Distinct exciton dissociation behavior of organolead trihalide perovskite and excitonic semiconductors studied in a same device

Hu, Miao; Bi, Cheng; Yuan, Yongbo; Xiao, Zhengguo; Dong, Qingfeng; Shao, Yuchuan; Huang, Jinsong

doi:10.1002/smll.201402905

Title: Distinct exciton dissociation behavior of organolead trihalide perovskite and excitonic semiconductors studied in a same device

Journal Article · Wed Jan 14 23:00:00 EST 2015 · Small

DOI: https://doi.org/10.1002/smll.201402905 · OSTI ID:1237992

Hu, Miao ^[1]; Bi, Cheng ^[2]; Yuan, Yongbo ^[2]; Xiao, Zhengguo ^[2]; Dong, Qingfeng ^[2]; Shao, Yuchuan ^[2]; Huang, Jinsong ^[2]

Univ. of Nebraska, Lincoln, NE (United States); University of Nebraska, Lincoln
Univ. of Nebraska, Lincoln, NE (United States)

The nonexcitonic character for organometal trihalide perovskites is demonstrated by examining the field-dependent exciton dissociation behavior. Moreover, it is found that photogenerated excitons can be effectively dissociated into free charges inside perovskite without the assistance of charge extraction layer or external field, which is a stark contrast to the charge-separation behavior in excitonic materials in the same photovoltaic operation system.

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Research Organization:: Univ. of Nebraska, Lincoln, NE (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0006709

OSTI ID:: 1237992

Journal Information:: Small, Journal Name: Small Journal Issue: 18 Vol. 11; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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