Thermodynamic Hydricity of Transition Metal Hydrides
Abstract
Transition metal hydrides play a critical role in stoichiometric and catalytic transformations. Knowledge of free energies for cleaving metal hydride bonds can enable the prediction of chemical reactivity, such as for the bond-forming and bond-breaking events that occur in a catalytic reaction. Thermodynamic hydricity is the free energy required to cleave an M–H bond to generate a hydride ion (H–). Three primary methods have been developed for hydricity determination: the “reference hydride” method establishes hydride transfer equilibrium with a hydride donor/acceptor pair of known hydricity, the “H2 heterolysis” method involves measuring the equilibrium of heterolytic cleavage of H2 in the presence of a base, and the “potential–pKa” method considers stepwise transfer of a proton and two electrons to give a net hydride transfer. Using these methods, over 100 thermodynamic hydricity values for transition metal hydrides have been determined in acetonitrile or water. In acetonitrile, the hydricity of metal hydrides spans a range of more than 50 kcal/mol. Methods for using hydricity values to predict chemical reactivity are also discussed, including organic transformations, the reduction of CO2, and the production and oxidation of hydrogen. E.S.W. and A.M.A. were supported by the U.S. Department of Energy, Office of Science, Office of Basicmore »
- Authors:
-
- Pacific Northwest National Laboratory, Richland, Washington 99352, United States
- Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, United States
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1280195
- Alternate Identifier(s):
- OSTI ID: 1313998; OSTI ID: 1773427
- Report Number(s):
- PNNL-SA-116484
Journal ID: ISSN 0009-2665
- Grant/Contract Number:
- SC0014255; CHE-1205189; AC05-76RL01830
- Resource Type:
- Published Article
- Journal Name:
- Chemical Reviews
- Additional Journal Information:
- Journal Name: Chemical Reviews Journal Volume: 116 Journal Issue: 15; Journal ID: ISSN 0009-2665
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; hydride; hydricity; catalysis; hydrogen; carbon dioxide
Citation Formats
Wiedner, Eric S., Chambers, Matthew B., Pitman, Catherine L., Bullock, R. Morris, Miller, Alexander J. M., and Appel, Aaron M.. Thermodynamic Hydricity of Transition Metal Hydrides. United States: N. p., 2016.
Web. doi:10.1021/acs.chemrev.6b00168.
Wiedner, Eric S., Chambers, Matthew B., Pitman, Catherine L., Bullock, R. Morris, Miller, Alexander J. M., & Appel, Aaron M.. Thermodynamic Hydricity of Transition Metal Hydrides. United States. https://doi.org/10.1021/acs.chemrev.6b00168
Wiedner, Eric S., Chambers, Matthew B., Pitman, Catherine L., Bullock, R. Morris, Miller, Alexander J. M., and Appel, Aaron M.. Tue .
"Thermodynamic Hydricity of Transition Metal Hydrides". United States. https://doi.org/10.1021/acs.chemrev.6b00168.
@article{osti_1280195,
title = {Thermodynamic Hydricity of Transition Metal Hydrides},
author = {Wiedner, Eric S. and Chambers, Matthew B. and Pitman, Catherine L. and Bullock, R. Morris and Miller, Alexander J. M. and Appel, Aaron M.},
abstractNote = {Transition metal hydrides play a critical role in stoichiometric and catalytic transformations. Knowledge of free energies for cleaving metal hydride bonds can enable the prediction of chemical reactivity, such as for the bond-forming and bond-breaking events that occur in a catalytic reaction. Thermodynamic hydricity is the free energy required to cleave an M–H bond to generate a hydride ion (H–). Three primary methods have been developed for hydricity determination: the “reference hydride” method establishes hydride transfer equilibrium with a hydride donor/acceptor pair of known hydricity, the “H2 heterolysis” method involves measuring the equilibrium of heterolytic cleavage of H2 in the presence of a base, and the “potential–pKa” method considers stepwise transfer of a proton and two electrons to give a net hydride transfer. Using these methods, over 100 thermodynamic hydricity values for transition metal hydrides have been determined in acetonitrile or water. In acetonitrile, the hydricity of metal hydrides spans a range of more than 50 kcal/mol. Methods for using hydricity values to predict chemical reactivity are also discussed, including organic transformations, the reduction of CO2, and the production and oxidation of hydrogen. E.S.W. and A.M.A. were supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. R.M.B. was supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy. M.B.C. and A.J.M.M. were supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences (DE-SC0014255). C.L.P. was supported by the National Science Foundation Center for Enabling New Technologies through Catalysis (CHE-1205189) and the Royster Society of Fellows (C.L.P.).},
doi = {10.1021/acs.chemrev.6b00168},
journal = {Chemical Reviews},
number = 15,
volume = 116,
place = {United States},
year = {2016},
month = {8}
}
https://doi.org/10.1021/acs.chemrev.6b00168
Web of Science
Works referenced in this record:
Trialkylborane-Assisted CO 2 Reduction by Late Transition Metal Hydrides
journal, August 2011
- Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E.
- Organometallics, Vol. 30, Issue 16
Reversible, Metal-Free Hydrogen Activation
journal, November 2006
- Welch, G. C.; Juan, R. R. S.; Masuda, J. D.
- Science, Vol. 314, Issue 5802
B–N compounds for chemical hydrogenstorage
journal, January 2009
- Hamilton, Charles W.; Baker, R. Tom; Staubitz, Anne
- Chem. Soc. Rev., Vol. 38, Issue 1, p. 279-293
Ammonia–borane: the hydrogen source par excellence?
journal, January 2007
- Stephens, Frances H.; Pons, Vincent; Tom Baker, R.
- Dalton Trans., Issue 25, p. 2613-2626
Ferrocene as an internal standard for electrochemical measurements
journal, September 1980
- Gagne, Robert R.; Koval, Carl A.; Lisensky, George C.
- Inorganic Chemistry, Vol. 19, Issue 9
Computing Free Energy Landscapes: Application to Ni-based Electrocatalysts with Pendant Amines for H 2 Production and Oxidation
journal, December 2013
- Chen, Shentan; Ho, Ming-Hsun; Bullock, R. Morris
- ACS Catalysis, Vol. 4, Issue 1
Nature of bis(2,2'-bipyridine)rhodium(I) in aqueous solutions
journal, November 1982
- Chou, Mei.; Creutz, Carol.; Mahajan, Devinder.
- Inorganic Chemistry, Vol. 21, Issue 11
Formation and Reactivity of a Porphyrin Iridium Hydride in Water: Acid Dissociation Constants and Equilibrium Thermodynamics Relevant to Ir–H, Ir–OH, and Ir–CH 2 – Bond Dissociation Energetics
journal, November 2011
- Bhagan, Salome; Wayland, Bradford B.
- Inorganic Chemistry, Vol. 50, Issue 21
A Cobalt-Based Catalyst for the Hydrogenation of CO 2 under Ambient Conditions
journal, July 2013
- Jeletic, Matthew S.; Mock, Michael T.; Appel, Aaron M.
- Journal of the American Chemical Society, Vol. 135, Issue 31
An Electrochemical Study of Frustrated Lewis Pairs: A Metal-Free Route to Hydrogen Oxidation
journal, April 2014
- Lawrence, Elliot J.; Oganesyan, Vasily S.; Hughes, David L.
- Journal of the American Chemical Society, Vol. 136, Issue 16
Formation of Novel 1:1 Adducts Accompanied by Regioselective Hydride Transfer from Transition-Metal Hydrido Complexes to NAD(P) Models
journal, August 2001
- Kobayashi, Atsuo; Takatori, Ryosuke; Kikuchi, Itsumi
- Organometallics, Vol. 20, Issue 16
Hydricities of d 6 Metal Hydride Complexes in Water
journal, March 2009
- Creutz, Carol; Chou, Mei H.
- Journal of the American Chemical Society, Vol. 131, Issue 8
HRh(dppb) 2 , a Powerful Hydride Donor
journal, October 2002
- Price, Andrew J.; Ciancanelli, Rebecca; Noll, Bruce C.
- Organometallics, Vol. 21, Issue 22
Platinum Complexes of a Borane-Appended Analogue of 1,1′-Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ Vinylborane Formation
journal, October 2014
- Cowie, Bradley E.; Emslie, David J. H.
- Chemistry - A European Journal, Vol. 20, Issue 51
Catalysis of regioselective reduction of NAD+ by ruthenium(II) arene complexes under biologically relevant conditions
journal, April 2006
- Yan, Yaw Kai; Melchart, Michael; Habtemariam, Abraha
- JBIC Journal of Biological Inorganic Chemistry, Vol. 11, Issue 4
[Ni(P Me 2 N Ph 2 ) 2 ](BF 4 ) 2 as an Electrocatalyst for H 2 Production
journal, March 2012
- Wiese, Stefan; Kilgore, Uriah J.; DuBois, Daniel L.
- ACS Catalysis, Vol. 2, Issue 5
Guanidine-Functionalized Rhenium Cyclopentadienyl Carbonyl Complexes: Synthesis and Cooperative Activation of H–H and O–H Bonds
journal, July 2014
- Teets, Thomas S.; Labinger, Jay A.; Bercaw, John E.
- Organometallics, Vol. 33, Issue 15
Facile Si–H bond activation and hydrosilylation catalysis mediated by a nickel–borane complex
journal, January 2014
- MacMillan, Samantha N.; Hill Harman, W.; Peters, Jonas C.
- Chem. Sci., Vol. 5, Issue 2
Relative reactivity and mechanistic studies of the hydride-transfer reagents HM(CO)4L-(M = Cr, W; L = CO, PR3)
journal, January 1985
- Kao, S. C.; Spillett, Cris Tina.; Ash, Carlton.
- Organometallics, Vol. 4, Issue 1
Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid-Assisted Reductive Coupling of Carbon Monoxide
journal, October 2010
- Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E.
- Organometallics, Vol. 29, Issue 20
Spectroscopic behavior of a new family of mixed-ligand iridium(III) complexes
journal, September 1989
- Sandrini, Diana; Maestri, Mauro; Ziessel, Raymond
- Inorganica Chimica Acta, Vol. 163, Issue 2
Theoretical Analysis of the Sequential Proton-Coupled Electron Transfer Mechanisms for H 2 Oxidation and Production Pathways Catalyzed by Nickel Molecular Electrocatalysts
journal, January 2012
- Fernandez, Laura E.; Horvath, Samantha; Hammes-Schiffer, Sharon
- The Journal of Physical Chemistry C, Vol. 116, Issue 4
Toward Molecular Catalysts by Computer
journal, January 2015
- Raugei, Simone; DuBois, Daniel L.; Rousseau, Roger
- Accounts of Chemical Research, Vol. 48, Issue 2
Steric effect for proton, hydrogen-atom, and hydride transfer reactions with geometric isomers of NADH–model ruthenium complexes
journal, January 2012
- Cohen, Brian W.; Polyansky, Dmitry E.; Achord, Patrick
- Faraday Discuss., Vol. 155
Determination of S−H Bond Strengths in Dimolybdenum Tetrasulfide Complexes
journal, February 2009
- Appel, Aaron M.; Lee, Suh-Jane; Franz, James A.
- Organometallics, Vol. 28, Issue 3
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 3. Thermodynamic acidity of common mononuclear carbonyl hydrides
journal, April 1986
- Moore, Eric J.; Sullivan, Jeffrey M.; Norton, Jack R.
- Journal of the American Chemical Society, Vol. 108, Issue 9
Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More
journal, December 2009
- Stephan, Douglas W.; Erker, Gerhard
- Angewandte Chemie International Edition, Vol. 49, Issue 1
Photocatalytic Reduction of Artificial and Natural Nucleotide Co-factors with a Chlorophyll-Like Tin-Dihydroporphyrin Sensitizer
journal, September 2013
- Oppelt, Kerstin T.; Wöß, Eva; Stiftinger, Martin
- Inorganic Chemistry, Vol. 52, Issue 20
Carbanion mechanisms. 6. Metalation of arylmethanes by potassium hydride/18-crown-6 ether in tetrahydrofuran and the acidity of hydrogen
journal, June 1977
- Buncel, Erwin; Menon, Balachandran
- Journal of the American Chemical Society, Vol. 99, Issue 13
Comprehensive Thermodynamic Characterization of the Metal−Hydrogen Bond in a Series of Cobalt-Hydride Complexes
journal, March 2002
- Ciancanelli, Rebecca; Noll, Bruce C.; DuBois, Daniel L.
- Journal of the American Chemical Society, Vol. 124, Issue 12, p. 2984-2992
Hydridic character of early transition metal hydride complexes
journal, August 1978
- Labinger, Jay A.; Komadina, Kevin H.
- Journal of Organometallic Chemistry, Vol. 155, Issue 2
Redox-active ligands in catalysis
journal, January 2013
- Luca, Oana R.; Crabtree, Robert H.
- Chem. Soc. Rev., Vol. 42, Issue 4
Organometallic thermodynamics. Redox couples involving metal-metal bonds
journal, May 1992
- Pugh, J. Richard; Meyer, Thomas J.
- Journal of the American Chemical Society, Vol. 114, Issue 10
Catalytic ionic hydrogenations of ketones using molybdenum and tungsten complexesBased on the presentation given at Dalton Discussion No. 4, 10–13th January 2002, Kloster Banz, Germany.
journal, January 2002
- Voges, Mark H.; Bullock, R. Morris
- Journal of the Chemical Society, Dalton Transactions, Issue 5
A pendant proton shuttle on [Fe 4 N(CO) 12 ] − alters product selectivity in formate vs. H 2 production via the hydride [H–Fe 4 N(CO) 12 ] −
journal, January 2016
- Loewen, Natalia D.; Thompson, Emily J.; Kagan, Michael
- Chemical Science, Vol. 7, Issue 4
Thermochemical Insight into the Reduction of CO to CH 3 OH with [Re(CO)] + and [Mn(CO)] + Complexes
journal, June 2014
- Wiedner, Eric S.; Appel, Aaron M.
- Journal of the American Chemical Society, Vol. 136, Issue 24
The development of aqueous transfer hydrogenation catalysts
journal, January 2011
- Robertson, Andrew; Matsumoto, Takahiro; Ogo, Seiji
- Dalton Transactions, Vol. 40, Issue 40
Measurement of the Hydride Donor Abilities of [HM(diphosphine) 2 ] + Complexes (M = Ni, Pt) by Heterolytic Activation of Hydrogen
journal, March 2002
- Curtis, Calvin J.; Miedaner, Alex; Ellis, William W.
- Journal of the American Chemical Society, Vol. 124, Issue 9
Competing nucleophilic displacement and radical-chain reduction in reactions of transition-metal hydride anions with alkyl bromides
journal, May 1987
- Ash, Carlton E.; Hurd, Philip W.; Darensbourg, Marcetta Y.
- Journal of the American Chemical Society, Vol. 109, Issue 11
Hydride Affinities of Arylcarbenium Ions and Iminium Ions in Dimethyl Sulfoxide and Acetonitrile
journal, July 1998
- Zhang, Xian-Man; Bruno, Joseph W.; Enyinnaya, Emmeline
- The Journal of Organic Chemistry, Vol. 63, Issue 14
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production
journal, August 2011
- Helm, M. L.; Stewart, M. P.; Bullock, R. M.
- Science, Vol. 333, Issue 6044, p. 863-866
Hydrogenase Enzyme Reactivity Modeling with a Transition-Metal Dihydrogen Complex
journal, March 1994
- Hembre, Robert T.; McQueen, Scott
- Journal of the American Chemical Society, Vol. 116, Issue 5
Thermodynamic Studies of [H 2 Rh(diphosphine) 2 ] + and [HRh(diphosphine) 2 (CH 3 CN)] 2+ Complexes in Acetonitrile
journal, April 2010
- Wilson, Aaron D.; Miller, Alexander J. M.; DuBois, Daniel L.
- Inorganic Chemistry, Vol. 49, Issue 8
Metal–Polypyridyl Catalysts for Electro- and Photochemical Reduction of Water to Hydrogen
journal, June 2015
- Zee, David Z.; Chantarojsiri, Teera; Long, Jeffrey R.
- Accounts of Chemical Research, Vol. 48, Issue 7
Homogeneous Hydrogenation of Carbon Dioxide
journal, March 1995
- Jessop, Philip G.; Ikariya, Takao.; Noyori, Ryoji.
- Chemical Reviews, Vol. 95, Issue 2
Ligand steals spotlight from metal to orchestrate hydrogen production
journal, January 2016
- Dempsey, Jillian L.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 3
On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o -R 2 P(Ph)BR‘ 2
journal, September 2006
- Bontemps, Sébastien; Bouhadir, Ghenwa; Miqueu, Karinne
- Journal of the American Chemical Society, Vol. 128, Issue 37
Excited-State Deprotonation and H/D Exchange of an Iridium Hydride Complex
journal, November 2003
- Suenobu, Tomoyoshi; Guldi, Dirk M.; Ogo, Seiji
- Angewandte Chemie International Edition, Vol. 42, Issue 44
Mechanism of the reaction of a solvated rhenium acyl complex with neutral transition-metal hydrides. Relative nucleophilicity of such hydrides
journal, January 1986
- Martin, Bruce D.; Warner, Keith E.; Norton, Jack R.
- Journal of the American Chemical Society, Vol. 108, Issue 1
Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX 3 Compounds
journal, December 2011
- Mock, Michael T.; Potter, Robert G.; O’Hagan, Molly J.
- Inorganic Chemistry, Vol. 50, Issue 23
Bioorganometallic Chemistry. 13. Regioselective Reduction of NAD + Models, 1-Benzylnicotinamde Triflate and β-Nicotinamide Ribose-5‘-methyl Phosphate, with in Situ Generated [Cp*Rh(Bpy)H] + : Structure−Activity Relationships, Kinetics, and Mechanistic Aspects in the Formation of the 1,4-NADH Derivatives †
journal, December 2001
- Lo, H. Christine; Leiva, Carmen; Buriez, Olivier
- Inorganic Chemistry, Vol. 40, Issue 26
E–H Bond Activations and Hydrosilylation Catalysis with Iron and Cobalt Metalloboranes
journal, August 2015
- Nesbit, Mark A.; Suess, Daniel L. M.; Peters, Jonas C.
- Organometallics, Vol. 34, Issue 19
H 2 Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation
journal, November 2010
- Fourmond, Vincent; Jacques, Pierre-André; Fontecave, Marc
- Inorganic Chemistry, Vol. 49, Issue 22
Hydricity of transition-metal hydrides and its role in CO2 reduction
journal, January 2000
- DuBois, Daniel L.; Berning, Douglas E.
- Applied Organometallic Chemistry, Vol. 14, Issue 12
Isotope Effects on Hydride Transfer Reactions from Transition Metal Hydrides to Trityl Cation. An Inverse Isotope Effect for a Hydride Transfer
journal, April 1999
- Cheng, Tan-Yun; Bullock, R. Morris
- Journal of the American Chemical Society, Vol. 121, Issue 13
Contrasting Anticancer Activity of Half-Sandwich Iridium(III) Complexes Bearing Functionally Diverse 2-Phenylpyridine Ligands
journal, November 2014
- Millett, Adam J.; Habtemariam, Abraha; Romero-Canelón, Isolda
- Organometallics, Vol. 34, Issue 11
Transition Metal Complexes Coordinated by an NAD(P)H Model Compound and their Enhanced Hydride-Donating Abilities in the Presence of a Base
journal, July 2005
- Kobayashi, Atsuo; Konno, Hideo; Sakamoto, Kazuhiko
- Chemistry - A European Journal, Vol. 11, Issue 14
Free-Energy Relationships between the Proton and Hydride Donor Abilities of [HNi(diphosphine) 2 ] + Complexes and the Half-Wave Potentials of Their Conjugate Bases
journal, April 2001
- Berning, Douglas E.; Miedaner, Alex; Curtis, Calvin J.
- Organometallics, Vol. 20, Issue 9
Hydride Donor Abilities and Bond Dissociation Free Energies of Transition Metal Formyl Complexes
journal, March 2002
- Ellis, William W.; Miedaner, Alex; Curtis, Calvin J.
- Journal of the American Chemical Society, Vol. 124, Issue 9
Visible Light Driven Benzyl Alcohol Dehydrogenation in a Dye-Sensitized Photoelectrosynthesis Cell
journal, June 2014
- Song, Wenjing; Vannucci, Aaron K.; Farnum, Byron H.
- Journal of the American Chemical Society, Vol. 136, Issue 27
Predicting the reactivity of hydride donors in water: thermodynamic constants for hydrogen
journal, January 2015
- Connelly, Samantha J.; Wiedner, Eric S.; Appel, Aaron M.
- Dalton Transactions, Vol. 44, Issue 13
The Tightness Contribution to the Brønsted α for Hydride Transfer between NAD + Analogues
journal, July 2002
- Lee, In-Sook Han; Chow, Kim-Hung; Kreevoy, Maurice M.
- Journal of the American Chemical Society, Vol. 124, Issue 26
Periodic Trends in Metal Hydride Donor Thermodynamics: Measurement and Comparison of the Hydride Donor Abilities of the Series HM(PNP) 2 + (M = Ni, Pd, Pt; PNP = Et 2 PCH 2 N(Me)CH 2 PEt 2 )
journal, February 2004
- Curtis, Calvin J.; Miedaner, Alex; Raebiger, James W.
- Organometallics, Vol. 23, Issue 3
PROTON-COUPLED ELECTRON TRANSFER: A Reaction Chemist's View
journal, June 2004
- Mayer, James M.
- Annual Review of Physical Chemistry, Vol. 55, Issue 1
Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation
journal, March 2010
- Warren, J. J.; Mayer, J. M.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 12
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
journal, January 2014
- Qiao, Jinli; Liu, Yuyu; Hong, Feng
- Chem. Soc. Rev., Vol. 43, Issue 2
Solvent influence on the thermodynamics for hydride transfer from bis(diphosphine) complexes of nickel
journal, January 2016
- Connelly Robinson, Samantha J.; Zall, Christopher M.; Miller, Deanna L.
- Dalton Transactions, Vol. 45, Issue 24
Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentafluorophenyl)borane. A Synthetic,Structural, Solution Dynamic, and Polymerization Catalytic Study
journal, November 1994
- Yang, Xinmin; Stern, Charlotte L.; Marks, Tobin J.
- Journal of the American Chemical Society, Vol. 116, Issue 22
Complex Hydrides for Hydrogen Storage
journal, October 2007
- Orimo, Shin-ichi; Nakamori, Yuko; Eliseo, Jennifer R.
- Chemical Reviews, Vol. 107, Issue 10
Extension of the Self-Consistent Spectrophotometric Basicity Scale in Acetonitrile to a Full Span of 28 p K a Units: Unification of Different Basicity Scales
journal, February 2005
- Kaljurand, Ivari; Kütt, Agnes; Sooväli, Lilli
- The Journal of Organic Chemistry, Vol. 70, Issue 3
Development of an Efficient and Durable Photocatalytic System for Hydride Reduction of an NAD(P) + Model Compound Using a Ruthenium(II) Complex Based on Mechanistic Studies
journal, August 2010
- Matsubara, Yasuo; Koga, Kichitaro; Kobayashi, Atsuo
- Journal of the American Chemical Society, Vol. 132, Issue 30
Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism
journal, December 2015
- Solis, Brian H.; Maher, Andrew G.; Dogutan, Dilek K.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 3
Electron transfers in chemistry and biology
journal, August 1985
- Marcus, R. A.; Sutin, Norman
- Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, Vol. 811, Issue 3
Catalytic Reductive Transformations of Carboxylic and Carbonic Acid Derivatives Using Molecular Hydrogen
journal, July 2012
- Dub, Pavel A.; Ikariya, Takao
- ACS Catalysis, Vol. 2, Issue 8
Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides
journal, January 2014
- Bullock, R. Morris; Appel, Aaron M.; Helm, Monte L.
- Chem. Commun., Vol. 50, Issue 24
Thermodynamic and Kinetic Studies of Hydride Transfer for a Series of Molybdenum and Tungsten Hydrides
journal, March 1999
- Sarker, Niladri; Bruno, Joseph W.
- Journal of the American Chemical Society, Vol. 121, Issue 10
Determination of the C4H Bond Dissociation Energies of NADH Models and Their Radical Cations in Acetonitrile
journal, February 2003
- Zhu, Xiao-Qing; Li, Hai-Rong; Li, Qian
- Chemistry - A European Journal, Vol. 9, Issue 4
Alcohol Complexes of Tungsten Prepared by Ionic Hydrogenations of Ketones
journal, July 2001
- Song, Jeong-Sup; Szalda, David J.; Bullock, R. Morris
- Organometallics, Vol. 20, Issue 15
Relative Hydride, Proton, and Hydrogen Atom Transfer Abilities of [HM(diphosphine) 2 ]PF 6 Complexes (M = Pt, Ni)
journal, December 1999
- Berning, Douglas E.; Noll, Bruce C.; DuBois, Daniel L.
- Journal of the American Chemical Society, Vol. 121, Issue 49
Hydrocarbon Oxidation by Bis-μ-oxo Manganese Dimers: Electron Transfer, Hydride Transfer, and Hydrogen Atom Transfer Mechanisms
journal, August 2002
- Larsen, Anna S.; Wang, Kun; Lockwood, Mark A.
- Journal of the American Chemical Society, Vol. 124, Issue 34, p. 10112-10123
Regiospecific Hydride Transfer from cis-[Ru(bpy)2(CO)(CHO)]+ to NAD+ Model Compounds: A Model for Enzymatic Reactions by Aldehyde Dehydrogenases
journal, November 2000
- Konno, Hideo; Sakamoto, Kazuhiko; Ishitani, Osamu
- Angewandte Chemie, Vol. 39, Issue 22
The Reaction Mechanism with Free Energy Barriers for Electrochemical Dihydrogen Evolution on MoS 2
journal, May 2015
- Huang, Yufeng; Nielsen, Robert J.; Goddard, William A.
- Journal of the American Chemical Society, Vol. 137, Issue 20
Molybdenum Carbonyl Complexes in the Solvent-Free Catalytic Hydrogenation of Ketones
journal, December 2005
- Kimmich, Barbara F. M.; Fagan, Paul J.; Hauptman, Elisabeth
- Organometallics, Vol. 24, Issue 25
Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium–Triphos catalyst: from mechanistic investigations to multiphase catalysis
journal, January 2015
- Wesselbaum, Sebastian; Moha, Verena; Meuresch, Markus
- Chemical Science, Vol. 6, Issue 1
Electrochemistry as a diagnostic tool to discriminate between classical M-(H)2 and nonclassical M-(H2) structures within a family of dihydride and dihydrogen metal complexes
journal, September 1990
- Bianchini, Claudio; Laschi, Franco; Peruzzini, Maurizio
- Inorganic Chemistry, Vol. 29, Issue 18
The Mononuclear Molybdenum Enzymes
journal, January 2014
- Hille, Russ; Hall, James; Basu, Partha
- Chemical Reviews, Vol. 114, Issue 7
Anionic group 6 transition-metal carbonyl hydrides as reducing agents. ketones, aldehydes, and epoxides
journal, April 1985
- Gaus, Paul L.; Kao, S. C.; Youngdahl, Kay
- Journal of the American Chemical Society, Vol. 107, Issue 8
Reactivity and Equilibrium Thermodynamic Studies of Rhodium Tetrakis(3,5-disulfonatomesityl)porphyrin Species with H 2 , CO, and Olefins in Water
journal, November 2006
- Fu, Xuefeng; Li, Shan; Wayland, Bradford B.
- Inorganic Chemistry, Vol. 45, Issue 24
Photochemistry of Transition Metal Hydrides
journal, June 2016
- Perutz, Robin N.; Procacci, Barbara
- Chemical Reviews, Vol. 116, Issue 15
A Comprehensive Self-Consistent Spectrophotometric Acidity Scale of Neutral Brønsted Acids in Acetonitrile
journal, March 2006
- Kütt, Agnes; Leito, Ivo; Kaljurand, Ivari
- The Journal of Organic Chemistry, Vol. 71, Issue 7
Thermodynamic Studies of [HPt(EtXantphos) 2 ] + and [(H) 2 Pt(EtXantphos) 2 ] 2+
journal, May 2004
- Miedaner, Alex; Raebiger, James W.; Curtis, Calvin J.
- Organometallics, Vol. 23, Issue 11
Molecular Photoelectrocatalysts for Visible Light-Driven Hydrogen Evolution from Neutral Water
journal, July 2014
- Pitman, Catherine L.; Miller, Alexander J. M.
- ACS Catalysis, Vol. 4, Issue 8
Thermochemical and Mechanistic Studies of Electrocatalytic Hydrogen Production by Cobalt Complexes Containing Pendant Amines
journal, November 2013
- Wiedner, Eric S.; Appel, Aaron M.; DuBois, Daniel L.
- Inorganic Chemistry, Vol. 52, Issue 24
Ab Initio Calculations of Thermodynamic Hydricities of Transition-Metal Hydrides in Acetonitrile
journal, August 2007
- Qi, Xiu-Juan; Fu, Yao; Liu, Lei
- Organometallics, Vol. 26, Issue 17
Acid–base equilibria in systems involving substituted pyridines in polar aprotic protophobic media and in the amphiprotic methanol
journal, August 2000
- Augustin-Nowacka, D.; Makowski, M.; Chmurzynski, L.
- Analytica Chimica Acta, Vol. 418, Issue 2
Thermodynamic Properties of the Ni−H Bond in Complexes of the Type [HNi(P 2 R N 2 R ‘ ) 2 ](BF 4 ) and Evaluation of Factors That Control Catalytic Activity for Hydrogen Oxidation/Production
journal, July 2007
- Fraze, Kendra; Wilson, Aaron D.; Appel, Aaron M.
- Organometallics, Vol. 26, Issue 16
Effects of Phosphine–Carbene Substitutions on the Electrochemical and Thermodynamic Properties of Nickel Complexes
journal, April 2014
- Galan, Brandon R.; Wiedner, Eric S.; Helm, Monte L.
- Organometallics, Vol. 33, Issue 9
Making Hydrogen from Water Using a Homogeneous System Without Noble Metals
journal, July 2009
- Lazarides, Theodore; McCormick, Theresa; Du, Pingwu
- Journal of the American Chemical Society, Vol. 131, Issue 26
Hydrogen Production by Molecular Photocatalysis
journal, October 2007
- Esswein, Arthur J.; Nocera, Daniel G.
- Chemical Reviews, Vol. 107, Issue 10
Hydrogen atom transfer reactions of transition-metal hydrides. Kinetics and mechanism of the hydrogenation of .alpha.-cyclopropylstyrene by metal carbonyl hydrides
journal, September 1990
- Bullock, R. Morris; Samsel, Edward G.
- Journal of the American Chemical Society, Vol. 112, Issue 19
Calculated Hydride Donor Abilities of Five-Coordinate Transition Metal Hydrides [HM(diphosphine) 2 ] + (M = Ni, Pd, Pt) as a Function of the Bite Angle and Twist Angle of Diphosphine Ligands
journal, June 2008
- Nimlos, Mark R.; Chang, Christopher H.; Curtis, Calvin J.
- Organometallics, Vol. 27, Issue 12
Water Oxidation Intermediates Applied to Catalysis: Benzyl Alcohol Oxidation
journal, February 2012
- Vannucci, Aaron K.; Hull, Jonathan F.; Chen, Zuofeng
- Journal of the American Chemical Society, Vol. 134, Issue 9
Theoretical Analysis of Cobalt Hangman Porphyrins: Ligand Dearomatization and Mechanistic Implications for Hydrogen Evolution
journal, November 2014
- Solis, Brian H.; Maher, Andrew G.; Honda, Tatsuhiko
- ACS Catalysis, Vol. 4, Issue 12
Effect of Molecular Acid-Base Dissociation of Salts on Conductometric Titration Curves in Acetonitrile 1
journal, March 1965
- Kolthoff, I. M.; Chantooni, M. K.
- Journal of the American Chemical Society, Vol. 87, Issue 5
Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions
journal, January 2012
- Lyaskovskyy, Volodymyr; de Bruin, Bas
- ACS Catalysis, Vol. 2, Issue 2
An experimentally based family of potential energy surfaces for hydride transfer between NAD+ analogs
journal, October 1991
- Kim, Yongho; Truhlar, Donald G.; Kreevoy, Maurice M.
- Journal of the American Chemical Society, Vol. 113, Issue 21
Reversible Hydride Generation and Release from the Ligand of [Ru(pbn)(bpy)2](PF6)2 Driven by a pbn-Localized Redox Reaction
journal, September 2005
- Koizumi, Take-aki; Tanaka, Koji
- Angewandte Chemie International Edition, Vol. 44, Issue 36
Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011
- Wang, Wei; Wang, Shengping; Ma, Xinbin
- Chemical Society Reviews, Vol. 40, Issue 7
Iron catalyzed CO 2 hydrogenation to formate enhanced by Lewis acid co-catalysts
journal, January 2015
- Zhang, Yuanyuan; MacIntosh, Alex D.; Wong, Janice L.
- Chemical Science, Vol. 6, Issue 7
Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes
journal, March 2011
- Choi, Jongwook; MacArthur, Amy H. Roy; Brookhart, Maurice
- Chemical Reviews, Vol. 111, Issue 3
The Ionic Work Function and its Role in Estimating Absolute Electrode Potentials
journal, September 2008
- Fawcett, W. Ronald
- Langmuir, Vol. 24, Issue 17
Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A Predictive Model through Computations
journal, November 2011
- Chen, Shentan; Rousseau, Roger; Raugei, Simone
- Organometallics, Vol. 30, Issue 22
Cobalt Complexes Containing Pendant Amines in the Second Coordination Sphere as Electrocatalysts for H 2 Production
journal, June 2014
- Fang, Ming; Wiedner, Eric S.; Dougherty, William G.
- Organometallics, Vol. 33, Issue 20
A new group of ruthenium complexes: structure and catalysis
journal, November 1986
- Shvo, Youval.; Czarkie, Dorotha.; Rahamim, Yocheved.
- Journal of the American Chemical Society, Vol. 108, Issue 23
Proton–hydride tautomerism in hydrogen evolution catalysis
journal, May 2016
- Quintana, Luis M. Aguirre; Johnson, Samantha I.; Corona, Sydney L.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 23
Direct Comparison of the Performance of a Bio-inspired Synthetic Nickel Catalyst and a [NiFe]-Hydrogenase, Both Covalently Attached to Electrodes
journal, July 2015
- Rodriguez-Maciá, Patricia; Dutta, Arnab; Lubitz, Wolfgang
- Angewandte Chemie International Edition, Vol. 54, Issue 42
Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes
journal, March 2016
- Morris, Robert H.
- Chemical Reviews, Vol. 116, Issue 15
Striking Differences in Properties of Geometric Isomers of [Ir(tpy)(ppy)H] + : Experimental and Computational Studies of their Hydricities, Interaction with CO 2 , and Photochemistry
journal, October 2015
- Garg, Komal; Matsubara, Yasuo; Ertem, Mehmed Z.
- Angewandte Chemie International Edition, Vol. 54, Issue 47
Making Oxygen with Ruthenium Complexes
journal, December 2009
- Concepcion, Javier J.; Jurss, Jonah W.; Brennaman, M. Kyle
- Accounts of Chemical Research, Vol. 42, Issue 12
Molybdenum−Sulfur Dimers as Electrocatalysts for the Production of Hydrogen at Low Overpotentials
journal, September 2005
- Appel, Aaron M.; DuBois, Daniel L.; Rakowski DuBois, M.
- Journal of the American Chemical Society, Vol. 127, Issue 36
Two Pathways for Electrocatalytic Oxidation of Hydrogen by a Nickel Bis(diphosphine) Complex with Pendant Amines in the Second Coordination Sphere
journal, June 2013
- Yang, Jenny Y.; Smith, Stuart E.; Liu, Tianbiao
- Journal of the American Chemical Society, Vol. 135, Issue 26
Combinations of Ethers and B(C 6 F 5 ) 3 Function as Hydrogenation Catalysts
journal, June 2013
- Hounjet, Lindsay J.; Bannwarth, Christoph; Garon, Christian N.
- Angewandte Chemie International Edition, Vol. 52, Issue 29
A DFT Study: Why Do [Ni(P R 2 N R ′ 2 ) 2 ] 2+ Complexes Facilitate the Electrocatalytic Oxidation of Formate?
journal, March 2014
- Xue, Liqin; Ahlquist, Mårten S. G.
- Inorganic Chemistry, Vol. 53, Issue 7
First Estimation of C 4 −H Bond Dissociation Energies of NADH and Its Radical Cation in Aqueous Solution
journal, December 2003
- Zhu, Xiao-Qing; Yang, Yuan; Zhang, Ming
- Journal of the American Chemical Society, Vol. 125, Issue 50
Comparison of primary oxidants for water-oxidation catalysis
journal, January 2013
- Parent, Alexander R.; Crabtree, Robert H.; Brudvig, Gary W.
- Chem. Soc. Rev., Vol. 42, Issue 6
A d 10 Ni-(H 2 ) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond
journal, December 2013
- Harman, W. Hill; Lin, Tzu-Pin; Peters, Jonas C.
- Angewandte Chemie International Edition, Vol. 53, Issue 4
Aqueous Hydricity of Late Metal Catalysts as a Continuum Tuned by Ligands and the Medium
journal, February 2016
- Pitman, Catherine L.; Brereton, Kelsey R.; Miller, Alexander J. M.
- Journal of the American Chemical Society, Vol. 138, Issue 7
Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory
journal, January 2011
- Mayer, James M.
- Accounts of Chemical Research, Vol. 44, Issue 1
Acid−Base Equilibria in Nonpolar Media. 4. Extension of the Self-Consistent Basicity Scale in THF Medium. Gas-Phase Basicities of Phosphazenes
journal, December 2003
- Kaljurand, Ivari; Rodima, Toomas; Pihl, Aino
- The Journal of Organic Chemistry, Vol. 68, Issue 26
Hydride, Hydrogen Atom, Proton, and Electron Transfer Driving Forces of Various Five-Membered Heterocyclic Organic Hydrides and Their Reaction Intermediates in Acetonitrile
journal, February 2008
- Zhu, Xiao-Qing; Zhang, Ming-Tian; Yu, Ao
- Journal of the American Chemical Society, Vol. 130, Issue 8
Comprehensive Thermochemistry of W–H Bonding in the Metal Hydrides CpW(CO) 2 (IMes)H, [CpW(CO) 2 (IMes)H] •+ , and [CpW(CO) 2 (IMes)(H) 2 ] + . Influence of an N -Heterocyclic Carbene Ligand on Metal Hydride Bond Energies
journal, September 2011
- Roberts, John A. S.; Appel, Aaron M.; DuBois, Daniel L.
- Journal of the American Chemical Society, Vol. 133, Issue 37
Synthesis, Electrochemistry, and Reactivity of New Iridium(III) and Rhodium(III) Hydrides
journal, June 2012
- Hu, Yue; Li, Ling; Shaw, Anthony P.
- Organometallics, Vol. 31, Issue 14
The Golden Age of Transfer Hydrogenation
journal, June 2015
- Wang, Dong; Astruc, Didier
- Chemical Reviews, Vol. 115, Issue 13
Formation of η 2 -Coordinated Dihydropyridine–Ruthenium(II) Complexes by Hydride Transfer from Ruthenium(II) to Pyridinium Cations
journal, October 2013
- Matsubara, Yasuo; Kosaka, Tatsumi; Koga, Kichitaro
- Organometallics, Vol. 32, Issue 21
Equilibrium acidities in dimethyl sulfoxide solution
journal, December 1988
- Bordwell, Frederick G.
- Accounts of Chemical Research, Vol. 21, Issue 12
Isolation and Crystal Structure of a Water-Soluble Iridium Hydride: A Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media
journal, April 2003
- Abura, Tsutomu; Ogo, Seiji; Watanabe, Yoshihito
- Journal of the American Chemical Society, Vol. 125, Issue 14
Hydride Transfer from Rhodium Complexes to Triethylborane
journal, August 2006
- DuBois, Daniel L.; Blake, Daniel M.; Miedaner, Alex
- Organometallics, Vol. 25, Issue 18
Double Bond Isomerisation and Migration-New Playgrounds for Transition Metal-Catalysis
journal, July 2014
- Hilt, Gerhard
- ChemCatChem, Vol. 6, Issue 9
Directing the Reactivity of [HFe 4 N(CO) 12 ] − toward H + or CO 2 Reduction by Understanding the Electrocatalytic Mechanism
journal, November 2011
- Rail, M. Diego; Berben, Louise A.
- Journal of the American Chemical Society, Vol. 133, Issue 46
Organometallic Ruthenium and Iridium Transfer-Hydrogenation Catalysts Using Coenzyme NADH as a Cofactor
journal, March 2012
- Betanzos-Lara, Soledad; Liu, Zhe; Habtemariam, Abraha
- Angewandte Chemie International Edition, Vol. 51, Issue 16
Cyclopentadiene-mediated hydride transfer from rhodium complexes
journal, January 2016
- Pitman, C. L.; Finster, O. N. L.; Miller, A. J. M.
- Chemical Communications, Vol. 52, Issue 58
Theoretical studies of the mechanism of catalytic hydrogen production by a cobaloxime
journal, January 2011
- Muckerman, James T.; Fujita, Etsuko
- Chemical Communications, Vol. 47, Issue 46
Reductive Coupling of Carbon Monoxide in a Rhenium Carbonyl Complex with Pendant Lewis Acids
journal, September 2008
- Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E.
- Journal of the American Chemical Society, Vol. 130, Issue 36
Thermodynamic and Kinetic Hydricity of Ruthenium(II) Hydride Complexes
journal, September 2012
- Matsubara, Yasuo; Fujita, Etsuko; Doherty, Mark D.
- Journal of the American Chemical Society, Vol. 134, Issue 38
Electrocatalytic pathways towards sustainable fuel production from water and CO2
journal, November 2012
- Inglis, Jane L.; MacLean, Brian J.; Pryce, Mary T.
- Coordination Chemistry Reviews, Vol. 256, Issue 21-22
Incorporation of Pendant Bases into Rh(diphosphine) 2 Complexes: Synthesis, Thermodynamic Studies, And Catalytic CO 2 Hydrogenation Activity of [Rh(P 2 N 2 ) 2 ] + Complexes
journal, June 2015
- Lilio, Alyssia M.; Reineke, Mark H.; Moore, Curtis E.
- Journal of the American Chemical Society, Vol. 137, Issue 25
A novel type of hydride-transfer photocatalysis by Ru II –pyridine complexes: regiocontrolled reduction of an NAD(P) model compound by triethylamine
journal, January 1994
- Ishitani, Osamu; Inoue, Nobuyo; Koike, Kazuhide
- J. Chem. Soc., Chem. Commun., Issue 4
Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production
journal, April 2012
- Horvath, S.; Fernandez, L. E.; Soudackov, A. V.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
journal, October 2014
- Kärkäs, Markus D.; Verho, Oscar; Johnston, Eric V.
- Chemical Reviews, Vol. 114, Issue 24
Reversible H 2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis
journal, March 2012
- Harman, W. Hill; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 134, Issue 11
Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis
journal, February 2010
- Boyer, Julie L.; Rochford, Jonathan; Tsai, Ming-Kang
- Coordination Chemistry Reviews, Vol. 254, Issue 3-4
Studies of a Series of [Ni(P R 2 N Ph 2 ) 2 (CH 3 CN)] 2+ Complexes as Electrocatalysts for H 2 Production: Substituent Variation at the Phosphorus Atom of the P 2 N 2 Ligand
journal, November 2011
- Kilgore, Uriah J.; Stewart, Michael P.; Helm, Monte L.
- Inorganic Chemistry, Vol. 50, Issue 21
Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium
journal, October 2013
- Brewster, Timothy P.; Miller, Alexander J. M.; Heinekey, D. Michael
- Journal of the American Chemical Society, Vol. 135, Issue 43
Hydricities of BzNADH, C 5 H 5 Mo(PMe 3 )(CO) 2 H, and C 5 Me 5 Mo(PMe 3 )(CO) 2 H in Acetonitrile
journal, March 2004
- Ellis, William W.; Raebiger, James W.; Curtis, Calvin J.
- Journal of the American Chemical Society, Vol. 126, Issue 9
Selective reduction of acyl chlorides to aldehydes by anionic Group VIB transition metal hydrides
journal, October 1984
- Kao, S. C.; Gaus, Paul L.; Youngdahl, Kay
- Organometallics, Vol. 3, Issue 10
Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media
journal, June 2014
- Moret, Séverine; Dyson, Paul J.; Laurenczy, Gábor
- Nature Communications, Vol. 5, Issue 1
Metal-Ligand Cooperation
journal, September 2015
- Khusnutdinova, Julia R.; Milstein, David
- Angewandte Chemie International Edition, Vol. 54, Issue 42
Mechanism of Hydride Donor Generation Using a Ru(II) Complex Containing an NAD + Model Ligand: Pulse and Steady-State Radiolysis Studies
journal, May 2008
- Polyansky, Dmitry E.; Cabelli, Diane; Muckerman, James T.
- Inorganic Chemistry, Vol. 47, Issue 10
Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins
journal, October 2014
- Bediako, D. Kwabena; Solis, Brian H.; Dogutan, Dilek K.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 42
Using Ligand Bite Angles To Control the Hydricity of Palladium Diphosphine Complexes
journal, May 2004
- Raebiger, James W.; Miedaner, Alex; Curtis, Calvin J.
- Journal of the American Chemical Society, Vol. 126, Issue 17
Rhodium(I) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal→Borane Interaction
journal, February 2006
- Bontemps, Sébastien; Gornitzka, Heinz; Bouhadir, Ghenwa
- Angewandte Chemie International Edition, Vol. 45, Issue 10
Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate
journal, July 2014
- Barnett, Brandon R.; Moore, Curtis E.; Rheingold, Arnold L.
- Journal of the American Chemical Society, Vol. 136, Issue 29
Drastic difference in the photo-driven hydrogenation reactions of ruthenium complexes containing NAD model ligands
journal, January 2012
- Ohtsu, Hideki; Tanaka, Koji
- Chemical Communications, Vol. 48, Issue 12
Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes
journal, December 2004
- Clapham, Sean E.; Hadzovic, Alen; Morris, Robert H.
- Coordination Chemistry Reviews, Vol. 248, Issue 21-24
Bond energies in solution from electrode potentials and thermochemical cycles. A simplified and general approach
journal, May 1993
- Wayner, Danial D. M.; Parker, Vernon D.
- Accounts of Chemical Research, Vol. 26, Issue 5
Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile
journal, June 2012
- Roberts, John A. S.; Bullock, R. Morris
- Inorganic Chemistry, Vol. 52, Issue 7
Equilibrium Thermodynamic Studies in Water: Reactions of Dihydrogen with Rhodium(III) Porphyrins Relevant to Rh−Rh, Rh−H, and Rh−OH Bond Energetics
journal, March 2004
- Fu, Xuefeng; Wayland, Bradford B.
- Journal of the American Chemical Society, Vol. 126, Issue 8
Cooperating Ligands in Catalysis
journal, February 2008
- Grützmacher, Hansjörg
- Angewandte Chemie International Edition, Vol. 47, Issue 10
Incorporating Amino Acid Esters into Catalysts for Hydrogen Oxidation: Steric and Electronic Effects and the Role of Water as a Base
journal, September 2012
- Lense, Sheri; Ho, Ming-Hsun; Chen, Shentan
- Organometallics, Vol. 31, Issue 19
Hydrogen Evolution Catalyzed by Cobaloximes
journal, December 2009
- Dempsey, Jillian L.; Brunschwig, Bruce S.; Winkler, Jay R.
- Accounts of Chemical Research, Vol. 42, Issue 12
Kinetics of Hydrogen Atom Transfer from (η 5 -C 5 H 5 )Cr(CO) 3 H to Various Olefins: Influence of Olefin Structure
journal, January 2007
- Choi, Jongwook; Tang, Lihao; Norton, Jack R.
- Journal of the American Chemical Society, Vol. 129, Issue 1
Hydride Transfer by Hydrido Transition-Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex
journal, September 1992
- Song, Jeong-Sup; Szalda, David J.; Bullock, R. Morris
- Angewandte Chemie International Edition in English, Vol. 31, Issue 9
Hydride Transfer from (η 5 -C 5 Me 5 )(CO) 2 MH (M = Fe, Ru, Os) to Trityl Cation: Different Products from Different Metals and the Kinetics of Hydride Transfer
journal, May 2002
- Cheng, Tan-Yun; Bullock, R. Morris
- Organometallics, Vol. 21, Issue 11
A modular, energy-based approach to the development of nickel containing molecular electrocatalysts for hydrogen production and oxidation
journal, August 2013
- Shaw, Wendy J.; Helm, Monte L.; DuBois, Daniel L.
- Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1827, Issue 8-9
Oxygen−Oxygen Bond Formation Pathways Promoted by Ruthenium Complexes
journal, December 2009
- Romain, Sophie; Vigara, Laura; Llobet, Antoni
- Accounts of Chemical Research, Vol. 42, Issue 12
Half-sandwich rhodium(III) transfer hydrogenation catalysts: Reduction of NAD+ and pyruvate, and antiproliferative activity
journal, December 2015
- Soldevila-Barreda, Joan J.; Habtemariam, Abraha; Romero-Canelón, Isolda
- Journal of Inorganic Biochemistry, Vol. 153
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
journal, April 2005
- Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob
- Journal of the American Chemical Society, Vol. 127, Issue 15
Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants
journal, January 2014
- Morris, Robert H.
- Journal of the American Chemical Society, Vol. 136, Issue 5
New approaches to hydrogen storage
journal, January 2009
- Graetz, Jason
- Chem. Soc. Rev., Vol. 38, Issue 1
A thermodynamic and kinetic study of the heterolytic activation of hydrogen by frustrated borane–amine Lewis pairs
journal, January 2013
- Karkamkar, Abhi; Parab, Kshitij; Camaioni, Donald M.
- Dalton Trans., Vol. 42, Issue 3
Hydride-Donor Abilities of 1,4-Dihydropyridines: A Comparison with π Nucleophiles and Borohydride Anions
journal, March 2009
- Richter, Dorothea; Mayr, Herbert
- Angewandte Chemie International Edition, Vol. 48, Issue 11
Experimental and Computational Mechanistic Studies Guiding the Rational Design of Molecular Electrocatalysts for Production and Oxidation of Hydrogen
journal, November 2015
- Raugei, Simone; Helm, Monte L.; Hammes-Schiffer, Sharon
- Inorganic Chemistry, Vol. 55, Issue 2
Bio-Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal-Activated Substrate
journal, February 2013
- McSkimming, Alex; Bhadbhade, Mohan M.; Colbran, Stephen B.
- Angewandte Chemie International Edition, Vol. 52, Issue 12
Molecular artificial photosynthesis
journal, January 2014
- Berardi, Serena; Drouet, Samuel; Francàs, Laia
- Chem. Soc. Rev., Vol. 43, Issue 22
Electrocatalytic H 2 production with a turnover frequency >10 7 s −1 : the medium provides an increase in rate but not overpotential
journal, January 2014
- Hou, Jianbo; Fang, Ming; Cardenas, Allan Jay P.
- Energy Environ. Sci., Vol. 7, Issue 12
Photochemical Stereospecific Hydrogenation of a Ru Complex with an NAD + /NADH-Type Ligand
journal, December 2009
- Fukushima, Takashi; Fujita, Etsuko; Muckerman, James T.
- Inorganic Chemistry, Vol. 48, Issue 24
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
journal, February 2010
- Lyons, Thomas W.; Sanford, Melanie S.
- Chemical Reviews, Vol. 110, Issue 2
Transition-Metal-Catalyzed Regeneration of Nicotinamide Coenzymes with Hydrogen 1
journal, March 2003
- Wagenknecht, Paul S.; Penney, Jonathan M.; Hembre, Robert T.
- Organometallics, Vol. 22, Issue 6
Photochemical Formic Acid Dehydrogenation by Iridium Complexes: Understanding Mechanism and Overcoming Deactivation
journal, September 2015
- Barrett, Seth M.; Slattery, Samuel A.; Miller, Alexander J. M.
- ACS Catalysis, Vol. 5, Issue 11
The roles of the first and second coordination spheres in the design of molecular catalysts for H 2 production and oxidation
journal, January 2009
- Rakowski DuBois, M.; DuBois, Daniel L.
- Chem. Soc. Rev., Vol. 38, Issue 1
Theoretical Analysis of Mechanistic Pathways for Hydrogen Evolution Catalyzed by Cobaloximes
journal, November 2011
- Solis, Brian H.; Hammes-Schiffer, Sharon
- Inorganic Chemistry, Vol. 50, Issue 21
Bond Activation and Catalysis by Ruthenium Pincer Complexes
journal, November 2014
- Gunanathan, Chidambaram; Milstein, David
- Chemical Reviews, Vol. 114, Issue 24
p K a Measurements of P(RNCH 2 CH 3 ) 3 N
journal, August 2000
- Kisanga, Philip B.; Verkade, John G.; Schwesinger, Reinhard
- The Journal of Organic Chemistry, Vol. 65, Issue 17
Regeneration of nicotinamide cofactors for use in organic synthesis
journal, March 1987
- Chenault, H. Keith; Whitesides, George M.
- Applied Biochemistry and Biotechnology, Vol. 14, Issue 2
Transition-Metal Hydride Radical Cations
journal, February 2016
- Hu, Yue; Shaw, Anthony P.; Estes, Deven P.
- Chemical Reviews, Vol. 116, Issue 15
Electrocatalytic Oxidation of Formate by [Ni(P R 2 N R′ 2 ) 2 (CH 3 CN)] 2+ Complexes
journal, August 2011
- Galan, Brandon R.; Schöffel, Julia; Linehan, John C.
- Journal of the American Chemical Society, Vol. 133, Issue 32
Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes
journal, February 2009
- Casey, Charles P.; Guan, Hairong
- Journal of the American Chemical Society, Vol. 131, Issue 7
Hydrogen storage and evolution catalysed by metal hydride complexes
journal, January 2013
- Fukuzumi, Shunichi; Suenobu, Tomoyoshi
- Dalton Trans., Vol. 42, Issue 1
Cooperation between Transition Metals and Lewis Acids: A Way To Activate H 2 and HE bonds
journal, December 2014
- Devillard, Marc; Bouhadir, Ghenwa; Bourissou, Didier
- Angewandte Chemie International Edition, Vol. 54, Issue 3
Hydride ion-carrier ability in Rh(i) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand
journal, January 2010
- McSkimming, Alex; Bhadbhade, Mohan; Colbran, Stephen B.
- Dalton Transactions, Vol. 39, Issue 44
Hydride Transfer Reactions of Transition Metal Hydrides: Kinetic Hydricity of Metal Carbonyl Hydrides
journal, December 1998
- Cheng, Tan-Yun; Brunschwig, Bruce S.; Bullock, R. Morris
- Journal of the American Chemical Society, Vol. 120, Issue 50
Using combinations of oxidants and bases as PCET reactants: thermochemical and practical considerations
journal, January 2012
- Waidmann, Christopher R.; Miller, Alexander J. M.; Ng, Cheuk-Wa Angela
- Energy & Environmental Science, Vol. 5, Issue 7
Understanding and exploiting C–H bond activation
journal, May 2002
- Labinger, Jay A.; Bercaw, John E.
- Nature, Vol. 417, Issue 6888
Thermodynamic Hydride Donor Abilities of [HW(CO) 4 L] - Complexes (L = PPh 3 , P(OMe) 3 , CO) and Their Reactions with [C 5 Me 5 Re(PMe 3 )(NO)(CO)] +
journal, October 2003
- Ellis, William W.; Ciancanelli, Rebecca; Miller, Susie M.
- Journal of the American Chemical Society, Vol. 125, Issue 40
Prediction of acidity in acetonitrile solution with COSMO-RS
journal, April 2009
- Eckert, Frank; Leito, Ivo; Kaljurand, Ivari
- Journal of Computational Chemistry, Vol. 30, Issue 5
Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H 2 Activation and the Role of Acid−Base Properties
journal, August 2009
- Rokob, Tibor András; Hamza, Andrea; Pápai, Imre
- Journal of the American Chemical Society, Vol. 131, Issue 30
Nitrosyl Substituted Hydride Complexes–An Activated Class of Compounds
journal, September 1994
- Berke, Heinz; Burger, Peter
- Comments on Inorganic Chemistry, Vol. 16, Issue 5
Mechanistic Insights into Catalytic H 2 Oxidation by Ni Complexes Containing a Diphosphine Ligand with a Positioned Amine Base
journal, April 2009
- Yang, Jenny Y.; Bullock, R. Morris; Shaw, Wendy J.
- Journal of the American Chemical Society, Vol. 131, Issue 16
Transition metal-hydrogen and metal-carbon bond strengths: the keys to catalysis
journal, June 1990
- Simoes, J. A. Martinho; Beauchamp, J. L.
- Chemical Reviews, Vol. 90, Issue 4
Chemical approaches to artificial photosynthesis
journal, May 1989
- Meyer, Thomas J.
- Accounts of Chemical Research, Vol. 22, Issue 5
Chemically catalyzed net electrochemical oxidation of alcohols, aldehydes, and unsaturated hydrocarbons using the system (trpy)(bpy)Ru(OH2)2+/(trpy)(bpy)RuO2+
journal, March 1980
- Moyer, Bruce A.; Thompson, Mark S.; Meyer, Thomas J.
- Journal of the American Chemical Society, Vol. 102, Issue 7
Homogeneous Catalysis with Inexpensive Metals: Ionic Hydrogenation of Ketones with Molybdenum and Tungsten Catalysts
journal, December 2000
- Bullock, R. Morris; Voges, Mark H.
- Journal of the American Chemical Society, Vol. 122, Issue 50
Single-Step Hydride Transfer from CpMo(CO) 2 (PPh 3 )H to Protonated Ketones
journal, January 1996
- Smith, Kjell-Tore; Norton, Jack R.; Tilset, Mats
- Organometallics, Vol. 15, Issue 21
Solvent, ligand, and ionic charge effects on reaction entropies for simple transition-metal redox couples
journal, October 1984
- Hupp, Joseph T.; Weaver, Michael J.
- Inorganic Chemistry, Vol. 23, Issue 22
Very efficient reduction of NAD(P)+ with formate catalysed by cationic rhodium complexes
journal, January 1988
- Ruppert, Romain; Herrmann, Sabine; Steckhan, Eberhard
- Journal of the Chemical Society, Chemical Communications, Issue 17
A Highly Efficient Mononuclear Iridium Complex Photocatalyst for CO 2 Reduction under Visible Light
journal, November 2012
- Sato, Shunsuke; Morikawa, Takeshi; Kajino, Tsutomu
- Angewandte Chemie International Edition, Vol. 52, Issue 3
Radical Ligands Confer Nobility on Base-Metal Catalysts
journal, February 2010
- Chirik, P. J.; Wieghardt, K.
- Science, Vol. 327, Issue 5967
Kinetics and Thermodynamics of H – /H•/H + Transfer from a Rhodium(III) Hydride
journal, April 2014
- Hu, Yue; Norton, Jack R.
- Journal of the American Chemical Society, Vol. 136, Issue 16
Solvation Effects on Transition Metal Hydricity
journal, November 2015
- Tsay, Charlene; Livesay, Brooke N.; Ruelas, Samantha
- Journal of the American Chemical Society, Vol. 137, Issue 44
Frustrated Lewis Pairs
journal, August 2015
- Stephan, Douglas W.
- Journal of the American Chemical Society, Vol. 137, Issue 32
Ionic Hydrogenations of Hindered Olefins at Low Temperature. Hydride Transfer Reactions of Transition Metal Hydrides
journal, September 1994
- Bullock, R. Morris; Song, Jeong-Sup
- Journal of the American Chemical Society, Vol. 116, Issue 19
Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex
journal, March 2010
- Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E.
- Journal of the American Chemical Society, Vol. 132, Issue 10
Heterolytic H 2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane
journal, May 2013
- Fong, Henry; Moret, Marc-Etienne; Lee, Yunho
- Organometallics, Vol. 32, Issue 10
Synthesis and Structure of CpMo(CO)(dppe)H and Its Oxidation by Ph 3 C +
journal, June 2006
- Cheng, Tan-Yun; Szalda, David J.; Zhang, Jie
- Inorganic Chemistry, Vol. 45, Issue 12
Thermodynamic Studies of HRh(depx) 2 and [(H) 2 Rh(depx) 2 ](CF 3 SO 3 ): Relationships between Five-Coordinate Monohydrides and Six-Coordinate Dihydrides
journal, January 2005
- Raebiger, James W.; DuBois, Daniel L.
- Organometallics, Vol. 24, Issue 1
Formate oxidation via β-deprotonation in [Ni(PR2NR′2)2(CH3CN)]2+ complexes
journal, January 2012
- Seu, Candace S.; Appel, Aaron M.; Doud, Michael D.
- Energy & Environmental Science, Vol. 5, Issue 4
Ionization potentials and electron affinities in aqueous solution
journal, October 1986
- Pearson, Ralph G.
- Journal of the American Chemical Society, Vol. 108, Issue 20
Hydride sponge: 1,8-naphthalenediylbis(dimethylborane)
journal, March 1985
- Katz, Howard Edan
- Journal of the American Chemical Society, Vol. 107, Issue 5
Biomimetic NAD+ Models for Tandem Cofactor Regeneration, Horse Liver Alcohol Dehydrogenase Recognition of 1,4-NADH Derivatives, and Chiral Synthesis
journal, January 2002
- Lo, H. Christine; Fish, Richard H.
- Angewandte Chemie International Edition, Vol. 41, Issue 3
Homogeneous syngas conversion
journal, April 2011
- West, Nathan M.; Miller, Alexander J. M.; Labinger, Jay A.
- Coordination Chemistry Reviews, Vol. 255, Issue 7-8
Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts
journal, January 2012
- Wang, Mei; Chen, Lin; Sun, Licheng
- Energy & Environmental Science, Vol. 5, Issue 5
Catalytic Ionic Hydrogenations
journal, May 2004
- Bullock, R. Morris
- Chemistry - A European Journal, Vol. 10, Issue 10
Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions
journal, December 2011
- Engle, Keary M.; Mei, Tian-Sheng; Wasa, Masayuki
- Accounts of Chemical Research, Vol. 45, Issue 6
Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs
journal, October 2014
- Mahdi, Tayseer; Stephan, Douglas W.
- Journal of the American Chemical Society, Vol. 136, Issue 45
Improved Catalytic Activity of Ruthenium–Arene Complexes in the Reduction of NAD +
journal, August 2012
- Soldevila-Barreda, Joan J.; Bruijnincx, Pieter C. A.; Habtemariam, Abraha
- Organometallics, Vol. 31, Issue 16
Metal−Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds
journal, November 2001
- Noyori, Ryoji; Yamakawa, Masashi; Hashiguchi, Shohei
- The Journal of Organic Chemistry, Vol. 66, Issue 24
The coordination chemistry of organo-hydride donors: new prospects for efficient multi-electron reduction
journal, January 2013
- McSkimming, Alex; Colbran, Stephen B.
- Chemical Society Reviews, Vol. 42, Issue 12
Thermodynamic Scales for Sulfur Atom Transfer and Oxo-for-Sulfido Exchange Reactions
journal, November 2006
- Donahue, James P.
- Chemical Reviews, Vol. 106, Issue 11
CO 2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO 2 Reduction
journal, August 2015
- Wang, Wan-Hui; Himeda, Yuichiro; Muckerman, James T.
- Chemical Reviews, Vol. 115, Issue 23
Hydride transfer and dihydrogen elimination from osmium and ruthenium metalloporphyrin hydrides: model processes for hydrogenase enzymes and the hydrogen electrode reaction
journal, July 1992
- Collman, James P.; Wagenknecht, Paul S.; Lewis, Nathan S.
- Journal of the American Chemical Society, Vol. 114, Issue 14
Catalysis of the electrochemical reduction of carbon dioxide
journal, January 2013
- Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
- Chem. Soc. Rev., Vol. 42, Issue 6
The Remarkable Reactivity of High Oxidation State Ruthenium and Osmium Polypyridyl Complexes
journal, December 2003
- Meyer, Thomas J.; Huynh, My Hang V.
- Inorganic Chemistry, Vol. 42, Issue 25
Acidities of water and simple alcohols in dimethyl sulfoxide solution
journal, August 1980
- Olmstead, William N.; Margolin, Zafra; Bordwell, Frederick G.
- The Journal of Organic Chemistry, Vol. 45, Issue 16
[Ni(Et 2 PCH 2 NMeCH 2 PEt 2 ) 2 ] 2+ as a Functional Model for Hydrogenases
journal, January 2003
- Curtis, Calvin J.; Miedaner, Alex; Ciancanelli, Rebecca
- Inorganic Chemistry, Vol. 42, Issue 1
Synthesis of transition metal formyl compounds by nucleophilic attack of hydride on coordinated carbon monoxide
journal, August 1976
- Casey, Charles P.; Neumann, Stephen M.
- Journal of the American Chemical Society, Vol. 98, Issue 17
Regioselective Reduction of NAD+ Models with [Cp*Rh(bpy)H]+: Structure-Activity Relationships and Mechanistic Aspects in the Formation of the 1,4-NADH Derivatives
journal, May 1999
- Lo, H. Christine; Buriez, Olivier; Kerr, John B.
- Angewandte Chemie International Edition, Vol. 38, Issue 10
Cooperative Catalysis with First-Row Late Transition Metals
journal, September 2011
- van der Vlugt, Jarl Ivar; de Bruin, Bas
- European Journal of Inorganic Chemistry, Vol. 2012, Issue 3, p. 363-375
Analytical study of a series of substituted (2,2'-bipyridyl)(pentamethylcyclopentadienyl)rhodium and -iridium complexes with regard to their effectiveness as redox catalysts for the indirect electrochemical and chemical reduction of NAD(P)+
journal, May 1991
- Steckhan, Eberhard.; Herrmann, Sabine.; Ruppert, Romain.
- Organometallics, Vol. 10, Issue 5
Acid-base equilibriums in dipolar aprotic solvents
journal, November 1974
- Kolthoff, I. M.
- Analytical Chemistry, Vol. 46, Issue 13
Hydrogen Generation from Weak Acids: Electrochemical and Computational Studies in the [(η 5 -C 5 H 5 )Fe(CO) 2 ] 2 System
journal, September 2008
- Felton, Greg A. N.; Vannucci, Aaron K.; Okumura, Noriko
- Organometallics, Vol. 27, Issue 18
Efficient Catalytic Interconversion between NADH and NAD + Accompanied by Generation and Consumption of Hydrogen with a Water-Soluble Iridium Complex at Ambient Pressure and Temperature
journal, December 2011
- Maenaka, Yuta; Suenobu, Tomoyoshi; Fukuzumi, Shunichi
- Journal of the American Chemical Society, Vol. 134, Issue 1
Hydricity of an Fe–H Species and Catalytic CO 2 Hydrogenation
journal, December 2014
- Fong, Henry; Peters, Jonas C.
- Inorganic Chemistry, Vol. 54, Issue 11
Reactions of tris- and bis(2,2'-bipyridine)rhodium(II) complexes in aqueous solution
journal, March 1983
- Schwarz, Harold A.; Creutz, Carol
- Inorganic Chemistry, Vol. 22, Issue 5
Ammonia-Borane and Related Compounds as Dihydrogen Sources
journal, July 2010
- Staubitz, Anne; Robertson, Alasdair P. M.; Manners, Ian
- Chemical Reviews, Vol. 110, Issue 7
Hydride Reduction of NAD(P) + Model Compounds with a Ru(II)–Hydrido Complex
journal, November 2015
- Koga, Kichitaro; Matsubara, Yasuo; Kosaka, Tatsumi
- Organometallics, Vol. 34, Issue 23
Visible light photocatalytic reduction of aldehydes by Rh( iii )–H: a detailed mechanistic study
journal, January 2015
- Ghosh, T.; Slanina, T.; König, B.
- Chemical Science, Vol. 6, Issue 3
Thermodynamic Diagnosis of the Properties and Mechanism of Dihydropyridine-Type Compounds as Hydride Source in Acetonitrile with “Molecule ID Card”
journal, February 2010
- Zhu, Xiao-Qing; Tan, Yue; Cao, Chao-Tun
- The Journal of Physical Chemistry B, Vol. 114, Issue 5
Structure sensitivity of the Marcus .lambda. for hydride transfer between NAD+ analogs
journal, January 1988
- Kreevoy, Maurice M.; Ostovic, Drazen.; Lee, In Sook Han.
- Journal of the American Chemical Society, Vol. 110, Issue 2
Recommendations on reporting electrode potentials in nonaqueous solvents (Recommendations 1983)
journal, January 1984
- Gritzner, G.; Kuta, J.
- Pure and Applied Chemistry, Vol. 56, Issue 4
Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry
journal, September 2014
- Rountree, Eric S.; McCarthy, Brian D.; Eisenhart, Thomas T.
- Inorganic Chemistry, Vol. 53, Issue 19
Oxidation of Toluene by [(phen) 2 Mn(μ-O) 2 Mn(phen) 2 ] 4+ via Initial Hydride Abstraction
journal, December 1999
- Lockwood, Mark A.; Wang, Kun; Mayer, James M.
- Journal of the American Chemical Society, Vol. 121, Issue 50
Development of Molecular Electrocatalysts for Energy Storage
journal, February 2014
- DuBois, Daniel L.
- Inorganic Chemistry, Vol. 53, Issue 8
Solution homolytic bond dissociation energies of organotransition-metal hydrides
journal, August 1989
- Tilset, Mats; Parker, Vernon D.
- Journal of the American Chemical Society, Vol. 111, Issue 17
A potentiometric study of acid–base equilibria of substituted pyridines in acetonitrile
journal, February 1999
- Augustin-Nowacka, D.; Chmurzyñski, L.
- Analytica Chimica Acta, Vol. 381, Issue 2-3
Photoswitchable Hydride Transfer from Iridium to 1-Methylnicotinamide Rationalized by Thermochemical Cycles
journal, October 2014
- Barrett, Seth M.; Pitman, Catherine L.; Walden, Andrew G.
- Journal of the American Chemical Society, Vol. 136, Issue 42
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications
journal, December 2010
- Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M.
- Chemical Reviews, Vol. 110, Issue 12
Towards a Comprehensive Hydride Donor Ability Scale
journal, November 2012
- Horn, Markus; Schappele, Ludwig H.; Lang-Wittkowski, Gabriele
- Chemistry - A European Journal, Vol. 19, Issue 1
Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions
journal, May 1994
- Mayr, Herbert; Patz, Matthias
- Angewandte Chemie International Edition in English, Vol. 33, Issue 9
Substituent Effects on Cobalt Diglyoxime Catalysts for Hydrogen Evolution
journal, November 2011
- Solis, Brian H.; Hammes-Schiffer, Sharon
- Journal of the American Chemical Society, Vol. 133, Issue 47
Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes
journal, May 2016
- Maity, Ayan; Teets, Thomas S.
- Chemical Reviews, Vol. 116, Issue 15
Properties of Bases in Acetonitrile as Solvent. IV. Proton Acceptor Power and Homoconjugation of Mono- and Diamines
journal, November 1965
- Coetzee, J. F.; Padmanabhan, G. R.
- Journal of the American Chemical Society, Vol. 87, Issue 22
Calculation of thermodynamic hydricities and the design of hydride donors for CO2 reduction
journal, July 2012
- Muckerman, J. T.; Achord, P.; Creutz, C.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
Making C–H bonds with CO 2 : production of formate by molecular electrocatalysts
journal, January 2016
- Taheri, Atefeh; Berben, Louise A.
- Chemical Communications, Vol. 52, Issue 9
Heterolytic dihydrogen activation by B(C6F5)3 and carbonyl compounds
journal, January 2012
- Lindqvist, Markus; Sarnela, Nina; Sumerin, Victor
- Dalton Transactions, Vol. 41, Issue 15
Determining the Overpotential for a Molecular Electrocatalyst
journal, December 2013
- Appel, Aaron M.; Helm, Monte L.
- ACS Catalysis, Vol. 4, Issue 2
An Iron Electrocatalyst for Selective Reduction of CO 2 to Formate in Water: Including Thermochemical Insights
journal, November 2015
- Taheri, Atefeh; Thompson, Emily J.; Fettinger, James C.
- ACS Catalysis, Vol. 5, Issue 12
Kinetic hydricity of transition-metal hydrides toward trityl cation
journal, September 1995
- Cheng, Tan-Yun; Bullock, R. Morris
- Organometallics, Vol. 14, Issue 9
Oxidation of Benzyl Alcohol by a Dioxo Complex of Ruthenium(VI)
journal, May 1999
- Lebeau, Estelle L.; Meyer, Thomas J.
- Inorganic Chemistry, Vol. 38, Issue 9
Enzymes in organic synthesis: oxidoreductions
journal, January 1995
- Fang, Jim-Min; Lin, Chun-Hung; Bradshaw, Curt W.
- Journal of the Chemical Society, Perkin Transactions 1, Issue 8
Metal-Hydrogen Bond Cleavage Reactions of Transition Metal Hydrides: Hydrogen Atom, Hydride, and Proton Transfer Reactions
journal, May 1991
- Bullock, R. Morris
- Comments on Inorganic Chemistry, Vol. 12, Issue 1
Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation
journal, September 2014
- Lin, Tzu-Pin; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 136, Issue 39
Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes
journal, February 1997
- Noyori, Ryoji; Hashiguchi, Shohei
- Accounts of Chemical Research, Vol. 30, Issue 2
Basicity of Phosphanes and Diphosphanes in Acetonitrile
journal, February 2012
- Haav, Kristjan; Saame, Jaan; Kütt, Agnes
- European Journal of Organic Chemistry, Vol. 2012, Issue 11
Boryl-Mediated Reversible H 2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation
journal, October 2013
- Lin, Tzu-Pin; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 135, Issue 41
Photochemical and Radiolytic Production of an Organic Hydride Donor with a RuII Complex Containing an NAD+ Model Ligand
journal, May 2007
- Polyansky, Dmitry; Cabelli, Diane; Muckerman, James T.
- Angewandte Chemie International Edition, Vol. 46, Issue 22
Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes
journal, February 2007
- Welch, Gregory C.; Stephan, Douglas W.
- Journal of the American Chemical Society, Vol. 129, Issue 7
Isomerization of Allylbenzenes
journal, May 2015
- Hassam, Mohammad; Taher, Abu; Arnott, Gareth E.
- Chemical Reviews, Vol. 115, Issue 11
Estimates of hydride ion stability in condensed systems: energy of formation and solvation in aqueous and polar-organic solvents
journal, January 2001
- Kelly, Craig A.; Rosseinsky, David R.
- Physical Chemistry Chemical Physics, Vol. 3, Issue 11
Oxidation-Reduction Potentials of the Diphosphopyridine Nucleotide System
journal, April 1955
- Rodkey, F. Lee
- Journal of Biological Chemistry, Vol. 213, Issue 2
Hydride transfer reactions of transition metal hydrides in the preparation of [Cp(CO)3W(η1-aldehyde)]+OTf− and [Cp(CO)3W(η1-ketone)]+OTf− complexes
journal, June 1997
- Song, Jeong-Sup; Szalda, David J.; Morris Bullock, R.
- Inorganica Chimica Acta, Vol. 259, Issue 1-2
Establishing the Hydride Donor Abilities of Main Group Hydrides
journal, May 2015
- Heiden, Zachariah M.; Lathem, A. Paige
- Organometallics, Vol. 34, Issue 10
Multiple Pathways for Benzyl Alcohol Oxidation by Ru V ═O 3+ and Ru IV ═O 2+
journal, February 2011
- Paul, Amit; Hull, Jonathan F.; Norris, Michael R.
- Inorganic Chemistry, Vol. 50, Issue 4
σ-Acceptor, Z-type ligands for transition metals
journal, January 2011
- Amgoune, Abderrahmane; Bourissou, Didier
- Chem. Commun., Vol. 47, Issue 3
Carbon monoxide and carbon dioxide fixation: relevant C1 and C2 ligand reactions emphasizing (.eta.5-C5H5)Fe-containing complexes
journal, November 1988
- Cutler, Alan R.; Hanna, Paul K.; Vites, Jose C.
- Chemical Reviews, Vol. 88, Issue 7
Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX 3 Compounds
journal, October 2009
- Mock, Michael T.; Potter, Robert G.; Camaioni, Donald M.
- Journal of the American Chemical Society, Vol. 131, Issue 40
Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation
journal, December 2009
- Rakowski Dubois, M.; Dubois, Daniel L.
- Accounts of Chemical Research, Vol. 42, Issue 12, p. 1974-1982
Tailoring Electrocatalysts for Selective CO 2 or H + Reduction: Iron Carbonyl Clusters as a Case Study
journal, November 2015
- Taheri, Atefeh; Berben, Louise A.
- Inorganic Chemistry, Vol. 55, Issue 2
Free Energy Landscapes for S−H Bonds in Cp* 2 Mo 2 S 4 Complexes
journal, April 2009
- Appel, Aaron M.; Lee, Suh-Jane; Franz, James A.
- Journal of the American Chemical Society, Vol. 131, Issue 14
Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels
journal, January 2009
- Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J.
- Chem. Soc. Rev., Vol. 38, Issue 1
Synthesis and properties of [Ru(tpy)(4,4′-X2bpy)H]+ (tpy=2,2′:6′,2″-terpyridine, bpy=2,2′-bipyridine, X=H and MeO), and their reactions with CO2
journal, March 2000
- Konno, Hideo; Kobayashi, Atsuo; Sakamoto, Kazuhiko
- Inorganica Chimica Acta, Vol. 299, Issue 2
Generation of metal formyl complexes using nickel and platinum hydrides as reducing agents
journal, February 1993
- Miedaner, Alex; DuBois, Daniel L.; Curtis, Calvin J.
- Organometallics, Vol. 12, Issue 2
Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts
journal, July 2007
- Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.
- Science, Vol. 317, Issue 5834, p. 100-102
Pentakis(trifluoromethyl)phenyl, a Sterically Crowded and Electron-withdrawing Group: Synthesis and Acidity of Pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline
journal, April 2008
- Kütt, Agnes; Movchun, Valeria; Rodima, Toomas
- The Journal of Organic Chemistry, Vol. 73, Issue 7
Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au + ) Derived from a Triphosphine−Borane
journal, December 2008
- Sircoglou, Marie; Bontemps, Sébastien; Bouhadir, Ghenwa
- Journal of the American Chemical Society, Vol. 130, Issue 49
Relative reactivities of anionic transition metal hydrides. Reduction of alkyl halides
journal, April 1984
- Kao, S. C.; Darensbourg, Marcetta Y.
- Organometallics, Vol. 3, Issue 4
Thermodynamics of the Metal–Hydrogen Bonds in (η 5 -C 5 H 5 )M(CO) 2 H (M = Fe, Ru, Os)
journal, June 2011
- Estes, Deven P.; Vannucci, Aaron K.; Hall, Ariel R.
- Organometallics, Vol. 30, Issue 12
Relative rates of hydrogen atom (H.cntdot.) transfer from transition-metal hydrides to trityl radicals
journal, June 1991
- Eisenberg, David C.; Lawrie, Christophe J. C.; Moody, Anne E.
- Journal of the American Chemical Society, Vol. 113, Issue 13
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
journal, June 2013
- Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
- Chemical Reviews, Vol. 113, Issue 8
Fuel from Water: The Photochemical Generation of Hydrogen from Water
journal, June 2014
- Han, Zhiji; Eisenberg, Richard
- Accounts of Chemical Research, Vol. 47, Issue 8
Ab Initio Calculations of p K a Values of Transition-Metal Hydrides in Acetonitrile
journal, December 2006
- Qi, Xiu-Juan; Liu, Lei; Fu, Yao
- Organometallics, Vol. 25, Issue 25
A Thermodynamic Analysis of Rhenium(I)–Formyl C–H Bond Formation via Base-Assisted Heterolytic H 2 Cleavage in the Secondary Coordination Sphere
journal, September 2013
- Teets, Thomas S.; Labinger, Jay A.; Bercaw, John E.
- Organometallics, Vol. 32, Issue 19
Acid−Base Equilibria in Nonpolar Media. 1. A Spectrophotometric Method for Acidity Measurements in Heptane
journal, November 1997
- Leito, Ivo; Rodima, Toomas; Koppel, Ilmar A.
- The Journal of Organic Chemistry, Vol. 62, Issue 24
Water-Soluble Phenanthroline Complexes of Rhodium, Iridium and Ruthenium for the Regeneration of NADH in the Enzymatic Reduction of Ketones
journal, October 2007
- Canivet, Jérôme; Süss-Fink, Georg; Štěpnička, Petr
- European Journal of Inorganic Chemistry, Vol. 2007, Issue 30