Nanoporous Gold as a Platform for a Building Block Catalyst

Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

doi:10.1021/cs300231u

Title: Nanoporous Gold as a Platform for a Building Block Catalyst

Journal Article · Tue Sep 25 04:00:00 UTC 2012 · ACS Catalysis

DOI: https://doi.org/10.1021/cs300231u · OSTI ID:1237542

Wittstock, Arne ^[1]; Wichmann, Andre ^[2]; Baeumer, Marcus ^[2]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Univ. of Bremen (Germany)

The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporous gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1237542

Report Number(s):: LLNL-JRNL--547431

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 10 Vol. 2; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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