DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis of uniformly distributed single- and double-sided zinc oxide (ZnO) nanocombs

Abstract

Uniformly distributed single- and double-sided zinc oxide (ZnO) nanocomb structures have been prepared by a vapor-liquid-solid technique from a mixture of ZnO nanoparticles and graphene nanoplatelets. The ZnO seed nanoparticles were synthesized via a simple precipitation method. The structure of the ZnO nanocombs could easily be controlled by tuning the carrier-gas flow rate during growth. Higher flow rate resulted in the formation of uniformly-distributed single-sided comb structures with nanonail-shaped teeth, as a result of the self-catalysis effect of the catalytically active Zn-terminated polar (0001) surface. Lower gas flow rate was favorable for production of double-sided comb structures with the two sets of teeth at an angle of similar to 110 degrees to each other along the comb ribbon, which was attributed to the formation of a bicrystal nanocomb ribbon. Lastly, the formation of such a double-sided structure with nanonail-shaped teeth has not previously been reported.

Authors:
 [1];  [2];  [3]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Middle East Technical Univ., Ankara (Turkey); Selcuk Univ., Konya (Turkey)
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1237680
Alternate Identifier(s):
OSTI ID: 1359313
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Crystal Growth
Additional Journal Information:
Journal Volume: 430; Journal Issue: C; Journal ID: ISSN 0022-0248
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Nanostructures; Growth from vapor; Semiconducting II–VI materials

Citation Formats

Altintas Yildirim, Ozlem, Liu, Yuzi, and Petford-Long, Amanda K. Synthesis of uniformly distributed single- and double-sided zinc oxide (ZnO) nanocombs. United States: N. p., 2015. Web. doi:10.1016/j.jcrysgro.2015.08.007.
Altintas Yildirim, Ozlem, Liu, Yuzi, & Petford-Long, Amanda K. Synthesis of uniformly distributed single- and double-sided zinc oxide (ZnO) nanocombs. United States. https://doi.org/10.1016/j.jcrysgro.2015.08.007
Altintas Yildirim, Ozlem, Liu, Yuzi, and Petford-Long, Amanda K. Fri . "Synthesis of uniformly distributed single- and double-sided zinc oxide (ZnO) nanocombs". United States. https://doi.org/10.1016/j.jcrysgro.2015.08.007. https://www.osti.gov/servlets/purl/1237680.
@article{osti_1237680,
title = {Synthesis of uniformly distributed single- and double-sided zinc oxide (ZnO) nanocombs},
author = {Altintas Yildirim, Ozlem and Liu, Yuzi and Petford-Long, Amanda K.},
abstractNote = {Uniformly distributed single- and double-sided zinc oxide (ZnO) nanocomb structures have been prepared by a vapor-liquid-solid technique from a mixture of ZnO nanoparticles and graphene nanoplatelets. The ZnO seed nanoparticles were synthesized via a simple precipitation method. The structure of the ZnO nanocombs could easily be controlled by tuning the carrier-gas flow rate during growth. Higher flow rate resulted in the formation of uniformly-distributed single-sided comb structures with nanonail-shaped teeth, as a result of the self-catalysis effect of the catalytically active Zn-terminated polar (0001) surface. Lower gas flow rate was favorable for production of double-sided comb structures with the two sets of teeth at an angle of similar to 110 degrees to each other along the comb ribbon, which was attributed to the formation of a bicrystal nanocomb ribbon. Lastly, the formation of such a double-sided structure with nanonail-shaped teeth has not previously been reported.},
doi = {10.1016/j.jcrysgro.2015.08.007},
journal = {Journal of Crystal Growth},
number = C,
volume = 430,
place = {United States},
year = {Fri Aug 21 00:00:00 EDT 2015},
month = {Fri Aug 21 00:00:00 EDT 2015}
}

Journal Article:

Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Oriented ZnO thin films synthesis by sol–gel process for laser application
journal, March 2003


Next generation of oxide photonic devices: ZnO-based ultraviolet light emitting diodes
journal, June 2006

  • Ryu, Yungryel; Lee, Tae-Seok; Lubguban, Jorge A.
  • Applied Physics Letters, Vol. 88, Issue 24
  • DOI: 10.1063/1.2210452

Dual-mode mechanical resonance of individual ZnO nanobelts
journal, June 2003

  • Bai, X. D.; Gao, P. X.; Wang, Z. L.
  • Applied Physics Letters, Vol. 82, Issue 26
  • DOI: 10.1063/1.1587878

Synthesis and optical property of ZnO nanonail arrays with controllable morphology
journal, June 2010

  • Fan, Donghua; Zhang, Rong; Wang, Xianghu
  • Physica E: Low-dimensional Systems and Nanostructures, Vol. 42, Issue 8
  • DOI: 10.1016/j.physe.2010.03.031

Effects of flower-like ZnO nanowhiskers on the mechanical, thermal and antibacterial properties of waterborne polyurethane
journal, July 2009


Morphogenesis of One-Dimensional ZnO Nano- and Microcrystals
journal, March 2003


Zinc oxide nanocomb biosensor for glucose detection
journal, June 2006

  • Wang, J. X.; Sun, X. W.; Wei, A.
  • Applied Physics Letters, Vol. 88, Issue 23
  • DOI: 10.1063/1.2210078

Growth of Comb-like ZnO Nanostructures for Dye-sensitized Solar Cells Applications
journal, May 2009


Dendritic Nanowire Ultraviolet Laser Array
journal, April 2003

  • Yan, Haoquan; He, Rongrui; Johnson, Justin
  • Journal of the American Chemical Society, Vol. 125, Issue 16
  • DOI: 10.1021/ja034327m

Induced Growth of Asymmetric Nanocantilever Arrays on Polar Surfaces
journal, October 2003


Symmetric and asymmetric growth of ZnO hierarchical nanostructures: nanocombs and their optical properties
journal, March 2006


Formation of double-side teethed nanocombs of ZnO and self-catalysis of Zn-terminated polar surface
journal, January 2006


Effect of precipitation temperature and organic additives on size and morphology of ZnO nanoparticles
journal, March 2012

  • Yıldırım, Özlem Altıntaş; Durucan, Caner
  • Journal of Materials Research, Vol. 27, Issue 11
  • DOI: 10.1557/jmr.2012.58

Morphology-controlled synthesis, growth mechanism, optical and microwave absorption properties of ZnO nanocombs
journal, August 2008


Characterization and Field-Emission Properties of Vertically Aligned ZnO Nanonails and Nanopencils Fabricated by a Modified Thermal-Evaporation Process
journal, February 2006

  • Shen, G. Z.; Bando, Y.; Liu, B. D.
  • Advanced Functional Materials, Vol. 16, Issue 3
  • DOI: 10.1002/adfm.200500571

Substrate Atomic-Termination-Induced Anisotropic Growth of ZnO Nanowires/Nanorods by the VLS Process
journal, June 2004

  • Gao, Pu Xian; Wang, Zhong L.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 23
  • DOI: 10.1021/jp049657n

One-Step Hydrothermal Synthesis of Comb-Like ZnO Nanostructures
journal, September 2012

  • Xu, Xiaobin; Wu, Min; Asoro, Michael
  • Crystal Growth & Design, Vol. 12, Issue 10
  • DOI: 10.1021/cg3005773

Fabrication and characterization of ZnO comb-like nanostructures
journal, January 2006


Growth mechanism and characterization of ZnO microbelts and self-assembled microcombs
journal, November 2005


Preparation and Photoluminescence of ZnO Comb-Like Structure and Nanorod Arrays
journal, June 2007


Zinc oxide ribbon and comb structures: synthesis and optical properties
journal, August 2004


Bicrystalline Zinc Oxide Nanocombs
journal, August 2006

  • Huang, Yunhua; Zhang, Yue; Bai, Xuedong
  • Journal of Nanoscience and Nanotechnology, Vol. 6, Issue 8
  • DOI: 10.1166/jnn.2006.545

Structural Characterization of CVD-grown ZnO Nanocombs
journal, July 2011

  • Phan, Long The; Sun, Yuekui; Vincent, R.
  • Journal of the Korean Physical Society, Vol. 59, Issue 1
  • DOI: 10.3938/jkps.59.60

Growth of anisotropic one-dimensional ZnS nanostructures
journal, January 2006

  • Moore, Daniel; Wang, Zhong L.
  • Journal of Materials Chemistry, Vol. 16, Issue 40
  • DOI: 10.1039/b607902b

Growth Analysis of Hierarchical ZnO Nanorod Array with Changed Diameter from the Aspect of Supersaturation Ratio
journal, February 2010

  • Yan, Youguo; Zhou, Lixia; Han, Zhide
  • The Journal of Physical Chemistry C, Vol. 114, Issue 9
  • DOI: 10.1021/jp9122826

Band gap variation of size-controlled ZnO quantum dots synthesized by sol–gel method
journal, June 2005


Preparation and band gap energies of ZnO nanotubes, nanorods and spherical nanostructures
journal, June 2011


Highly Efficient Room Temperature Synthesis of Silver-Doped Zinc Oxide (ZnO:Ag) Nanoparticles: Structural, Optical, and Photocatalytic Properties
journal, February 2013

  • Yıldırım, Özlem Altıntaş; Unalan, Husnu Emrah; Durucan, Caner
  • Journal of the American Ceramic Society, Vol. 96, Issue 3
  • DOI: 10.1111/jace.12218

Polyvinylpyrrolidone-Directed Crystallization of ZnO with Tunable Morphology and Bandgap
journal, December 2007


Synthesis and morphology control of ZnO nanostructures in microemulsions
journal, May 2009

  • Li, Xiangcun; He, Gaohong; Xiao, Gongkui
  • Journal of Colloid and Interface Science, Vol. 333, Issue 2
  • DOI: 10.1016/j.jcis.2009.02.029

Effect of pH on the morphology and optical properties of modified ZnO particles by SDS via a precipitation method
journal, November 2010


Role of zinc interstitials and oxygen vacancies of ZnO in photocatalysis: a bottom-up approach to control defect density
journal, January 2014

  • Kayaci, Fatma; Vempati, Sesha; Donmez, Inci
  • Nanoscale, Vol. 6, Issue 17
  • DOI: 10.1039/C4NR01887G

First-principles study of intrinsic point defects in ZnO: Role of band structure, volume relaxation, and finite-size effects
journal, May 2006


Photoluminescence study of ZnO films prepared by thermal oxidation of Zn metallic films in air
journal, July 2003

  • Wang, Y. G.; Lau, S. P.; Lee, H. W.
  • Journal of Applied Physics, Vol. 94, Issue 1
  • DOI: 10.1063/1.1577819

Temperature-dependent shifts of near band-edge emission and their second-order diffraction for ZnO nanorods
journal, September 2012


Temperature-dependent shifts of three emission bands for ZnO nanoneedle arrays
journal, April 2006

  • Cao, Bingqiang; Cai, Weiping; Zeng, Haibo
  • Applied Physics Letters, Vol. 88, Issue 16
  • DOI: 10.1063/1.2195694

Annealing effect on the property of ultraviolet and green emissions of ZnO thin films
journal, February 2004

  • Kang, Hong Seong; Kang, Jeong Seok; Kim, Jae Won
  • Journal of Applied Physics, Vol. 95, Issue 3
  • DOI: 10.1063/1.1633343

Anomalous blueshift in emission spectra of ZnO nanorods with sizes beyond quantum confinement regime
journal, June 2006

  • Chen, Chun-Wei; Chen, Kuei-Hsien; Shen, Ching-Hsing
  • Applied Physics Letters, Vol. 88, Issue 24
  • DOI: 10.1063/1.2211047

Fabrication of a High-Brightness Blue-Light-Emitting Diode Using a ZnO-Nanowire Array Grown on p-GaN Thin Film
journal, March 2009


Current and Temperature Dependences of Electroluminescence of InGaN-Based UV/Blue/Green Light-Emitting Diodes
journal, November 1998

  • Mukai, Takashi; Yamada, Motokazu; Nakamura, Shuji
  • Japanese Journal of Applied Physics, Vol. 37, Issue Part 2, No. 11B
  • DOI: 10.1143/JJAP.37.L1358

Metalorganic vapor-phase epitaxial growth of vertically well-aligned ZnO nanorods
journal, June 2002

  • Park, W. I.; Kim, D. H.; Jung, S. -W.
  • Applied Physics Letters, Vol. 80, Issue 22
  • DOI: 10.1063/1.1482800

Simple Solvothermal Route To Synthesize ZnO Nanosheets, Nanonails, and Well-Aligned Nanorod Arrays
journal, September 2006

  • Kar, Soumitra; Dev, Apurba; Chaudhuri, Subhadra
  • The Journal of Physical Chemistry B, Vol. 110, Issue 36
  • DOI: 10.1021/jp0629902

Large-Scale Synthesis of Six-Nanometer-Wide ZnO Nanobelts
journal, July 2004

  • Wang, Xudong; Ding, Yong; Summers, Christopher J.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 26
  • DOI: 10.1021/jp048482e

Detailed understanding of the excitation-intensity dependent photoluminescence of ZnO materials: Role of defects
journal, June 2014

  • Prasada Rao, T.; Goswami, G. K.; Nanda, K. K.
  • Journal of Applied Physics, Vol. 115, Issue 21
  • DOI: 10.1063/1.4881779

Works referencing / citing this record:

PEG—assisted morphological transformation of 3D flower-like ZnO to 1D micro-/nanorods and nanoparticles for enhanced photocatalytic activity
journal, October 2017

  • Ghoderao, Karuna P.; Jamble, Shweta N.; Kale, Rohidas B.
  • Materials Research Express, Vol. 4, Issue 10
  • DOI: 10.1088/2053-1591/aa885b

Controllable Growth of Ultrathin P-doped ZnO Nanosheets
journal, April 2016


Controllable Growth of Ultrathin P-doped ZnO Nanosheets
journal, April 2016