Spontaneous liquid crystal and ferromagnetic ordering of colloidal magnetic nanoplates

Shuai, M.; Klittnick, A.; Shen, Y.; Smith, G. P.; Tuchband, M. R.; Zhu, C.; Petschek, R. G.; Mertelj, A.; Lisjak, D.; Čopič, M.; Maclennan, J. E.; Glaser, M. A.; Clark, N. A.

doi:10.1038/ncomms10394

Title: Spontaneous liquid crystal and ferromagnetic ordering of colloidal magnetic nanoplates

Journal Article · Wed Jan 27 23:00:00 EST 2016 · Nature Communications

DOI: https://doi.org/10.1038/ncomms10394 · OSTI ID:1255545

Shuai, M. ^[1]; Klittnick, A. ^[1]; Shen, Y. ^[1]; Smith, G. P. ^[1]; Tuchband, M. R. ^[1]; Zhu, C. ^[2]; Petschek, R. G. ^[3]; Mertelj, A. ^[4]; Lisjak, D. ^[4]; Čopič, M. ^[5]; Maclennan, J. E. ^[1]; Glaser, M. A. ^[1]; Clark, N. A. ^[1]

Univ. of Colorado, Boulder, CO (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Case Western Reserve Univ., Cleveland, OH (United States)
Jozef Stefan Inst. (IJS), Ljubljana (Slovenia)
Jozef Stefan Inst. (IJS), Ljubljana (Slovenia); Univ. of Ljubljana, Ljubljana (Slovenia)

Ferrofluids are familiar as colloidal suspensions of ferromagnetic nanoparticles in aqueous or organic solvents. The dispersed particles are randomly oriented but their moments become aligned if a magnetic field is applied, producing a variety of exotic and useful magnetomechanical effects. A longstanding interest and challenge has been to make such suspensions macroscopically ferromagnetic, that is having uniform magnetic alignment in the absence of a field. Here we report a fluid suspension of magnetic nanoplates that spontaneously aligns into an equilibrium nematic liquid crystal phase that is also macroscopically ferromagnetic. We find Its zero-field magnetization produces distinctive magnetic self-interaction effects, including liquid crystal textures of fluid block domains arranged in closed flux loops, and makes this phase highly sensitive, with it dramatically changing shape even in the Earth’s magnetic field.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1255545

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 7; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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