Investigation of CaO–CO2 reaction kinetics by in-situ XRD using synchrotron radiation

Biasin, A.; Segre, C. U.; Salviulo, G.; Zorzi, F.; Strumendo, M.

doi:10.1016/j.ces.2014.12.058

Title: Investigation of CaO–CO2 reaction kinetics by in-situ XRD using synchrotron radiation

Authors:: Biasin, A.; Segre, C. U.; Salviulo, G.; Zorzi, F.; Strumendo, M.

Publication Date:: Fri May 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1249649

Grant/Contract Number:: AC02-06CH11357; DMR-086935

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Chemical Engineering Science

Additional Journal Information:: Journal Name: Chemical Engineering Science Journal Volume: 127 Journal Issue: C; Journal ID: ISSN 0009-2509

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Biasin, A., Segre, C. U., Salviulo, G., Zorzi, F., and Strumendo, M. Investigation of CaO–CO2 reaction kinetics by in-situ XRD using synchrotron radiation.  United Kingdom: N. p., 2015. 
Web.  doi:10.1016/j.ces.2014.12.058.

Copy to clipboard


                    Biasin, A., Segre, C. U., Salviulo, G., Zorzi, F., & Strumendo, M. Investigation of CaO–CO2 reaction kinetics by in-situ XRD using synchrotron radiation.  United Kingdom.  https://doi.org/10.1016/j.ces.2014.12.058

Copy to clipboard


                    Biasin, A., Segre, C. U., Salviulo, G., Zorzi, F., and Strumendo, M. Fri .  
"Investigation of CaO–CO2 reaction kinetics by in-situ XRD using synchrotron radiation".  United Kingdom.  https://doi.org/10.1016/j.ces.2014.12.058.

Copy to clipboard


                    
@article{osti_1249649,

  title        = {Investigation of CaO–CO2 reaction kinetics by in-situ XRD using synchrotron radiation},

  author       = {Biasin, A. and Segre, C. U. and Salviulo, G. and Zorzi, F. and Strumendo, M.},

  abstractNote = {},

  doi          = {10.1016/j.ces.2014.12.058},

  journal      = {Chemical Engineering Science},

  number       = C,

  volume       = 127,

  place        = {United Kingdom},

  year         = {Fri May 01 00:00:00 EDT 2015},

  month        = {Fri May 01 00:00:00 EDT 2015}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.ces.2014.12.058

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 34 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Influence of Diffusion on Thermogravimetric Analysis of Carbon Black Oxidation
journal, September 2006

Song, Qiang; He, Bailei; Yao, Qiang
Energy & Fuels, Vol. 20, Issue 5
DOI: 10.1021/ef0600659

Diffusional effects in TGA gasification experiments for kinetic determination
journal, October 2002

Ollero, P.
Fuel, Vol. 81, Issue 15
DOI: 10.1016/S0016-2361(02)00126-6

Mathematical modeling of CO2 removal using carbonation with CaO: The grain model
journal, March 2010

Khoshandam, Behnam; Kumar, Ramachandran Vasant; Allahgholi, Leila
Korean Journal of Chemical Engineering, Vol. 27, Issue 3
DOI: 10.1007/s11814-010-0119-5

Calcination and sintering models for application to high-temperature, short-time sulfation of calcium-based sorbents
journal, February 1990

Milne, Corey R.; Silcox, Geoffrey D.; Pershing, David W.
Industrial & Engineering Chemistry Research, Vol. 29, Issue 2
DOI: 10.1021/ie00098a001

A Review of CO2 Capture by Absorption and Adsorption
journal, January 2012

Yu, Cheng-Hsiu; Huang, Chih-Hung; Tan, Chung-Sung
Aerosol and Air Quality Research, Vol. 12, Issue 5
DOI: 10.4209/aaqr.2012.05.0132

Application of the random pore model to the carbonation cyclic reaction
journal, May 2009

Grasa, Gemma; Murillo, Ramón; Alonso, Mónica
AIChE Journal, Vol. 55, Issue 5
DOI: 10.1002/aic.11746

Effect of pore geometry on the sintering of Ca-based sorbents during calcination at high temperatures
journal, September 2004

Fierro, V.; Adánez, J.; Garcı́a-Labiano, F.
Fuel, Vol. 83, Issue 13
DOI: 10.1016/j.fuel.2004.03.011

A kinetic model of nano-CaO reactions with CO2 in a sorption complex catalyst
journal, June 2011

Wu, S. F.; Lan, P. Q.
AIChE Journal, Vol. 58, Issue 5
DOI: 10.1002/aic.12675

An apparent kinetic model for the carbonation of calcium oxide by carbon dioxide
journal, July 2004

Lee, D.
Chemical Engineering Journal, Vol. 100, Issue 1-3
DOI: 10.1016/j.cej.2003.12.003

Advances in CO₂ capture technology—The U.S. Department of Energy's Carbon Sequestration Program
journal, January 2008

Figueroa, José D.; Fout, Timothy; Plasynski, Sean
International Journal of Greenhouse Gas Control, Vol. 2, Issue 1, p. 9-20
DOI: 10.1016/S1750-5836(07)00094-1

Surface area and pore size Changes During Sintering of Calcium Oxide Particles
journal, October 1991

Fuertes, A. B.; Alvarez, D.; Rubiera, F.
Chemical Engineering Communications, Vol. 109, Issue 1
DOI: 10.1080/00986449108910974

Influence of calcination conditions on carrying capacity of CaO-based sorbent in CO2 looping cycles
journal, October 2009

Manovic, Vasilije; Charland, Jean-Pierre; Blamey, John
Fuel, Vol. 88, Issue 10
DOI: 10.1016/j.fuel.2009.04.012

Product Layer Diffusion during the Reaction of Calcium Oxide with Carbon Dioxide
journal, September 1999

Mess, Derek; Sarofim, Adel F.; Longwell, John P.
Energy & Fuels, Vol. 13, Issue 5
DOI: 10.1021/ef980266f

The calcium looping cycle for CO2 capture from power generation, cement manufacture and hydrogen production
journal, June 2011

Dean, C. C.; Blamey, J.; Florin, N. H.
Chemical Engineering Research and Design, Vol. 89, Issue 6
DOI: 10.1016/j.cherd.2010.10.013

Study of Carbonation Reactions of Ca-Mg Oxides for High Temperature Energy Storage and Heat Transformation.
journal, January 1996

Kyaw, Kyaw; Kanamori, Michito; Matsuda, Hitoki
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 29, Issue 1
DOI: 10.1252/jcej.29.112

CO2 capture by solid adsorbents and their applications: current status and new trends
journal, January 2011

Wang, Qiang; Luo, Jizhong; Zhong, Ziyi
Energy Environ. Sci., Vol. 4, Issue 1
DOI: 10.1039/C0EE00064G

A discrete-pore-size-distribution-based gas–solid model and its application to the CaO+CO2 reaction
journal, January 2008

Sun, Ping; Grace, John R.; Lim, C. Jim
Chemical Engineering Science, Vol. 63, Issue 1
DOI: 10.1016/j.ces.2007.08.054

The calcium looping cycle for large-scale CO2 capture
journal, April 2010

Blamey, J.; Anthony, E. J.; Wang, J.
Progress in Energy and Combustion Science, Vol. 36, Issue 2
DOI: 10.1016/j.pecs.2009.10.001

Determination of intrinsic rate constants of the CaO–CO2 reaction
journal, January 2008

Sun, Ping; Grace, John R.; Lim, C. Jim
Chemical Engineering Science, Vol. 63, Issue 1
DOI: 10.1016/j.ces.2007.08.055

Analysis of the kinetic slowing down during carbonation of CaO by CO2
journal, February 2013

Rouchon, Lydie; Favergeon, Loïc; Pijolat, Michèle
Journal of Thermal Analysis and Calorimetry, Vol. 113, Issue 3
DOI: 10.1007/s10973-013-2950-5

The effects of steam and carbon dioxide on calcite decomposition using dynamic X-ray diffraction
journal, May 1995

Wang, Yong; Thomson, William J.
Chemical Engineering Science, Vol. 50, Issue 9
DOI: 10.1016/0009-2509(95)00002-M

Kinetics of the thermal decomposition of CaCo3 in Co2 and some observations on the kinetic compensation effect
journal, March 1976

Gallagher, P. K.; Johnson, D. W.
Thermochimica Acta, Vol. 14, Issue 3
DOI: 10.1016/0040-6031(76)85002-2

Study of Carbonation of CaO for High Temperature Thermal Energy Storage.
journal, January 1998

Kyaw, Kyaw; Kubota, Mitsuhiro; Watanabe, Fujio
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 31, Issue 2
DOI: 10.1252/jcej.31.281

Nano CaO grain characteristics and growth model under calcination
journal, November 2011

Zhu, Yanqing; Wu, Sufang; Wang, Xieqing
Chemical Engineering Journal, Vol. 175
DOI: 10.1016/j.cej.2011.09.084

Modeling of the carbonation kinetics of a synthetic CaO-based sorbent
journal, May 2013

Zhou, Zhiming; Xu, Pan; Xie, Miaomiao
Chemical Engineering Science, Vol. 95
DOI: 10.1016/j.ces.2013.03.047

In situ X-ray diffraction of CaO based CO2 sorbents
journal, January 2012

Molinder, R.; Comyn, T. P.; Hondow, N.
Energy & Environmental Science, Vol. 5, Issue 10
DOI: 10.1039/c2ee21779a

The effect of the CO2 pressure on the thermal decomposition kinetics of calcium carbonate
journal, April 1995

Criado, JoséM.; González, Manuel; Málek, Jirí
Thermochimica Acta, Vol. 254
DOI: 10.1016/0040-6031(94)01998-V

Review—calcination and carbonation of limestone during thermal cycling for CO2 sequestration
journal, November 2005

Stanmore, B. R.; Gilot, P.
Fuel Processing Technology, Vol. 86, Issue 16
DOI: 10.1016/j.fuproc.2005.01.023

The effect of sample preparation on the thermal decomposition of CaCO3
journal, May 1995

Wang, Yong; Thomson, William J.
Thermochimica Acta, Vol. 255
DOI: 10.1016/0040-6031(94)02151-D

Effect of the product layer on the kinetics of the CO2-lime reaction
journal, January 1983

Bhatia, S. K.; Perlmutter, D. D.
AIChE Journal, Vol. 29, Issue 1
DOI: 10.1002/aic.690290111

The Nature of CaO Produced by Calcite Powder Decomposition in Vacuum and in CO2
journal, November 1979

Ewing, Jay; Beruto, Dario; Searcy, Alan W.
Journal of the American Ceramic Society, Vol. 62, Issue 11-12
DOI: 10.1111/j.1151-2916.1979.tb12736.x

Surface area evolution of calcium hydroxide during calcination and sintering
journal, January 1989

Mai, M. C.; Edgar, T. F.
AIChE Journal, Vol. 35, Issue 1
DOI: 10.1002/aic.690350103

The effects of sample size and heating rate on the kinetics of the thermal decomposition of CaCO3
journal, March 1973

Gallagher, P. K.; Johnson, D. W.
Thermochimica Acta, Vol. 6, Issue 1
DOI: 10.1016/0040-6031(73)80007-3

Calcination kinetics and surface area of dispersed limestone particles
journal, January 1985

Borgwardt, R. H.
AIChE Journal, Vol. 31, Issue 1
DOI: 10.1002/aic.690310112

Sintering of nascent calcium oxide
journal, January 1989

H. Borgwardt, Robert
Chemical Engineering Science, Vol. 44, Issue 1
DOI: 10.1016/0009-2509(89)85232-7

Calcium carbonate decomposition
journal, March 2012

Galan, Isabel; Glasser, Fredrik P.; Andrade, Carmen
Journal of Thermal Analysis and Calorimetry, Vol. 111, Issue 2
DOI: 10.1007/s10973-012-2290-x

Crystallite size effect in the sulfidation of ZnO by H2S: Geometric and kinetic modelling of the transformation
journal, September 2012

Babé, Céline; Tayakout-Fayolle, Melaz; Geantet, Christophe
Chemical Engineering Science, Vol. 82
DOI: 10.1016/j.ces.2012.07.026

The effect of CaO sintering on cyclic CO2 capture in energy systems
journal, January 2007

Sun, P.; Grace, J. R.; Lim, C. J.
AIChE Journal, Vol. 53, Issue 9
DOI: 10.1002/aic.11251

Modeling of the carbonation behavior of a calcium based sorbent for CO2 capture
journal, September 2012

Yu, Y. S.; Liu, W. Q.; An, H.
International Journal of Greenhouse Gas Control, Vol. 10
DOI: 10.1016/j.ijggc.2012.07.016

CO2-Catalyzed Surface Area and Porosity Changes in High-Surface-Area CaO Aggregates
journal, July 1984

Beruto, Dario; Barco, Luigi; Searcy, Alan W.
Journal of the American Ceramic Society, Vol. 67, Issue 7
DOI: 10.1111/j.1151-2916.1984.tb19644.x

Method for variation of grain size in studies of gas-solid reactions involving calcium oxide
journal, February 1986

Borgwardt, Robert H.; Roache, Nancy F.; Bruce, Kevin R.
Industrial & Engineering Chemistry Fundamentals, Vol. 25, Issue 1
DOI: 10.1021/i100021a026

A versatile sample-environment cell for non-ambient X-ray scattering experiments
journal, July 2008

Chupas, Peter J.; Chapman, Karena W.; Kurtz, Charles
Journal of Applied Crystallography, Vol. 41, Issue 4
DOI: 10.1107/S0021889808020165

In situ synchrotron X-ray diffraction studies of hydrogen desorption and absorption properties of Mg and Mg–Mm–Ni after reactive ball milling in hydrogen
journal, August 2009

Denys, R. V.; Riabov, A. B.; Maehlen, J. P.
Acta Materialia, Vol. 57, Issue 13
DOI: 10.1016/j.actamat.2009.05.004

CaO-Based CO ₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials
journal, July 2013

Kierzkowska, Agnieszka M.; Pacciani, Roberta; Müller, Christoph R.
ChemSusChem, Vol. 6, Issue 7
DOI: 10.1002/cssc.201300178

Rate Equation Theory for the Carbonation Reaction of CaO with CO ₂
journal, June 2012

Li, Zhenshan; Sun, Hongming; Cai, Ningsheng
Energy & Fuels, Vol. 26, Issue 7
DOI: 10.1021/ef300607z

Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996

Hammersley, A. P.; Svensson, S. O.; Hanfland, M.
High Pressure Research, Vol. 14, Issue 4-6, p. 235-248
DOI: 10.1080/08957959608201408

The effect of procedural variables on TG, DTG and DTA curves of calcium carbonate
journal, September 1991

Wilburn, F. W.; Sharp, J. H.; Tinsley, D. M.
Journal of Thermal Analysis, Vol. 37, Issue 9
DOI: 10.1007/BF01905576

Similar Records in DOE PAGES and OSTI.GOV collections:

Investigation of CaO-CO₂ reaction kinetics by in-situ XRD using synchrotron radiation

Journal Article Biasin, A. ; Segre, C. U. ; Salviulo, G. ; ... - Chem. Eng. Sci.

In this work, in-situ synchrotron radiation x-ray powder diffraction (SR-XRPD), performed at the Advanced Photon Source (APS) facilities of the Argonne National Laboratory, was applied to investigate the CaO–CO₂ reaction. A set of CO₂ absorption experiments were conducted in a high temperature reaction capillary with a controlled atmosphere (CO₂ partial pressure of 1 bar), in the temperature range between 450 °C and 750 °C using CaO based sorbents obtained by calcination of commercial calcium carbonate. The evolution of the crystalline phases during CO₂ uptake by the CaO solid sorbents was monitored for a carbonation time of 20 min as amore »« less
https://doi.org/10.1016/j.ces.2014.12.058
CaCO₃ Crystallite Evolution during CaO Carbonation: Critical Crystallite Size and Rate Constant Measurement by In-Situ Synchrotron Radiation X-ray Powder Diffraction

Journal Article Biasin, A. ; Segre, C. U. ; Strumendo, M. - Crystal Growth and Design

In this work, the evolution of the CaCO₃ crystalline phase during the CaO–CO₂ reaction was investigated by means of in situ synchrotron radiation X-ray powder diffraction performed at the Advanced Photon Source (APS) facilities of the Argonne National Laboratory. CO₂ absorption experiments were carried out in a high temperature reaction capillary with a controlled atmosphere of pure carbon dioxide (CO₂ partial pressure of 1 bar) and in the temperature range between 450 and 750 °C, using CaO-based sorbents obtained by calcination of commercial calcium carbonate. The Rietveld refinement method was applied to estimate the average size of the CaCO₃ crystallitesmore »« less
Cited by 29
https://doi.org/10.1021/acs.cgd.5b00563

Full Text Available
An experimental study of the (Ti-6Al-4V)-xH phase diagram using in situ synchrotron XRD and TGA/DSC techniques.

Journal Article Sun, Pei ; Fang, Z. Zak ; Koopman, Mark ; ... - Acta Materialia

Hydrogen has been investigated for decades as a temporary alloying element to refine the microstructure of Ti-6Al-4V, and is now being used in a novel powder metallurgy method known as "hydrogen sintering and phase transformation". Pseudo-binary phase diagrams of (Ti-6Al-4V)-xH have been studied and developed, but are not well established due to methodological limitations. In this paper, in situ studies of phase transformations during hydrogenation and dehydrogenation of (Ti-6Al-4V)-xH alloys were conducted using high-energy synchrotron X-ray diffraction (XRD), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The eutectoid phase transformation of β ↔ α + δ was observed in themore »« less
https://doi.org/10.1016/j.actamat.2014.10.045
An experimental study of the (Ti–6Al–4V)–xH phase diagram using in situ synchrotron XRD and TGA/DSC techniques

Journal Article Sun, Pei ; Fang, Z. Zak ; Koopman, Mark ; ... - Acta Materialia
Cited by 61
https://doi.org/10.1016/j.actamat.2014.10.045
Investigation of High-Energy Ion-Irradiated MA957 Using Synchrotron Radiation under In-Situ Tension

Journal Article Mo, Kun ; Yun, Di ; Miao, Yinbin ; ... - Materials

In this paper, an MA957 oxide dispersion-strengthened (ODS) alloy was irradiated with high-energy ions in the Argonne Tandem Linac Accelerator System. Fe ions at an energy of 84 MeV bombarded MA957 tensile specimens, creating a damage region similar to 7.5 μm in depth; the peak damage (similar to 40 dpa) was estimated to be at similar to 7 μm from the surface. Following the irradiation, in-situ high-energy X-ray diffraction measurements were performed at the Advanced Photon Source in order to study the dynamic deformation behavior of the specimens after ion irradiation damage. In-situ X-ray measurements taken during tensile testing ofmore »« less
Cited by 10
https://doi.org/10.3390/ma9010015

Similar Records

Title: Investigation of CaO–CO2 reaction kinetics by in-situ XRD using synchrotron radiation

Citation Formats

Influence of Diffusion on Thermogravimetric Analysis of Carbon Black Oxidation journal, September 2006

Diffusional effects in TGA gasification experiments for kinetic determination journal, October 2002

Mathematical modeling of CO2 removal using carbonation with CaO: The grain model journal, March 2010

Calcination and sintering models for application to high-temperature, short-time sulfation of calcium-based sorbents journal, February 1990

A Review of CO2 Capture by Absorption and Adsorption journal, January 2012

Application of the random pore model to the carbonation cyclic reaction journal, May 2009

Effect of pore geometry on the sintering of Ca-based sorbents during calcination at high temperatures journal, September 2004

A kinetic model of nano-CaO reactions with CO2 in a sorption complex catalyst journal, June 2011

An apparent kinetic model for the carbonation of calcium oxide by carbon dioxide journal, July 2004

Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program journal, January 2008

Surface area and pore size Changes During Sintering of Calcium Oxide Particles journal, October 1991

Influence of calcination conditions on carrying capacity of CaO-based sorbent in CO2 looping cycles journal, October 2009

Product Layer Diffusion during the Reaction of Calcium Oxide with Carbon Dioxide journal, September 1999

The calcium looping cycle for CO2 capture from power generation, cement manufacture and hydrogen production journal, June 2011

Study of Carbonation Reactions of Ca-Mg Oxides for High Temperature Energy Storage and Heat Transformation. journal, January 1996

CO2 capture by solid adsorbents and their applications: current status and new trends journal, January 2011

A discrete-pore-size-distribution-based gas–solid model and its application to the CaO+CO2 reaction journal, January 2008

The calcium looping cycle for large-scale CO2 capture journal, April 2010

Determination of intrinsic rate constants of the CaO–CO2 reaction journal, January 2008

Analysis of the kinetic slowing down during carbonation of CaO by CO2 journal, February 2013

The effects of steam and carbon dioxide on calcite decomposition using dynamic X-ray diffraction journal, May 1995

Kinetics of the thermal decomposition of CaCo3 in Co2 and some observations on the kinetic compensation effect journal, March 1976

Study of Carbonation of CaO for High Temperature Thermal Energy Storage. journal, January 1998

Nano CaO grain characteristics and growth model under calcination journal, November 2011

Modeling of the carbonation kinetics of a synthetic CaO-based sorbent journal, May 2013

In situ X-ray diffraction of CaO based CO2 sorbents journal, January 2012

The effect of the CO2 pressure on the thermal decomposition kinetics of calcium carbonate journal, April 1995

Review—calcination and carbonation of limestone during thermal cycling for CO2 sequestration journal, November 2005

The effect of sample preparation on the thermal decomposition of CaCO3 journal, May 1995

Effect of the product layer on the kinetics of the CO2-lime reaction journal, January 1983

The Nature of CaO Produced by Calcite Powder Decomposition in Vacuum and in CO2 journal, November 1979

Surface area evolution of calcium hydroxide during calcination and sintering journal, January 1989

The effects of sample size and heating rate on the kinetics of the thermal decomposition of CaCO3 journal, March 1973

Calcination kinetics and surface area of dispersed limestone particles journal, January 1985

Sintering of nascent calcium oxide journal, January 1989

Calcium carbonate decomposition journal, March 2012

Crystallite size effect in the sulfidation of ZnO by H2S: Geometric and kinetic modelling of the transformation journal, September 2012

The effect of CaO sintering on cyclic CO2 capture in energy systems journal, January 2007

Modeling of the carbonation behavior of a calcium based sorbent for CO2 capture journal, September 2012

CO2-Catalyzed Surface Area and Porosity Changes in High-Surface-Area CaO Aggregates journal, July 1984

Method for variation of grain size in studies of gas-solid reactions involving calcium oxide journal, February 1986

A versatile sample-environment cell for non-ambient X-ray scattering experiments journal, July 2008

In situ synchrotron X-ray diffraction studies of hydrogen desorption and absorption properties of Mg and Mg–Mm–Ni after reactive ball milling in hydrogen journal, August 2009

CaO-Based CO 2 Sorbents: From Fundamentals to the Development of New, Highly Effective Materials journal, July 2013

Rate Equation Theory for the Carbonation Reaction of CaO with CO 2 journal, June 2012

Two-dimensional detector software: From real detector to idealised image or two-theta scan journal, January 1996

The effect of procedural variables on TG, DTG and DTA curves of calcium carbonate journal, September 1991

Influence of Diffusion on Thermogravimetric Analysis of Carbon Black Oxidation
journal, September 2006

Diffusional effects in TGA gasification experiments for kinetic determination
journal, October 2002

Mathematical modeling of CO2 removal using carbonation with CaO: The grain model
journal, March 2010

Calcination and sintering models for application to high-temperature, short-time sulfation of calcium-based sorbents
journal, February 1990

A Review of CO2 Capture by Absorption and Adsorption
journal, January 2012

Application of the random pore model to the carbonation cyclic reaction
journal, May 2009

Effect of pore geometry on the sintering of Ca-based sorbents during calcination at high temperatures
journal, September 2004

A kinetic model of nano-CaO reactions with CO2 in a sorption complex catalyst
journal, June 2011

An apparent kinetic model for the carbonation of calcium oxide by carbon dioxide
journal, July 2004

Advances in CO₂ capture technology—The U.S. Department of Energy's Carbon Sequestration Program
journal, January 2008

Surface area and pore size Changes During Sintering of Calcium Oxide Particles
journal, October 1991

Influence of calcination conditions on carrying capacity of CaO-based sorbent in CO2 looping cycles
journal, October 2009

Product Layer Diffusion during the Reaction of Calcium Oxide with Carbon Dioxide
journal, September 1999

The calcium looping cycle for CO2 capture from power generation, cement manufacture and hydrogen production
journal, June 2011

Study of Carbonation Reactions of Ca-Mg Oxides for High Temperature Energy Storage and Heat Transformation.
journal, January 1996

CO2 capture by solid adsorbents and their applications: current status and new trends
journal, January 2011

A discrete-pore-size-distribution-based gas–solid model and its application to the CaO+CO2 reaction
journal, January 2008

The calcium looping cycle for large-scale CO2 capture
journal, April 2010

Determination of intrinsic rate constants of the CaO–CO2 reaction
journal, January 2008

Analysis of the kinetic slowing down during carbonation of CaO by CO2
journal, February 2013

The effects of steam and carbon dioxide on calcite decomposition using dynamic X-ray diffraction
journal, May 1995

Kinetics of the thermal decomposition of CaCo3 in Co2 and some observations on the kinetic compensation effect
journal, March 1976

Study of Carbonation of CaO for High Temperature Thermal Energy Storage.
journal, January 1998

Nano CaO grain characteristics and growth model under calcination
journal, November 2011

Modeling of the carbonation kinetics of a synthetic CaO-based sorbent
journal, May 2013

In situ X-ray diffraction of CaO based CO2 sorbents
journal, January 2012

The effect of the CO2 pressure on the thermal decomposition kinetics of calcium carbonate
journal, April 1995

Review—calcination and carbonation of limestone during thermal cycling for CO2 sequestration
journal, November 2005

The effect of sample preparation on the thermal decomposition of CaCO3
journal, May 1995

Effect of the product layer on the kinetics of the CO2-lime reaction
journal, January 1983

The Nature of CaO Produced by Calcite Powder Decomposition in Vacuum and in CO2
journal, November 1979

Surface area evolution of calcium hydroxide during calcination and sintering
journal, January 1989

The effects of sample size and heating rate on the kinetics of the thermal decomposition of CaCO3
journal, March 1973

Calcination kinetics and surface area of dispersed limestone particles
journal, January 1985

Sintering of nascent calcium oxide
journal, January 1989

Calcium carbonate decomposition
journal, March 2012

Crystallite size effect in the sulfidation of ZnO by H2S: Geometric and kinetic modelling of the transformation
journal, September 2012

The effect of CaO sintering on cyclic CO2 capture in energy systems
journal, January 2007

Modeling of the carbonation behavior of a calcium based sorbent for CO2 capture
journal, September 2012

CO2-Catalyzed Surface Area and Porosity Changes in High-Surface-Area CaO Aggregates
journal, July 1984

Method for variation of grain size in studies of gas-solid reactions involving calcium oxide
journal, February 1986

A versatile sample-environment cell for non-ambient X-ray scattering experiments
journal, July 2008

In situ synchrotron X-ray diffraction studies of hydrogen desorption and absorption properties of Mg and Mg–Mm–Ni after reactive ball milling in hydrogen
journal, August 2009

CaO-Based CO ₂ Sorbents: From Fundamentals to the Development of New, Highly Effective Materials
journal, July 2013

Rate Equation Theory for the Carbonation Reaction of CaO with CO ₂
journal, June 2012

Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996

The effect of procedural variables on TG, DTG and DTA curves of calcium carbonate
journal, September 1991