Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation

Szanyi, János; Kwak, Ja Hun

doi:10.1016/j.molcata.2015.05.025

Title: Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation

Authors:: Szanyi, János; Kwak, Ja Hun

Publication Date:: Tue Sep 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1252825

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Molecular Catalysis A: Chemical

Additional Journal Information:: Journal Name: Journal of Molecular Catalysis A: Chemical Journal Volume: 406 Journal Issue: C; Journal ID: ISSN 1381-1169

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Szanyi, János, and Kwak, Ja Hun. Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.molcata.2015.05.025.

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                    Szanyi, János, & Kwak, Ja Hun. Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation.  Netherlands.  https://doi.org/10.1016/j.molcata.2015.05.025

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                    Szanyi, János, and Kwak, Ja Hun. Tue .  
"Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation".  Netherlands.  https://doi.org/10.1016/j.molcata.2015.05.025.

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@article{osti_1252825,

  title        = {Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation},

  author       = {Szanyi, János and Kwak, Ja Hun},

  abstractNote = {},

  doi          = {10.1016/j.molcata.2015.05.025},

  journal      = {Journal of Molecular Catalysis A: Chemical},

  number       = C,

  volume       = 406,

  place        = {Netherlands},

  year         = {Tue Sep 01 00:00:00 EDT 2015},

  month        = {Tue Sep 01 00:00:00 EDT 2015}

}

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Works referenced in this record:

Product selectivity during methanol decomposition on titania powders
journal, January 1988

Taylor, E. A.; Griffin, G. L.
The Journal of Physical Chemistry, Vol. 92, Issue 2
DOI: 10.1021/j100313a046

Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972

Fujishima, Akira; Honda, Kenichi
Nature, Vol. 238, Issue 5358, p. 37-38
DOI: 10.1038/238037a0

Photooxidation Mechanism of Methanol on Rutile TiO ₂ Nanoparticles
journal, March 2012

Panayotov, Dimitar A.; Burrows, Steven P.; Morris, John R.
The Journal of Physical Chemistry C, Vol. 116, Issue 11
DOI: 10.1021/jp209215c

Environmental Applications of Semiconductor Photocatalysis
journal, January 1995

Hoffmann, Michael R.; Martin, Scot T.; Choi, Wonyong.
Chemical Reviews, Vol. 95, Issue 1
DOI: 10.1021/cr00033a004

In Situ FT-IR Spectroscopic Study of CO ₂ and CO Adsorption on Y ₂ O ₃ , ZrO ₂ , and Yttria-Stabilized ZrO ₂
journal, August 2013

Köck, Eva-Maria; Kogler, Michaela; Bielz, Thomas
The Journal of Physical Chemistry C, Vol. 117, Issue 34
DOI: 10.1021/jp405625x

Acetone and Water on TiO ₂ (110): Competition for Sites
journal, March 2005

Henderson, Michael A.
Langmuir, Vol. 21, Issue 8
DOI: 10.1021/la0476579

Localized Partial Oxidation of Acetic Acid at the Dual Perimeter Sites of the Au/TiO ₂ Catalyst—Formation of Gold Ketenylidene
journal, August 2012

Green, Isabel Xiaoye; Tang, Wenjie; Neurock, Matthew
Journal of the American Chemical Society, Vol. 134, Issue 33
DOI: 10.1021/ja305911e

Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
journal, May 1995

Linsebigler, Amy L.; Lu, Guangquan.; Yates, John T.
Chemical Reviews, Vol. 95, Issue 3
DOI: 10.1021/cr00035a013

A surface science perspective on TiO2 photocatalysis
journal, June 2011

Henderson, Michael A.
Surface Science Reports, Vol. 66, Issue 6-7
DOI: 10.1016/j.surfrep.2011.01.001

Effect of Irradiation Sources and Oxygen Concentration on the Photocatalytic Oxidation of 2-Propanol and Acetone Studied by in Situ FTIR
journal, May 2003

Xu, Weizong; Raftery, Daniel; Francisco, Joseph S.
The Journal of Physical Chemistry B, Vol. 107, Issue 19
DOI: 10.1021/jp025995h

Photoreaction of the Rutile TiO ₂ (011) Single-Crystal Surface: Reaction with Acetic Acid
journal, February 2010

Quah, E. L.; Wilson, J. N.; Idriss, H.
Langmuir, Vol. 26, Issue 9
DOI: 10.1021/la9040985

FTIR study of adsorption and photoreactions of acetic acid on TiO2
journal, January 2001

Liao, Li-Fen; Lien, Chen-Fu; Lin, Jong-Liang
Physical Chemistry Chemical Physics, Vol. 3, Issue 17
DOI: 10.1039/b103419g

Relationship of O ₂ Photodesorption in Photooxidation of Acetone on TiO ₂
journal, July 2008

Henderson, Michael A.
The Journal of Physical Chemistry C, Vol. 112, Issue 30
DOI: 10.1021/jp802551x

Photochemistry of Methanol and Methoxy Groups Adsorbed on Powdered TiO ₂
journal, April 1999

Chuang, Chih-Chung; Chen, Chih-Cheng; Lin, Jong-Liang
The Journal of Physical Chemistry B, Vol. 103, Issue 13
DOI: 10.1021/jp983750s

Dynamic phenomena during the photocatalytic oxidation of ethanol and acetone over nanocrystalline TiO2: simultaneous FTIR analysis of gas and surface species
journal, October 2003

Coronado, Juan M.; Kataoka, Sho; Tejedor-Tejedor, Isabel
Journal of Catalysis, Vol. 219, Issue 1
DOI: 10.1016/S0021-9517(03)00199-4

Effect of coadsorbed water on the photodecomposition of acetone on TiO2(110)
journal, June 2008

Henderson, M.
Journal of Catalysis, Vol. 256, Issue 2
DOI: 10.1016/j.jcat.2008.03.020

Photochemistry of the Indoor Air Pollutant Acetone on Degussa P25 TiO₂ Studied by Chemical Ionization Mass Spectrometry
journal, November 2007

Schmidt, Catherine M.; Buchbinder, Avram M.; Weitz, Eric
The Journal of Physical Chemistry A, Vol. 111, Issue 50
DOI: 10.1021/jp076745+

TiO2 photocatalysis and related surface phenomena
journal, December 2008

Fujishima, A.; Zhang, X.; Tryk, D.
Surface Science Reports, Vol. 63, Issue 12
DOI: 10.1016/j.surfrep.2008.10.001

Dissecting the steps of CO ₂ reduction: 1. The interaction of CO and CO ₂ with γ-Al ₂ O ₃ : an in situ FTIR study
journal, January 2014

Szanyi, János; Kwak, Ja Hun
Phys. Chem. Chem. Phys., Vol. 16, Issue 29
DOI: 10.1039/C4CP00616J

Photooxidation of Acetone on TiO ₂ (110): Conversion to Acetate via Methyl Radical Ejection
journal, June 2005

Henderson, Michael A.
The Journal of Physical Chemistry B, Vol. 109, Issue 24
DOI: 10.1021/jp0507546

Adsorption and photo-oxidation of acetaldehyde on TiO2 and sulfate-modified TiO2: Studies by in situ FTIR spectroscopy and micro-kinetic modeling
journal, November 2013

Topalian, Z.; Stefanov, B. I.; Granqvist, C. G.
Journal of Catalysis, Vol. 307
DOI: 10.1016/j.jcat.2013.08.004

Adsorption of formic acid on rutile TiO ₂ (110) revisited: An infrared reflection-absorption spectroscopy and density functional theory study
journal, January 2014

Mattsson, A.; Hu, Shuanglin; Hermansson, K.
The Journal of Chemical Physics, Vol. 140, Issue 3
DOI: 10.1063/1.4855176

Ethyl radical ejection during photodecomposition of butanone on TiO2(110)
journal, October 2008

Henderson, Michael A.
Surface Science, Vol. 602, Issue 20
DOI: 10.1016/j.susc.2007.06.079

Adsorption and Photocatalytic Oxidation of Acetone on TiO2: An in Situ Transmission FT-IR Study
journal, April 2000

El-Maazawi, M.; Finken, A. N.; Nair, A. B.
Journal of Catalysis, Vol. 191, Issue 1
DOI: 10.1006/jcat.1999.2794

Adsorbed Species of CO ₂ and H ₂ on Ga ₂ O ₃ for the Photocatalytic Reduction of CO ₂
journal, April 2010

Tsuneoka, Hideo; Teramura, Kentaro; Shishido, Tetsuya
The Journal of Physical Chemistry C, Vol. 114, Issue 19
DOI: 10.1021/jp910835k

Heterogeneous photocatalysis
journal, January 1993

Fox, Marye Anne.; Dulay, Maria T.
Chemical Reviews, Vol. 93, Issue 1
DOI: 10.1021/cr00017a016

Acetone Chemistry on Oxidized and Reduced TiO ₂ (110)
journal, December 2004

Henderson, Michael A.
The Journal of Physical Chemistry B, Vol. 108, Issue 49
DOI: 10.1021/jp046357x

Abatement of volatile organic compounds using an annular photocatalytic reactor: Study of gaseous acetone
journal, June 2008

Vincent, G.; Marquaire, P. M.; Zahraa, O.
Journal of Photochemistry and Photobiology A: Chemistry, Vol. 197, Issue 2-3
DOI: 10.1016/j.jphotochem.2007.12.021

Vibrational Spectroscopic Observation of Weakly Bound Adsorbed Molecular Oxygen on Powdered Titanium Dioxide
journal, June 2010

Green, Isabel Xiaoye; Yates, John T.
The Journal of Physical Chemistry C, Vol. 114, Issue 27
DOI: 10.1021/jp103574t

Acetone and Water on TiO ₂ (110): H/D Exchange
journal, March 2005

Henderson, Michael A.
Langmuir, Vol. 21, Issue 8
DOI: 10.1021/la0476581

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Title: Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation

Citation Formats

Product selectivity during methanol decomposition on titania powders journal, January 1988

Electrochemical Photolysis of Water at a Semiconductor Electrode journal, July 1972

Photooxidation Mechanism of Methanol on Rutile TiO 2 Nanoparticles journal, March 2012

Environmental Applications of Semiconductor Photocatalysis journal, January 1995

In Situ FT-IR Spectroscopic Study of CO 2 and CO Adsorption on Y 2 O 3 , ZrO 2 , and Yttria-Stabilized ZrO 2 journal, August 2013

Acetone and Water on TiO 2 (110): Competition for Sites journal, March 2005

Localized Partial Oxidation of Acetic Acid at the Dual Perimeter Sites of the Au/TiO 2 Catalyst—Formation of Gold Ketenylidene journal, August 2012

Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results journal, May 1995

A surface science perspective on TiO2 photocatalysis journal, June 2011

Effect of Irradiation Sources and Oxygen Concentration on the Photocatalytic Oxidation of 2-Propanol and Acetone Studied by in Situ FTIR journal, May 2003

Photoreaction of the Rutile TiO 2 (011) Single-Crystal Surface: Reaction with Acetic Acid journal, February 2010

FTIR study of adsorption and photoreactions of acetic acid on TiO2 journal, January 2001

Relationship of O 2 Photodesorption in Photooxidation of Acetone on TiO 2 journal, July 2008

Photochemistry of Methanol and Methoxy Groups Adsorbed on Powdered TiO 2 journal, April 1999

Dynamic phenomena during the photocatalytic oxidation of ethanol and acetone over nanocrystalline TiO2: simultaneous FTIR analysis of gas and surface species journal, October 2003

Effect of coadsorbed water on the photodecomposition of acetone on TiO2(110) journal, June 2008

Photochemistry of the Indoor Air Pollutant Acetone on Degussa P25 TiO2 Studied by Chemical Ionization Mass Spectrometry journal, November 2007

TiO2 photocatalysis and related surface phenomena journal, December 2008

Dissecting the steps of CO 2 reduction: 1. The interaction of CO and CO 2 with γ-Al 2 O 3 : an in situ FTIR study journal, January 2014

Photooxidation of Acetone on TiO 2 (110): Conversion to Acetate via Methyl Radical Ejection journal, June 2005

Adsorption and photo-oxidation of acetaldehyde on TiO2 and sulfate-modified TiO2: Studies by in situ FTIR spectroscopy and micro-kinetic modeling journal, November 2013

Adsorption of formic acid on rutile TiO 2 (110) revisited: An infrared reflection-absorption spectroscopy and density functional theory study journal, January 2014

Ethyl radical ejection during photodecomposition of butanone on TiO2(110) journal, October 2008

Adsorption and Photocatalytic Oxidation of Acetone on TiO2: An in Situ Transmission FT-IR Study journal, April 2000

Adsorbed Species of CO 2 and H 2 on Ga 2 O 3 for the Photocatalytic Reduction of CO 2 journal, April 2010

Heterogeneous photocatalysis journal, January 1993

Acetone Chemistry on Oxidized and Reduced TiO 2 (110) journal, December 2004

Abatement of volatile organic compounds using an annular photocatalytic reactor: Study of gaseous acetone journal, June 2008

Vibrational Spectroscopic Observation of Weakly Bound Adsorbed Molecular Oxygen on Powdered Titanium Dioxide journal, June 2010

Acetone and Water on TiO 2 (110): H/D Exchange journal, March 2005

Product selectivity during methanol decomposition on titania powders
journal, January 1988

Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972

Photooxidation Mechanism of Methanol on Rutile TiO ₂ Nanoparticles
journal, March 2012

Environmental Applications of Semiconductor Photocatalysis
journal, January 1995

In Situ FT-IR Spectroscopic Study of CO ₂ and CO Adsorption on Y ₂ O ₃ , ZrO ₂ , and Yttria-Stabilized ZrO ₂
journal, August 2013

Acetone and Water on TiO ₂ (110): Competition for Sites
journal, March 2005

Localized Partial Oxidation of Acetic Acid at the Dual Perimeter Sites of the Au/TiO ₂ Catalyst—Formation of Gold Ketenylidene
journal, August 2012

Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
journal, May 1995

A surface science perspective on TiO2 photocatalysis
journal, June 2011

Effect of Irradiation Sources and Oxygen Concentration on the Photocatalytic Oxidation of 2-Propanol and Acetone Studied by in Situ FTIR
journal, May 2003

Photoreaction of the Rutile TiO ₂ (011) Single-Crystal Surface: Reaction with Acetic Acid
journal, February 2010

FTIR study of adsorption and photoreactions of acetic acid on TiO2
journal, January 2001

Relationship of O ₂ Photodesorption in Photooxidation of Acetone on TiO ₂
journal, July 2008

Photochemistry of Methanol and Methoxy Groups Adsorbed on Powdered TiO ₂
journal, April 1999

Dynamic phenomena during the photocatalytic oxidation of ethanol and acetone over nanocrystalline TiO2: simultaneous FTIR analysis of gas and surface species
journal, October 2003

Effect of coadsorbed water on the photodecomposition of acetone on TiO2(110)
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journal, November 2007

TiO2 photocatalysis and related surface phenomena
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Heterogeneous photocatalysis
journal, January 1993

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journal, June 2008

Vibrational Spectroscopic Observation of Weakly Bound Adsorbed Molecular Oxygen on Powdered Titanium Dioxide
journal, June 2010

Acetone and Water on TiO ₂ (110): H/D Exchange
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