A-site stoichiometry and piezoelectric response in thin film PbZr1-xTixO3
Abstract
Lead zirconate titanate (PZT) films with Zr/Ti ratios of 52/48 and 30/70 annealed at varying partial pressures of PbO within the perovskite phase field exhibited permittivities of 1150 and 600, respectively, with loss tangents of 0.02. Many of the functional properties, including the permittivity, piezoelectricity as indicated via the Rayleigh coefficients, and the aging rates were found to be weakly dependent of the lead content in the single phase field. Minor polarization electric field hysteresis loops and piezoelectric coefficient e31,f values after a hot poling process suggest that the point defect helps stabilize the aligned domain states. Measurements of the local nonlinear response show an increased low response cluster size with decreasing PbO content, indicating that PbO deficiency acts to reduce domain wall motion where it is already low
- Authors:
-
- Pennsylvania State Univ., University Park, PA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1265758
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 117; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Lead zirconate titanate; Polarization; Lead; Domain walls; Furnaces
Citation Formats
Marincel, Dan, Jesse, Stephen, Belianinov, Alex, Okatan, Mahmut Baris, Kalinin, Sergei V., Jackson, T. N., Randall, Clive, and Trolier-McKinstry, Susan E. A-site stoichiometry and piezoelectric response in thin film PbZr1-xTixO3. United States: N. p., 2015.
Web. doi:10.1063/1.4921869.
Marincel, Dan, Jesse, Stephen, Belianinov, Alex, Okatan, Mahmut Baris, Kalinin, Sergei V., Jackson, T. N., Randall, Clive, & Trolier-McKinstry, Susan E. A-site stoichiometry and piezoelectric response in thin film PbZr1-xTixO3. United States. https://doi.org/10.1063/1.4921869
Marincel, Dan, Jesse, Stephen, Belianinov, Alex, Okatan, Mahmut Baris, Kalinin, Sergei V., Jackson, T. N., Randall, Clive, and Trolier-McKinstry, Susan E. Fri .
"A-site stoichiometry and piezoelectric response in thin film PbZr1-xTixO3". United States. https://doi.org/10.1063/1.4921869. https://www.osti.gov/servlets/purl/1265758.
@article{osti_1265758,
title = {A-site stoichiometry and piezoelectric response in thin film PbZr1-xTixO3},
author = {Marincel, Dan and Jesse, Stephen and Belianinov, Alex and Okatan, Mahmut Baris and Kalinin, Sergei V. and Jackson, T. N. and Randall, Clive and Trolier-McKinstry, Susan E},
abstractNote = {Lead zirconate titanate (PZT) films with Zr/Ti ratios of 52/48 and 30/70 annealed at varying partial pressures of PbO within the perovskite phase field exhibited permittivities of 1150 and 600, respectively, with loss tangents of 0.02. Many of the functional properties, including the permittivity, piezoelectricity as indicated via the Rayleigh coefficients, and the aging rates were found to be weakly dependent of the lead content in the single phase field. Minor polarization electric field hysteresis loops and piezoelectric coefficient e31,f values after a hot poling process suggest that the point defect helps stabilize the aligned domain states. Measurements of the local nonlinear response show an increased low response cluster size with decreasing PbO content, indicating that PbO deficiency acts to reduce domain wall motion where it is already low},
doi = {10.1063/1.4921869},
journal = {Journal of Applied Physics},
number = ,
volume = 117,
place = {United States},
year = {Fri May 29 00:00:00 EDT 2015},
month = {Fri May 29 00:00:00 EDT 2015}
}
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