The corrosivity and passivity of sputtered Mg-Ti alloys

Song, Guang -Ling; Unocic, Kinga A.; Meyer, III, Harry M.; Cakmak, Ercan; Brady, Michael P.; Gannon, Paul E.; Himmer, Phil; Andrews, Quinn

doi:10.1016/j.corsci.2015.11.028

Title: The corrosivity and passivity of sputtered Mg-Ti alloys

Journal Article · Mon Nov 30 04:00:00 UTC 2015 · Corrosion Science

DOI: https://doi.org/10.1016/j.corsci.2015.11.028 · OSTI ID:1237147

Song, Guang -Ling ^[1]; Unocic, Kinga A. ^[2]; Meyer, III, Harry M. ^[2]; Cakmak, Ercan ^[2]; Brady, Michael P. ^[2]; Gannon, Paul E. ^[3]; Himmer, Phil ^[3]; Andrews, Quinn ^[3]

Xiamen Univ., Xiamen (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Montana State Univ., Bozeman, MT (United States)

Our study explored the possibility of forming a “stainless” Mg–Ti alloy. The electrochemical behavior of magnetron-sputtered Mg–Ti alloys was measured in a NaCl solution, and the surface films on the alloys were examined by XPS, SEM and TEM. Increased corrosion resistance was observed with increased Ti content in the sputtered Mg–Ti alloys, but passive-like behavior was not reached until the Ti level (atomic %) was higher than the Mg level. Moreover, the surface film that formed on sputtered Mg–Ti based alloys in NaCl solution was thick, discontinuous and non-protective, whereas a thin, continuous and protective Mg and Ti oxide film was formed on a sputtered Ti–Mg based alloy.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1237147

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Journal Issue: 3 Vol. 104; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Magnesium Alloy Effects on Plasma Electrolytic Oxidation Electro-Ceramic and Electro-Coat Formation and Corrosion Resistance Brady, Michael P.; Leonard, Donovan N.; McNally, Elizabeth A. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0531914jes	journal	January 2019

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