {YOsO}_{6}$ : Structural characterization, magnetic properties, and neutron scattering studies
journal, February 2015

Magnetically Frustrated Double Perovskites: Synthesis, Structural Properties, and Magnetic Order of Sr ₂ B OsO ₆ ( B = Y, In, Sc) : Magnetically Frustrated Double Perovskites Sr
journal, February 2015

Coupled Nd and $B^{'}$ spin ordering in the double perovskites Nd $_{2}$ Na $B^{'}$ O $_{6}$ ( $B^{'} = Ru$ , Os)
journal, July 2013

Magnetic properties of the $S = \frac{3}{2}$ geometrically frustrated double perovskites ${La}_{2} {LiRuO}_{6}$ and ${Ba}_{2} {YRuO}_{6}$
journal, October 2009

Frustration by competing interactions in the highly distorted double perovskites La $_{2}$ Na $B^{'}$ O $_{6}$ ( $B^{'} = Ru$ , Os)
journal, January 2013

Exotic Magnetism on the Quasi-fcc Lattices of the $d^{3}$ Double Perovskites ${La}_{2} Na B^{'} O_{6}$ ( $B^{'} = Ru$ , Os)
journal, March 2014

Magnetism in $S = \frac{1}{2}$ double perovskites with strong spin-orbit interactions
journal, November 2014

Crystal growth of Ba2MOsO6 (MLi, Na) from reactive hydroxide fluxes
journal, March 2002

Ferromagnetism in the Mott Insulator ${Ba}_{2} {NaOsO}_{6}$
journal, July 2007

Frustration-driven spin freezing in the $S = \frac{1}{2}$ fcc perovskite ${Sr}_{2} {MgReO}_{6}$
journal, October 2003

Magnetic properties of the geometrically frustrated $S = \frac{1}{2}$ antiferromagnets, ${La}_{2} {LiMoO}_{6}$ and ${Ba}_{2} {YMoO}_{6}$ , with the B-site ordered double perovskite structure: Evidence for a collective spin-singlet ground state
journal, June 2010

Triplet and in-gap magnetic states in the ground state of the quantum frustrated fcc antiferromagnet Ba $_{2}$ YMoO $_{6}$
journal, September 2011

Novel Magnetism of ${Ir}^{5 +} (5 d^{4})$ Ions in the Double Perovskite ${Sr}_{2} {YIrO}_{6}$
journal, February 2014

Structural and Magnetic Properties of the Iridium Double Perovskites Ba _{2– x} Sr _x YIrO ₆
journal, October 2015

Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds
journal, June 2015

${Ba}_{2} {YIrO}_{6}$ : A cubic double perovskite material with ${Ir}^{5 +}$ ions
journal, January 2016

Compounds of Osmium and Rhenium with the Ordered Perovskite Structure
journal, May 1962

Sr ₂ MgOsO ₆ : A Frustrated Os ⁶⁺ (5d ² ) Double Perovskite with Strong Antiferromagnetic Interactions : Sr
journal, March 2015

High-Pressure Synthesis, Crystal Structures, and Magnetic Properties of 5d Double-Perovskite Oxides Ca ₂ MgOsO ₆ and Sr ₂ MgOsO ₆
journal, March 2015

Structural and magnetic properties of the $5 d^{2}$ double perovskites ${Sr}_{2} B {ReO}_{6}$ ( $B = Y$ , In)
journal, June 2016

Structure and magnetic properties of the $S = 1$ geometrically frustrated double perovskites ${La}_{2} {LiReO}_{6}$ and ${Ba}_{2} {YReO}_{6}$
journal, February 2010

Anisotropic thermal expansion behavior in tetragonal Sr2MgWO6
journal, March 2006

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Radial integrals for the magnetic form factor of 5 d transition elements
journal, August 2011

Spin-orbit coupling controlled ground state in ${Sr}_{2} {ScOsO}_{6}$
journal, June 2016

Generalized Gradient Approximation Made Simple
journal, October 1996

Independent Ordering of Two Interpenetrating Magnetic Sublattices in the Double Perovskite Sr ₂ CoOsO ₆
journal, December 2013

Lattice-Site-Specific Spin Dynamics in Double Perovskite ${Sr}_{2} {CoOsO}_{6}$
journal, April 2014

Probing the Links between Structure and Magnetism in Sr _{2– x} Ca _x FeOsO ₆ Double Perovskites
journal, July 2014

Lattice Instability and Competing Spin Structures in the Double Perovskite Insulator ${Sr}_{2} {FeOsO}_{6}$
journal, October 2013

Synthesis, Structure, and Magnetic Properties of Sr₂NiOsO₆ and Ca₂NiOsO₆: Two New Osmium-Containing Double Perovskites
journal, November 2005

The classification of tilted octahedra in perovskites
journal, November 1972

Effects of chemical pressure on the magnetic ground states of the osmate double perovskites $SrCaCoOs O_{6}$ and $C a_{2} CoOs O_{6}$
journal, September 2015

Flux growth and characterization of Sr2NiWO6 single crystals
journal, July 2015

Spin gap and the nature of the 4 $d^{3}$ magnetic ground state in the frustrated fcc antiferromagnet Ba $_{2}$ YRuO $_{6}$
journal, July 2013

Structural phase transition and magnetic properties of double perovskites Ba2CaMO6 (M=W, Re, Os)
journal, March 2006

High-pressure crystal growth and electromagnetic properties of 5d double-perovskite Ca3OsO6
journal, May 2013

Effect of frustrations on magnetism in the Ru double perovskite ${Sr}_{2} {YRuO}_{6}$
journal, July 2003

Strongly Geometrically Frustrated Magnets
journal, January 1994

Synthesis, Structure, and Magnetic Properties of Sr2NiOsO6 and Ca2NiOsO6: Two New Osmium-Containing Double Perovskites.
journal, March 2006

Correlated quantum phenomena in the strong spin-orbit regime
text, January 2013

Structural phase transition and magnetic properties of double perovskites Ba2CaMO6 (M=W, Re, Os)
journal, March 2006

Anisotropic thermal expansion behavior in tetragonal Sr2MgWO6
journal, March 2006

High-Pressure Synthesis, Crystal Structures, and Magnetic Properties of 5d Double-Perovskite Oxides Ca ₂ MgOsO ₆ and Sr ₂ MgOsO ₆
journal, March 2015

Independent Ordering of Two Interpenetrating Magnetic Sublattices in the Double Perovskite Sr ₂ CoOsO ₆
journal, December 2013

Spin liquids in frustrated magnets
journal, March 2010

Long-range magnetic order in the 5 d ² double perovskite Ba ₂ CaOsO ₆ : comparison with spin-disordered Ba ₂ YReO ₆
journal, July 2014

Magnetism in S=1/2 Double-Perovskites with Strong Spin-Orbit Interactions
text, January 2014

Magnetic ground states in the three $O s^{6 +}$ $(5 d^{2})$ double perovskites $B a_{2} M Os O_{6}$ $(M = Mg, Zn, and Cd)$ from Néel order to its suppression
journal, October 2016

Octupolar order in d-orbital Mott insulators
text, January 2019