Increased photocatalytic activity of TiO2 mesoporous microspheres from codoping with transition metals and nitrogen

Mathis, John E.; Lieffers, Justin J.; Mitra, Chandrima; Reboredo, Fernando A.; Bi, Z.; Bridges, Craig A.; Kidder, Michelle K.; Paranthaman, Mariappan Parans

doi:10.1016/j.ceramint.2015.10.164

Title: Increased photocatalytic activity of TiO₂ mesoporous microspheres from codoping with transition metals and nitrogen

Abstract

The composition of anatase TiO₂ was modified by codoping using combinations of a transition metal and nitrogen in order to increase its photocatalytic activity and extend it performance in the visible region of the electromagnetic spectrum. The transition metals (Mn, Co, Ni, Cu) were added during the hydrothermal preparation of mesoporous TiO₂ particles, and the nitrogen was introduced by post-annealing in flowing ammonia gas at high temperature. The samples were analyzed by SEM, XRD, BET, inductively-coupled plasma spectroscopy, and diffuse reflectance UV-vis spectroscopy. The photocatalytic activity was assessed by observing the change in methylene blue concentrations under both UV-vis and visible-only light irradiation. As a result, the photocatalytic activity of the (Mn,N), (Co,N), (Cu,N), and Ni,N) codoped TiO₂ was significantly enhanced relative to (N) TiO₂.

Authors:

Mathis, John E. ^[1]; Lieffers, Justin J. ^[1]; Mitra, Chandrima ^[1]; Reboredo, Fernando A. ^[1]; Bi, Z. ^[1]; Bridges, Craig A. ^[1]; Kidder, Michelle K. ^[1]; Paranthaman, Mariappan Parans ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Fri Nov 06 00:00:00 EST 2015

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1237636

Alternate Identifier(s):: OSTI ID: 1397675

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Ceramics International

Additional Journal Information:: Journal Volume: 42; Journal Issue: 1; Journal ID: ISSN 0272-8842

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; TiO₂; codoped; diffuse reflectance; photocatalysis

Citation Formats


                    Mathis, John E., Lieffers, Justin J., Mitra, Chandrima, Reboredo, Fernando A., Bi, Z., Bridges, Craig A., Kidder, Michelle K., and Paranthaman, Mariappan Parans. Increased photocatalytic activity of TiO2 mesoporous microspheres from codoping with transition metals and nitrogen.  United States: N. p., 2015. 
Web.  doi:10.1016/j.ceramint.2015.10.164.

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                    Mathis, John E., Lieffers, Justin J., Mitra, Chandrima, Reboredo, Fernando A., Bi, Z., Bridges, Craig A., Kidder, Michelle K., & Paranthaman, Mariappan Parans. Increased photocatalytic activity of TiO2 mesoporous microspheres from codoping with transition metals and nitrogen.  United States.  https://doi.org/10.1016/j.ceramint.2015.10.164

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                    Mathis, John E., Lieffers, Justin J., Mitra, Chandrima, Reboredo, Fernando A., Bi, Z., Bridges, Craig A., Kidder, Michelle K., and Paranthaman, Mariappan Parans. Fri .  
"Increased photocatalytic activity of TiO2 mesoporous microspheres from codoping with transition metals and nitrogen".  United States.  https://doi.org/10.1016/j.ceramint.2015.10.164.  https://www.osti.gov/servlets/purl/1237636.

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@article{osti_1237636,

  title        = {Increased photocatalytic activity of TiO2 mesoporous microspheres from codoping with transition metals and nitrogen},

  author       = {Mathis, John E. and Lieffers, Justin J. and Mitra, Chandrima and Reboredo, Fernando A. and Bi, Z. and Bridges, Craig A. and Kidder, Michelle K. and Paranthaman, Mariappan Parans},

  abstractNote = {The composition of anatase TiO2 was modified by codoping using combinations of a transition metal and nitrogen in order to increase its photocatalytic activity and extend it performance in the visible region of the electromagnetic spectrum. The transition metals (Mn, Co, Ni, Cu) were added during the hydrothermal preparation of mesoporous TiO2 particles, and the nitrogen was introduced by post-annealing in flowing ammonia gas at high temperature. The samples were analyzed by SEM, XRD, BET, inductively-coupled plasma spectroscopy, and diffuse reflectance UV-vis spectroscopy. The photocatalytic activity was assessed by observing the change in methylene blue concentrations under both UV-vis and visible-only light irradiation. As a result, the photocatalytic activity of the (Mn,N), (Co,N), (Cu,N), and Ni,N) codoped TiO2 was significantly enhanced relative to (N) TiO2.},

  doi          = {10.1016/j.ceramint.2015.10.164},

  journal      = {Ceramics International},

  number       = 1,

  volume       = 42,

  place        = {United States},

  year         = {Fri Nov 06 00:00:00 EST 2015},

  month        = {Fri Nov 06 00:00:00 EST 2015}

}

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https://doi.org/10.1016/j.ceramint.2015.10.164

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Works referencing / citing this record:

Sulfur-, nitrogen- and platinum-doped titania thin films with high catalytic efficiency under visible-light illumination
journal, January 2018

Žener, Boštjan; Matoh, Lev; Carraro, Giorgio
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Active packaging based on cellulose-chitosan-Ag/TiO2 nanocomposite for storage of clarified butter
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Žener, Boštjan; Matoh, Lev; Carraro, Giorgio
Beilstein Journal of Nanotechnology, Vol. 9
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Similar Records

Title: Increased photocatalytic activity of TiO2 mesoporous microspheres from codoping with transition metals and nitrogen

Abstract

Citation Formats

Photoelectrolysis of Water in Sunlight with Sensitized Semiconductor Electrodes journal, October 1977

The influence of niobium doping on the efficiency of n-TiO2 electrode in water photoelectrolysis journal, July 1980

Photocatalytic degradation of organic compounds diluted in water using visible light-responsive metal ion-implanted TiO2 catalysts: Fe ion-implanted TiO2 journal, September 2003

A novel preparation of iron-doped TiO2 nanoparticles with enhanced photocatalytic activity journal, January 2000

Characterization of metal ion-implanted titanium oxide photocatalysts operating under visible light irradiation journal, May 1999

Effects of altervalent cation doping of titania on its performance as a photocatalyst for water cleavage journal, February 1993

Hydrothermal synthesis and photocatalytic performance of metal-ions doped TiO2 journal, January 2012

Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides journal, July 2001

Preparation of Boron-Doped Porous Titania Networks Containing Gold Nanoparticles with Enhanced Visible-Light Photocatalytic Activity journal, January 2012

Band Gap Narrowing of Titanium Oxide Semiconductors by Noncompensated Anion-Cation Codoping for Enhanced Visible-Light Photoactivity journal, November 2009

Optical properties of N and transition metal R (R=V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) codoped anatase TiO2 journal, July 2012

Comparing Cr, and N only doping with (Cr, N)-codoping for enhancing visible light reactivity of TiO2 journal, November 2011

Hollow Core–Shell Mesoporous TiO 2 Spheres for Lithium Ion Storage journal, April 2011

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The direct synthesis of mesoporous structured MnO 2 /TiO 2 nanocomposite: a novel visible-light active photocatalyst with large pore size journal, April 2008

Preparation, Photocatalytic Activity, and Mechanism of Nano-TiO 2 Co-Doped with Nitrogen and Iron (III) journal, July 2007

Improving the thermal stability and photocatalytic activity of nanosized titanium dioxide via La3+ and N co-doping journal, January 2011

Correlation of electronic structures and crystal structures with photocatalytic properties of undoped, N-doped and I-doped TiO2 journal, March 2006

Efficient hybrid density functional calculations in solids: Assessment of the Heyd–Scuseria–Ernzerhof screened Coulomb hybrid functional journal, July 2004

Hybrid functionals based on a screened Coulomb potential journal, May 2003

Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)] journal, June 2006

Screened hybrid density functionals for solid-state chemistry and physics journal, January 2009

Generalized Gradient Approximation Made Simple journal, October 1996

Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)] journal, February 1997

Rationale for mixing exact exchange with density functional approximations journal, December 1996

Coupling-constant dependence of atomization energies journal, January 1997

Ab initiomolecular dynamics for liquid metals journal, January 1993

Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal, May 1994

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Projector augmented-wave method journal, December 1994

A Comparison Between Hybrid Functional, GW Approach and the Bethe Salpether Equation: Optical Properties of High Pressure Phases of TiO2 journal, June 2014

Urbach tail of anatase TiO 2 journal, September 1995

Understanding electronic and optical properties of anatase TiO2 photocatalysts co-doped with nitrogen and transition metals journal, January 2013

Enhanced visible-light absorption of mesoporous TiO 2 by co-doping with transition-metal/nitrogen ions journal, January 2013

Sulfur-, nitrogen- and platinum-doped titania thin films with high catalytic efficiency under visible-light illumination journal, January 2018

Active packaging based on cellulose-chitosan-Ag/TiO2 nanocomposite for storage of clarified butter journal, January 2019

Sulfur-, nitrogen- and platinum-doped titania thin films with high catalytic efficiency under visible-light illumination journal, January 2018

Title: Increased photocatalytic activity of TiO₂ mesoporous microspheres from codoping with transition metals and nitrogen

Photoelectrolysis of Water in Sunlight with Sensitized Semiconductor Electrodes
journal, October 1977

The influence of niobium doping on the efficiency of n-TiO2 electrode in water photoelectrolysis
journal, July 1980

Photocatalytic degradation of organic compounds diluted in water using visible light-responsive metal ion-implanted TiO2 catalysts: Fe ion-implanted TiO2
journal, September 2003

A novel preparation of iron-doped TiO2 nanoparticles with enhanced photocatalytic activity
journal, January 2000

Characterization of metal ion-implanted titanium oxide photocatalysts operating under visible light irradiation
journal, May 1999

Effects of altervalent cation doping of titania on its performance as a photocatalyst for water cleavage
journal, February 1993

Hydrothermal synthesis and photocatalytic performance of metal-ions doped TiO2
journal, January 2012

Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides
journal, July 2001

Preparation of Boron-Doped Porous Titania Networks Containing Gold Nanoparticles with Enhanced Visible-Light Photocatalytic Activity
journal, January 2012

Band Gap Narrowing of Titanium Oxide Semiconductors by Noncompensated Anion-Cation Codoping for Enhanced Visible-Light Photoactivity
journal, November 2009

Optical properties of N and transition metal R (R=V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) codoped anatase TiO2
journal, July 2012

Comparing Cr, and N only doping with (Cr, N)-codoping for enhancing visible light reactivity of TiO2
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Hollow Core–Shell Mesoporous TiO ₂ Spheres for Lithium Ion Storage
journal, April 2011

Mesoporous TiO2 spheres with a nitridated conducting layer for lithium-ion batteries
journal, May 2013

The direct synthesis of mesoporous structured MnO ₂ /TiO ₂ nanocomposite: a novel visible-light active photocatalyst with large pore size
journal, April 2008

Preparation, Photocatalytic Activity, and Mechanism of Nano-TiO ₂ Co-Doped with Nitrogen and Iron (III)
journal, July 2007

Improving the thermal stability and photocatalytic activity of nanosized titanium dioxide via La3+ and N co-doping
journal, January 2011

Correlation of electronic structures and crystal structures with photocatalytic properties of undoped, N-doped and I-doped TiO2
journal, March 2006

Efficient hybrid density functional calculations in solids: Assessment of the Heyd–Scuseria–Ernzerhof screened Coulomb hybrid functional
journal, July 2004

Hybrid functionals based on a screened Coulomb potential
journal, May 2003

Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)]
journal, June 2006

Screened hybrid density functionals for solid-state chemistry and physics
journal, January 2009

Generalized Gradient Approximation Made Simple
journal, October 1996

Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)]
journal, February 1997

Rationale for mixing exact exchange with density functional approximations
journal, December 1996

Coupling-constant dependence of atomization energies
journal, January 1997

Ab initiomolecular dynamics for liquid metals
journal, January 1993

Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Projector augmented-wave method
journal, December 1994

A Comparison Between Hybrid Functional, GW Approach and the Bethe Salpether Equation: Optical Properties of High Pressure Phases of TiO₂
journal, June 2014

Urbach tail of anatase ${TiO}_{2}$
journal, September 1995

Understanding electronic and optical properties of anatase TiO2 photocatalysts co-doped with nitrogen and transition metals
journal, January 2013

Enhanced visible-light absorption of mesoporous TiO ₂ by co-doping with transition-metal/nitrogen ions
journal, January 2013

Sulfur-, nitrogen- and platinum-doped titania thin films with high catalytic efficiency under visible-light illumination
journal, January 2018

Active packaging based on cellulose-chitosan-Ag/TiO2 nanocomposite for storage of clarified butter
journal, January 2019

Sulfur-, nitrogen- and platinum-doped titania thin films with high catalytic efficiency under visible-light illumination
journal, January 2018