Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO4

Cybinska, Joanna; Lorbeer, Chantal; Mudring, Anja -Verena

doi:10.1016/j.jlumin.2015.06.051

Title: Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO₄

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Abstract

Ln³⁺-doped (Ln=Sm, Eu, Tb, Dy) nanoparticles of BiPO₄ with a particle size below 10 nm were synthesized in a straightforward manner from the appropriate mixture of the respective metal acetates and the task-specific ionic liquids choline or butylammonium dihydrogen-phosphate by conversion in a laboratory microwave (120 °C, 10 min). The ionic liquid acts not only as a solvent and microwave susceptor, but also as the reaction partner and nanoparticle stabilizer. The materials were thoroughly characterized not only with respect to their optical properties but also by PXRD, FT-IR, TEM techniques. Furthermore, depending on the lanthanide, the nanomaterial shows intense luminescence of different colors such as: orange (Sm³⁺), red (Eu³⁺), green (Tb³⁺) or even white (Dy³⁺).

Authors:

Cybinska, Joanna ^[1]; Lorbeer, Chantal ^[2]; Mudring, Anja -Verena ^[3]

Univ. of Wroclaw, Wroclaw (Poland)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States)

Publication Date:: Wed Jul 08 00:00:00 EDT 2015

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1239836

Alternate Identifier(s):: OSTI ID: 1396520

Report Number(s):: IS-J-8923
Journal ID: ISSN 0022-2313; PII: S0022231315003695

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Luminescence

Additional Journal Information:: Journal Volume: 170; Journal Issue: P2; Journal ID: ISSN 0022-2313

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY; ionic liquid; lanthanides; nanomaterials; luminescence; optical materials; synthesis

Citation Formats


                    Cybinska, Joanna, Lorbeer, Chantal, and Mudring, Anja -Verena. Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO4.  United States: N. p., 2015. 
Web.  doi:10.1016/j.jlumin.2015.06.051.

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                    Cybinska, Joanna, Lorbeer, Chantal, & Mudring, Anja -Verena. Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO4.  United States.  https://doi.org/10.1016/j.jlumin.2015.06.051

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                    Cybinska, Joanna, Lorbeer, Chantal, and Mudring, Anja -Verena. Wed .  
"Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO4".  United States.  https://doi.org/10.1016/j.jlumin.2015.06.051.  https://www.osti.gov/servlets/purl/1239836.

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@article{osti_1239836,

  title        = {Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO4},

  author       = {Cybinska, Joanna and Lorbeer, Chantal and Mudring, Anja -Verena},

  abstractNote = {Ln3+-doped (Ln=Sm, Eu, Tb, Dy) nanoparticles of BiPO4 with a particle size below 10 nm were synthesized in a straightforward manner from the appropriate mixture of the respective metal acetates and the task-specific ionic liquids choline or butylammonium dihydrogen-phosphate by conversion in a laboratory microwave (120 °C, 10 min). The ionic liquid acts not only as a solvent and microwave susceptor, but also as the reaction partner and nanoparticle stabilizer. The materials were thoroughly characterized not only with respect to their optical properties but also by PXRD, FT-IR, TEM techniques. Furthermore, depending on the lanthanide, the nanomaterial shows intense luminescence of different colors such as: orange (Sm3+), red (Eu3+), green (Tb3+) or even white (Dy3+).},

  doi          = {10.1016/j.jlumin.2015.06.051},

  journal      = {Journal of Luminescence},

  number       = P2,

  volume       = 170,

  place        = {United States},

  year         = {Wed Jul 08 00:00:00 EDT 2015},

  month        = {Wed Jul 08 00:00:00 EDT 2015}

}

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Title: Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO4

Abstract

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Title: Ionic liquid assisted microwave synthesis route towards color-tunable luminescence of lanthanide- doped BiPO₄