Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures

Ashton, Thomas E.; Borras, David Hevia; Iadecola, Antonella; Wiaderek, Kamila Magdalena; Chapman, Karena W.; Corr, Serena A.

doi:10.1107/S2052520615021289

Title: Microwave-assisted synthesis and electrochemical evaluation of VO₂ (B) nanostructures

Abstract

Understanding how intercalation materials change during electrochemical operation is paramount to optimising their behaviour and function and in situ characterisation methods allow us to observe these changes without sample destruction. Here, we first report the improved intercalation properties of bronze phase vanadium dioxide VO2 (B) prepared by a microwave assisted route which exhibits a larger electrochemical capacity (232 mAh g^-1) compared to VO₂ (B) prepared by a solvothermal route (197 mAh g^-1). These electrochemical differences have also been followed using in situ X-ray absorption spectroscopy allowing us to follow oxidation state changes as they occur during battery operation.

Authors:

Ashton, Thomas E. ^[1]; Borras, David Hevia ^[1]; Iadecola, Antonella ^[2]; Wiaderek, Kamila Magdalena ^[3]; Chapman, Karena W. ^[3]; Corr, Serena A. ^[1]

Univ. of Glasgow, Scotland (United Kingdom). School of Chemistry
European Synchrotron, Grenoble (France); Network on the Electrochemical Storage of Energy (France); Synchrotron SOLEIL, Saint Aubin, Gif sur Yvette (France)
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division

Publication Date:: Tue Dec 01 00:00:00 EST 2015

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Royal Society

OSTI Identifier:: 1240688

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Acta Crystallographica. Section B: Structural Science

Additional Journal Information:: Journal Volume: 71; Journal Issue: 6; Journal ID: ISSN 0108-7681

Publisher:: International Union of Crystallography

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; in situ; intercalation; li-ion battery; vanadium dioxide; x-ray absorption spectroscopy

Citation Formats


                    Ashton, Thomas E., Borras, David Hevia, Iadecola, Antonella, Wiaderek, Kamila Magdalena, Chapman, Karena W., and Corr, Serena A. Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures.  United States: N. p., 2015. 
Web.  doi:10.1107/S2052520615021289.

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                    Ashton, Thomas E., Borras, David Hevia, Iadecola, Antonella, Wiaderek, Kamila Magdalena, Chapman, Karena W., & Corr, Serena A. Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures.  United States.  https://doi.org/10.1107/S2052520615021289

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                    Ashton, Thomas E., Borras, David Hevia, Iadecola, Antonella, Wiaderek, Kamila Magdalena, Chapman, Karena W., and Corr, Serena A. Tue .  
"Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures".  United States.  https://doi.org/10.1107/S2052520615021289.  https://www.osti.gov/servlets/purl/1240688.

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@article{osti_1240688,

  title        = {Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures},

  author       = {Ashton, Thomas E. and Borras, David Hevia and Iadecola, Antonella and Wiaderek, Kamila Magdalena and Chapman, Karena W. and Corr, Serena A.},

  abstractNote = {Understanding how intercalation materials change during electrochemical operation is paramount to optimising their behaviour and function and in situ characterisation methods allow us to observe these changes without sample destruction. Here, we first report the improved intercalation properties of bronze phase vanadium dioxide VO2 (B) prepared by a microwave assisted route which exhibits a larger electrochemical capacity (232 mAh g-1) compared to VO2 (B) prepared by a solvothermal route (197 mAh g-1). These electrochemical differences have also been followed using in situ X-ray absorption spectroscopy allowing us to follow oxidation state changes as they occur during battery operation.},

  doi          = {10.1107/S2052520615021289},

  journal      = {Acta Crystallographica. Section B: Structural Science},

  number       = 6,

  volume       = 71,

  place        = {United States},

  year         = {Tue Dec 01 00:00:00 EST 2015},

  month        = {Tue Dec 01 00:00:00 EST 2015}

}

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Works referencing / citing this record:

Vanadium (III) Oxide/Carbon Core/Shell Hybrids as an Anode for Lithium-Ion Batteries
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Budak, Öznil; Srimuk, Pattarachai; Tolosa, Aura
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Title: Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures

Abstract

Citation Formats

Power and temperature controlled microwave synthesis of SVO journal, March 2007

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The AMPIX electrochemical cell: a versatile apparatus for in situ X-ray scattering and spectroscopic measurements journal, November 2012

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VO2(B) nanorods: solvothermal preparation, electrical properties, and conversion to rutile VO2 and V2O3 journal, January 2009

Challenges for Rechargeable Li Batteries journal, February 2010

Template-free hydrothermal synthesis of VO2 hollow microspheres journal, January 2012

Chemical intercalation of lithium into a V6O13 host journal, November 1995

Microwave-assisted hydrothermal synthesis of vanadium oxides for Li-ion supercapacitors: The influences of Li-ion doping and crystallinity on the capacitive performances journal, February 2013

A general and simple method to synthesize well-crystallized nanostructured vanadium oxides for high performance Li-ion batteries journal, January 2015

Enhancing the performances of Li-ion batteries by carbon-coating: present and future journal, January 2012

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Phase Transition and V4+-V4+ Pairing in VO2(B) journal, July 1993

Template-Free Synthesis of VO 2 Hollow Microspheres with Various Interiors and Their Conversion into V 2 O 5 for Lithium-Ion Batteries journal, January 2013

The intercalation chemistry of H2V3O8 nanobelts synthesised by a green, fast and cost-effective procedure journal, June 2013

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Ultrathin Nanosheets of Li 2 MSiO 4 (M = Fe, Mn) as High-Capacity Li-Ion Battery Electrode journal, February 2012

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Microwave-assisted solid-state synthesis of LiCoO2 and its electrochemical properties as a cathode material for lithium batteries journal, October 2001

Synthesis of Nanocrystalline VO[sub 2] and Its Electrochemical Behavior in Lithium Batteries journal, January 1997

K -edge absorption spectra of selected vanadium compounds journal, November 1984

Quadrupolar transitions and medium-range-order effects in metal K -edge x-ray absorption spectra of 3 d transition-metal compounds journal, July 2004

In Situ X-ray Absorption Spectroscopic Study on LiNi 0.5 Mn 0.5 O 2 Cathode Material during Electrochemical Cycling journal, August 2003

Tailoring Two Polymorphs of LiFePO 4 by Efficient Microwave-Assisted Synthesis: A Combined Experimental and Theoretical Study journal, August 2013

Electrochemical Lithium Intercalation in VO 2 ( B ) in Aqueous Electrolytes journal, January 1996

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Title: Microwave-assisted synthesis and electrochemical evaluation of VO₂ (B) nanostructures

Power and temperature controlled microwave synthesis of SVO
journal, March 2007

The synthesis and lithium intercalation electrochemistry of VO2(B) ultra-thin nanowires
journal, April 2008

MW-assisted synthesis of SVO for ICD primary batteries
journal, June 2006

The AMPIX electrochemical cell: a versatile apparatus for in situ X-ray scattering and spectroscopic measurements
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Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008

Self-Assembled Vanadium Pentoxide (V2O5) Hollow Microspheres from Nanorods and Their Application in Lithium-Ion Batteries
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VO2(B) nanorods: solvothermal preparation, electrical properties, and conversion to rutile VO2 and V2O3
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Challenges for Rechargeable Li Batteries
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Template-free hydrothermal synthesis of VO2 hollow microspheres
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journal, November 1995

Microwave-assisted hydrothermal synthesis of vanadium oxides for Li-ion supercapacitors: The influences of Li-ion doping and crystallinity on the capacitive performances
journal, February 2013

A general and simple method to synthesize well-crystallized nanostructured vanadium oxides for high performance Li-ion batteries
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Enhancing the performances of Li-ion batteries by carbon-coating: present and future
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Synthesis and electrochemical properties of single-crystalline LiV3O8 nanorods as cathode materials for rechargeable lithium batteries
journal, July 2009

Nanoscroll Buffered Hybrid Nanostructural VO ₂ (B) Cathodes for High-Rate and Long-Life Lithium Storage
journal, March 2013

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LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
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VO ₂ Nanowires Assembled into Hollow Microspheres for High-Rate and Long-Life Lithium Batteries
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Phase Transition and V4+-V4+ Pairing in VO2(B)
journal, July 1993

Template-Free Synthesis of VO ₂ Hollow Microspheres with Various Interiors and Their Conversion into V ₂ O ₅ for Lithium-Ion Batteries
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Ultrathin Nanosheets of Li ₂ MSiO ₄ (M = Fe, Mn) as High-Capacity Li-Ion Battery Electrode
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journal, January 1997

$K$ -edge absorption spectra of selected vanadium compounds
journal, November 1984

Quadrupolar transitions and medium-range-order effects in metal $K$ -edge x-ray absorption spectra of $3 d$ transition-metal compounds
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