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Title: Addition of CFCl 3 to Aromatic Aldehydes via in Situ Grignard Reaction

In the case of synthetic modification of trichlorofluoromethane (CFCl 3) to non-volatile and useful fluorinated precursors, we realized that it is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In our report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl 3 for synthesis of dichlorofluoromethyl aromatic alcohols.
Authors:
 [1] ;  [2] ;  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Independent Researcher, Guwahati (India)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Molecules
Additional Journal Information:
Journal Volume: 20; Journal Issue: 8; Journal ID: ISSN 1420-3049
Publisher:
MDPI
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CFCl3; magnesium; grignard reaction; in-situ process; aromatic aldehydes
OSTI Identifier:
1265863

Barkakaty, Balaka, Talukdar, Bandana, and Lokitz, Bradley. Addition of CFCl3 to Aromatic Aldehydes via in Situ Grignard Reaction. United States: N. p., Web. doi:10.3390/molecules200815098.
Barkakaty, Balaka, Talukdar, Bandana, & Lokitz, Bradley. Addition of CFCl3 to Aromatic Aldehydes via in Situ Grignard Reaction. United States. doi:10.3390/molecules200815098.
Barkakaty, Balaka, Talukdar, Bandana, and Lokitz, Bradley. 2015. "Addition of CFCl3 to Aromatic Aldehydes via in Situ Grignard Reaction". United States. doi:10.3390/molecules200815098. https://www.osti.gov/servlets/purl/1265863.
@article{osti_1265863,
title = {Addition of CFCl3 to Aromatic Aldehydes via in Situ Grignard Reaction},
author = {Barkakaty, Balaka and Talukdar, Bandana and Lokitz, Bradley},
abstractNote = {In the case of synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors, we realized that it is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In our report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.},
doi = {10.3390/molecules200815098},
journal = {Molecules},
number = 8,
volume = 20,
place = {United States},
year = {2015},
month = {8}
}