Excess wing in glass-forming glycerol and LiCl-glycerol mixtures detected by neutron scattering

Gupta, S.; Arend, N.; Lunkenheimer, P.; Loidl, A.; Stingaciu, L.; Jalarvo, N.; Mamontov, E.; Ohl, M.

doi:10.1140/epje/i2015-15001-0

Title: Excess wing in glass-forming glycerol and LiCl-glycerol mixtures detected by neutron scattering

Journal Article · Thu Jan 22 04:00:00 UTC 2015 · European Physical Journal. E, Soft Matter (print)

DOI: https://doi.org/10.1140/epje/i2015-15001-0 · OSTI ID:1261408

Gupta, S. ^[1]; Arend, N. ^[2]; Lunkenheimer, P. ^[3]; Loidl, A. ^[3]; Stingaciu, L. ^[1]; Jalarvo, N. ^[1]; Mamontov, E. ^[4]; Ohl, M. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS) and Julich Centre for Neutron Science (JCNS)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS) and Julich Centre for Neutron Science (JCNS); Julich Centre for Neutron Science JCNS, Garching (Germany). Outstation at MLZ
Univ. of Augsburg, Augsburg (Germany). Center for Electronic Correlations and Magnetism
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

The relaxational dynamics in glass-forming glycerol and glycerol mixed with LiCl is investigated using different neutron scattering techniques. The performed neutron spin echo experiments, which extend up to relatively long relaxation time scales of the order of 10 ns, should allow for the detection of contributions from the so-called excess wing. This phenomenon, whose microscopic origin is controversially discussed, arises in a variety of glass formers and, until now, was almost exclusively investigated by dielectric spectroscopy and light scattering. In conclusion, we show here that the relaxational process causing the excess wing can also be detected by neutron scattering, which directly couples to density fluctuations.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261408

Journal Information:: European Physical Journal. E, Soft Matter (print), Journal Name: European Physical Journal. E, Soft Matter (print) Journal Issue: 1 Vol. 38; ISSN 1292-8941

Publisher:: EDP SciencesCopyright Statement

Country of Publication:: United States

Language:: English

References (58)

Theorie des elektrischen Rückstandes in der Leidener Flasche Kohlrausch, R. Annalen der Physik und Chemie, Vol. 167, Issue 1 https://doi.org/10.1002/andp.18541670103	journal	January 1854
Theorie des elektrischen Rückstandes in der Leidener Flasche Kohlrausch, R. Annalen der Physik und Chemie, Vol. 167, Issue 2 https://doi.org/10.1002/andp.18541670203	journal	January 1854
Soft Matter and Biology Monkenbusch, M. Neutron Spin Echo Spectroscopy https://doi.org/10.1007/3-540-45823-9_20	book	January 2002
Time-of-Flight Neutron Spin Echo: Present Status Farago, B. Neutron Spin Echo Spectroscopy https://doi.org/10.1007/3-540-45823-9_3	book	January 2002
Light scattering and dielectric susceptibility spectra of glassforming liquids Lebon, M. J.; Dreyfus, C.; Guissani, Y. Zeitschrift für Physik B Condensed Matter, Vol. 103, Issue 3 https://doi.org/10.1007/s002570050397	journal	April 1997
The dielectric response of simple organic glass formers Kudlik, A.; Benkhof, S.; Blochowicz, T. Journal of Molecular Structure, Vol. 479, Issue 2-3 https://doi.org/10.1016/S0022-2860(98)00871-0	journal	April 1999
Heterogeneity at the glass transition: a review Sillescu, Hans Journal of Non-Crystalline Solids, Vol. 243, Issue 2-3 https://doi.org/10.1016/S0022-3093(98)00831-X	journal	February 1999
Dielectric spectroscopy of glass-forming materials: α-relaxation and excess wing Lunkenheimer, P.; Loidl, A. Chemical Physics, Vol. 284, Issue 1-2 https://doi.org/10.1016/S0301-0104(02)00549-9	journal	November 2002
Diffusion in confinement as a microscopic relaxation mechanism in glass-forming liquids Mamontov, Eugene Chemical Physics Letters, Vol. 530 https://doi.org/10.1016/j.cplett.2012.01.073	journal	March 2012
High-frequency excitations in glassy crystals Lunkenheimer, P.; Loidl, A. Journal of Non-Crystalline Solids, Vol. 352, Issue 42-49 https://doi.org/10.1016/j.jnoncrysol.2006.02.133	journal	November 2006
High-frequency dynamics of type B glass formers investigated by broadband dielectric spectroscopy Kastner, S.; Köhler, M.; Goncharov, Y. Journal of Non-Crystalline Solids, Vol. 357, Issue 2 https://doi.org/10.1016/j.jnoncrysol.2010.06.074	journal	January 2011
The spin-echo spectrometer at the Spallation Neutron Source (SNS) Ohl, M.; Monkenbusch, M.; Arend, N. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 696 https://doi.org/10.1016/j.nima.2012.08.059	journal	December 2012
The high-resolution neutron spin-echo spectrometer for the SNS with τ⩾1μs Ohl, M.; Monkenbusch, M.; Richter, D. Physica B: Condensed Matter, Vol. 350, Issue 1-3 https://doi.org/10.1016/j.physb.2004.04.014	journal	July 2004
Slow dynamics of water molecules in an aqueous solution of lithium chloride probed by neutron spin-echo Mamontov, E.; Ohl, M. Physical Chemistry Chemical Physics, Vol. 15, Issue 26 https://doi.org/10.1039/c3cp51355f	journal	January 2013
Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function Williams, Graham; Watts, David C. Transactions of the Faraday Society, Vol. 66 https://doi.org/10.1039/tf9706600080	journal	January 1970
Nature and properties of the Johari–Goldstein β-relaxation in the equilibrium liquid state of a class of glass-formers Ngai, K. L.; Lunkenheimer, P.; León, C. The Journal of Chemical Physics, Vol. 115, Issue 3 https://doi.org/10.1063/1.1381054	journal	July 2001
Viscous Liquids and the Glass Transition. II. Secondary Relaxations in Glasses of Rigid Molecules Johari, Gyan P.; Goldstein, Martin The Journal of Chemical Physics, Vol. 53, Issue 6 https://doi.org/10.1063/1.1674335	journal	September 1970
Evolution of excess wing and β-process in simple glass formers Gainaru, Catalin; Kahlau, Robert; Rössler, Ernst A. The Journal of Chemical Physics, Vol. 131, Issue 18 https://doi.org/10.1063/1.3258430	journal	November 2009
A time-of-flight backscattering spectrometer at the Spallation Neutron Source, BASIS Mamontov, E.; Herwig, K. W. Review of Scientific Instruments, Vol. 82, Issue 8 https://doi.org/10.1063/1.3626214	journal	August 2011
Dynamics of glass-forming liquids. III. Comparing the dielectric α- and β-relaxation of 1-propanol and o-terphenyl Hansen, C.; Stickel, F.; Berger, T. The Journal of Chemical Physics, Vol. 107, Issue 4 https://doi.org/10.1063/1.474456	journal	July 1997
Evolution of the dynamic susceptibility in molecular glass formers: Results from light scattering, dielectric spectroscopy, and NMR Petzold, N.; Schmidtke, B.; Kahlau, R. The Journal of Chemical Physics, Vol. 138, Issue 12 https://doi.org/10.1063/1.4770055	journal	March 2013
Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols Bauer, S.; Burlafinger, K.; Gainaru, C. The Journal of Chemical Physics, Vol. 138, Issue 9 https://doi.org/10.1063/1.4793469	journal	March 2013
Glassy dynamics Lunkenheimer, P.; Schneider, U.; Brand, R. Contemporary Physics, Vol. 41, Issue 1 https://doi.org/10.1080/001075100181259	journal	January 2000
Relaxation processes in supercooled liquids Gotze, W.; Sjogren, L. Reports on Progress in Physics, Vol. 55, Issue 3 https://doi.org/10.1088/0034-4885/55/3/001	journal	March 1992
Correlations in Space and Time and Born Approximation Scattering in Systems of Interacting Particles Van Hove, Léon Physical Review, Vol. 95, Issue 1 https://doi.org/10.1103/PhysRev.95.249	journal	July 1954
Ultrasonic investigation of the glass transition in glycerol Jeong, Yoon H.; Nagel, Sidney R.; Bhattacharya, S. Physical Review A, Vol. 34, Issue 1 https://doi.org/10.1103/PhysRevA.34.602	journal	July 1986
Testing mode-coupling predictions for α and β relaxation in Ca 0.4 K 0.6 ( NO 3 ) 1.4 near the liquid-glass transition by light scattering Li, G.; Du, W. M.; Chen, X. K. Physical Review A, Vol. 45, Issue 6 https://doi.org/10.1103/PhysRevA.45.3867	journal	March 1992
Light-scattering investigation of α and β relaxation near the liquid-glass transition of the molecular glass Salol Li, G.; Du, W. M.; Sakai, A. Physical Review A, Vol. 46, Issue 6 https://doi.org/10.1103/PhysRevA.46.3343	journal	September 1992
Specific-heat spectroscopy of glycerol and propylene glycol near the glass transition Birge, Norman O. Physical Review B, Vol. 34, Issue 3 https://doi.org/10.1103/PhysRevB.34.1631	journal	August 1986
Comparison between frequency-dependent specific heat and dielectric relaxation of glycerol and propylene glycol Ngai, K. L.; Rendell, R. W. Physical Review B, Vol. 41, Issue 1 https://doi.org/10.1103/PhysRevB.41.754	journal	January 1990
Light-scattering spectroscopy of the liquid-glass transition in CaKNO 3 and in the molecular glass Salol: Extended-mode-coupling-theory analysis Cummins, H. Z.; Du, W. M.; Fuchs, M. Physical Review E, Vol. 47, Issue 6 https://doi.org/10.1103/PhysRevE.47.4223	journal	June 1993
Fast dynamics of glass-forming glycerol Wuttke, J.; Petry, W.; Coddens, G. Physical Review E, Vol. 52, Issue 4 https://doi.org/10.1103/PhysRevE.52.4026	journal	October 1995
Origin of depolarized light scattering in supercooled liquids: Orientational fluctuation versus induced scattering mechanisms Cummins, H. Z.; Li, Gen; Du, Weimin Physical Review E, Vol. 53, Issue 1 https://doi.org/10.1103/PhysRevE.53.896	journal	January 1996
Mode coupling approach to the ideal glass transition of molecular liquids: Linear molecules Schilling, Rolf; Scheidsteger, Thomas Physical Review E, Vol. 56, Issue 3 https://doi.org/10.1103/PhysRevE.56.2932	journal	September 1997
Broadband dielectric spectroscopy on glass-forming propylene carbonate Schneider, U.; Lunkenheimer, P.; Brand, R. Physical Review E, Vol. 59, Issue 6 https://doi.org/10.1103/PhysRevE.59.6924	journal	June 1999
Light-scattering study of a supercooled epoxy resin Comez, L.; Fioretto, D.; Palmieri, L. Physical Review E, Vol. 60, Issue 3 https://doi.org/10.1103/PhysRevE.60.3086	journal	September 1999
Propylene carbonate reexamined: Mode-coupling β scaling without factorization? Wuttke, J.; Ohl, M.; Goldammer, M. Physical Review E, Vol. 61, Issue 3 https://doi.org/10.1103/PhysRevE.61.2730	journal	March 2000
Universal and nonuniversal features of glassy relaxation in propylene carbonate Götze, W.; Voigtmann, Th. Physical Review E, Vol. 61, Issue 4 https://doi.org/10.1103/PhysRevE.61.4133	journal	April 2000
Glassy dynamics under superhigh pressure Pronin, A. A.; Kondrin, M. V.; Lyapin, A. G. Physical Review E, Vol. 81, Issue 4 https://doi.org/10.1103/PhysRevE.81.041503	journal	April 2010
Glassy relaxation and excess wing in mode-coupling theory: The dynamic susceptibility of propylene carbonate above and below T c Domschke, Markus; Marsilius, Mie; Blochowicz, Thomas Physical Review E, Vol. 84, Issue 3 https://doi.org/10.1103/PhysRevE.84.031506	journal	September 2011
Ions in glass-forming glycerol: Close correlation of primary and fast β relaxation Köhler, M.; Lunkenheimer, P.; Goncharov, Y. Physical Review E, Vol. 87, Issue 6 https://doi.org/10.1103/PhysRevE.87.062320	journal	June 2013
Neutron and light scattering study of supercooled glycerol Wuttke, J.; Hernandez, J.; Li, G. Physical Review Letters, Vol. 72, Issue 19 https://doi.org/10.1103/PhysRevLett.72.3052	journal	May 1994
Is There an Excess Wing in the Dielectric Loss of Plastic Crystals? Brand, R.; Lunkenheimer, P.; Schneider, U. Physical Review Letters, Vol. 82, Issue 9 https://doi.org/10.1103/PhysRevLett.82.1951	journal	March 1999
Mesoscopic Mean-Field Theory for Supercooled Liquids and the Glass Transition Chamberlin, R. V. Physical Review Letters, Vol. 82, Issue 12 https://doi.org/10.1103/PhysRevLett.82.2520	journal	March 1999
Excess Wing in the Dielectric Loss of Glass Formers: A Johari-Goldstein β Relaxation? Schneider, U.; Brand, R.; Lunkenheimer, P. Physical Review Letters, Vol. 84, Issue 24 https://doi.org/10.1103/PhysRevLett.84.5560	journal	June 2000
From Strong to Fragile Glass Formers: Secondary Relaxation in Polyalcohols Döß, A.; Paluch, M.; Sillescu, H. Physical Review Letters, Vol. 88, Issue 9 https://doi.org/10.1103/PhysRevLett.88.095701	journal	February 2002
Origin of the High-Frequency Contributions to the Dielectric Loss in Supercooled Liquids Hensel-Bielowka, S.; Paluch, M. Physical Review Letters, Vol. 89, Issue 2 https://doi.org/10.1103/PhysRevLett.89.025704	journal	June 2002
Nearly Logarithmic Decay of Correlations in Glass-Forming Liquids Götze, W.; Sperl, M. Physical Review Letters, Vol. 92, Issue 10 https://doi.org/10.1103/PhysRevLett.92.105701	journal	March 2004
Beta Relaxation versus High Frequency Wing in the Dielectric Spectra of a Binary Molecular Glass Former Blochowicz, T.; Rössler, E. A. Physical Review Letters, Vol. 92, Issue 22 https://doi.org/10.1103/PhysRevLett.92.225701	journal	June 2004
Anelastic to Plastic Transition in Metallic Glass-Forming Liquids Harmon, John S.; Demetriou, Marios D.; Johnson, William L. Physical Review Letters, Vol. 99, Issue 13 https://doi.org/10.1103/PhysRevLett.99.135502	journal	September 2007
A Topographic View of Supercooled Liquids and Glass Formation Stillinger, F. H. Science, Vol. 267, Issue 5206 https://doi.org/10.1126/science.267.5206.1935	journal	March 1995
Light scattering and dielectric manifestations of secondary relaxations in molecular glassformers Brodin, A.; Bergman, R.; Mattsson, J. The European Physical Journal B - Condensed Matter, Vol. 36, Issue 3 https://doi.org/10.1140/epjb/e2003-00353-6	journal	December 2003
Dielectric and conductivity relaxation in mixtures of glycerol with LiCl Köhler, M.; Lunkenheimer, P.; Loidl, A. The European Physical Journal E, Vol. 27, Issue 2 https://doi.org/10.1140/epje/i2008-10357-8	journal	August 2008
S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS Ediger, M. D. Annual Review of Physical Chemistry, Vol. 51, Issue 1 https://doi.org/10.1146/annurev.physchem.51.1.99	journal	October 2000
High-frequency asymptotic shape of the primary relaxation in supercooled liquids Leheny, R. L.; Nagel, S. R. Europhysics Letters (EPL), Vol. 39, Issue 4 https://doi.org/10.1209/epl/i1997-00375-2	journal	August 1997
Glassy Dynamics Under Superhigh Pressure Pronin, A. A.; Kondrin, M. V.; Lyapin, A. G. arXiv https://doi.org/10.48550/arxiv.0911.3496	text	January 2009
Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols Bauer, S.; Burlafinger, K.; Gainaru, C. arXiv https://doi.org/10.48550/arxiv.1301.4852	text	January 2013
Universal and non-universal features of glassy relaxation in propylene carbonate Gotze, W.; Voigtmann, Th. arXiv https://doi.org/10.48550/arxiv.cond-mat/0001188	text	January 2000

Cited By (6)

Hydrodynamic instabilities, waves and turbulence in spreading epithelia Blanch-Mercader, C.; Casademunt, J. Soft Matter, Vol. 13, Issue 38 https://doi.org/10.1039/c7sm01128h	journal	January 2017
A new ultrasonic transducer sample cell for in situ small-angle scattering experiments Gupta, Sudipta; Bleuel, Markus; Schneider, Gerald J. Review of Scientific Instruments, Vol. 89, Issue 1 https://doi.org/10.1063/1.5021370	journal	January 2018
Exponential trajectories, cell size fluctuations and the adder property in bacteria follow from simple chemical dynamics and division control Pandey, Parth Pratim; Singh, Harshant; Jain, Sanjay bioRxiv https://doi.org/10.1101/487504	posted_content	December 2018
Exponential trajectories, cell size fluctuations, and the adder property in bacteria follow from simple chemical dynamics and division control Pandey, Parth Pratim; Singh, Harshant; Jain, Sanjay Physical Review E, Vol. 101, Issue 6 https://doi.org/10.1103/PhysRevE.101.062406	journal	June 2020
Effects of Magnetic and Kinetic Helicities on the Growth of Magnetic Fields in Laminar and Turbulent Flows by Helical Fourier Decomposition Linkmann, Moritz; Sahoo, Ganapati; McKay, Mairi The Astrophysical Journal, Vol. 836, Issue 1 https://doi.org/10.3847/1538-4357/836/1/26	journal	February 2017
Effects of magnetic and kinetic helicities on the growth of magnetic fields in laminar and turbulent flows by helical-Fourier decomposition Linkmann, Moritz; Sahoo, Ganapati; McKay, Mairi arXiv https://doi.org/10.48550/arxiv.1609.01781	text	January 2016

Similar Records

Effect of adding nanometre-sized heterogeneities on the structural dynamics and the excess wing of a molecular glass former

Journal Article · Tue Oct 11 04:00:00 UTC 2016 · Scientific Reports · OSTI ID:1624863

Gupta, S.; Fischer, J. K. H.; Lunkenheimer, P.; +4 more

Dielectric spectroscopy at high frequencies on glass forming liquids

Book · Wed Dec 31 04:00:00 UTC 1997 · OSTI ID:580850

Lunkenheimer, P; Pimenov, A; Dressel, M; +5 more

Fundamental Link between β Relaxation, Excess Wings, and Cage-Breaking in Metallic Glasses

Journal Article · Fri Sep 21 04:00:00 UTC 2018 · Journal of Physical Chemistry Letters · OSTI ID:1478229

Yu, Hai -Bin; Yang, Meng -Hao; Sun, Yang; +6 more

Related Subjects

73 NUCLEAR PHYSICS AND RADIATION PHYSICS

Title: Excess wing in glass-forming glycerol and LiCl-glycerol mixtures detected by neutron scattering

Citation Formats

References (58)

Cited By (6)

Similar Records

Related Subjects