DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation

Abstract

In the cores of pressurized water nuclear reactors, water-flow induced vibration is known to cause claddings on the fuel rods to rub against their supporting grids. Such grid-to-rod-fretting (GTRF) may lead to fretting wear-through and the leakage of radioactive species. The surfaces of actual zirconium alloy claddings in a reactor are inevitably oxidized in the high-temperature pressurized water, and some claddings are even pre-oxidized. As a result, the wear process of the surface oxide film is expected to be quite different from the zirconium alloy substrate. In this paper, we attempt to measure the wear coefficients of zirconium claddings without and with pre-oxidation rubbing against grid samples using a bench-scale fretting tribometer. Results suggest that the volumetric wear coefficient of the pre-oxidized cladding is 50 to 200 times lower than that of the untreated cladding. In terms of the linear rate of wear depth, the pre-oxidized alloy wears about 15 times more slowly than the untreated cladding. Finally, fitted with the experimentally-determined wear rates, a stage-wise GTRF engineering wear model demonstrates good agreement with in-reactor experience in predicting the trend of cladding lives.

Authors:
 [1];  [1];  [1];  [2];  [3]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  2. Westinghouse Electric Company, Hopkins, SC (United States)
  3. Blau Tribology Consulting, Enka, NC (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1261283
Alternate Identifier(s):
OSTI ID: 1359968
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Wear
Additional Journal Information:
Journal Volume: 356-357; Journal ID: ISSN 0043-1648
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS; grid-to-rod-fretting (GTRF); nuclear zirconium claddings; wear coefficient; pre-oxidation; stage-wise wear model

Citation Formats

Qu, Jun, Cooley, Kevin M., Shaw, Austin H., Lu, Roger Y., and Blau, Peter J. Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation. United States: N. p., 2016. Web. doi:10.1016/j.wear.2016.02.020.
Qu, Jun, Cooley, Kevin M., Shaw, Austin H., Lu, Roger Y., & Blau, Peter J. Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation. United States. https://doi.org/10.1016/j.wear.2016.02.020
Qu, Jun, Cooley, Kevin M., Shaw, Austin H., Lu, Roger Y., and Blau, Peter J. Wed . "Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation". United States. https://doi.org/10.1016/j.wear.2016.02.020. https://www.osti.gov/servlets/purl/1261283.
@article{osti_1261283,
title = {Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation},
author = {Qu, Jun and Cooley, Kevin M. and Shaw, Austin H. and Lu, Roger Y. and Blau, Peter J.},
abstractNote = {In the cores of pressurized water nuclear reactors, water-flow induced vibration is known to cause claddings on the fuel rods to rub against their supporting grids. Such grid-to-rod-fretting (GTRF) may lead to fretting wear-through and the leakage of radioactive species. The surfaces of actual zirconium alloy claddings in a reactor are inevitably oxidized in the high-temperature pressurized water, and some claddings are even pre-oxidized. As a result, the wear process of the surface oxide film is expected to be quite different from the zirconium alloy substrate. In this paper, we attempt to measure the wear coefficients of zirconium claddings without and with pre-oxidation rubbing against grid samples using a bench-scale fretting tribometer. Results suggest that the volumetric wear coefficient of the pre-oxidized cladding is 50 to 200 times lower than that of the untreated cladding. In terms of the linear rate of wear depth, the pre-oxidized alloy wears about 15 times more slowly than the untreated cladding. Finally, fitted with the experimentally-determined wear rates, a stage-wise GTRF engineering wear model demonstrates good agreement with in-reactor experience in predicting the trend of cladding lives.},
doi = {10.1016/j.wear.2016.02.020},
journal = {Wear},
number = ,
volume = 356-357,
place = {United States},
year = {Wed Mar 16 00:00:00 EDT 2016},
month = {Wed Mar 16 00:00:00 EDT 2016}
}

Journal Article:

Citation Metrics:
Cited by: 24 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Compliance of Elastic Bodies in Contact
journal, September 1949

  • Mindlin, R. D.
  • Journal of Applied Mechanics, Vol. 16, Issue 3
  • DOI: 10.1115/1.4009973

The third-body approach: A mechanical view of wear
journal, December 1984


On fretting maps
journal, September 1988


Slip Index: A New Unified Approach to Fretting
journal, October 2004


The study on grid-to-rod fretting wear models for PWR fuel
journal, December 2009


On the fretting wear mechanism of Zr-alloys
journal, October 2006


Wear and fretting wear behaviour of ion-implanted Zircaloy-4
journal, September 1996


Deposition and properties of zirconia coatings on a zirconium alloy produced by pulsed DC plasma electrolytic oxidation
journal, April 2013


A multi-stage wear model for grid-to-rod fretting of nuclear fuel rods
journal, May 2014


Effects of Loading Conditions and Types of Motion on PWR Fuel Rod Cladding Wear
conference, June 2008

  • Joulin, T. P.; Gue´rout, F. M.; Lina, A.
  • ASME 2002 International Mechanical Engineering Congress and Exposition, 5th International Symposium on Fluid Structure Interaction, Aeroelasticity, and Flow Induced Vibration and Noise
  • DOI: 10.1115/IMECE2002-32837

Waterside corrosion in zirconium alloys
journal, August 2011


Fretting-wear of zirconium alloys
journal, April 2002

  • Fisher, Nigel J.; Weckwerth, Murray K.; Grandison, Dwight A. E.
  • Nuclear Engineering and Design, Vol. 213, Issue 1
  • DOI: 10.1016/S0029-5493(02)00035-3

Comparative study on rod fretting behavior of different spacer spring geometries
journal, January 2009


Works referencing / citing this record:

Tribological properties of microarc oxidation coatings on Zirlo alloy
journal, February 2019