A bioorganometallic chemistry perspective: Organometallic chemistry at the interface with biology

Fish, Richard H.

doi:10.1016/j.jorganchem.2014.10.034

Title: A bioorganometallic chemistry perspective: Organometallic chemistry at the interface with biology

Full Record
Other Related Research

Authors:: Fish, Richard H.

Publication Date:: Wed Apr 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1246415

Grant/Contract Number:: DE AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Organometallic Chemistry

Additional Journal Information:: Journal Name: Journal of Organometallic Chemistry Journal Volume: 782 Journal Issue: C; Journal ID: ISSN 0022-328X

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Fish, Richard H. A bioorganometallic chemistry perspective: Organometallic chemistry at the interface with biology.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.jorganchem.2014.10.034.

Copy to clipboard


                    Fish, Richard H. A bioorganometallic chemistry perspective: Organometallic chemistry at the interface with biology.  Netherlands.  https://doi.org/10.1016/j.jorganchem.2014.10.034

Copy to clipboard


                    Fish, Richard H. Wed .  
"A bioorganometallic chemistry perspective: Organometallic chemistry at the interface with biology".  Netherlands.  https://doi.org/10.1016/j.jorganchem.2014.10.034.

Copy to clipboard


                    
@article{osti_1246415,

  title        = {A bioorganometallic chemistry perspective: Organometallic chemistry at the interface with biology},

  author       = {Fish, Richard H.},

  abstractNote = {},

  doi          = {10.1016/j.jorganchem.2014.10.034},

  journal      = {Journal of Organometallic Chemistry},

  number       = C,

  volume       = 782,

  place        = {Netherlands},

  year         = {Wed Apr 01 00:00:00 EDT 2015},

  month        = {Wed Apr 01 00:00:00 EDT 2015}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.jorganchem.2014.10.034

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 11 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Bioorganometallic chemistry: Structural diversity of organmetallic complexes with bioligands, and molecular recognition studies of several supramolecular hosts with biomolecules and alkali metal ions, including a potential organometallic breast cancer drug with estrogen receptor site proteins

Journal Article Fish, Richard H ; Jaouen, Gerard - Organometallics

No abstract prepared.
Full Text Available
Bioorganometallic chemistry. 7. A novel, linear, two-coordinate Rh(I) anionic amide complex formed by the reaction of the nucleobase, 1-methylthymine, with the [(C{sub p} Rh){sub 2}({mu}-OH){sub 3}]{sup +} cation at pH 10. Molecular recognition and electrostatic interaction within an organometallic hydrophobic cavity

Journal Article Chen, H ; Maestre, M F ; Fish, R H ; ... - Journal of the American Chemical Society

Recently authors were able to characterize several ({eta}{sup 5}-pentamethylcyclopentadienyl) rhodium(Cp{sup *}Rh) -cyclic trimer structures with 9-methyladenine 9-ethylhypoxanthine, adenosine, adenosine 3`-, methyl-5`-, and 5`-monophosphates and, in this process, discovered the first examples of molecular recognition by several bioorganometallic Cp{sup *}Rh-cycle trimer nucleobase, nucleoside, and nucleotide hosts with aromatic amino acid guests in H{sub 2}O at pH 7.0. They now extend their bioorganometallic/molecular recognition studies to the nucleobase 1-methylthymine (1-MTH) and describe the synthesis and structural characterization of the first example of a novel, linear, two-coordinate Rh(I) anionic amide complex [Rh({eta}{sup 1},N{sup 3}-1-MT){sub 2}]{sup -} (1), from the reaction of 1-MTH withmore »« less
https://doi.org/10.1021/ja00140a039
Bioorganometallic chemistry. 12. reactions of [Cp*Rh(H2O)3](OTf)2 with nicotinamide adenine dinucleotide in water: Synthesis, structure, and a pH dependent 1H NMR and voltammetric study of the cyclic trimer product, [Cp*Rh(mu-eta1(N1):eta2(N6,N7)-9-(5'-ribose-pyrophosphate-5

Journal Article Ogo, Seiji ; Buriez, Olivier ; Kerr, John B ; ... - Journal of Organometallic Chemistry

Reaction of [Cp*Rh(H2O)](OTf)2 with NAD+ provided a cyclic trimer structure, [Cp*Rh(NAD)3](OTf)3, that was determined via 1H NMR, ESI/MS, and CV studies.
Fuzzy interface between surface chemistry, heterogeneous catalysis, and organometallic chemistry

Journal Article Schaefer, III, H F - Acc. Chem. Res.; (United States)

Data from various previously reported works in the fields of surface chemistry, heterogeneous catalysis, and organometallic chemistry are cited to serve as a foundation for the development of a hypothesis to explain the interrelation of these three areas of study. The simplest possible interface between the three areas is illustrated, and this cited system provides a testing ground for molecular theories of catalysis. It is concluded that all three fields have a common denominator in the reacting bonded species which can be denoted as M-OF where M = transition metal and OF = organic fragment. (BLM)
https://doi.org/10.1021/ar50116a003
Reciprocal interactions between Beta1-integrin and epidermal growth factor in three-dimensional basement membrane breast cultures: A different perspective in epithelial biology

Journal Article Wang, F ; Weaver, V M ; Petersen, O W ; ... - Proceedings of the National Academy of Science

Anchorage and growth factor independence are cardinal features of the transformed phenotype. Although it is logical that the two pathways must be coregulated in normal tissues to maintain homeostasis, this has not been demonstrated directly. We showed previously that down-modulation of {beta}1-integrin signaling reverted the malignant behavior of a human breast tumor cell line (T4-2) derived from phenotypically normal cells (HMT-3522) and led to growth arrest in a threedimensional (3D) basement membrane assay in which the cells formed tissue-like acini (14). Here, we show that there is a bidirectional cross-modulation of {beta}1-integrin and epidermal growth factor receptor (EGFR) signaling viamore »« less
Full Text Available

Similar Records