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Title: Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning

Abstract

RENiO3 (RE=rare-earth element) and V2O3 are archetypal Mott insulator systems. When tuned by chemical substitution (RENiO3) or pressure (V2O3), they exhibit a quantum phase transition (QPT) between an antiferromagnetic Mott insulating state and a paramagnetic metallic state. Because novel physics often appears near a Mott QPT, the details of this transition, such as whether it is first or second order, are important. Here, we demonstrate through muon spin relaxation/rotation (μSR) experiments that the QPT in RENiO3 and V2O3 is first order: the magnetically ordered volume fraction decreases to zero at the QPT, resulting in a broad region of intrinsic phase separation, while the ordered magnetic moment retains its full value until it is suddenly destroyed at the QPT. These findings bring to light a surprising universality of the pressure-driven Mott transition, revealing the importance of phase separation and calling for further investigation into the nature of quantum fluctuations underlying the transition.

Authors:
;  [1];  [1];  [2];  [2];  [2];  [3];  [3];  [3];  [3];  [4];  [5];  [5];  [5];  [6];  [6];  [6];  [7];  [7];  [8] more »;  [9];  [9];  [10];  [10];  [11];  [12];  [9];  [1] « less
  1. Columbia Univ., New York, NY (United States)
  2. Paul Scherrer Inst. (PSI), Villigen (Switzerland)
  3. McMaster Univ., Hamilton, ON (Canada)
  4. McMaster Univ., Hamilton, ON (Canada); Canadian Inst. for Advanced Research, Toronto (Canada)
  5. Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Physics
  6. Zhejiang Univ., Hangzhou (China)
  7. Japan Atomic Energy Agency (JAEA), Tokai (Japan). Advanced Science Research Center
  8. Brookhaven National Lab. (BNL), Upton, NY (United States)
  9. Univ. of Tokyo (Japan)
  10. Kyoto Univ. (Japan)
  11. Consejo Superior de Investigaciones Cientificas (CSIC), Madrid (Spain). Inst. de Ciencia de Materiales de Madrid, Cantoblanco
  12. Brookhaven National Lab. (BNL), Upton, NY (United States); Rutgers Univ., Piscataway, NJ (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1303008
Report Number(s):
BNL-112476-2016-JA
Journal ID: ISSN 2041-1723; R&D Project: PO011; KC0201060
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

B. A. Frandsen, Liu, L., Cheung, S. C., Guguchia, Z., Khasanov, R., Morenzoni, E., Munsie, T. J.S., Hallas, A. M., Wilson, M. N., Cai, Y., Luke, G. M., Chen, B., Li, W., Jin, C., Ding, C, Guo, S., Ning, F., Ito, T. U., Higemoto, W., Billinge, S. J.L., Sakamoto, S., Fujimori, A., Murakami, T., Kageyama, H., Alonso, J. A., Kotliar, G., Imada, M., and Uemura, Y. J. Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning. United States: N. p., 2016. Web. doi:10.1038/ncomms12519.
B. A. Frandsen, Liu, L., Cheung, S. C., Guguchia, Z., Khasanov, R., Morenzoni, E., Munsie, T. J.S., Hallas, A. M., Wilson, M. N., Cai, Y., Luke, G. M., Chen, B., Li, W., Jin, C., Ding, C, Guo, S., Ning, F., Ito, T. U., Higemoto, W., Billinge, S. J.L., Sakamoto, S., Fujimori, A., Murakami, T., Kageyama, H., Alonso, J. A., Kotliar, G., Imada, M., & Uemura, Y. J. Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning. United States. doi:10.1038/ncomms12519.
B. A. Frandsen, Liu, L., Cheung, S. C., Guguchia, Z., Khasanov, R., Morenzoni, E., Munsie, T. J.S., Hallas, A. M., Wilson, M. N., Cai, Y., Luke, G. M., Chen, B., Li, W., Jin, C., Ding, C, Guo, S., Ning, F., Ito, T. U., Higemoto, W., Billinge, S. J.L., Sakamoto, S., Fujimori, A., Murakami, T., Kageyama, H., Alonso, J. A., Kotliar, G., Imada, M., and Uemura, Y. J. Wed . "Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning". United States. doi:10.1038/ncomms12519. https://www.osti.gov/servlets/purl/1303008.
@article{osti_1303008,
title = {Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning},
author = {B. A. Frandsen and Liu, L. and Cheung, S. C. and Guguchia, Z. and Khasanov, R. and Morenzoni, E. and Munsie, T. J.S. and Hallas, A. M. and Wilson, M. N. and Cai, Y. and Luke, G. M. and Chen, B. and Li, W. and Jin, C. and Ding, C and Guo, S. and Ning, F. and Ito, T. U. and Higemoto, W. and Billinge, S. J.L. and Sakamoto, S. and Fujimori, A. and Murakami, T. and Kageyama, H. and Alonso, J. A. and Kotliar, G. and Imada, M. and Uemura, Y. J.},
abstractNote = {RENiO3 (RE=rare-earth element) and V2O3 are archetypal Mott insulator systems. When tuned by chemical substitution (RENiO3) or pressure (V2O3), they exhibit a quantum phase transition (QPT) between an antiferromagnetic Mott insulating state and a paramagnetic metallic state. Because novel physics often appears near a Mott QPT, the details of this transition, such as whether it is first or second order, are important. Here, we demonstrate through muon spin relaxation/rotation (μSR) experiments that the QPT in RENiO3 and V2O3 is first order: the magnetically ordered volume fraction decreases to zero at the QPT, resulting in a broad region of intrinsic phase separation, while the ordered magnetic moment retains its full value until it is suddenly destroyed at the QPT. These findings bring to light a surprising universality of the pressure-driven Mott transition, revealing the importance of phase separation and calling for further investigation into the nature of quantum fluctuations underlying the transition.},
doi = {10.1038/ncomms12519},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {2016},
month = {8}
}

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    Works referencing / citing this record:

    Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning
    text, January 2016

    • Frandsen, Benjamin A.; Liu, Lian; Cheung, Sky Chance
    • Columbia University
    • DOI: 10.7916/d8vm4ckp

    Mott-Hubbard transition in V 2 O 3 revisited
    journal, March 2013

    • Hansmann, P.; Toschi, A.; Sangiovanni, G.
    • physica status solidi (b), Vol. 250, Issue 7
    • DOI: 10.1002/pssb.201248476

    Musrfit: A Free Platform-Independent Framework for μSR Data Analysis
    journal, January 2012


    From quantum matter to high-temperature superconductivity in copper oxides
    journal, February 2015

    • Keimer, B.; Kivelson, S. A.; Norman, M. R.
    • Nature, Vol. 518, Issue 7538
    • DOI: 10.1038/nature14165

    A microscopic view on the Mott transition in chromium-doped V2O3
    journal, November 2010

    • Lupi, S.; Baldassarre, L.; Mansart, B.
    • Nature Communications, Vol. 1, Issue 1
    • DOI: 10.1038/ncomms1109

    Li(Zn,Mn)As as a new generation ferromagnet based on a I–II–V semiconductor
    journal, August 2011

    • Deng, Z.; Jin, C. Q.; Liu, Q. Q.
    • Nature Communications, Vol. 2, Issue 1
    • DOI: 10.1038/ncomms1425

    Commonalities in phase and mode
    journal, April 2009


    Phase separation and suppression of critical dynamics at quantum phase transitions of MnSi and (Sr1−xCax)RuO3
    journal, December 2006

    • Uemura, Y. J.; Goko, T.; Gat-Malureanu, I. M.
    • Nature Physics, Vol. 3, Issue 1
    • DOI: 10.1038/nphys488

    Gaps and pseudogaps in perovskite rare earth nickelates
    journal, June 2015

    • Allen, S. James; Hauser, Adam J.; Mikheev, Evgeny
    • APL Materials, Vol. 3, Issue 6
    • DOI: 10.1063/1.4907771

    Enhanced thermoelectric power and electronic correlations in RuSe 2
    journal, April 2015

    • Wang, Kefeng; Wang, Aifeng; Tomic, A.
    • APL Materials, Vol. 3, Issue 4
    • DOI: 10.1063/1.4913919

    PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals
    journal, July 2007


    Sudden Appearance of an Unusual Spin Density Wave At the Metal-Insulator Transition in the Perovskites RNiO 3 (R = Pr, Nd)
    journal, October 1992

    • García-Muñoz, J. L.; Rodríguez-Carvajal, J.; Lacorre, P.
    • Europhysics Letters (EPL), Vol. 20, Issue 3
    • DOI: 10.1209/0295-5075/20/3/009