Structural properties of Sb2S3 under pressure: Evidence of an electronic topological transition
Abstract
High-pressure Raman spectroscopy and x-ray diffraction of Sb2S3 up to 53 GPa reveals two phase transitions at 5 GPa and 15 GPa. The first transition is evidenced by noticeable compressibility changes in distinct Raman-active modes, in the lattice parameter axial ratios, the unit cell volume, as well as in specific interatomic bond lengths and bond angles. By taking into account relevant results from the literature, we assign these effects to a second-order isostructural transition arising from an electronic topological transition in Sb2S3 near 5 GPa. Close comparison between Sb2S3 and Sb2S3 up to 10 GPa reveals a slightly diverse structural behavior for these two compounds after the isostructural transition pressure. This structural diversity appears to account for the different pressure-induced electronic behavior of Sb2S3 and Sb2S3 up to 10 GPa, i.e. the absence of an insulator-metal transition in Sb2S3 up to that pressure. Lastly, the second high-pressure modification appearing above 15 GPa appears to trigger a structural disorder at ~20 GPa; full decompression from 53 GPa leads to the recovery of an amorphous state.
- Authors:
-
- Oakland Univ., Rochester, MI (United States); Helmholtz-Zentrum Potsdam, Potsdam (Germany)
- Oakland Univ., Rochester, MI (United States)
- Publication Date:
- Research Org.:
- Carnegie Institute of Washington, Washington, DC (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1255814
- Grant/Contract Number:
- FG02-99ER45775
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; structure of solids and liquids; topological insulators
Citation Formats
Efthimiopoulos, Ilias, Buchan, Cienna, and Wang, Yuejian. Structural properties of Sb2S3 under pressure: Evidence of an electronic topological transition. United States: N. p., 2016.
Web. doi:10.1038/srep24246.
Efthimiopoulos, Ilias, Buchan, Cienna, & Wang, Yuejian. Structural properties of Sb2S3 under pressure: Evidence of an electronic topological transition. United States. https://doi.org/10.1038/srep24246
Efthimiopoulos, Ilias, Buchan, Cienna, and Wang, Yuejian. Wed .
"Structural properties of Sb2S3 under pressure: Evidence of an electronic topological transition". United States. https://doi.org/10.1038/srep24246. https://www.osti.gov/servlets/purl/1255814.
@article{osti_1255814,
title = {Structural properties of Sb2S3 under pressure: Evidence of an electronic topological transition},
author = {Efthimiopoulos, Ilias and Buchan, Cienna and Wang, Yuejian},
abstractNote = {High-pressure Raman spectroscopy and x-ray diffraction of Sb2S3 up to 53 GPa reveals two phase transitions at 5 GPa and 15 GPa. The first transition is evidenced by noticeable compressibility changes in distinct Raman-active modes, in the lattice parameter axial ratios, the unit cell volume, as well as in specific interatomic bond lengths and bond angles. By taking into account relevant results from the literature, we assign these effects to a second-order isostructural transition arising from an electronic topological transition in Sb2S3 near 5 GPa. Close comparison between Sb2S3 and Sb2S3 up to 10 GPa reveals a slightly diverse structural behavior for these two compounds after the isostructural transition pressure. This structural diversity appears to account for the different pressure-induced electronic behavior of Sb2S3 and Sb2S3 up to 10 GPa, i.e. the absence of an insulator-metal transition in Sb2S3 up to that pressure. Lastly, the second high-pressure modification appearing above 15 GPa appears to trigger a structural disorder at ~20 GPa; full decompression from 53 GPa leads to the recovery of an amorphous state.},
doi = {10.1038/srep24246},
journal = {Scientific Reports},
number = ,
volume = 6,
place = {United States},
year = {Wed Apr 06 00:00:00 EDT 2016},
month = {Wed Apr 06 00:00:00 EDT 2016}
}
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