Photovoltaic switching mechanism in lateral structure hybrid perovskite solar cells

Yuan, Yongbo; Chae, Jungseok; Shao, Yuchuan; Wang, Qi; Xiao, Zhengguo; Centrone, Andrea; Huang, Jinsong

doi:10.1002/aenm.201500615

Title: Photovoltaic switching mechanism in lateral structure hybrid perovskite solar cells

Journal Article · Fri Jun 05 00:00:00 EDT 2015 · Advanced Energy Materials

DOI: https://doi.org/10.1002/aenm.201500615 · OSTI ID:1238032

Yuan, Yongbo ^[1]; Chae, Jungseok ^[2]; Shao, Yuchuan ^[3]; Wang, Qi ^[3]; Xiao, Zhengguo ^[3]; Centrone, Andrea ^[4]; Huang, Jinsong ^[3]

Univ. of Nebraska, Lincoln, NE (United States); University of Nebraska, Lincoln
National Institute of Standards and Technology, Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States)
Univ. of Nebraska, Lincoln, NE (United States)
National Institute of Standards and Technology, Gaithersburg, MD (United States)

In this study, long range electromigration of methylammonium ions (MA⁺) in methyl ammonium lead tri-iodide (MAPbI₃) film is observed directly using the photothermal induced resonance technique. The electromigration of MA⁺ leads to the formation of a lateral p-i-n structure, which is the origin of the switchable photovoltaic effect in MAPbI₃ perovskite devices.

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Research Organization:: Univ. of Nebraska, Lincoln, NE (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0006709

OSTI ID:: 1238032

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 15 Vol. 5; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Understanding the Impact of Bismuth Heterovalent Doping on the Structural and Photophysical Properties of CH ₃ NH ₃ PbBr ₃ Halide Perovskite Crystals with Near‐IR Photoluminescence Meng, Rui; Wu, Guangbao; Zhou, Jiyu Chemistry – A European Journal, Vol. 25, Issue 21 https://doi.org/10.1002/chem.201805370	journal	March 2019
Stability Challenges for Perovskite Solar Cells Fu, Rui; Zhou, Wenke; Li, Qi ChemNanoMat, Vol. 5, Issue 3 https://doi.org/10.1002/cnma.201800503	journal	January 2019
Ionic and Optical Properties of Methylammonium Lead Iodide Perovskite across the Tetragonal-Cubic Structural Phase Transition Hoque, Md Nadim Ferdous; Islam, Nazifah; Li, Zhen ChemSusChem, Vol. 9, Issue 18 https://doi.org/10.1002/cssc.201600949	journal	September 2016
Interdigitated Hierarchical Integration of an Efficient Lateral Perovskite Single‐Crystal Solar Cell Park, Jinseon; Bak, Yeong Eun; Lee, Lynn ChemSusChem, Vol. 13, Issue 7 https://doi.org/10.1002/cssc.201903038	journal	February 2020
The Influence of Structural Configuration on Charge Accumulation, Transport, Recombination, and Hysteresis in Perovskite Solar Cells Wang, Yi; Wang, Hao-Yi; Han, Jun Energy Technology, Vol. 5, Issue 3 https://doi.org/10.1002/ente.201600320	journal	September 2016
Ionic Liquid-Assisted Improvements in the Thermal Stability of CH ₃ NH ₃ PbI ₃ Perovskite Photovoltaics Du, Jinglun; Wang, Yinglin; Zhang, Yu physica status solidi (RRL) - Rapid Research Letters, Vol. 12, Issue 8 https://doi.org/10.1002/pssr.201800130	journal	May 2018
Lattice‐Defect‐Induced Piezo Response in Methylammonium‐Lead‐Iodide Perovskite Based Nanogenerator Dhar, Joydeep; Sil, Sayantan; Hoque, Nur A. ChemistrySelect, Vol. 3, Issue 19 https://doi.org/10.1002/slct.201801034	journal	May 2018
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Methodologies toward Highly Efficient Perovskite Solar Cells Seok, Sang Il; Grätzel, Michael; Park, Nam-Gyu Small, Vol. 14, Issue 20 https://doi.org/10.1002/smll.201704177	journal	February 2018
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From Macroscopic to Nanoscopic Current Hysteresis Suppressed by Fullerene in Perovskite Solar Cells Lu, Chunyan; Hu, Ziyang; Wang, Yanyan Solar RRL, Vol. 3, Issue 10 https://doi.org/10.1002/solr.201900235	journal	August 2019
Conductive metallic filaments dominate in hybrid perovskite-based memory devices Huang, Yang; Zhao, Zhenxuan; Wang, Chen Science China Materials, Vol. 62, Issue 9 https://doi.org/10.1007/s40843-019-9433-4	journal	May 2019
A study of structural and dielectric properties of Ba2+ doped CH3NH3PbI3 crystals Jayathissa, Rasanjali; Burns, Clement A. SN Applied Sciences, Vol. 2, Issue 3 https://doi.org/10.1007/s42452-020-2157-x	journal	February 2020
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Hybrid organic—inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties Brenner, Thomas M.; Egger, David A.; Kronik, Leeor Nature Reviews Materials, Vol. 1, Issue 1 https://doi.org/10.1038/natrevmats.2015.7	journal	January 2016
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Photo-induced halide redistribution in organic–inorganic perovskite films deQuilettes, Dane W.; Zhang, Wei; Burlakov, Victor M. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11683	journal	May 2016
Evidence for ion migration in hybrid perovskite solar cells with minimal hysteresis Calado, Philip; Telford, Andrew M.; Bryant, Daniel Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13831	journal	December 2016
Defects in perovskite-halides and their effects in solar cells Ball, James M.; Petrozza, Annamaria Nature Energy, Vol. 1, Issue 11 https://doi.org/10.1038/nenergy.2016.149	journal	October 2016
Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite Leblebici, Sibel Y.; Leppert, Linn; Li, Yanbo Nature Energy, Vol. 1, Issue 8 https://doi.org/10.1038/nenergy.2016.93	journal	July 2016
Spectroscopic study on the impact of methylammonium iodide loading time on the electronic properties in perovskite thin films Cheng, Yuanhang; Li, Ho-Wa; Zhang, Jinfeng Journal of Materials Chemistry A, Vol. 4, Issue 2 https://doi.org/10.1039/c5ta08262e	journal	January 2016
Defect trapping states and charge carrier recombination in organic–inorganic halide perovskites Wen, Xiaoming; Feng, Yu; Huang, Shujuan Journal of Materials Chemistry C, Vol. 4, Issue 4 https://doi.org/10.1039/c5tc03109e	journal	January 2016
Ultrafast ion migration in hybrid perovskite polycrystalline thin films under light and suppression in single crystals Xing, Jie; Wang, Qi; Dong, Qingfeng Physical Chemistry Chemical Physics, Vol. 18, Issue 44 https://doi.org/10.1039/c6cp06496e	journal	January 2016
Interpretation of inverted photocurrent transients in organic lead halide perovskite solar cells: proof of the field screening by mobile ions and determination of the space charge layer widths Belisle, Rebecca A.; Nguyen, William H.; Bowring, Andrea R. Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/c6ee02914k	journal	January 2017
Fast self-diffusion of ions in CH ₃ NH ₃ PbI ₃ : the interstiticaly mechanism versus vacancy-assisted mechanism Yang, Ji-Hui; Yin, Wan-Jian; Park, Ji-Sang Journal of Materials Chemistry A, Vol. 4, Issue 34 https://doi.org/10.1039/c6ta03599j	journal	January 2016
The detrimental effect of excess mobile ions in planar CH ₃ NH ₃ PbI ₃ perovskite solar cells Cheng, Yuanhang; Li, Ho-Wa; Qing, Jian Journal of Materials Chemistry A, Vol. 4, Issue 33 https://doi.org/10.1039/c6ta05053k	journal	January 2016
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Recent advances in hybrid measurement methods based on atomic force microscopy and surface sensitive measurement techniques Handschuh-Wang, Stephan; Wang, Tao; Zhou, Xuechang RSC Adv., Vol. 7, Issue 75 https://doi.org/10.1039/c7ra08515j	journal	January 2017
Towards enabling stable lead halide perovskite solar cells; interplay between structural, environmental, and thermal stability Leijtens, Tomas; Bush, Kevin; Cheacharoen, Rongrong Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/c7ta00434f	journal	January 2017
Improved carriers injection capacity in perovskite solar cells by introducing A-site interstitial defects Zhao, Pengjun; Yin, Wenping; Kim, Minwoo Journal of Materials Chemistry A, Vol. 5, Issue 17 https://doi.org/10.1039/c7ta01203a	journal	January 2017
A strategic review on processing routes towards highly efficient perovskite solar cells Dubey, Ashish; Adhikari, Nirmal; Mabrouk, Sally Journal of Materials Chemistry A, Vol. 6, Issue 6 https://doi.org/10.1039/c7ta08277k	journal	January 2018
Vacuum-evaporated all-inorganic cesium lead bromine perovskites for high-performance light-emitting diodes Hu, Yun; Wang, Qiang; Shi, Ying-Li Journal of Materials Chemistry C, Vol. 5, Issue 32 https://doi.org/10.1039/c7tc02477k	journal	January 2017
Photocarrier dynamics in perovskite-based solar cells revealed by intensity-modulated photovoltage spectroscopy Chen, Xiaoqing; Shirai, Yasuhiro; Yanagida, Masatoshi Physical Chemistry Chemical Physics, Vol. 20, Issue 26 https://doi.org/10.1039/c8cp01227j	journal	January 2018
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How the formation of interfacial charge causes hysteresis in perovskite solar cells Weber, Stefan A. L.; Hermes, Ilka M.; Turren-Cruz, Silver-Hamill Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/c8ee01447g	journal	January 2018
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Boosting the performance of perovskite solar cells through a novel active passivation method Wang, Pengfei; Wang, Jiao; Zhang, Xin Journal of Materials Chemistry A, Vol. 6, Issue 32 https://doi.org/10.1039/c8ta05593a	journal	January 2018
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Flower-like MoS ₂ nanocrystals: a powerful sorbent of Li ⁺ in the Spiro-OMeTAD layer for highly efficient and stable perovskite solar cells Jiang, Lu-Lu; Wang, Zhao-Kui; Li, Meng Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta11800k	journal	January 2019
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Phenethylammonium bismuth halides: from single crystals to bulky-organic cation promoted thin-film deposition for potential optoelectronic applications Ghasemi, Mehri; Lyu, Miaoqiang; Roknuzzaman, Md Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta07454f	journal	January 2019
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Performance-enhanced solar-blind photodetector based on a CH ₃ NH ₃ PbI ₃ /β-Ga ₂ O ₃ hybrid structure Dong, Linpeng; Pang, Tiqiang; Yu, Jiangang Journal of Materials Chemistry C, Vol. 7, Issue 45 https://doi.org/10.1039/c9tc05115e	journal	January 2019
Photothermoelastic contrast in nanoscale infrared spectroscopy Morozovska, Anna N.; Eliseev, Eugene A.; Borodinov, Nikolay Applied Physics Letters, Vol. 112, Issue 3 https://doi.org/10.1063/1.4985584	journal	January 2018
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Dependence of power conversion properties of perovskite solar cells on operating temperature Liu, Gang; Zhou, Conghua; Wan, Fang Applied Physics Letters, Vol. 113, Issue 11 https://doi.org/10.1063/1.5041028	journal	September 2018
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Verification and mitigation of ion migration in perovskite solar cells Lee, Jin-Wook; Kim, Seul-Gi; Yang, June-Mo APL Materials, Vol. 7, Issue 4 https://doi.org/10.1063/1.5085643	journal	April 2019
Assessment of dynamic structural instabilities across 24 cubic inorganic halide perovskites Yang, Ruo Xi; Skelton, Jonathan M.; da Silva, Estelina L. The Journal of Chemical Physics, Vol. 152, Issue 2 https://doi.org/10.1063/1.5131575	journal	January 2020
Defect proliferation in CsPbBr ₃ crystal induced by ion migration Zhang, Bin-Bin; Wang, Fangbao; Zhang, Hongjian Applied Physics Letters, Vol. 116, Issue 6 https://doi.org/10.1063/1.5134108	journal	February 2020
Highly efficient perovskite solar cells by tuning electronic structures of thienothiophene-based as hole transport materials Han, Bingjie; Li, Zhuo; Li, Yuanzuo Molecular Physics https://doi.org/10.1080/00268976.2019.1644383	journal	July 2019
Unraveling surface and bulk trap states in lead halide perovskite solar cells using impedance spectroscopy Han, Changfeng; Wang, Kai; Zhu, Xixiang Journal of Physics D: Applied Physics, Vol. 51, Issue 9 https://doi.org/10.1088/1361-6463/aaa7cd	journal	February 2018
Inverted hysteresis in MAPbI ₃ perovskite solar cells induced by presetting bias voltage Xiang, Jin; Li, Yana; Huang, Feng Journal of Physics D: Applied Physics, Vol. 52, Issue 31 https://doi.org/10.1088/1361-6463/ab1e2b	journal	May 2019
Identifying inverted-hysteresis behavior of CH ₃ NH ₃ PbI _3−x Cl _x planar hybrid perovskite solar cells based on external bias precondition Jiang, Yurong; Feng, Yanxing; Sun, Xiaodong Journal of Physics D: Applied Physics, Vol. 52, Issue 38 https://doi.org/10.1088/1361-6463/ab28d0	journal	July 2019
Improved air stability and low voltage resistive switching behaviors of NiO-buffered CH ₃ NH ₃ PbI ₃ films prepared by a solution method Wang, Y. Y.; Li, L. T.; Jiang, X. Journal of Physics D: Applied Physics, Vol. 53, Issue 7 https://doi.org/10.1088/1361-6463/ab550a	journal	December 2019
Modeling hybrid perovskites by molecular dynamics Mattoni, Alessandro; Filippetti, Alessio; Caddeo, Claudia Journal of Physics: Condensed Matter, Vol. 29, Issue 4 https://doi.org/10.1088/1361-648x/29/4/043001	journal	November 2016
Operational stability of perovskite light emitting diodes Dong, Qi; Lei, Lei; Mendes, Juliana Journal of Physics: Materials, Vol. 3, Issue 1 https://doi.org/10.1088/2515-7639/ab60c4	journal	January 2020
Advances in modelling and simulation of halide perovskites for solar cell applications Yu, Chol-Jun Journal of Physics: Energy, Vol. 1, Issue 2 https://doi.org/10.1088/2515-7655/aaf143	journal	January 2019
Inorganic–organic halide perovskites for new photovoltaic technology Li, Dongmei; Shi, Jiangjian; Xu, Yuzhuan National Science Review, Vol. 5, Issue 4 https://doi.org/10.1093/nsr/nwx100	journal	August 2017
Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells Zhao, Jingjing; Deng, Yehao; Wei, Haotong Science Advances, Vol. 3, Issue 11 https://doi.org/10.1126/sciadv.aao5616	journal	November 2017
The existence and impact of persistent ferroelectric domains in MAPbI ₃ Garten, Lauren M.; Moore, David T.; Nanayakkara, Sanjini U. Science Advances, Vol. 5, Issue 1 https://doi.org/10.1126/sciadv.aas9311	journal	January 2019
Nanoscale mapping of chemical composition in organic-inorganic hybrid perovskite films Szostak, R.; Silva, J. C.; Turren-Cruz, S. -H. Science Advances, Vol. 5, Issue 10 https://doi.org/10.1126/sciadv.aaw6619	journal	October 2019
Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells Jinsong, Huang,; Haotong, Wei,; E., Shield, Jeffrey The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/74eg-ak28	text	January 2017
Assessment of Dynamic Structural Instabilities Across 24 Cubic Inorganic Halide Perovskites Yang, Ruo Xi; Skelton, Jonathan; Da Silva, E. Lora https://doi.org/10.26434/chemrxiv.9976868	posted_content	October 2019
Assessment of Dynamic Structural Instabilities Across 24 Cubic Inorganic Halide Perovskites Yang, Ruo Xi; Yang, Jonathan Skelton; Da Silva, E. Lora https://doi.org/10.26434/chemrxiv.9976868.v1	posted_content	October 2019
Mixed 3D-2D passivation treatment for mixed-cation lead mixed-halide perovskite solar cells for higher efficiency and better stability Cho, Yongyoon; Soufiani, Arman Mahboubi; Yun, Jae Sung Proceedings of the 10th International Conference on Hybrid and Organic Photovoltaics https://doi.org/10.29363/nanoge.hopv.2018.080	conference	February 2018
Giant Zero-Drift Electronic Behaviors in Methylammonium Lead Halide Perovskite Diodes by Doping Iodine Ions Pang, Tiqiang; Jia, Renxu; Wang, Yucheng Materials, Vol. 11, Issue 9 https://doi.org/10.3390/ma11091606	journal	September 2018
Influence of Electrical Traps on the Current Density Degradation of Inverted Perovskite Solar Cells Lee, Hyunho; Lee, Changhee; Song, Hyung-Jun Materials, Vol. 12, Issue 10 https://doi.org/10.3390/ma12101644	journal	May 2019

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