Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media
Abstract
Materials in the LaxSr1–xCoyMn1–yO3–δ (LSCM) and LaxSr1–xCoyFe1–yO3–δ (LSCF) families are candidates for high-temperature thermochemical energy storage due to their facility for cyclic endothermic reduction and exothermic oxidation. A set of 16 LSCM and 21 LSCF compositions were synthesized by a modified Pechini method and characterized by powder X-ray diffraction and thermogravimetric analysis. All materials were found to be various symmetries of the perovskite phase. LSCM was indexed as tetragonal, cubic, rhombohedral, or orthorhombic as a function of increased lanthanum content. For LSCF, compositions containing low lanthanum content were indexed as cubic while materials with high lanthanum content were indexed as rhombohedral. An initial screening of redox activity was completed by thermogravimetric analysis for each composition. The top three compositions with the greatest recoverable redox capacity for each family were further characterized in equilibrium thermogravimetric experiments over a range of temperatures and oxygen partial pressures. As a result, these equilibrium experiments allowed the extraction of thermodynamic parameters for LSCM and LSCF compositions operated in thermochemical energy storage conditions.
- Authors:
-
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1235322
- Alternate Identifier(s):
- OSTI ID: 1237378; OSTI ID: 1245221
- Report Number(s):
- SAND-2015-4972J; SAND-2015-1455J
Journal ID: ISSN 0038-092X; 594399
- Grant/Contract Number:
- AC04-94AL85000; FOA-0000805
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Solar Energy
- Additional Journal Information:
- Journal Volume: 118; Journal Issue: C; Journal ID: ISSN 0038-092X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; concentrating solar power; thermochemical energy storage; perovskite; thermogravimetric analysis; 14 SOLAR ENERGY; 36 MATERIALS SCIENCE
Citation Formats
Babiniec, Sean Michael, Coker, Eric Nicholas, Miller, James E., and Ambrosini, Andrea. Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media. United States: N. p., 2015.
Web. doi:10.1016/j.solener.2015.05.040.
Babiniec, Sean Michael, Coker, Eric Nicholas, Miller, James E., & Ambrosini, Andrea. Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media. United States. https://doi.org/10.1016/j.solener.2015.05.040
Babiniec, Sean Michael, Coker, Eric Nicholas, Miller, James E., and Ambrosini, Andrea. Tue .
"Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media". United States. https://doi.org/10.1016/j.solener.2015.05.040. https://www.osti.gov/servlets/purl/1235322.
@article{osti_1235322,
title = {Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media},
author = {Babiniec, Sean Michael and Coker, Eric Nicholas and Miller, James E. and Ambrosini, Andrea},
abstractNote = {Materials in the LaxSr1–xCoyMn1–yO3–δ (LSCM) and LaxSr1–xCoyFe1–yO3–δ (LSCF) families are candidates for high-temperature thermochemical energy storage due to their facility for cyclic endothermic reduction and exothermic oxidation. A set of 16 LSCM and 21 LSCF compositions were synthesized by a modified Pechini method and characterized by powder X-ray diffraction and thermogravimetric analysis. All materials were found to be various symmetries of the perovskite phase. LSCM was indexed as tetragonal, cubic, rhombohedral, or orthorhombic as a function of increased lanthanum content. For LSCF, compositions containing low lanthanum content were indexed as cubic while materials with high lanthanum content were indexed as rhombohedral. An initial screening of redox activity was completed by thermogravimetric analysis for each composition. The top three compositions with the greatest recoverable redox capacity for each family were further characterized in equilibrium thermogravimetric experiments over a range of temperatures and oxygen partial pressures. As a result, these equilibrium experiments allowed the extraction of thermodynamic parameters for LSCM and LSCF compositions operated in thermochemical energy storage conditions.},
doi = {10.1016/j.solener.2015.05.040},
journal = {Solar Energy},
number = C,
volume = 118,
place = {United States},
year = {Tue Jun 23 00:00:00 EDT 2015},
month = {Tue Jun 23 00:00:00 EDT 2015}
}
Web of Science
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