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Title: Thermodynamic Hydricity of Transition Metal Hydrides

Authors:
 [1];  [2];  [2];  [1];  [2];  [1]
  1. Pacific Northwest National Laboratory, Richland, Washington 99352, United States
  2. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, United States
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1280195
Alternate Identifier(s):
OSTI ID: 1313998
Grant/Contract Number:  
SC0014255; CHE-1205189; AC05-76RL01830
Resource Type:
Published Article
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Name: Chemical Reviews Journal Volume: 116 Journal Issue: 15; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wiedner, Eric S., Chambers, Matthew B., Pitman, Catherine L., Bullock, R. Morris, Miller, Alexander J. M., and Appel, Aaron M. Thermodynamic Hydricity of Transition Metal Hydrides. United States: N. p., 2016. Web. doi:10.1021/acs.chemrev.6b00168.
Wiedner, Eric S., Chambers, Matthew B., Pitman, Catherine L., Bullock, R. Morris, Miller, Alexander J. M., & Appel, Aaron M. Thermodynamic Hydricity of Transition Metal Hydrides. United States. doi:10.1021/acs.chemrev.6b00168.
Wiedner, Eric S., Chambers, Matthew B., Pitman, Catherine L., Bullock, R. Morris, Miller, Alexander J. M., and Appel, Aaron M. Wed . "Thermodynamic Hydricity of Transition Metal Hydrides". United States. doi:10.1021/acs.chemrev.6b00168.
@article{osti_1280195,
title = {Thermodynamic Hydricity of Transition Metal Hydrides},
author = {Wiedner, Eric S. and Chambers, Matthew B. and Pitman, Catherine L. and Bullock, R. Morris and Miller, Alexander J. M. and Appel, Aaron M.},
abstractNote = {},
doi = {10.1021/acs.chemrev.6b00168},
journal = {Chemical Reviews},
number = 15,
volume = 116,
place = {United States},
year = {2016},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/acs.chemrev.6b00168

Citation Metrics:
Cited by: 33 works
Citation information provided by
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Works referencing / citing this record:

Changing the Mechanism for CO 2 Hydrogenation Using Solvent-Dependent Thermodynamics
journal, October 2017

  • Burgess, Samantha A.; Appel, Aaron M.; Linehan, John C.
  • Angewandte Chemie International Edition, Vol. 56, Issue 47
  • DOI: 10.1002/anie.201709319

Molecular Mimics of Heterogeneous Metal Phosphides: Thermochemistry, Hydride-Proton Isomerism, and HER Reactivity
journal, November 2018

  • Buss, Joshua A.; Hirahara, Masanari; Ueda, Yohei
  • Angewandte Chemie International Edition, Vol. 57, Issue 50
  • DOI: 10.1002/anie.201808307

Snapshots of a Migrating H-Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring-Protonated Iron(I) Isomer
journal, September 2019

  • Drover, Marcus W.; Schild, Dirk J.; Oyala, Paul H.
  • Angewandte Chemie International Edition, Vol. 58, Issue 43
  • DOI: 10.1002/anie.201909050

Small “Yaw” Angles, Large “Bite” Angles and an Electron-Rich Metal: Revealing a Stereoelectronic Synergy To Enhance Hydride-Transfer Activity
journal, August 2017

  • Semwal, Shrivats; Mukkatt, Indulekha; Thenarukandiyil, Ranjeesh
  • Chemistry - A European Journal, Vol. 23, Issue 53
  • DOI: 10.1002/chem.201702173

Cobalt Complex with Redox-Active Imino Bipyridyl Ligand for Electrocatalytic Reduction of Carbon Dioxide to Formate
journal, May 2018


Hydricity, electrochemistry, and excited-state chemistry of Ir complexes for CO 2 reduction
journal, January 2017

  • Manbeck, Gerald F.; Garg, Komal; Shimoda, Tomoe
  • Faraday Discussions, Vol. 198
  • DOI: 10.1039/c6fd00223d

CO 2 reduction or HCO 2 oxidation? Solvent-dependent thermochemistry of a nickel hydride complex
journal, January 2017

  • Ceballos, Bianca M.; Tsay, Charlene; Yang, Jenny Y.
  • Chemical Communications, Vol. 53, Issue 53
  • DOI: 10.1039/c7cc02511d

Iridium–NHC-based catalyst for ambient pressure storage and low temperature release of H 2 via the CO 2 /HCO 2 H couple
journal, January 2018

  • Semwal, Shrivats; Kumar, Abhishek; Choudhury, Joyanta
  • Catalysis Science & Technology, Vol. 8, Issue 23
  • DOI: 10.1039/c8cy02069h

Bimetallic nickel–cobalt hydrides in H 2 activation and catalytic proton reduction
journal, January 2019

  • Chu, Xiaoxiao; Jin, Jihao; Ming, Bangrong
  • Chemical Science, Vol. 10, Issue 3
  • DOI: 10.1039/c8sc04346a

Electrocatalytic hydrogen evolution with gallium hydride and ligand-centered reduction
journal, January 2019

  • Wang, Ni; Lei, Haitao; Zhang, Zongyao
  • Chemical Science, Vol. 10, Issue 8
  • DOI: 10.1039/c8sc05247f

A look at periodic trends in d-block molecular electrocatalysts for CO 2 reduction
journal, January 2019

  • Jiang, Changcheng; Nichols, Asa W.; Machan, Charles W.
  • Dalton Transactions, Vol. 48, Issue 26
  • DOI: 10.1039/c9dt00491b

Mapping free energy regimes in electrocatalytic reductions to screen transition metal-based catalysts
journal, January 2019

  • Ramakrishnan, Srinivasan; Moretti, Ross A.; Chidsey, Christopher E. D.
  • Chemical Science, Vol. 10, Issue 32
  • DOI: 10.1039/c9sc01766f

Electrocatalytic H 2 Evolution by the Co‐Mabiq Complex Requires Tempering of the Redox‐Active Ligand
journal, June 2019

  • Tok, G. Ceren; Freiberg, Anna T. S.; Gasteiger, Hubert A.
  • ChemCatChem, Vol. 11, Issue 16
  • DOI: 10.1002/cctc.201900953

Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes
journal, January 2019

  • Freeman, Lucas A.; Walley, Jacob E.; Dickie, Diane A.
  • Dalton Transactions, Vol. 48, Issue 46
  • DOI: 10.1039/c9dt03915e

Molecular Mimics of Heterogeneous Metal Phosphides: Thermochemistry, Hydride-Proton Isomerism, and HER Reactivity
journal, November 2018

  • Buss, Joshua A.; Hirahara, Masanari; Ueda, Yohei
  • Angewandte Chemie, Vol. 130, Issue 50
  • DOI: 10.1002/ange.201808307

Changing the Mechanism for CO 2 Hydrogenation Using Solvent-Dependent Thermodynamics
journal, October 2017

  • Burgess, Samantha A.; Appel, Aaron M.; Linehan, John C.
  • Angewandte Chemie International Edition, Vol. 56, Issue 47
  • DOI: 10.1002/anie.201709319

Snapshots of a Migrating H-Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring-Protonated Iron(I) Isomer
journal, September 2019

  • Drover, Marcus W.; Schild, Dirk J.; Oyala, Paul H.
  • Angewandte Chemie International Edition, Vol. 58, Issue 43
  • DOI: 10.1002/anie.201909050

Electrocatalytic H 2 Evolution by the Co‐Mabiq Complex Requires Tempering of the Redox‐Active Ligand
journal, June 2019

  • Tok, G. Ceren; Freiberg, Anna T. S.; Gasteiger, Hubert A.
  • ChemCatChem, Vol. 11, Issue 16
  • DOI: 10.1002/cctc.201900953

Small “Yaw” Angles, Large “Bite” Angles and an Electron-Rich Metal: Revealing a Stereoelectronic Synergy To Enhance Hydride-Transfer Activity
journal, August 2017

  • Semwal, Shrivats; Mukkatt, Indulekha; Thenarukandiyil, Ranjeesh
  • Chemistry - A European Journal, Vol. 23, Issue 53
  • DOI: 10.1002/chem.201702173

Cobalt Complex with Redox-Active Imino Bipyridyl Ligand for Electrocatalytic Reduction of Carbon Dioxide to Formate
journal, May 2018


Hydricity, electrochemistry, and excited-state chemistry of Ir complexes for CO 2 reduction
journal, January 2017

  • Manbeck, Gerald F.; Garg, Komal; Shimoda, Tomoe
  • Faraday Discussions, Vol. 198
  • DOI: 10.1039/c6fd00223d

CO 2 reduction or HCO 2 oxidation? Solvent-dependent thermochemistry of a nickel hydride complex
journal, January 2017

  • Ceballos, Bianca M.; Tsay, Charlene; Yang, Jenny Y.
  • Chemical Communications, Vol. 53, Issue 53
  • DOI: 10.1039/c7cc02511d

Iridium–NHC-based catalyst for ambient pressure storage and low temperature release of H 2 via the CO 2 /HCO 2 H couple
journal, January 2018

  • Semwal, Shrivats; Kumar, Abhishek; Choudhury, Joyanta
  • Catalysis Science & Technology, Vol. 8, Issue 23
  • DOI: 10.1039/c8cy02069h

Bimetallic nickel–cobalt hydrides in H 2 activation and catalytic proton reduction
journal, January 2019

  • Chu, Xiaoxiao; Jin, Jihao; Ming, Bangrong
  • Chemical Science, Vol. 10, Issue 3
  • DOI: 10.1039/c8sc04346a

Electrocatalytic hydrogen evolution with gallium hydride and ligand-centered reduction
journal, January 2019

  • Wang, Ni; Lei, Haitao; Zhang, Zongyao
  • Chemical Science, Vol. 10, Issue 8
  • DOI: 10.1039/c8sc05247f

A look at periodic trends in d-block molecular electrocatalysts for CO 2 reduction
journal, January 2019

  • Jiang, Changcheng; Nichols, Asa W.; Machan, Charles W.
  • Dalton Transactions, Vol. 48, Issue 26
  • DOI: 10.1039/c9dt00491b

Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes
journal, January 2019

  • Freeman, Lucas A.; Walley, Jacob E.; Dickie, Diane A.
  • Dalton Transactions, Vol. 48, Issue 46
  • DOI: 10.1039/c9dt03915e

Mapping free energy regimes in electrocatalytic reductions to screen transition metal-based catalysts
journal, January 2019

  • Ramakrishnan, Srinivasan; Moretti, Ross A.; Chidsey, Christopher E. D.
  • Chemical Science, Vol. 10, Issue 32
  • DOI: 10.1039/c9sc01766f