Hierarchically Superstructured Prussian Blue Analogues: Spontaneous Assembly Synthesis and Applications as Pseudocapacitive Materials

Yue, Yanfeng; Zhang, Zhiyong; Binder, Andrew J.; Chen, Jihua; Jin, Xianbo; Overbury, Steven; Dai, Sheng

doi:10.1002/cssc.201402520

Title: Hierarchically Superstructured Prussian Blue Analogues: Spontaneous Assembly Synthesis and Applications as Pseudocapacitive Materials

Journal Article · Sun Nov 09 23:00:00 EST 2014 · ChemSusChem (Online)

DOI: https://doi.org/10.1002/cssc.201402520 · OSTI ID:1286909

Yue, Yanfeng ^[1]; Zhang, Zhiyong ^[2]; Binder, Andrew J. ^[3]; Chen, Jihua ^[1]; Jin, Xianbo ^[4]; Overbury, Steven ^[1]; Dai, Sheng ^[5]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
ORNLOak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Wuhan Univ. (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Hierarchically superstructured Prussian blue analogues (hexa- conventional hybrid graphene/MnO₂ nanostructured textiles. cyanoferrate, M = Ni^II, Co^II and Cu^II) are synthesized through Because sodium or potassium ions are involved in energy stor- a spontaneous assembly technique. In sharp contrast to mac- age processes, more environmentally neutral electrolytes can roporous-only Prussian blue analogues, the hierarchically su- be utilized, making the superstructured porous Prussian blue perstructured porous Prussian blue materials are demonstrated analogues a great contender for applications as high-per- to possess a high capacitance, which is similar to those of the formance pseudocapacitors.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1286909

Journal Information:: ChemSusChem (Online), Journal Name: ChemSusChem (Online) Journal Issue: 1 Vol. 8; ISSN 1864-564X

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Self-assembled Prussian blue–polypyrrole nanocomposites for energy storage application Lee, Pui Kee; Nia, Pooria Moozarm; Woi, Pei Meng Journal of Applied Electrochemistry, Vol. 49, Issue 6 https://doi.org/10.1007/s10800-019-01310-5	journal	April 2019
Flexible metal–organic frameworks as superior cathodes for rechargeable sodium-ion batteries Nie, Ping; Shen, Laifa; Pang, Gang Journal of Materials Chemistry A, Vol. 3, Issue 32 https://doi.org/10.1039/c5ta03197d	journal	January 2015
An advanced aqueous sodium-ion supercapacitor with a manganous hexacyanoferrate cathode and a Fe ₃ O ₄ /rGO anode Lu, Ke; Li, Dan; Gao, Xiang Journal of Materials Chemistry A, Vol. 3, Issue 31 https://doi.org/10.1039/c5ta04244e	journal	January 2015
Fabrication of an advanced asymmetric supercapacitor based on a microcubical PB@MnO ₂ hybrid and PANI/GNP composite with excellent electrochemical behaviour Das, Amit Kumar; Bera, Ranadip; Maitra, Anirban J. Mater. Chem. A, Vol. 5, Issue 42 https://doi.org/10.1039/c7ta05134d	journal	January 2017
Concentration as a trigger to improve electrocatalytic activity of a Prussian blue analogue in glucose oxidation Zhao, Zhimin; Ding, Jiawei; Zhou, Huijie CrystEngComm, Vol. 21, Issue 36 https://doi.org/10.1039/c9ce00947g	journal	January 2019
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