Thermodynamic Hydricity of Transition Metal Hydrides

Wiedner, Eric S.; Chambers, Matthew B.; Pitman, Catherine L.; Bullock, R. Morris; Miller, Alexander J.  M.; Appel, Aaron M.

doi:10.1021/acs.chemrev.6b00168

Title: Thermodynamic Hydricity of Transition Metal Hydrides

Journal Article · 02 August 2016 · Chemical Reviews

DOI: https://doi.org/10.1021/acs.chemrev.6b00168 · OSTI ID:1280195

^[1]; Chambers, Matthew B. ^[2]; Pitman, Catherine L. ^[2];

^[1]; Miller, Alexander J. M. ^[2]; Appel, Aaron M. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Univ. of North Carolina, Chapel Hill, NC (United States). Dept. of Chemistry

Transition metal hydrides play a critical role in stoichiometric and catalytic transformations. Knowledge of free energies for cleaving metal hydride bonds enables the prediction of chemical reactivity, such as for the bond-forming and bondbreaking events that occur in a catalytic reaction. Thermodynamic hydricity is the free energy required to cleave an M-H bond to generate a hydride ion (H^-). Three primary methods have been developed for hydricity determination: the hydride transfer method establishes hydride transfer equilibrium with a hydride donor/acceptor pair of known hydricity, the H₂ heterolysis method involves measuring the equilibrium of heterolytic cleavage of H₂ in the presence of a base, and the potential-pK_a method considers stepwise transfer of a proton and two electrons to give a net hydride transfer. Using these methods, over 100 thermodynamic hydricity values for transition metal hydrides have been determined in acetonitrile or water. In acetonitrile, the hydricity of metal hydrides spans a range of more than 50 kcal/mol. Finally, methods for using hydricity values to predict chemical reactivity are also discussed, including organic transformations, the reduction of CO₂, and the production and oxidation of hydrogen.

View Journal Article

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0014255; CHE-1205189; AC05-76RL01830

OSTI ID:: 1280195

Alternate ID(s):: OSTI ID: 1313998; OSTI ID: 1773427

Report Number(s):: PNNL-SA-116484

Journal Information:: Chemical Reviews, Vol. 116, Issue 15; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (319)

Trialkylborane-Assisted CO ₂ Reduction by Late Transition Metal Hydrides Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E. Organometallics, Vol. 30, Issue 16 https://doi.org/10.1021/om200364w	journal	August 2011
Reversible, Metal-Free Hydrogen Activation Welch, G. C.; Juan, R. R. S.; Masuda, J. D. Science, Vol. 314, Issue 5802 https://doi.org/10.1126/science.1134230	journal	November 2006
B–N compounds for chemical hydrogenstorage Hamilton, Charles W.; Baker, R. Tom; Staubitz, Anne Chem. Soc. Rev., Vol. 38, Issue 1, p. 279-293 https://doi.org/10.1039/B800312M	journal	January 2009
Ammonia–borane: the hydrogen source par excellence? Stephens, Frances H.; Pons, Vincent; Tom Baker, R. Dalton Trans., Issue 25, p. 2613-2626 https://doi.org/10.1039/B703053C	journal	January 2007
Ferrocene as an internal standard for electrochemical measurements Gagne, Robert R.; Koval, Carl A.; Lisensky, George C. Inorganic Chemistry, Vol. 19, Issue 9 https://doi.org/10.1021/ic50211a080	journal	September 1980
Computing Free Energy Landscapes: Application to Ni-based Electrocatalysts with Pendant Amines for H ₂ Production and Oxidation Chen, Shentan; Ho, Ming-Hsun; Bullock, R. Morris ACS Catalysis, Vol. 4, Issue 1 https://doi.org/10.1021/cs401104w	journal	December 2013
Nature of bis(2,2'-bipyridine)rhodium(I) in aqueous solutions Chou, Mei.; Creutz, Carol.; Mahajan, Devinder. Inorganic Chemistry, Vol. 21, Issue 11 https://doi.org/10.1021/ic00141a023	journal	November 1982
Formation and Reactivity of a Porphyrin Iridium Hydride in Water: Acid Dissociation Constants and Equilibrium Thermodynamics Relevant to Ir–H, Ir–OH, and Ir–CH ₂ – Bond Dissociation Energetics Bhagan, Salome; Wayland, Bradford B. Inorganic Chemistry, Vol. 50, Issue 21 https://doi.org/10.1021/ic201553k	journal	November 2011
A Cobalt-Based Catalyst for the Hydrogenation of CO ₂ under Ambient Conditions Jeletic, Matthew S.; Mock, Michael T.; Appel, Aaron M. Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja406601v	journal	July 2013
An Electrochemical Study of Frustrated Lewis Pairs: A Metal-Free Route to Hydrogen Oxidation Lawrence, Elliot J.; Oganesyan, Vasily S.; Hughes, David L. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja500477g	journal	April 2014
Formation of Novel 1:1 Adducts Accompanied by Regioselective Hydride Transfer from Transition-Metal Hydrido Complexes to NAD(P) Models Kobayashi, Atsuo; Takatori, Ryosuke; Kikuchi, Itsumi Organometallics, Vol. 20, Issue 16 https://doi.org/10.1021/om010362v	journal	August 2001
Hydricities of d ⁶ Metal Hydride Complexes in Water Creutz, Carol; Chou, Mei H. Journal of the American Chemical Society, Vol. 131, Issue 8 https://doi.org/10.1021/ja809724s	journal	March 2009
HRh(dppb) ₂ , a Powerful Hydride Donor Price, Andrew J.; Ciancanelli, Rebecca; Noll, Bruce C. Organometallics, Vol. 21, Issue 22 https://doi.org/10.1021/om020421k	journal	October 2002
Platinum Complexes of a Borane-Appended Analogue of 1,1′-Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ Vinylborane Formation Cowie, Bradley E.; Emslie, David J. H. Chemistry - A European Journal, Vol. 20, Issue 51 https://doi.org/10.1002/chem.201404846	journal	October 2014
Catalysis of regioselective reduction of NAD+ by ruthenium(II) arene complexes under biologically relevant conditions Yan, Yaw Kai; Melchart, Michael; Habtemariam, Abraha JBIC Journal of Biological Inorganic Chemistry, Vol. 11, Issue 4 https://doi.org/10.1007/s00775-006-0098-5	journal	April 2006
[Ni(P ^Me ₂ N ^Ph ₂ ) ₂ ](BF ₄ ) ₂ as an Electrocatalyst for H ₂ Production Wiese, Stefan; Kilgore, Uriah J.; DuBois, Daniel L. ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs300019h	journal	March 2012
Guanidine-Functionalized Rhenium Cyclopentadienyl Carbonyl Complexes: Synthesis and Cooperative Activation of H–H and O–H Bonds Teets, Thomas S.; Labinger, Jay A.; Bercaw, John E. Organometallics, Vol. 33, Issue 15 https://doi.org/10.1021/om500650b	journal	July 2014
Facile Si–H bond activation and hydrosilylation catalysis mediated by a nickel–borane complex MacMillan, Samantha N.; Hill Harman, W.; Peters, Jonas C. Chem. Sci., Vol. 5, Issue 2 https://doi.org/10.1039/C3SC52626G	journal	January 2014
Relative reactivity and mechanistic studies of the hydride-transfer reagents HM(CO)4L-(M = Cr, W; L = CO, PR3) Kao, S. C.; Spillett, Cris Tina.; Ash, Carlton. Organometallics, Vol. 4, Issue 1 https://doi.org/10.1021/om00120a015	journal	January 1985
Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid-Assisted Reductive Coupling of Carbon Monoxide Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E. Organometallics, Vol. 29, Issue 20 https://doi.org/10.1021/om100638d	journal	October 2010
Spectroscopic behavior of a new family of mixed-ligand iridium(III) complexes Sandrini, Diana; Maestri, Mauro; Ziessel, Raymond Inorganica Chimica Acta, Vol. 163, Issue 2 https://doi.org/10.1016/S0020-1693(00)83449-0	journal	September 1989
Theoretical Analysis of the Sequential Proton-Coupled Electron Transfer Mechanisms for H ₂ Oxidation and Production Pathways Catalyzed by Nickel Molecular Electrocatalysts Fernandez, Laura E.; Horvath, Samantha; Hammes-Schiffer, Sharon The Journal of Physical Chemistry C, Vol. 116, Issue 4 https://doi.org/10.1021/jp210690q	journal	January 2012
Toward Molecular Catalysts by Computer Raugei, Simone; DuBois, Daniel L.; Rousseau, Roger Accounts of Chemical Research, Vol. 48, Issue 2 https://doi.org/10.1021/ar500342g	journal	January 2015
Steric effect for proton, hydrogen-atom, and hydride transfer reactions with geometric isomers of NADH–model ruthenium complexes Cohen, Brian W.; Polyansky, Dmitry E.; Achord, Patrick Faraday Discuss., Vol. 155 https://doi.org/10.1039/C1FD00094B	journal	January 2012
Determination of S−H Bond Strengths in Dimolybdenum Tetrasulfide Complexes Appel, Aaron M.; Lee, Suh-Jane; Franz, James A. Organometallics, Vol. 28, Issue 3 https://doi.org/10.1021/om800875n	journal	February 2009
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 3. Thermodynamic acidity of common mononuclear carbonyl hydrides Moore, Eric J.; Sullivan, Jeffrey M.; Norton, Jack R. Journal of the American Chemical Society, Vol. 108, Issue 9 https://doi.org/10.1021/ja00269a022	journal	April 1986
Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More Stephan, Douglas W.; Erker, Gerhard Angewandte Chemie International Edition, Vol. 49, Issue 1 https://doi.org/10.1002/anie.200903708	journal	December 2009
Photocatalytic Reduction of Artificial and Natural Nucleotide Co-factors with a Chlorophyll-Like Tin-Dihydroporphyrin Sensitizer Oppelt, Kerstin T.; Wöß, Eva; Stiftinger, Martin Inorganic Chemistry, Vol. 52, Issue 20 https://doi.org/10.1021/ic401611v	journal	September 2013
Carbanion mechanisms. 6. Metalation of arylmethanes by potassium hydride/18-crown-6 ether in tetrahydrofuran and the acidity of hydrogen Buncel, Erwin; Menon, Balachandran Journal of the American Chemical Society, Vol. 99, Issue 13 https://doi.org/10.1021/ja00455a040	journal	June 1977
Comprehensive Thermodynamic Characterization of the Metal−Hydrogen Bond in a Series of Cobalt-Hydride Complexes Ciancanelli, Rebecca; Noll, Bruce C.; DuBois, Daniel L. Journal of the American Chemical Society, Vol. 124, Issue 12, p. 2984-2992 https://doi.org/10.1021/ja0122804	journal	March 2002
Hydridic character of early transition metal hydride complexes Labinger, Jay A.; Komadina, Kevin H. Journal of Organometallic Chemistry, Vol. 155, Issue 2 https://doi.org/10.1016/S0022-328X(00)93299-6	journal	August 1978
Redox-active ligands in catalysis Luca, Oana R.; Crabtree, Robert H. Chem. Soc. Rev., Vol. 42, Issue 4 https://doi.org/10.1039/C2CS35228A	journal	January 2013
Organometallic thermodynamics. Redox couples involving metal-metal bonds Pugh, J. Richard; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 114, Issue 10 https://doi.org/10.1021/ja00036a030	journal	May 1992
Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions Thoi, V. Sara; Sun, Yujie; Long, Jeffrey R. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35272A	journal	January 2013
Catalytic ionic hydrogenations of ketones using molybdenum and tungsten complexesBased on the presentation given at Dalton Discussion No. 4, 10–13th January 2002, Kloster Banz, Germany. Voges, Mark H.; Bullock, R. Morris Journal of the Chemical Society, Dalton Transactions, Issue 5 https://doi.org/10.1039/b107754f	journal	January 2002
A pendant proton shuttle on [Fe ₄ N(CO) ₁₂ ] ⁻ alters product selectivity in formate vs. H ₂ production via the hydride [H–Fe ₄ N(CO) ₁₂ ] ⁻ Loewen, Natalia D.; Thompson, Emily J.; Kagan, Michael Chemical Science, Vol. 7, Issue 4 https://doi.org/10.1039/C5SC03169A	journal	January 2016
Thermochemical Insight into the Reduction of CO to CH ₃ OH with [Re(CO)] ⁺ and [Mn(CO)] ⁺ Complexes Wiedner, Eric S.; Appel, Aaron M. Journal of the American Chemical Society, Vol. 136, Issue 24 https://doi.org/10.1021/ja502316e	journal	June 2014
The development of aqueous transfer hydrogenation catalysts Robertson, Andrew; Matsumoto, Takahiro; Ogo, Seiji Dalton Transactions, Vol. 40, Issue 40 https://doi.org/10.1039/c1dt10544b	journal	January 2011
Measurement of the Hydride Donor Abilities of [HM(diphosphine) ₂ ] ⁺ Complexes (M = Ni, Pt) by Heterolytic Activation of Hydrogen Curtis, Calvin J.; Miedaner, Alex; Ellis, William W. Journal of the American Chemical Society, Vol. 124, Issue 9 https://doi.org/10.1021/ja0116829	journal	March 2002
Competing nucleophilic displacement and radical-chain reduction in reactions of transition-metal hydride anions with alkyl bromides Ash, Carlton E.; Hurd, Philip W.; Darensbourg, Marcetta Y. Journal of the American Chemical Society, Vol. 109, Issue 11 https://doi.org/10.1021/ja00245a021	journal	May 1987
Hydride Affinities of Arylcarbenium Ions and Iminium Ions in Dimethyl Sulfoxide and Acetonitrile Zhang, Xian-Man; Bruno, Joseph W.; Enyinnaya, Emmeline The Journal of Organic Chemistry, Vol. 63, Issue 14 https://doi.org/10.1021/jo980120d	journal	July 1998
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s^-1 for H₂ Production Helm, M. L.; Stewart, M. P.; Bullock, R. M. Science, Vol. 333, Issue 6044, p. 863-866 https://doi.org/10.1126/science.1205864	journal	August 2011
Hydrogenase Enzyme Reactivity Modeling with a Transition-Metal Dihydrogen Complex Hembre, Robert T.; McQueen, Scott Journal of the American Chemical Society, Vol. 116, Issue 5 https://doi.org/10.1021/ja00084a063	journal	March 1994
Thermodynamic Studies of [H ₂ Rh(diphosphine) ₂ ] ⁺ and [HRh(diphosphine) ₂ (CH ₃ CN)] ²⁺ Complexes in Acetonitrile Wilson, Aaron D.; Miller, Alexander J. M.; DuBois, Daniel L. Inorganic Chemistry, Vol. 49, Issue 8 https://doi.org/10.1021/ic100117y	journal	April 2010
Metal–Polypyridyl Catalysts for Electro- and Photochemical Reduction of Water to Hydrogen Zee, David Z.; Chantarojsiri, Teera; Long, Jeffrey R. Accounts of Chemical Research, Vol. 48, Issue 7 https://doi.org/10.1021/acs.accounts.5b00082	journal	June 2015
Homogeneous Hydrogenation of Carbon Dioxide Jessop, Philip G.; Ikariya, Takao.; Noyori, Ryoji. Chemical Reviews, Vol. 95, Issue 2 https://doi.org/10.1021/cr00034a001	journal	March 1995
Ligand steals spotlight from metal to orchestrate hydrogen production Dempsey, Jillian L. Proceedings of the National Academy of Sciences, Vol. 113, Issue 3 https://doi.org/10.1073/pnas.1522759113	journal	January 2016
On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o -R ₂ P(Ph)BR‘ ₂ Bontemps, Sébastien; Bouhadir, Ghenwa; Miqueu, Karinne Journal of the American Chemical Society, Vol. 128, Issue 37 https://doi.org/10.1021/ja0637494	journal	September 2006
Excited-State Deprotonation and H/D Exchange of an Iridium Hydride Complex Suenobu, Tomoyoshi; Guldi, Dirk M.; Ogo, Seiji Angewandte Chemie International Edition, Vol. 42, Issue 44 https://doi.org/10.1002/anie.200352061	journal	November 2003
Mechanism of the reaction of a solvated rhenium acyl complex with neutral transition-metal hydrides. Relative nucleophilicity of such hydrides Martin, Bruce D.; Warner, Keith E.; Norton, Jack R. Journal of the American Chemical Society, Vol. 108, Issue 1 https://doi.org/10.1021/ja00261a008	journal	January 1986
Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX ₃ Compounds Mock, Michael T.; Potter, Robert G.; O’Hagan, Molly J. Inorganic Chemistry, Vol. 50, Issue 23 https://doi.org/10.1021/ic200857x	journal	December 2011
Bioorganometallic Chemistry. 13. Regioselective Reduction of NAD ⁺ Models, 1-Benzylnicotinamde Triflate and β-Nicotinamide Ribose-5‘-methyl Phosphate, with in Situ Generated [Cp*Rh(Bpy)H] ⁺ : Structure−Activity Relationships, Kinetics, and Mechanistic Aspects in the Formation of the 1,4-NADH Derivatives ^† Lo, H. Christine; Leiva, Carmen; Buriez, Olivier Inorganic Chemistry, Vol. 40, Issue 26 https://doi.org/10.1021/ic010562z	journal	December 2001
E–H Bond Activations and Hydrosilylation Catalysis with Iron and Cobalt Metalloboranes Nesbit, Mark A.; Suess, Daniel L. M.; Peters, Jonas C. Organometallics, Vol. 34, Issue 19 https://doi.org/10.1021/acs.organomet.5b00530	journal	August 2015
H ₂ Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation Fourmond, Vincent; Jacques, Pierre-André; Fontecave, Marc Inorganic Chemistry, Vol. 49, Issue 22 https://doi.org/10.1021/ic101187v	journal	November 2010
Hydricity of transition-metal hydrides and its role in CO2 reduction DuBois, Daniel L.; Berning, Douglas E. Applied Organometallic Chemistry, Vol. 14, Issue 12 https://doi.org/10.1002/1099-0739(200012)14:12<860::AID-AOC87>3.0.CO;2-A	journal	January 2000
Isotope Effects on Hydride Transfer Reactions from Transition Metal Hydrides to Trityl Cation. An Inverse Isotope Effect for a Hydride Transfer Cheng, Tan-Yun; Bullock, R. Morris Journal of the American Chemical Society, Vol. 121, Issue 13 https://doi.org/10.1021/ja983448x	journal	April 1999
Contrasting Anticancer Activity of Half-Sandwich Iridium(III) Complexes Bearing Functionally Diverse 2-Phenylpyridine Ligands Millett, Adam J.; Habtemariam, Abraha; Romero-Canelón, Isolda Organometallics, Vol. 34, Issue 11 https://doi.org/10.1021/acs.organomet.5b00097	journal	November 2014
Transition Metal Complexes Coordinated by an NAD(P)H Model Compound and their Enhanced Hydride-Donating Abilities in the Presence of a Base Kobayashi, Atsuo; Konno, Hideo; Sakamoto, Kazuhiko Chemistry - A European Journal, Vol. 11, Issue 14 https://doi.org/10.1002/chem.200401211	journal	July 2005
Free-Energy Relationships between the Proton and Hydride Donor Abilities of [HNi(diphosphine) ₂ ] ⁺ Complexes and the Half-Wave Potentials of Their Conjugate Bases Berning, Douglas E.; Miedaner, Alex; Curtis, Calvin J. Organometallics, Vol. 20, Issue 9 https://doi.org/10.1021/om0100582	journal	April 2001
Hydride Donor Abilities and Bond Dissociation Free Energies of Transition Metal Formyl Complexes Ellis, William W.; Miedaner, Alex; Curtis, Calvin J. Journal of the American Chemical Society, Vol. 124, Issue 9 https://doi.org/10.1021/ja0116831	journal	March 2002
Visible Light Driven Benzyl Alcohol Dehydrogenation in a Dye-Sensitized Photoelectrosynthesis Cell Song, Wenjing; Vannucci, Aaron K.; Farnum, Byron H. Journal of the American Chemical Society, Vol. 136, Issue 27 https://doi.org/10.1021/ja505022f	journal	June 2014
Predicting the reactivity of hydride donors in water: thermodynamic constants for hydrogen Connelly, Samantha J.; Wiedner, Eric S.; Appel, Aaron M. Dalton Transactions, Vol. 44, Issue 13 https://doi.org/10.1039/C4DT03841J	journal	January 2015
The Tightness Contribution to the Brønsted α for Hydride Transfer between NAD ⁺ Analogues Lee, In-Sook Han; Chow, Kim-Hung; Kreevoy, Maurice M. Journal of the American Chemical Society, Vol. 124, Issue 26 https://doi.org/10.1021/ja011855u	journal	July 2002
Periodic Trends in Metal Hydride Donor Thermodynamics: Measurement and Comparison of the Hydride Donor Abilities of the Series HM(PNP) ₂ ⁺ (M = Ni, Pd, Pt; PNP = Et ₂ PCH ₂ N(Me)CH ₂ PEt ₂ ) Curtis, Calvin J.; Miedaner, Alex; Raebiger, James W. Organometallics, Vol. 23, Issue 3 https://doi.org/10.1021/om0342816	journal	February 2004
PROTON-COUPLED ELECTRON TRANSFER: A Reaction Chemist's View Mayer, James M. Annual Review of Physical Chemistry, Vol. 55, Issue 1 https://doi.org/10.1146/annurev.physchem.55.091602.094446	journal	June 2004
Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation Warren, J. J.; Mayer, J. M. Proceedings of the National Academy of Sciences, Vol. 107, Issue 12 https://doi.org/10.1073/pnas.0910347107	journal	March 2010
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Qiao, Jinli; Liu, Yuyu; Hong, Feng Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60323G	journal	January 2014
Transition Metal Formyl Complexes Gladysz, J. A. Advances in Organometallic Chemistry https://doi.org/10.1016/S0065-3055(08)60519-5	book	January 1982
Solvent influence on the thermodynamics for hydride transfer from bis(diphosphine) complexes of nickel Connelly Robinson, Samantha J.; Zall, Christopher M.; Miller, Deanna L. Dalton Transactions, Vol. 45, Issue 24 https://doi.org/10.1039/C6DT00309E	journal	January 2016
Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentafluorophenyl)borane. A Synthetic,Structural, Solution Dynamic, and Polymerization Catalytic Study Yang, Xinmin; Stern, Charlotte L.; Marks, Tobin J. Journal of the American Chemical Society, Vol. 116, Issue 22 https://doi.org/10.1021/ja00101a022	journal	November 1994
Complex Hydrides for Hydrogen Storage Orimo, Shin-ichi; Nakamori, Yuko; Eliseo, Jennifer R. Chemical Reviews, Vol. 107, Issue 10 https://doi.org/10.1021/cr0501846	journal	October 2007
Catalysis without Precious Metals Bullock, R. Morris Wiley‐VCH Verlag GmbH & Co https://doi.org/10.1002/9783527631582	book	August 2010
Extension of the Self-Consistent Spectrophotometric Basicity Scale in Acetonitrile to a Full Span of 28 p K _a Units: Unification of Different Basicity Scales Kaljurand, Ivari; Kütt, Agnes; Sooväli, Lilli The Journal of Organic Chemistry, Vol. 70, Issue 3 https://doi.org/10.1021/jo048252w	journal	February 2005
Development of an Efficient and Durable Photocatalytic System for Hydride Reduction of an NAD(P) ⁺ Model Compound Using a Ruthenium(II) Complex Based on Mechanistic Studies Matsubara, Yasuo; Koga, Kichitaro; Kobayashi, Atsuo Journal of the American Chemical Society, Vol. 132, Issue 30 https://doi.org/10.1021/ja1040122	journal	August 2010
Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism Solis, Brian H.; Maher, Andrew G.; Dogutan, Dilek K. Proceedings of the National Academy of Sciences, Vol. 113, Issue 3 https://doi.org/10.1073/pnas.1521834112	journal	December 2015
Electron transfers in chemistry and biology Marcus, R. A.; Sutin, Norman Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, Vol. 811, Issue 3 https://doi.org/10.1016/0304-4173(85)90014-X	journal	August 1985
Catalytic Reductive Transformations of Carboxylic and Carbonic Acid Derivatives Using Molecular Hydrogen Dub, Pavel A.; Ikariya, Takao ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs300341g	journal	July 2012
Thermodynamic and Kinetic Studies of Hydride Transfer for a Series of Molybdenum and Tungsten Hydrides Sarker, Niladri; Bruno, Joseph W. Journal of the American Chemical Society, Vol. 121, Issue 10 https://doi.org/10.1021/ja982017b	journal	March 1999
Determination of the C4H Bond Dissociation Energies of NADH Models and Their Radical Cations in Acetonitrile Zhu, Xiao-Qing; Li, Hai-Rong; Li, Qian Chemistry - A European Journal, Vol. 9, Issue 4 https://doi.org/10.1002/chem.200390108	journal	February 2003
Alcohol Complexes of Tungsten Prepared by Ionic Hydrogenations of Ketones Song, Jeong-Sup; Szalda, David J.; Bullock, R. Morris Organometallics, Vol. 20, Issue 15 https://doi.org/10.1021/om010222l	journal	July 2001
Relative Hydride, Proton, and Hydrogen Atom Transfer Abilities of [HM(diphosphine) ₂ ]PF ₆ Complexes (M = Pt, Ni) Berning, Douglas E.; Noll, Bruce C.; DuBois, Daniel L. Journal of the American Chemical Society, Vol. 121, Issue 49 https://doi.org/10.1021/ja991888y	journal	December 1999
Hydrocarbon Oxidation by Bis-μ-oxo Manganese Dimers: Electron Transfer, Hydride Transfer, and Hydrogen Atom Transfer Mechanisms Larsen, Anna S.; Wang, Kun; Lockwood, Mark A. Journal of the American Chemical Society, Vol. 124, Issue 34, p. 10112-10123 https://doi.org/10.1021/ja020204a	journal	August 2002
Regiospecific Hydride Transfer from cis-[Ru(bpy)2(CO)(CHO)]+ to NAD+ Model Compounds: A Model for Enzymatic Reactions by Aldehyde Dehydrogenases Konno, Hideo; Sakamoto, Kazuhiko; Ishitani, Osamu Angewandte Chemie, Vol. 39, Issue 22 https://doi.org/10.1002/1521-3773(20001117)39:22<4061::AID-ANIE4061>3.3.CO;2-#	journal	November 2000
The Reaction Mechanism with Free Energy Barriers for Electrochemical Dihydrogen Evolution on MoS ₂ Huang, Yufeng; Nielsen, Robert J.; Goddard, William A. Journal of the American Chemical Society, Vol. 137, Issue 20 https://doi.org/10.1021/jacs.5b03329	journal	May 2015
Molybdenum Carbonyl Complexes in the Solvent-Free Catalytic Hydrogenation of Ketones Kimmich, Barbara F. M.; Fagan, Paul J.; Hauptman, Elisabeth Organometallics, Vol. 24, Issue 25 https://doi.org/10.1021/om050564h	journal	December 2005
Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium–Triphos catalyst: from mechanistic investigations to multiphase catalysis Wesselbaum, Sebastian; Moha, Verena; Meuresch, Markus Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02087A	journal	January 2015
Electrochemistry as a diagnostic tool to discriminate between classical M-(H)2 and nonclassical M-(H2) structures within a family of dihydride and dihydrogen metal complexes Bianchini, Claudio; Laschi, Franco; Peruzzini, Maurizio Inorganic Chemistry, Vol. 29, Issue 18 https://doi.org/10.1021/ic00343a025	journal	September 1990
The Mononuclear Molybdenum Enzymes Hille, Russ; Hall, James; Basu, Partha Chemical Reviews, Vol. 114, Issue 7 https://doi.org/10.1021/cr400443z	journal	January 2014
Anionic group 6 transition-metal carbonyl hydrides as reducing agents. ketones, aldehydes, and epoxides Gaus, Paul L.; Kao, S. C.; Youngdahl, Kay Journal of the American Chemical Society, Vol. 107, Issue 8 https://doi.org/10.1021/ja00294a038	journal	April 1985
Reactivity and Equilibrium Thermodynamic Studies of Rhodium Tetrakis(3,5-disulfonatomesityl)porphyrin Species with H ₂ , CO, and Olefins in Water Fu, Xuefeng; Li, Shan; Wayland, Bradford B. Inorganic Chemistry, Vol. 45, Issue 24 https://doi.org/10.1021/ic0615022	journal	November 2006
Anionic Transition Metal Hydrides Darensbourg, Marcetta Y.; Ash, Carlton E. Advances in Organometallic Chemistry https://doi.org/10.1016/S0065-3055(08)60025-8	book	January 1987
Photochemistry of Transition Metal Hydrides Perutz, Robin N.; Procacci, Barbara Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00204	journal	June 2016
A Comprehensive Self-Consistent Spectrophotometric Acidity Scale of Neutral Brønsted Acids in Acetonitrile Kütt, Agnes; Leito, Ivo; Kaljurand, Ivari The Journal of Organic Chemistry, Vol. 71, Issue 7 https://doi.org/10.1021/jo060031y	journal	March 2006
Thermodynamic Studies of [HPt(EtXantphos) ₂ ] ⁺ and [(H) ₂ Pt(EtXantphos) ₂ ] ²⁺ Miedaner, Alex; Raebiger, James W.; Curtis, Calvin J. Organometallics, Vol. 23, Issue 11 https://doi.org/10.1021/om034238i	journal	May 2004
Molecular Photoelectrocatalysts for Visible Light-Driven Hydrogen Evolution from Neutral Water Pitman, Catherine L.; Miller, Alexander J. M. ACS Catalysis, Vol. 4, Issue 8 https://doi.org/10.1021/cs500441f	journal	July 2014
Thermochemical and Mechanistic Studies of Electrocatalytic Hydrogen Production by Cobalt Complexes Containing Pendant Amines Wiedner, Eric S.; Appel, Aaron M.; DuBois, Daniel L. Inorganic Chemistry, Vol. 52, Issue 24 https://doi.org/10.1021/ic4025475	journal	November 2013
Ab Initio Calculations of Thermodynamic Hydricities of Transition-Metal Hydrides in Acetonitrile Qi, Xiu-Juan; Fu, Yao; Liu, Lei Organometallics, Vol. 26, Issue 17 https://doi.org/10.1021/om0702429	journal	August 2007
Acid–base equilibria in systems involving substituted pyridines in polar aprotic protophobic media and in the amphiprotic methanol Augustin-Nowacka, D.; Makowski, M.; Chmurzynski, L. Analytica Chimica Acta, Vol. 418, Issue 2 https://doi.org/10.1016/S0003-2670(00)00967-3	journal	August 2000
Thermodynamic Properties of the Ni−H Bond in Complexes of the Type [HNi(P ₂ ^R N ₂ ^R ^‘ ) ₂ ](BF ₄ ) and Evaluation of Factors That Control Catalytic Activity for Hydrogen Oxidation/Production Fraze, Kendra; Wilson, Aaron D.; Appel, Aaron M. Organometallics, Vol. 26, Issue 16 https://doi.org/10.1021/om070143v	journal	July 2007
Effects of Phosphine–Carbene Substitutions on the Electrochemical and Thermodynamic Properties of Nickel Complexes Galan, Brandon R.; Wiedner, Eric S.; Helm, Monte L. Organometallics, Vol. 33, Issue 9 https://doi.org/10.1021/om500206e	journal	April 2014
Making Hydrogen from Water Using a Homogeneous System Without Noble Metals Lazarides, Theodore; McCormick, Theresa; Du, Pingwu Journal of the American Chemical Society, Vol. 131, Issue 26 https://doi.org/10.1021/ja903044n	journal	July 2009
Hydrogen Production by Molecular Photocatalysis Esswein, Arthur J.; Nocera, Daniel G. Chemical Reviews, Vol. 107, Issue 10 https://doi.org/10.1021/cr050193e	journal	October 2007
Hydrogen atom transfer reactions of transition-metal hydrides. Kinetics and mechanism of the hydrogenation of .alpha.-cyclopropylstyrene by metal carbonyl hydrides Bullock, R. Morris; Samsel, Edward G. Journal of the American Chemical Society, Vol. 112, Issue 19 https://doi.org/10.1021/ja00175a024	journal	September 1990
Calculated Hydride Donor Abilities of Five-Coordinate Transition Metal Hydrides [HM(diphosphine) ₂ ] ⁺ (M = Ni, Pd, Pt) as a Function of the Bite Angle and Twist Angle of Diphosphine Ligands Nimlos, Mark R.; Chang, Christopher H.; Curtis, Calvin J. Organometallics, Vol. 27, Issue 12 https://doi.org/10.1021/om701218x	journal	June 2008
Water Oxidation Intermediates Applied to Catalysis: Benzyl Alcohol Oxidation Vannucci, Aaron K.; Hull, Jonathan F.; Chen, Zuofeng Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja210718u	journal	February 2012
Theoretical Analysis of Cobalt Hangman Porphyrins: Ligand Dearomatization and Mechanistic Implications for Hydrogen Evolution Solis, Brian H.; Maher, Andrew G.; Honda, Tatsuhiko ACS Catalysis, Vol. 4, Issue 12 https://doi.org/10.1021/cs501454y	journal	November 2014
Effect of Molecular Acid-Base Dissociation of Salts on Conductometric Titration Curves in Acetonitrile ¹ Kolthoff, I. M.; Chantooni, M. K. Journal of the American Chemical Society, Vol. 87, Issue 5 https://doi.org/10.1021/ja01083a012	journal	March 1965
Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions Lyaskovskyy, Volodymyr; de Bruin, Bas ACS Catalysis, Vol. 2, Issue 2 https://doi.org/10.1021/cs200660v	journal	January 2012
An experimentally based family of potential energy surfaces for hydride transfer between NAD+ analogs Kim, Yongho; Truhlar, Donald G.; Kreevoy, Maurice M. Journal of the American Chemical Society, Vol. 113, Issue 21 https://doi.org/10.1021/ja00021a002	journal	October 1991
Reversible Hydride Generation and Release from the Ligand of [Ru(pbn)(bpy)2](PF6)2 Driven by a pbn-Localized Redox Reaction Koizumi, Take-aki; Tanaka, Koji Angewandte Chemie International Edition, Vol. 44, Issue 36 https://doi.org/10.1002/anie.200500760	journal	September 2005
Recent advances in catalytic hydrogenation of carbon dioxide Wang, Wei; Wang, Shengping; Ma, Xinbin Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c1cs15008a	journal	January 2011
Iron catalyzed CO ₂ hydrogenation to formate enhanced by Lewis acid co-catalysts Zhang, Yuanyuan; MacIntosh, Alex D.; Wong, Janice L. Chemical Science, Vol. 6, Issue 7 https://doi.org/10.1039/C5SC01467K	journal	January 2015
Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes Choi, Jongwook; MacArthur, Amy H. Roy; Brookhart, Maurice Chemical Reviews, Vol. 111, Issue 3 https://doi.org/10.1021/cr1003503	journal	March 2011
The Ionic Work Function and its Role in Estimating Absolute Electrode Potentials Fawcett, W. Ronald Langmuir, Vol. 24, Issue 17 https://doi.org/10.1021/la7038976	journal	September 2008
Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A Predictive Model through Computations Chen, Shentan; Rousseau, Roger; Raugei, Simone Organometallics, Vol. 30, Issue 22 https://doi.org/10.1021/om200645x	journal	November 2011
Cobalt Complexes Containing Pendant Amines in the Second Coordination Sphere as Electrocatalysts for H ₂ Production Fang, Ming; Wiedner, Eric S.; Dougherty, William G. Organometallics, Vol. 33, Issue 20 https://doi.org/10.1021/om5004607	journal	June 2014
A new group of ruthenium complexes: structure and catalysis Shvo, Youval.; Czarkie, Dorotha.; Rahamim, Yocheved. Journal of the American Chemical Society, Vol. 108, Issue 23 https://doi.org/10.1021/ja00283a041	journal	November 1986
Proton–hydride tautomerism in hydrogen evolution catalysis Quintana, Luis M. Aguirre; Johnson, Samantha I.; Corona, Sydney L. Proceedings of the National Academy of Sciences, Vol. 113, Issue 23 https://doi.org/10.1073/pnas.1606018113	journal	May 2016
Direct Comparison of the Performance of a Bio-inspired Synthetic Nickel Catalyst and a [NiFe]-Hydrogenase, Both Covalently Attached to Electrodes Rodriguez-Maciá, Patricia; Dutta, Arnab; Lubitz, Wolfgang Angewandte Chemie International Edition, Vol. 54, Issue 42 https://doi.org/10.1002/anie.201502364	journal	July 2015
Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes Morris, Robert H. Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.5b00695	journal	March 2016
Striking Differences in Properties of Geometric Isomers of [Ir(tpy)(ppy)H] ⁺ : Experimental and Computational Studies of their Hydricities, Interaction with CO ₂ , and Photochemistry Garg, Komal; Matsubara, Yasuo; Ertem, Mehmed Z. Angewandte Chemie International Edition, Vol. 54, Issue 47 https://doi.org/10.1002/anie.201506961	journal	October 2015
Making Oxygen with Ruthenium Complexes Concepcion, Javier J.; Jurss, Jonah W.; Brennaman, M. Kyle Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001526	journal	December 2009
Molybdenum−Sulfur Dimers as Electrocatalysts for the Production of Hydrogen at Low Overpotentials Appel, Aaron M.; DuBois, Daniel L.; Rakowski DuBois, M. Journal of the American Chemical Society, Vol. 127, Issue 36 https://doi.org/10.1021/ja054034o	journal	September 2005
Two Pathways for Electrocatalytic Oxidation of Hydrogen by a Nickel Bis(diphosphine) Complex with Pendant Amines in the Second Coordination Sphere Yang, Jenny Y.; Smith, Stuart E.; Liu, Tianbiao Journal of the American Chemical Society, Vol. 135, Issue 26 https://doi.org/10.1021/ja400705a	journal	June 2013
Combinations of Ethers and B(C ₆ F ₅ ) ₃ Function as Hydrogenation Catalysts Hounjet, Lindsay J.; Bannwarth, Christoph; Garon, Christian N. Angewandte Chemie International Edition, Vol. 52, Issue 29 https://doi.org/10.1002/anie.201303166	journal	June 2013
A DFT Study: Why Do [Ni(P ^R ₂ N ^{R ^′} ₂ ) ₂ ] ²⁺ Complexes Facilitate the Electrocatalytic Oxidation of Formate? Xue, Liqin; Ahlquist, Mårten S. G. Inorganic Chemistry, Vol. 53, Issue 7 https://doi.org/10.1021/ic4027317	journal	March 2014
First Estimation of C ₄ −H Bond Dissociation Energies of NADH and Its Radical Cation in Aqueous Solution Zhu, Xiao-Qing; Yang, Yuan; Zhang, Ming Journal of the American Chemical Society, Vol. 125, Issue 50 https://doi.org/10.1021/ja0385179	journal	December 2003
Comparison of primary oxidants for water-oxidation catalysis Parent, Alexander R.; Crabtree, Robert H.; Brudvig, Gary W. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35225G	journal	January 2013
A d ¹⁰ Ni-(H ₂ ) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond Harman, W. Hill; Lin, Tzu-Pin; Peters, Jonas C. Angewandte Chemie International Edition, Vol. 53, Issue 4 https://doi.org/10.1002/anie.201308175	journal	December 2013
Aqueous Hydricity of Late Metal Catalysts as a Continuum Tuned by Ligands and the Medium Pitman, Catherine L.; Brereton, Kelsey R.; Miller, Alexander J. M. Journal of the American Chemical Society, Vol. 138, Issue 7 https://doi.org/10.1021/jacs.5b12363	journal	February 2016
Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory Mayer, James M. Accounts of Chemical Research, Vol. 44, Issue 1 https://doi.org/10.1021/ar100093z	journal	January 2011
Acid−Base Equilibria in Nonpolar Media. 4. Extension of the Self-Consistent Basicity Scale in THF Medium. Gas-Phase Basicities of Phosphazenes Kaljurand, Ivari; Rodima, Toomas; Pihl, Aino The Journal of Organic Chemistry, Vol. 68, Issue 26 https://doi.org/10.1021/jo034537h	journal	December 2003
Hydride, Hydrogen Atom, Proton, and Electron Transfer Driving Forces of Various Five-Membered Heterocyclic Organic Hydrides and Their Reaction Intermediates in Acetonitrile Zhu, Xiao-Qing; Zhang, Ming-Tian; Yu, Ao Journal of the American Chemical Society, Vol. 130, Issue 8 https://doi.org/10.1021/ja075523m	journal	February 2008
Comprehensive Thermochemistry of W–H Bonding in the Metal Hydrides CpW(CO) ₂ (IMes)H, [CpW(CO) ₂ (IMes)H] ^•+ , and [CpW(CO) ₂ (IMes)(H) ₂ ] ⁺ . Influence of an N -Heterocyclic Carbene Ligand on Metal Hydride Bond Energies Roberts, John A. S.; Appel, Aaron M.; DuBois, Daniel L. Journal of the American Chemical Society, Vol. 133, Issue 37 https://doi.org/10.1021/ja202830w	journal	September 2011
Synthesis, Electrochemistry, and Reactivity of New Iridium(III) and Rhodium(III) Hydrides Hu, Yue; Li, Ling; Shaw, Anthony P. Organometallics, Vol. 31, Issue 14 https://doi.org/10.1021/om300398r	journal	June 2012
The Golden Age of Transfer Hydrogenation Wang, Dong; Astruc, Didier Chemical Reviews, Vol. 115, Issue 13 https://doi.org/10.1021/acs.chemrev.5b00203	journal	June 2015
Formation of η ² -Coordinated Dihydropyridine–Ruthenium(II) Complexes by Hydride Transfer from Ruthenium(II) to Pyridinium Cations Matsubara, Yasuo; Kosaka, Tatsumi; Koga, Kichitaro Organometallics, Vol. 32, Issue 21 https://doi.org/10.1021/om400862n	journal	October 2013
Equilibrium acidities in dimethyl sulfoxide solution Bordwell, Frederick G. Accounts of Chemical Research, Vol. 21, Issue 12 https://doi.org/10.1021/ar00156a004	journal	December 1988
Isolation and Crystal Structure of a Water-Soluble Iridium Hydride: A Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media Abura, Tsutomu; Ogo, Seiji; Watanabe, Yoshihito Journal of the American Chemical Society, Vol. 125, Issue 14 https://doi.org/10.1021/ja0288237	journal	April 2003
Hydride Transfer from Rhodium Complexes to Triethylborane DuBois, Daniel L.; Blake, Daniel M.; Miedaner, Alex Organometallics, Vol. 25, Issue 18 https://doi.org/10.1021/om060584z	journal	August 2006
Double Bond Isomerisation and Migration-New Playgrounds for Transition Metal-Catalysis Hilt, Gerhard ChemCatChem, Vol. 6, Issue 9 https://doi.org/10.1002/cctc.201402341	journal	July 2014
Directing the Reactivity of [HFe ₄ N(CO) ₁₂ ] ⁻ toward H ⁺ or CO ₂ Reduction by Understanding the Electrocatalytic Mechanism Rail, M. Diego; Berben, Louise A. Journal of the American Chemical Society, Vol. 133, Issue 46 https://doi.org/10.1021/ja208312t	journal	November 2011
Organometallic Ruthenium and Iridium Transfer-Hydrogenation Catalysts Using Coenzyme NADH as a Cofactor Betanzos-Lara, Soledad; Liu, Zhe; Habtemariam, Abraha Angewandte Chemie International Edition, Vol. 51, Issue 16 https://doi.org/10.1002/anie.201108175	journal	March 2012
Cyclopentadiene-mediated hydride transfer from rhodium complexes Pitman, C. L.; Finster, O. N. L.; Miller, A. J. M. Chemical Communications, Vol. 52, Issue 58 https://doi.org/10.1039/C6CC00575F	journal	January 2016
Theoretical studies of the mechanism of catalytic hydrogen production by a cobaloxime Muckerman, James T.; Fujita, Etsuko Chemical Communications, Vol. 47, Issue 46 https://doi.org/10.1039/c1cc15330g	journal	January 2011
Frustrated Lewis Pair Mediated Hydrogenations Stephan, Douglas W.; Erker, Gerhard Topics in Current Chemistry https://doi.org/10.1007/128_2012_392	book	January 2013
Reductive Coupling of Carbon Monoxide in a Rhenium Carbonyl Complex with Pendant Lewis Acids Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E. Journal of the American Chemical Society, Vol. 130, Issue 36 https://doi.org/10.1021/ja805108z	journal	September 2008
Thermodynamic and Kinetic Hydricity of Ruthenium(II) Hydride Complexes Matsubara, Yasuo; Fujita, Etsuko; Doherty, Mark D. Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja302937q	journal	September 2012
Electrocatalytic pathways towards sustainable fuel production from water and CO2 Inglis, Jane L.; MacLean, Brian J.; Pryce, Mary T. Coordination Chemistry Reviews, Vol. 256, Issue 21-22 https://doi.org/10.1016/j.ccr.2012.05.002	journal	November 2012
Incorporation of Pendant Bases into Rh(diphosphine) ₂ Complexes: Synthesis, Thermodynamic Studies, And Catalytic CO ₂ Hydrogenation Activity of [Rh(P ₂ N ₂ ) ₂ ] ⁺ Complexes Lilio, Alyssia M.; Reineke, Mark H.; Moore, Curtis E. Journal of the American Chemical Society, Vol. 137, Issue 25 https://doi.org/10.1021/jacs.5b04291	journal	June 2015
A novel type of hydride-transfer photocatalysis by Ru ^II –pyridine complexes: regiocontrolled reduction of an NAD(P) model compound by triethylamine Ishitani, Osamu; Inoue, Nobuyo; Koike, Kazuhide J. Chem. Soc., Chem. Commun., Issue 4 https://doi.org/10.1039/C39940000367	journal	January 1994
Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production Horvath, S.; Fernandez, L. E.; Soudackov, A. V. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1118333109	journal	April 2012
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation Kärkäs, Markus D.; Verho, Oscar; Johnston, Eric V. Chemical Reviews, Vol. 114, Issue 24 https://doi.org/10.1021/cr400572f	journal	October 2014
Reversible H ₂ Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis Harman, W. Hill; Peters, Jonas C. Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja211419t	journal	March 2012
Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis Boyer, Julie L.; Rochford, Jonathan; Tsai, Ming-Kang Coordination Chemistry Reviews, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.ccr.2009.09.006	journal	February 2010
Studies of a Series of [Ni(P ^R ₂ N ^Ph ₂ ) ₂ (CH ₃ CN)] ²⁺ Complexes as Electrocatalysts for H ₂ Production: Substituent Variation at the Phosphorus Atom of the P ₂ N ₂ Ligand Kilgore, Uriah J.; Stewart, Michael P.; Helm, Monte L. Inorganic Chemistry, Vol. 50, Issue 21 https://doi.org/10.1021/ic201461a	journal	November 2011
Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium Brewster, Timothy P.; Miller, Alexander J. M.; Heinekey, D. Michael Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja408149n	journal	October 2013
Hydricities of BzNADH, C ₅ H ₅ Mo(PMe ₃ )(CO) ₂ H, and C ₅ Me ₅ Mo(PMe ₃ )(CO) ₂ H in Acetonitrile Ellis, William W.; Raebiger, James W.; Curtis, Calvin J. Journal of the American Chemical Society, Vol. 126, Issue 9 https://doi.org/10.1021/ja038567d	journal	March 2004
Selective reduction of acyl chlorides to aldehydes by anionic Group VIB transition metal hydrides Kao, S. C.; Gaus, Paul L.; Youngdahl, Kay Organometallics, Vol. 3, Issue 10 https://doi.org/10.1021/om00088a031	journal	October 1984
Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media Moret, Séverine; Dyson, Paul J.; Laurenczy, Gábor Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5017	journal	June 2014
Metal-Ligand Cooperation Khusnutdinova, Julia R.; Milstein, David Angewandte Chemie International Edition, Vol. 54, Issue 42 https://doi.org/10.1002/anie.201503873	journal	September 2015
Mechanism of Hydride Donor Generation Using a Ru(II) Complex Containing an NAD ⁺ Model Ligand: Pulse and Steady-State Radiolysis Studies Polyansky, Dmitry E.; Cabelli, Diane; Muckerman, James T. Inorganic Chemistry, Vol. 47, Issue 10 https://doi.org/10.1021/ic702139n	journal	May 2008
Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins Bediako, D. Kwabena; Solis, Brian H.; Dogutan, Dilek K. Proceedings of the National Academy of Sciences, Vol. 111, Issue 42 https://doi.org/10.1073/pnas.1414908111	journal	October 2014
Using Ligand Bite Angles To Control the Hydricity of Palladium Diphosphine Complexes Raebiger, James W.; Miedaner, Alex; Curtis, Calvin J. Journal of the American Chemical Society, Vol. 126, Issue 17 https://doi.org/10.1021/ja0395240	journal	May 2004
Rhodium(I) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal→Borane Interaction Bontemps, Sébastien; Gornitzka, Heinz; Bouhadir, Ghenwa Angewandte Chemie International Edition, Vol. 45, Issue 10 https://doi.org/10.1002/anie.200503649	journal	February 2006
Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate Barnett, Brandon R.; Moore, Curtis E.; Rheingold, Arnold L. Journal of the American Chemical Society, Vol. 136, Issue 29 https://doi.org/10.1021/ja505843g	journal	July 2014
Drastic difference in the photo-driven hydrogenation reactions of ruthenium complexes containing NAD model ligands Ohtsu, Hideki; Tanaka, Koji Chemical Communications, Vol. 48, Issue 12 https://doi.org/10.1039/c2cc15886h	journal	January 2012
Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes Clapham, Sean E.; Hadzovic, Alen; Morris, Robert H. Coordination Chemistry Reviews, Vol. 248, Issue 21-24 https://doi.org/10.1016/j.ccr.2004.04.007	journal	December 2004
Bond energies in solution from electrode potentials and thermochemical cycles. A simplified and general approach Wayner, Danial D. M.; Parker, Vernon D. Accounts of Chemical Research, Vol. 26, Issue 5 https://doi.org/10.1021/ar00029a010	journal	May 1993
Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile Roberts, John A. S.; Bullock, R. Morris Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic302461q	journal	June 2012
Equilibrium Thermodynamic Studies in Water: Reactions of Dihydrogen with Rhodium(III) Porphyrins Relevant to Rh−Rh, Rh−H, and Rh−OH Bond Energetics Fu, Xuefeng; Wayland, Bradford B. Journal of the American Chemical Society, Vol. 126, Issue 8 https://doi.org/10.1021/ja039218m	journal	March 2004
Cooperating Ligands in Catalysis Grützmacher, Hansjörg Angewandte Chemie International Edition, Vol. 47, Issue 10 https://doi.org/10.1002/anie.200704654	journal	February 2008
Incorporating Amino Acid Esters into Catalysts for Hydrogen Oxidation: Steric and Electronic Effects and the Role of Water as a Base Lense, Sheri; Ho, Ming-Hsun; Chen, Shentan Organometallics, Vol. 31, Issue 19 https://doi.org/10.1021/om300409y	journal	September 2012
Hydrogen Evolution Catalyzed by Cobaloximes Dempsey, Jillian L.; Brunschwig, Bruce S.; Winkler, Jay R. Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar900253e	journal	December 2009
Kinetics of Hydrogen Atom Transfer from (η ⁵ -C ₅ H ₅ )Cr(CO) ₃ H to Various Olefins: Influence of Olefin Structure Choi, Jongwook; Tang, Lihao; Norton, Jack R. Journal of the American Chemical Society, Vol. 129, Issue 1 https://doi.org/10.1021/ja066325i	journal	January 2007
Hydride Transfer by Hydrido Transition-Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex Song, Jeong-Sup; Szalda, David J.; Bullock, R. Morris Angewandte Chemie International Edition in English, Vol. 31, Issue 9 https://doi.org/10.1002/anie.199212331	journal	September 1992
Hydride Transfer from (η ⁵ -C ₅ Me ₅ )(CO) ₂ MH (M = Fe, Ru, Os) to Trityl Cation: Different Products from Different Metals and the Kinetics of Hydride Transfer Cheng, Tan-Yun; Bullock, R. Morris Organometallics, Vol. 21, Issue 11 https://doi.org/10.1021/om020012o	journal	May 2002
A modular, energy-based approach to the development of nickel containing molecular electrocatalysts for hydrogen production and oxidation Shaw, Wendy J.; Helm, Monte L.; DuBois, Daniel L. Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1827, Issue 8-9 https://doi.org/10.1016/j.bbabio.2013.01.003	journal	August 2013
Oxygen−Oxygen Bond Formation Pathways Promoted by Ruthenium Complexes Romain, Sophie; Vigara, Laura; Llobet, Antoni Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar900240w	journal	December 2009
Half-sandwich rhodium(III) transfer hydrogenation catalysts: Reduction of NAD+ and pyruvate, and antiproliferative activity Soldevila-Barreda, Joan J.; Habtemariam, Abraha; Romero-Canelón, Isolda Journal of Inorganic Biochemistry, Vol. 153 https://doi.org/10.1016/j.jinorgbio.2015.10.008	journal	December 2015
Biomimetic Hydrogen Evolution: MoS ₂ Nanoparticles as Catalyst for Hydrogen Evolution Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob Journal of the American Chemical Society, Vol. 127, Issue 15 https://doi.org/10.1021/ja0504690	journal	April 2005
Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants Morris, Robert H. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja410718r	journal	January 2014
New approaches to hydrogen storage Graetz, Jason Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B718842K	journal	January 2009
A thermodynamic and kinetic study of the heterolytic activation of hydrogen by frustrated borane–amine Lewis pairs Karkamkar, Abhi; Parab, Kshitij; Camaioni, Donald M. Dalton Trans., Vol. 42, Issue 3 https://doi.org/10.1039/C2DT31628E	journal	January 2013
Hydride-Donor Abilities of 1,4-Dihydropyridines: A Comparison with π Nucleophiles and Borohydride Anions Richter, Dorothea; Mayr, Herbert Angewandte Chemie International Edition, Vol. 48, Issue 11 https://doi.org/10.1002/anie.200804263	journal	March 2009
Experimental and Computational Mechanistic Studies Guiding the Rational Design of Molecular Electrocatalysts for Production and Oxidation of Hydrogen Raugei, Simone; Helm, Monte L.; Hammes-Schiffer, Sharon Inorganic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/acs.inorgchem.5b02262	journal	November 2015
Bio-Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal-Activated Substrate McSkimming, Alex; Bhadbhade, Mohan M.; Colbran, Stephen B. Angewandte Chemie International Edition, Vol. 52, Issue 12 https://doi.org/10.1002/anie.201210086	journal	February 2013
Molecular artificial photosynthesis Berardi, Serena; Drouet, Samuel; Francàs, Laia Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60405E	journal	January 2014
Electrocatalytic H ₂ production with a turnover frequency >10 ⁷ s ⁻¹ : the medium provides an increase in rate but not overpotential Hou, Jianbo; Fang, Ming; Cardenas, Allan Jay P. Energy Environ. Sci., Vol. 7, Issue 12 https://doi.org/10.1039/C4EE01899K	journal	January 2014
Photochemical Stereospecific Hydrogenation of a Ru Complex with an NAD ⁺ /NADH-Type Ligand Fukushima, Takashi; Fujita, Etsuko; Muckerman, James T. Inorganic Chemistry, Vol. 48, Issue 24 https://doi.org/10.1021/ic901935u	journal	December 2009
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions Lyons, Thomas W.; Sanford, Melanie S. Chemical Reviews, Vol. 110, Issue 2 https://doi.org/10.1021/cr900184e	journal	February 2010
Transition-Metal-Catalyzed Regeneration of Nicotinamide Coenzymes with Hydrogen ¹ Wagenknecht, Paul S.; Penney, Jonathan M.; Hembre, Robert T. Organometallics, Vol. 22, Issue 6 https://doi.org/10.1021/om020843u	journal	March 2003
Hydridicity of Transition Metal Hydrides and its Implications for Reactivity Jacobsen, Heiko; Berke, Heinz Recent Advances in Hydride Chemistry https://doi.org/10.1016/B978-044450733-4/50004-8	book	January 2001
Photochemical Formic Acid Dehydrogenation by Iridium Complexes: Understanding Mechanism and Overcoming Deactivation Barrett, Seth M.; Slattery, Samuel A.; Miller, Alexander J. M. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01995	journal	September 2015
The roles of the first and second coordination spheres in the design of molecular catalysts for H ₂ production and oxidation Rakowski DuBois, M.; DuBois, Daniel L. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B801197B	journal	January 2009
Theoretical Analysis of Mechanistic Pathways for Hydrogen Evolution Catalyzed by Cobaloximes Solis, Brian H.; Hammes-Schiffer, Sharon Inorganic Chemistry, Vol. 50, Issue 21 https://doi.org/10.1021/ic201842v	journal	November 2011
Bond Activation and Catalysis by Ruthenium Pincer Complexes Gunanathan, Chidambaram; Milstein, David Chemical Reviews, Vol. 114, Issue 24 https://doi.org/10.1021/cr5002782	journal	November 2014
p K _a Measurements of P(RNCH ₂ CH ₃ ) ₃ N Kisanga, Philip B.; Verkade, John G.; Schwesinger, Reinhard The Journal of Organic Chemistry, Vol. 65, Issue 17 https://doi.org/10.1021/jo000427o	journal	August 2000
Regeneration of nicotinamide cofactors for use in organic synthesis Chenault, H. Keith; Whitesides, George M. Applied Biochemistry and Biotechnology, Vol. 14, Issue 2 https://doi.org/10.1007/BF02798431	journal	March 1987
Transition-Metal Hydride Radical Cations Hu, Yue; Shaw, Anthony P.; Estes, Deven P. Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.5b00532	journal	February 2016
Electrocatalytic Oxidation of Formate by [Ni(P ^R ₂ N ^R′ ₂ ) ₂ (CH ₃ CN)] ²⁺ Complexes Galan, Brandon R.; Schöffel, Julia; Linehan, John C. Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja204489e	journal	August 2011
Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes Casey, Charles P.; Guan, Hairong Journal of the American Chemical Society, Vol. 131, Issue 7 https://doi.org/10.1021/ja808683z	journal	February 2009
Hydrogen storage and evolution catalysed by metal hydride complexes Fukuzumi, Shunichi; Suenobu, Tomoyoshi Dalton Trans., Vol. 42, Issue 1 https://doi.org/10.1039/C2DT31823G	journal	January 2013
Cooperation between Transition Metals and Lewis Acids: A Way To Activate H ₂ and HE bonds Devillard, Marc; Bouhadir, Ghenwa; Bourissou, Didier Angewandte Chemie International Edition, Vol. 54, Issue 3 https://doi.org/10.1002/anie.201410781	journal	December 2014
Hydride ion-carrier ability in Rh(i) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand McSkimming, Alex; Bhadbhade, Mohan; Colbran, Stephen B. Dalton Transactions, Vol. 39, Issue 44 https://doi.org/10.1039/c0dt00289e	journal	January 2010
Hydride Transfer Reactions of Transition Metal Hydrides: Kinetic Hydricity of Metal Carbonyl Hydrides Cheng, Tan-Yun; Brunschwig, Bruce S.; Bullock, R. Morris Journal of the American Chemical Society, Vol. 120, Issue 50 https://doi.org/10.1021/ja9820036	journal	December 1998
Using combinations of oxidants and bases as PCET reactants: thermochemical and practical considerations Waidmann, Christopher R.; Miller, Alexander J. M.; Ng, Cheuk-Wa Angela Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee03300c	journal	January 2012
Understanding and exploiting C–H bond activation Labinger, Jay A.; Bercaw, John E. Nature, Vol. 417, Issue 6888 https://doi.org/10.1038/417507a	journal	May 2002
Thermodynamic Hydride Donor Abilities of [HW(CO) ₄ L] ^- Complexes (L = PPh ₃ , P(OMe) ₃ , CO) and Their Reactions with [C ₅ Me ₅ Re(PMe ₃ )(NO)(CO)] ⁺ Ellis, William W.; Ciancanelli, Rebecca; Miller, Susie M. Journal of the American Chemical Society, Vol. 125, Issue 40 https://doi.org/10.1021/ja036524r	journal	October 2003
Prediction of acidity in acetonitrile solution with COSMO-RS Eckert, Frank; Leito, Ivo; Kaljurand, Ivari Journal of Computational Chemistry, Vol. 30, Issue 5 https://doi.org/10.1002/jcc.21103	journal	April 2009
Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H ₂ Activation and the Role of Acid−Base Properties Rokob, Tibor András; Hamza, Andrea; Pápai, Imre Journal of the American Chemical Society, Vol. 131, Issue 30 https://doi.org/10.1021/ja903878z	journal	August 2009
Nitrosyl Substituted Hydride Complexes–An Activated Class of Compounds Berke, Heinz; Burger, Peter Comments on Inorganic Chemistry, Vol. 16, Issue 5 https://doi.org/10.1080/02603599408035773	journal	September 1994
Mechanistic Insights into Catalytic H ₂ Oxidation by Ni Complexes Containing a Diphosphine Ligand with a Positioned Amine Base Yang, Jenny Y.; Bullock, R. Morris; Shaw, Wendy J. Journal of the American Chemical Society, Vol. 131, Issue 16 https://doi.org/10.1021/ja900483x	journal	April 2009
Transition metal-hydrogen and metal-carbon bond strengths: the keys to catalysis Simoes, J. A. Martinho; Beauchamp, J. L. Chemical Reviews, Vol. 90, Issue 4 https://doi.org/10.1021/cr00102a004	journal	June 1990
Chemical approaches to artificial photosynthesis Meyer, Thomas J. Accounts of Chemical Research, Vol. 22, Issue 5 https://doi.org/10.1021/ar00161a001	journal	May 1989
Chemically catalyzed net electrochemical oxidation of alcohols, aldehydes, and unsaturated hydrocarbons using the system (trpy)(bpy)Ru(OH2)2+/(trpy)(bpy)RuO2+ Moyer, Bruce A.; Thompson, Mark S.; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 102, Issue 7 https://doi.org/10.1021/ja00527a030	journal	March 1980
Homogeneous Catalysis with Inexpensive Metals: Ionic Hydrogenation of Ketones with Molybdenum and Tungsten Catalysts Bullock, R. Morris; Voges, Mark H. Journal of the American Chemical Society, Vol. 122, Issue 50 https://doi.org/10.1021/ja0010599	journal	December 2000
Single-Step Hydride Transfer from CpMo(CO) ₂ (PPh ₃ )H to Protonated Ketones Smith, Kjell-Tore; Norton, Jack R.; Tilset, Mats Organometallics, Vol. 15, Issue 21 https://doi.org/10.1021/om950984e	journal	January 1996
Solvent, ligand, and ionic charge effects on reaction entropies for simple transition-metal redox couples Hupp, Joseph T.; Weaver, Michael J. Inorganic Chemistry, Vol. 23, Issue 22 https://doi.org/10.1021/ic00190a042	journal	October 1984
Very efficient reduction of NAD(P)+ with formate catalysed by cationic rhodium complexes Ruppert, Romain; Herrmann, Sabine; Steckhan, Eberhard Journal of the Chemical Society, Chemical Communications, Issue 17 https://doi.org/10.1039/c39880001150	journal	January 1988
A Highly Efficient Mononuclear Iridium Complex Photocatalyst for CO ₂ Reduction under Visible Light Sato, Shunsuke; Morikawa, Takeshi; Kajino, Tsutomu Angewandte Chemie International Edition, Vol. 52, Issue 3 https://doi.org/10.1002/anie.201206137	journal	November 2012
Radical Ligands Confer Nobility on Base-Metal Catalysts Chirik, P. J.; Wieghardt, K. Science, Vol. 327, Issue 5967 https://doi.org/10.1126/science.1183281	journal	February 2010
Kinetics and Thermodynamics of H ^– /H•/H ⁺ Transfer from a Rhodium(III) Hydride Hu, Yue; Norton, Jack R. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja412309j	journal	April 2014
Solvation Effects on Transition Metal Hydricity Tsay, Charlene; Livesay, Brooke N.; Ruelas, Samantha Journal of the American Chemical Society, Vol. 137, Issue 44 https://doi.org/10.1021/jacs.5b07777	journal	November 2015
Frustrated Lewis Pairs Stephan, Douglas W. Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b06794	journal	August 2015
Ionic Hydrogenations of Hindered Olefins at Low Temperature. Hydride Transfer Reactions of Transition Metal Hydrides Bullock, R. Morris; Song, Jeong-Sup Journal of the American Chemical Society, Vol. 116, Issue 19 https://doi.org/10.1021/ja00098a021	journal	September 1994
Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E. Journal of the American Chemical Society, Vol. 132, Issue 10 https://doi.org/10.1021/ja100574n	journal	March 2010
Heterolytic H ₂ Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane Fong, Henry; Moret, Marc-Etienne; Lee, Yunho Organometallics, Vol. 32, Issue 10 https://doi.org/10.1021/om400281v	journal	May 2013
Synthesis and Structure of CpMo(CO)(dppe)H and Its Oxidation by Ph ₃ C ⁺ Cheng, Tan-Yun; Szalda, David J.; Zhang, Jie Inorganic Chemistry, Vol. 45, Issue 12 https://doi.org/10.1021/ic060111k	journal	June 2006
Thermodynamic Studies of HRh(depx) ₂ and [(H) ₂ Rh(depx) ₂ ](CF ₃ SO ₃ ): Relationships between Five-Coordinate Monohydrides and Six-Coordinate Dihydrides Raebiger, James W.; DuBois, Daniel L. Organometallics, Vol. 24, Issue 1 https://doi.org/10.1021/om049437w	journal	January 2005
Formate oxidation via β-deprotonation in [Ni(PR2NR′2)2(CH3CN)]2+ complexes Seu, Candace S.; Appel, Aaron M.; Doud, Michael D. Energy & Environmental Science, Vol. 5, Issue 4 https://doi.org/10.1039/c2ee03341k	journal	January 2012
Ionization potentials and electron affinities in aqueous solution Pearson, Ralph G. Journal of the American Chemical Society, Vol. 108, Issue 20 https://doi.org/10.1021/ja00280a002	journal	October 1986
Hydride sponge: 1,8-naphthalenediylbis(dimethylborane) Katz, Howard Edan Journal of the American Chemical Society, Vol. 107, Issue 5 https://doi.org/10.1021/ja00291a057	journal	March 1985
Biomimetic NAD+ Models for Tandem Cofactor Regeneration, Horse Liver Alcohol Dehydrogenase Recognition of 1,4-NADH Derivatives, and Chiral Synthesis Lo, H. Christine; Fish, Richard H. Angewandte Chemie International Edition, Vol. 41, Issue 3 https://doi.org/10.1002/1521-3773(20020201)41:3<478::AID-ANIE478>3.0.CO;2-K	journal	January 2002
Homogeneous syngas conversion West, Nathan M.; Miller, Alexander J. M.; Labinger, Jay A. Coordination Chemistry Reviews, Vol. 255, Issue 7-8 https://doi.org/10.1016/j.ccr.2010.08.019	journal	April 2011
Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts Wang, Mei; Chen, Lin; Sun, Licheng Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03309g	journal	January 2012
Catalytic Ionic Hydrogenations Bullock, R. Morris Chemistry - A European Journal, Vol. 10, Issue 10 https://doi.org/10.1002/chem.200305639	journal	May 2004
Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions Engle, Keary M.; Mei, Tian-Sheng; Wasa, Masayuki Accounts of Chemical Research, Vol. 45, Issue 6 https://doi.org/10.1021/ar200185g	journal	December 2011
Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs Mahdi, Tayseer; Stephan, Douglas W. Journal of the American Chemical Society, Vol. 136, Issue 45 https://doi.org/10.1021/ja508829x	journal	October 2014
Improved Catalytic Activity of Ruthenium–Arene Complexes in the Reduction of NAD ⁺ Soldevila-Barreda, Joan J.; Bruijnincx, Pieter C. A.; Habtemariam, Abraha Organometallics, Vol. 31, Issue 16 https://doi.org/10.1021/om3006307	journal	August 2012
Metal−Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds Noyori, Ryoji; Yamakawa, Masashi; Hashiguchi, Shohei The Journal of Organic Chemistry, Vol. 66, Issue 24 https://doi.org/10.1021/jo010721w	journal	November 2001
The coordination chemistry of organo-hydride donors: new prospects for efficient multi-electron reduction McSkimming, Alex; Colbran, Stephen B. Chemical Society Reviews, Vol. 42, Issue 12 https://doi.org/10.1039/c3cs35466k	journal	January 2013
Thermodynamic Scales for Sulfur Atom Transfer and Oxo-for-Sulfido Exchange Reactions Donahue, James P. Chemical Reviews, Vol. 106, Issue 11 https://doi.org/10.1021/cr050044w	journal	November 2006
CO ₂ Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO ₂ Reduction Wang, Wan-Hui; Himeda, Yuichiro; Muckerman, James T. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00197	journal	August 2015
Hydride transfer and dihydrogen elimination from osmium and ruthenium metalloporphyrin hydrides: model processes for hydrogenase enzymes and the hydrogen electrode reaction Collman, James P.; Wagenknecht, Paul S.; Lewis, Nathan S. Journal of the American Chemical Society, Vol. 114, Issue 14 https://doi.org/10.1021/ja00040a028	journal	July 1992
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
The Remarkable Reactivity of High Oxidation State Ruthenium and Osmium Polypyridyl Complexes Meyer, Thomas J.; Huynh, My Hang V. Inorganic Chemistry, Vol. 42, Issue 25 https://doi.org/10.1021/ic020731v	journal	December 2003
Acidities of water and simple alcohols in dimethyl sulfoxide solution Olmstead, William N.; Margolin, Zafra; Bordwell, Frederick G. The Journal of Organic Chemistry, Vol. 45, Issue 16 https://doi.org/10.1021/jo01304a032	journal	August 1980
[Ni(Et ₂ PCH ₂ NMeCH ₂ PEt ₂ ) ₂ ] ²⁺ as a Functional Model for Hydrogenases Curtis, Calvin J.; Miedaner, Alex; Ciancanelli, Rebecca Inorganic Chemistry, Vol. 42, Issue 1 https://doi.org/10.1021/ic020610v	journal	January 2003
Synthesis of transition metal formyl compounds by nucleophilic attack of hydride on coordinated carbon monoxide Casey, Charles P.; Neumann, Stephen M. Journal of the American Chemical Society, Vol. 98, Issue 17 https://doi.org/10.1021/ja00433a059	journal	August 1976
Regioselective Reduction of NAD+ Models with [Cp*Rh(bpy)H]+: Structure-Activity Relationships and Mechanistic Aspects in the Formation of the 1,4-NADH Derivatives Lo, H. Christine; Buriez, Olivier; Kerr, John B. Angewandte Chemie International Edition, Vol. 38, Issue 10 https://doi.org/10.1002/(SICI)1521-3773(19990517)38:10<1429::AID-ANIE1429>3.0.CO;2-Q	journal	May 1999
Cooperative Catalysis with First-Row Late Transition Metals van der Vlugt, Jarl Ivar; de Bruin, Bas European Journal of Inorganic Chemistry, Vol. 2012, Issue 3, p. 363-375 https://doi.org/10.1002/ejic.201100752	journal	September 2011
Analytical study of a series of substituted (2,2'-bipyridyl)(pentamethylcyclopentadienyl)rhodium and -iridium complexes with regard to their effectiveness as redox catalysts for the indirect electrochemical and chemical reduction of NAD(P)+ Steckhan, Eberhard.; Herrmann, Sabine.; Ruppert, Romain. Organometallics, Vol. 10, Issue 5 https://doi.org/10.1021/om00051a056	journal	May 1991
Acid-base equilibriums in dipolar aprotic solvents Kolthoff, I. M. Analytical Chemistry, Vol. 46, Issue 13 https://doi.org/10.1021/ac60349a005	journal	November 1974
Hydrogen Generation from Weak Acids: Electrochemical and Computational Studies in the [(η ⁵ -C ₅ H ₅ )Fe(CO) ₂ ] ₂ System Felton, Greg A. N.; Vannucci, Aaron K.; Okumura, Noriko Organometallics, Vol. 27, Issue 18 https://doi.org/10.1021/om800366h	journal	September 2008
Efficient Catalytic Interconversion between NADH and NAD ⁺ Accompanied by Generation and Consumption of Hydrogen with a Water-Soluble Iridium Complex at Ambient Pressure and Temperature Maenaka, Yuta; Suenobu, Tomoyoshi; Fukuzumi, Shunichi Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja207785f	journal	December 2011
Hydricity of an Fe–H Species and Catalytic CO ₂ Hydrogenation Fong, Henry; Peters, Jonas C. Inorganic Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/ic502508p	journal	December 2014
Reactions of tris- and bis(2,2'-bipyridine)rhodium(II) complexes in aqueous solution Schwarz, Harold A.; Creutz, Carol Inorganic Chemistry, Vol. 22, Issue 5 https://doi.org/10.1021/ic00147a002	journal	March 1983
Ammonia-Borane and Related Compounds as Dihydrogen Sources Staubitz, Anne; Robertson, Alasdair P. M.; Manners, Ian Chemical Reviews, Vol. 110, Issue 7 https://doi.org/10.1021/cr100088b	journal	July 2010
Hydride Reduction of NAD(P) ⁺ Model Compounds with a Ru(II)–Hydrido Complex Koga, Kichitaro; Matsubara, Yasuo; Kosaka, Tatsumi Organometallics, Vol. 34, Issue 23 https://doi.org/10.1021/acs.organomet.5b00713	journal	November 2015
Visible light photocatalytic reduction of aldehydes by Rh( iii )–H: a detailed mechanistic study Ghosh, T.; Slanina, T.; König, B. Chemical Science, Vol. 6, Issue 3 https://doi.org/10.1039/C4SC03709J	journal	January 2015
Thermodynamic Diagnosis of the Properties and Mechanism of Dihydropyridine-Type Compounds as Hydride Source in Acetonitrile with “Molecule ID Card” Zhu, Xiao-Qing; Tan, Yue; Cao, Chao-Tun The Journal of Physical Chemistry B, Vol. 114, Issue 5 https://doi.org/10.1021/jp911137p	journal	February 2010
Structure sensitivity of the Marcus .lambda. for hydride transfer between NAD+ analogs Kreevoy, Maurice M.; Ostovic, Drazen.; Lee, In Sook Han. Journal of the American Chemical Society, Vol. 110, Issue 2 https://doi.org/10.1021/ja00210a036	journal	January 1988
Recommendations on reporting electrode potentials in nonaqueous solvents (Recommendations 1983) Gritzner, G.; Kuta, J. Pure and Applied Chemistry, Vol. 56, Issue 4 https://doi.org/10.1351/pac198456040461	journal	January 1984
Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry Rountree, Eric S.; McCarthy, Brian D.; Eisenhart, Thomas T. Inorganic Chemistry, Vol. 53, Issue 19 https://doi.org/10.1021/ic500658x	journal	September 2014
Oxidation of Toluene by [(phen) ₂ Mn(μ-O) ₂ Mn(phen) ₂ ] ⁴⁺ via Initial Hydride Abstraction Lockwood, Mark A.; Wang, Kun; Mayer, James M. Journal of the American Chemical Society, Vol. 121, Issue 50 https://doi.org/10.1021/ja992153w	journal	December 1999
Development of Molecular Electrocatalysts for Energy Storage DuBois, Daniel L. Inorganic Chemistry, Vol. 53, Issue 8 https://doi.org/10.1021/ic4026969	journal	February 2014
Solution homolytic bond dissociation energies of organotransition-metal hydrides Tilset, Mats; Parker, Vernon D. Journal of the American Chemical Society, Vol. 111, Issue 17 https://doi.org/10.1021/ja00199a034	journal	August 1989
A potentiometric study of acid–base equilibria of substituted pyridines in acetonitrile Augustin-Nowacka, D.; Chmurzyñski, L. Analytica Chimica Acta, Vol. 381, Issue 2-3 https://doi.org/10.1016/S0003-2670(98)00771-5	journal	February 1999
Photoswitchable Hydride Transfer from Iridium to 1-Methylnicotinamide Rationalized by Thermochemical Cycles Barrett, Seth M.; Pitman, Catherine L.; Walden, Andrew G. Journal of the American Chemical Society, Vol. 136, Issue 42 https://doi.org/10.1021/ja508762g	journal	October 2014
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M. Chemical Reviews, Vol. 110, Issue 12 https://doi.org/10.1021/cr100085k	journal	December 2010
Towards a Comprehensive Hydride Donor Ability Scale Horn, Markus; Schappele, Ludwig H.; Lang-Wittkowski, Gabriele Chemistry - A European Journal, Vol. 19, Issue 1 https://doi.org/10.1002/chem.201202839	journal	November 2012
Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions Mayr, Herbert; Patz, Matthias Angewandte Chemie International Edition in English, Vol. 33, Issue 9 https://doi.org/10.1002/anie.199409381	journal	May 1994
Substituent Effects on Cobalt Diglyoxime Catalysts for Hydrogen Evolution Solis, Brian H.; Hammes-Schiffer, Sharon Journal of the American Chemical Society, Vol. 133, Issue 47 https://doi.org/10.1021/ja208091e	journal	November 2011
Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes Maity, Ayan; Teets, Thomas S. Chemical Reviews, Vol. 116, Issue 15 https://doi.org/10.1021/acs.chemrev.6b00034	journal	May 2016
Properties of Bases in Acetonitrile as Solvent. IV. Proton Acceptor Power and Homoconjugation of Mono- and Diamines Coetzee, J. F.; Padmanabhan, G. R. Journal of the American Chemical Society, Vol. 87, Issue 22 https://doi.org/10.1021/ja00950a006	journal	November 1965
Calculation of thermodynamic hydricities and the design of hydride donors for CO2 reduction Muckerman, J. T.; Achord, P.; Creutz, C. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1201026109	journal	July 2012
Making C–H bonds with CO ₂ : production of formate by molecular electrocatalysts Taheri, Atefeh; Berben, Louise A. Chemical Communications, Vol. 52, Issue 9 https://doi.org/10.1039/C5CC09041E	journal	January 2016
Heterolytic dihydrogen activation by B(C6F5)3 and carbonyl compounds Lindqvist, Markus; Sarnela, Nina; Sumerin, Victor Dalton Transactions, Vol. 41, Issue 15 https://doi.org/10.1039/c2dt12268e	journal	January 2012
Determining the Overpotential for a Molecular Electrocatalyst Appel, Aaron M.; Helm, Monte L. ACS Catalysis, Vol. 4, Issue 2 https://doi.org/10.1021/cs401013v	journal	December 2013
An Iron Electrocatalyst for Selective Reduction of CO ₂ to Formate in Water: Including Thermochemical Insights Taheri, Atefeh; Thompson, Emily J.; Fettinger, James C. ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b01708	journal	November 2015
Kinetic hydricity of transition-metal hydrides toward trityl cation Cheng, Tan-Yun; Bullock, R. Morris Organometallics, Vol. 14, Issue 9 https://doi.org/10.1021/om00009a001	journal	September 1995
Oxidation of Benzyl Alcohol by a Dioxo Complex of Ruthenium(VI) Lebeau, Estelle L.; Meyer, Thomas J. Inorganic Chemistry, Vol. 38, Issue 9 https://doi.org/10.1021/ic981040v	journal	May 1999
Enzymes in organic synthesis: oxidoreductions Fang, Jim-Min; Lin, Chun-Hung; Bradshaw, Curt W. Journal of the Chemical Society, Perkin Transactions 1, Issue 8 https://doi.org/10.1039/p19950000967	journal	January 1995
Metal-Hydrogen Bond Cleavage Reactions of Transition Metal Hydrides: Hydrogen Atom, Hydride, and Proton Transfer Reactions Bullock, R. Morris Comments on Inorganic Chemistry, Vol. 12, Issue 1 https://doi.org/10.1080/02603599108018617	journal	May 1991
Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation Lin, Tzu-Pin; Peters, Jonas C. Journal of the American Chemical Society, Vol. 136, Issue 39 https://doi.org/10.1021/ja504667f	journal	September 2014
Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes Noyori, Ryoji; Hashiguchi, Shohei Accounts of Chemical Research, Vol. 30, Issue 2 https://doi.org/10.1021/ar9502341	journal	February 1997
Basicity of Phosphanes and Diphosphanes in Acetonitrile Haav, Kristjan; Saame, Jaan; Kütt, Agnes European Journal of Organic Chemistry, Vol. 2012, Issue 11 https://doi.org/10.1002/ejoc.201200009	journal	February 2012
Boryl-Mediated Reversible H ₂ Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation Lin, Tzu-Pin; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja408397v	journal	October 2013
Photochemical and Radiolytic Production of an Organic Hydride Donor with a RuII Complex Containing an NAD+ Model Ligand Polyansky, Dmitry; Cabelli, Diane; Muckerman, James T. Angewandte Chemie International Edition, Vol. 46, Issue 22 https://doi.org/10.1002/anie.200700304	journal	May 2007
Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes Welch, Gregory C.; Stephan, Douglas W. Journal of the American Chemical Society, Vol. 129, Issue 7 https://doi.org/10.1021/ja067961j	journal	February 2007
TMC Literature Highlights—30: C2 compounds directly from synthesis gas via organometallic catalysts Transition Metal Chemistry, Vol. 17, Issue 5, p. 474-480 https://doi.org/10.1007/BF02910736	journal	October 1992
Isomerization of Allylbenzenes Hassam, Mohammad; Taher, Abu; Arnott, Gareth E. Chemical Reviews, Vol. 115, Issue 11 https://doi.org/10.1021/acs.chemrev.5b00052	journal	May 2015
Estimates of hydride ion stability in condensed systems: energy of formation and solvation in aqueous and polar-organic solvents Kelly, Craig A.; Rosseinsky, David R. Physical Chemistry Chemical Physics, Vol. 3, Issue 11 https://doi.org/10.1039/b010092g	journal	January 2001
Hydride transfer reactions of transition metal hydrides in the preparation of [Cp(CO)3W(η1-aldehyde)]+OTf− and [Cp(CO)3W(η1-ketone)]+OTf− complexes Song, Jeong-Sup; Szalda, David J.; Morris Bullock, R. Inorganica Chimica Acta, Vol. 259, Issue 1-2 https://doi.org/10.1016/S0020-1693(97)05545-X	journal	June 1997
Establishing the Hydride Donor Abilities of Main Group Hydrides Heiden, Zachariah M.; Lathem, A. Paige Organometallics, Vol. 34, Issue 10 https://doi.org/10.1021/om5011512	journal	May 2015
Multiple Pathways for Benzyl Alcohol Oxidation by Ru ^V ═O ³⁺ and Ru ^IV ═O ²⁺ Paul, Amit; Hull, Jonathan F.; Norris, Michael R. Inorganic Chemistry, Vol. 50, Issue 4 https://doi.org/10.1021/ic1024923	journal	February 2011
σ-Acceptor, Z-type ligands for transition metals Amgoune, Abderrahmane; Bourissou, Didier Chem. Commun., Vol. 47, Issue 3 https://doi.org/10.1039/C0CC04109B	journal	January 2011
Carbon monoxide and carbon dioxide fixation: relevant C1 and C2 ligand reactions emphasizing (.eta.5-C5H5)Fe-containing complexes Cutler, Alan R.; Hanna, Paul K.; Vites, Jose C. Chemical Reviews, Vol. 88, Issue 7 https://doi.org/10.1021/cr00089a016	journal	November 1988
Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX ₃ Compounds Mock, Michael T.; Potter, Robert G.; Camaioni, Donald M. Journal of the American Chemical Society, Vol. 131, Issue 40 https://doi.org/10.1021/ja905287q	journal	October 2009
Development of Molecular Electrocatalysts for CO₂ Reduction and H₂ Production/Oxidation Rakowski Dubois, M.; Dubois, Daniel L. Accounts of Chemical Research, Vol. 42, Issue 12, p. 1974-1982 https://doi.org/10.1021/ar900110c	journal	December 2009
Tailoring Electrocatalysts for Selective CO ₂ or H ⁺ Reduction: Iron Carbonyl Clusters as a Case Study Taheri, Atefeh; Berben, Louise A. Inorganic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/acs.inorgchem.5b02293	journal	November 2015
Free Energy Landscapes for S−H Bonds in Cp* ₂ Mo ₂ S ₄ Complexes Appel, Aaron M.; Lee, Suh-Jane; Franz, James A. Journal of the American Chemical Society, Vol. 131, Issue 14 https://doi.org/10.1021/ja8093179	journal	April 2009
Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B804323J	journal	January 2009
Synthesis and properties of [Ru(tpy)(4,4′-X2bpy)H]+ (tpy=2,2′:6′,2″-terpyridine, bpy=2,2′-bipyridine, X=H and MeO), and their reactions with CO2 Konno, Hideo; Kobayashi, Atsuo; Sakamoto, Kazuhiko Inorganica Chimica Acta, Vol. 299, Issue 2 https://doi.org/10.1016/S0020-1693(99)00488-0	journal	March 2000
Generation of metal formyl complexes using nickel and platinum hydrides as reducing agents Miedaner, Alex; DuBois, Daniel L.; Curtis, Calvin J. Organometallics, Vol. 12, Issue 2 https://doi.org/10.1021/om00026a014	journal	February 1993
Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007
Pentakis(trifluoromethyl)phenyl, a Sterically Crowded and Electron-withdrawing Group: Synthesis and Acidity of Pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline Kütt, Agnes; Movchun, Valeria; Rodima, Toomas The Journal of Organic Chemistry, Vol. 73, Issue 7 https://doi.org/10.1021/jo702513w	journal	April 2008
Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au ⁺ ) Derived from a Triphosphine−Borane Sircoglou, Marie; Bontemps, Sébastien; Bouhadir, Ghenwa Journal of the American Chemical Society, Vol. 130, Issue 49 https://doi.org/10.1021/ja8070072	journal	December 2008
Relative reactivities of anionic transition metal hydrides. Reduction of alkyl halides Kao, S. C.; Darensbourg, Marcetta Y. Organometallics, Vol. 3, Issue 4 https://doi.org/10.1021/om00082a030	journal	April 1984
Thermodynamics of the Metal–Hydrogen Bonds in (η ⁵ -C ₅ H ₅ )M(CO) ₂ H (M = Fe, Ru, Os) Estes, Deven P.; Vannucci, Aaron K.; Hall, Ariel R. Organometallics, Vol. 30, Issue 12 https://doi.org/10.1021/om2001519	journal	June 2011
Relative rates of hydrogen atom (H.cntdot.) transfer from transition-metal hydrides to trityl radicals Eisenberg, David C.; Lawrie, Christophe J. C.; Moody, Anne E. Journal of the American Chemical Society, Vol. 113, Issue 13 https://doi.org/10.1021/ja00013a026	journal	June 1991
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Fuel from Water: The Photochemical Generation of Hydrogen from Water Han, Zhiji; Eisenberg, Richard Accounts of Chemical Research, Vol. 47, Issue 8 https://doi.org/10.1021/ar5001605	journal	June 2014
Ab Initio Calculations of p K _a Values of Transition-Metal Hydrides in Acetonitrile Qi, Xiu-Juan; Liu, Lei; Fu, Yao Organometallics, Vol. 25, Issue 25 https://doi.org/10.1021/om0608859	journal	December 2006
A Thermodynamic Analysis of Rhenium(I)–Formyl C–H Bond Formation via Base-Assisted Heterolytic H ₂ Cleavage in the Secondary Coordination Sphere Teets, Thomas S.; Labinger, Jay A.; Bercaw, John E. Organometallics, Vol. 32, Issue 19 https://doi.org/10.1021/om400810v	journal	September 2013
Acid−Base Equilibria in Nonpolar Media. 1. A Spectrophotometric Method for Acidity Measurements in Heptane Leito, Ivo; Rodima, Toomas; Koppel, Ilmar A. The Journal of Organic Chemistry, Vol. 62, Issue 24 https://doi.org/10.1021/jo9713013	journal	November 1997
Water-Soluble Phenanthroline Complexes of Rhodium, Iridium and Ruthenium for the Regeneration of NADH in the Enzymatic Reduction of Ketones Canivet, Jérôme; Süss-Fink, Georg; Štěpnička, Petr European Journal of Inorganic Chemistry, Vol. 2007, Issue 30 https://doi.org/10.1002/ejic.200700505	journal	October 2007
Oxidation-Reduction Potentials of the Diphosphopyridine Nucleotide System Rodkey, F. Lee Journal of Biological Chemistry, Vol. 213, Issue 2 https://doi.org/10.1016/S0021-9258(18)98209-8	journal	April 1955

Cited By (47)

Expanding the Boundaries of Water-Tolerant Frustrated Lewis Pair Hydrogenation: Enhanced Back Strain in the Lewis Acid Enables the Reductive Amination of Carbonyls Dorkó, Éva; Szabó, Márk; Kótai, Bianka Angewandte Chemie, Vol. 129, Issue 32 https://doi.org/10.1002/ange.201703591	journal	July 2017
Cobalt Complex with Redox-Active Imino Bipyridyl Ligand for Electrocatalytic Reduction of Carbon Dioxide to Formate Liu, Fang-Wei; Bi, Jiaojiao; Sun, Yuanyuan ChemSusChem, Vol. 11, Issue 10 https://doi.org/10.1002/cssc.201800136	journal	May 2018
Snapshots of a Migrating H-Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring-Protonated Iron(I) Isomer Drover, Marcus W.; Schild, Dirk J.; Oyala, Paul H. Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201909050	journal	September 2019
DFT methods applied to answer the question: how accurate is the ligand acidity constant method for estimating the p K _a of transition metal hydride complexes MHXL ₄ when X is varied? Unsleber, Jan P.; Neugebauer, Johannes; Morris, Robert H. Dalton Transactions, Vol. 47, Issue 8 https://doi.org/10.1039/c7dt03473c	journal	January 2018
Reversible and Selective CO ₂ to HCO ₂ ⁻ Electrocatalysis near the Thermodynamic Potential Cunningham, Drew W.; Barlow, Jeffrey M.; Velazquez, Reyna S. Angewandte Chemie, Vol. 132, Issue 11 https://doi.org/10.1002/ange.201913198	journal	March 2020
A look at periodic trends in d-block molecular electrocatalysts for CO ₂ reduction Jiang, Changcheng; Nichols, Asa W.; Machan, Charles W. Dalton Transactions, Vol. 48, Issue 26 https://doi.org/10.1039/c9dt00491b	journal	January 2019
Bimetallic nickel–cobalt hydrides in H ₂ activation and catalytic proton reduction Chu, Xiaoxiao; Jin, Jihao; Ming, Bangrong Chemical Science, Vol. 10, Issue 3 https://doi.org/10.1039/c8sc04346a	journal	January 2019
Importance of proton-coupled electron transfer in cathodic regeneration of organic hydrides Ilic, Stefan; Alherz, Abdulaziz; Musgrave, Charles B. Chemical Communications, Vol. 55, Issue 39 https://doi.org/10.1039/c9cc00928k	journal	January 2019
Hydricity, electrochemistry, and excited-state chemistry of Ir complexes for CO ₂ reduction Manbeck, Gerald F.; Garg, Komal; Shimoda, Tomoe Faraday Discussions, Vol. 198 https://doi.org/10.1039/c6fd00223d	journal	January 2017
The visible-light-driven transfer hydrogenation of nicotinamide cofactors with a robust ruthenium complex photocatalyst Dong, Wenjin; Tang, Jie; Zhao, Lijun Green Chemistry, Vol. 22, Issue 7 https://doi.org/10.1039/d0gc00331j	journal	January 2020
Reversible and Selective CO ₂ to HCO ₂ ⁻ Electrocatalysis near the Thermodynamic Potential Cunningham, Drew W.; Barlow, Jeffrey M.; Velazquez, Reyna S. Angewandte Chemie International Edition, Vol. 59, Issue 11 https://doi.org/10.1002/anie.201913198	journal	February 2020
Efficient catalytic hydrogenation of alkyl levulinates to γ-valerolactone Padilla, Rosa; Jørgensen, Mike S. B.; Paixão, Márcio W. Green Chemistry, Vol. 21, Issue 19 https://doi.org/10.1039/c9gc01651a	journal	January 2019
A mechanism study on the hydrogen evolution reaction catalyzed by molybdenum disulfide complexes Yang, Ti-Long; Ni, Shao-Fei; Qin, Peng Chemical Communications, Vol. 54, Issue 9 https://doi.org/10.1039/c7cc08632f	journal	January 2018
Hydride, chloride, and bromide show similar electronic effects in the Au ₉ (PPh ₃ ) ₈ ³⁺ nanocluster Cirri, Anthony; Hernández, Hanna Morales; Johnson, Christopher J. Chemical Communications, Vol. 56, Issue 8 https://doi.org/10.1039/c9cc08009k	journal	January 2020
Structural and Superconducting Properties of Tungsten Hydrides Under High Pressure Zheng, Shuang; Zhang, Shoutao; Sun, Yu Frontiers in Physics, Vol. 6 https://doi.org/10.3389/fphy.2018.00101	journal	September 2018
Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications Zhang, Jingjing; Yang, Jin-Dong; Cheng, Jin-Pei Chemical Science, Vol. 11, Issue 14 https://doi.org/10.1039/c9sc05883d	journal	January 2020
Snapshots of a Migrating H‐Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring‐Protonated Iron(I) Isomer Drover, Marcus W.; Schild, Dirk J.; Oyala, Paul H. Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201909050	journal	September 2019
Recent advances in the mechanisms of the hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes Drosou, Maria; Kamatsos, Fotios; Mitsopoulou, Christiana A. Inorganic Chemistry Frontiers, Vol. 7, Issue 1 https://doi.org/10.1039/c9qi01113g	journal	January 2020
Molecular Mimics of Heterogeneous Metal Phosphides: Thermochemistry, Hydride-Proton Isomerism, and HER Reactivity Buss, Joshua A.; Hirahara, Masanari; Ueda, Yohei Angewandte Chemie, Vol. 130, Issue 50 https://doi.org/10.1002/ange.201808307	journal	November 2018
Acid‐Promoted Hydroformylative Synthesis of Alcohol with Carbon Dioxide by Heterobimetallic Ruthenium‐Cobalt Catalytic System Zhang, Xuehua; Tian, Xinxin; Shen, Chaoren ChemCatChem, Vol. 11, Issue 7 https://doi.org/10.1002/cctc.201802091	journal	March 2019
Mapping free energy regimes in electrocatalytic reductions to screen transition metal-based catalysts Ramakrishnan, Srinivasan; Moretti, Ross A.; Chidsey, Christopher E. D. Chemical Science, Vol. 10, Issue 32 https://doi.org/10.1039/c9sc01766f	journal	January 2019
Phosphine-free ruthenium NCN-ligand complexes and their use in catalytic CO ₂ hydrogenation Sung, Molly M. H.; Prokopchuk, Demyan E.; Morris, Robert H. Dalton Transactions, Vol. 48, Issue 44 https://doi.org/10.1039/c9dt03143j	journal	January 2019
Electrocatalytic H 2 Evolution by the Co‐Mabiq Complex Requires Tempering of the Redox‐Active Ligand Tok, G. Ceren; Freiberg, Anna T. S.; Gasteiger, Hubert A. ChemCatChem, Vol. 11, Issue 16 https://doi.org/10.1002/cctc.201900953	journal	June 2019
Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field Filonenko, Georgy A.; van Putten, Robbert; Hensen, Emiel J. M. Chemical Society Reviews, Vol. 47, Issue 4 https://doi.org/10.1039/c7cs00334j	journal	January 2018
DFT study of CO ₂ hydrogenation catalyzed by a cobalt-based system: an unexpected formate anion-assisted deprotonation mechanism Zhang, Zhihan; Li, Yinwu; Hou, Cheng Catalysis Science & Technology, Vol. 8, Issue 2 https://doi.org/10.1039/c7cy02012k	journal	January 2018
Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes Freeman, Lucas A.; Walley, Jacob E.; Dickie, Diane A. Dalton Transactions, Vol. 48, Issue 46 https://doi.org/10.1039/c9dt03915e	journal	January 2019
Changing the Mechanism for CO ₂ Hydrogenation Using Solvent-Dependent Thermodynamics Burgess, Samantha A.; Appel, Aaron M.; Linehan, John C. Angewandte Chemie International Edition, Vol. 56, Issue 47 https://doi.org/10.1002/anie.201709319	journal	October 2017
Electrocatalytic hydrogen evolution with gallium hydride and ligand-centered reduction Wang, Ni; Lei, Haitao; Zhang, Zongyao Chemical Science, Vol. 10, Issue 8 https://doi.org/10.1039/c8sc05247f	journal	January 2019
Computational Design of Quaterpyridine‐Based Fe/Mn–Complexes for the Direct Hydrogenation of CO ₂ to HCOOH: A Direction for Atom‐Economic Approach Biswas, Santu; Pramanik, Anup; Sarkar, Pranab ChemistrySelect, Vol. 3, Issue 18 https://doi.org/10.1002/slct.201800169	journal	May 2018
Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization Asgari, Parham; Hua, Yuanda; Bokka, Apparao Nature Catalysis, Vol. 2, Issue 2 https://doi.org/10.1038/s41929-018-0217-z	journal	January 2019
Expanding the Boundaries of Water-Tolerant Frustrated Lewis Pair Hydrogenation: Enhanced Back Strain in the Lewis Acid Enables the Reductive Amination of Carbonyls Dorkó, Éva; Szabó, Márk; Kótai, Bianka Angewandte Chemie International Edition, Vol. 56, Issue 32 https://doi.org/10.1002/anie.201703591	journal	July 2017
Iridium–NHC-based catalyst for ambient pressure storage and low temperature release of H ₂ via the CO ₂ /HCO ₂ H couple Semwal, Shrivats; Kumar, Abhishek; Choudhury, Joyanta Catalysis Science & Technology, Vol. 8, Issue 23 https://doi.org/10.1039/c8cy02069h	journal	January 2018
Understanding the role of thermodynamics in catalytic imine reductions Yang, Jin-Dong; Xue, Jing; Cheng, Jin-Pei Chemical Society Reviews, Vol. 48, Issue 11 https://doi.org/10.1039/c9cs00036d	journal	January 2019
Hydrido Complexes of Calcium: A New Family of Molecular Alkaline-Earth-Metal Compounds Mukherjee, Debabrata; Schuhknecht, Danny; Okuda, Jun Angewandte Chemie International Edition, Vol. 57, Issue 31 https://doi.org/10.1002/anie.201801869	journal	June 2018
Phase diagrams and electronic properties of B-S and H-B-S systems under high pressure Du, Xin; Zhang, Shoutao; Lin, Jianyan Physical Review B, Vol. 100, Issue 13 https://doi.org/10.1103/physrevb.100.134110	journal	October 2019
Thermodynamic targeting of electrocatalytic CO ₂ reduction: advantages, limitations, and insights for catalyst design Ostericher, Andrew L.; Porter, Tyler M.; Reineke, Mark H. Dalton Transactions, Vol. 48, Issue 42 https://doi.org/10.1039/c9dt03255j	journal	January 2019
From Ruthenium to Iron and Manganese-A Mechanistic View on Challenges and Design Principles of Base-Metal Hydrogenation Catalysts Zell, Thomas; Langer, Robert ChemCatChem, Vol. 10, Issue 9 https://doi.org/10.1002/cctc.201701722	journal	March 2018
Small “Yaw” Angles, Large “Bite” Angles and an Electron-Rich Metal: Revealing a Stereoelectronic Synergy To Enhance Hydride-Transfer Activity Semwal, Shrivats; Mukkatt, Indulekha; Thenarukandiyil, Ranjeesh Chemistry - A European Journal, Vol. 23, Issue 53 https://doi.org/10.1002/chem.201702173	journal	August 2017
Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates Lohrey, Trevor D.; Fostvedt, Jade I.; Bergman, Robert G. Chemical Communications, Vol. 56, Issue 26 https://doi.org/10.1039/c9cc09475j	journal	January 2020
Efficient and Selective Hydrosilylation of Secondary and Tertiary Amides Catalyzed by an Iridium(III) Metallacycle: Development and Mechanistic Investigation Corre, Yann; Trivelli, Xavier; Capet, Frédéric ChemCatChem, Vol. 9, Issue 11 https://doi.org/10.1002/cctc.201700400	journal	May 2017
Computational mechanistic study of Ru-catalyzed CO ₂ reduction by pinacolborane revealing the σ–π coupling mechanism for CO ₂ decarbonylation Huang, Fang; Wang, Qiong; Guo, Jiandong Dalton Transactions, Vol. 47, Issue 14 https://doi.org/10.1039/c8dt00081f	journal	January 2018
Diverse Catalytic Systems and Mechanistic Pathways for Hydrosilylative Reduction of CO ₂ Chen, Jiawei; McGraw, Michael; Chen, Eugene Y. ‐X. ChemSusChem, Vol. 12, Issue 20 https://doi.org/10.1002/cssc.201901764	journal	September 2019
Hydrido-Komplexe des Calciums: eine neue Familie molekularer Erdalkalimetall-Verbindungen Mukherjee, Debabrata; Schuhknecht, Danny; Okuda, Jun Angewandte Chemie, Vol. 130, Issue 31 https://doi.org/10.1002/ange.201801869	journal	June 2018
Lewis-base-catalysed selective reductions of ynones with a mild hydride donor Schömberg, F.; Zi, Y.; Vilotijevic, I. Chemical Communications, Vol. 54, Issue 26 https://doi.org/10.1039/c8cc00058a	journal	January 2018
Making a Splash in Homogeneous CO ₂ Hydrogenation: Elucidating the Impact of Solvent on Catalytic Mechanisms Wiedner, Eric S.; Linehan, John C. Chemistry – A European Journal, Vol. 24, Issue 64 https://doi.org/10.1002/chem.201801759	journal	July 2018
Molecular Mimics of Heterogeneous Metal Phosphides: Thermochemistry, Hydride-Proton Isomerism, and HER Reactivity Buss, Joshua A.; Hirahara, Masanari; Ueda, Yohei Angewandte Chemie International Edition, Vol. 57, Issue 50 https://doi.org/10.1002/anie.201808307	journal	November 2018
Thermodynamic Properties of Hydrogen-Producing Cobaloxime Catalysts: A Density Functional Theory Analysis Chen, Jinfan; Sit, Patrick H. -L. ACS Omega, Vol. 4, Issue 1 https://doi.org/10.1021/acsomega.8b02107	journal	January 2019

Similar Records

Thermodynamic and kinetic hydricity of transition metal hydrides

Journal Article · 2020 · Chemical Society Reviews · OSTI ID:1851880

Brereton, Kelsey R.; Smith, Nicholas E.; Hazari, Nilay; +1 more

Temperature and Solvent Effects on H₂ Splitting and Hydricity: Ramifications on CO₂ Hydrogenation by a Rhenium Pincer Catalyst

Journal Article · 2020 · Journal of the American Chemical Society · OSTI ID:1782420

Hu, Jenny; Bruch, Quinton J.; Miller, Alexander M.

Electronic and Electrochemical Control of Isostructural Ruthenium Hydricities and the Implications for Catalytic Overpotentials

Journal Article · 2024 · ACS Catalysis · OSTI ID:2284065

Wang, Zongheng; DiMarco, Brian N.; Ertem, Mehmed Z.; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
hydride
hydricity
catalysis
hydrogen
carbon dioxide

Title: Thermodynamic Hydricity of Transition Metal Hydrides

Citation Formats

References (319)

Cited By (47)

Similar Records

Related Subjects