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Title: High-resolution x-ray diffraction study of the heavy-fermion compound YbBiPt

Abstract

In this study, YbBiPt is a heavy-fermion compound possessing significant short-range antiferromagnetic correlations below a temperature of T*=0.7K, fragile antiferromagnetic order below TN = 0.4K, a Kondo temperature of TK ≈ 1K, and crystalline-electric-field splitting on the order of E/kB = 1 – 10K. Whereas the compound has a face-centered-cubic lattice at ambient temperature, certain experimental data, particularly those from studies aimed at determining its crystalline-electric-field scheme, suggest that the lattice distorts at lower temperature. Here, we present results from high-resolution, high-energy x-ray diffraction experiments which show that, within our experimental resolution of ≈ 6 – 10 × 10–5 Å, no structural phase transition occurs between T = 1.5 and 50 K. In combination with results from dilatometry measurements, we further show that the compound's thermal expansion has a minimum at ≈ 18 K and a region of negative thermal expansion for 9 ≲ T ≲ 18 K. Despite diffraction patterns taken at 1.6 K which indicate that the lattice is face-centered cubic and that the Yb resides on a crystallographic site with cubic point symmetry, we demonstrate that the linear thermal expansion may be modeled using crystalline-electric-field level schemes appropriate for Yb3+ residing on a site with either cubicmore » or less than cubic point symmetry.« less

Authors:
 [1];  [1];  [1];  [2];  [1];  [1];  [1]
  1. Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
  2. Occidental College, Los Angeles, CA (United States)
Publication Date:
Research Org.:
Ames Lab., Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1235586
Alternate Identifier(s):
OSTI ID: 1227534
Report Number(s):
IS-J-8891
Journal ID: ISSN 1098-0121; PRBMDO
Grant/Contract Number:  
AC02-07CH11358; DMR1408598; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review. B, Condensed Matter and Materials Physics
Additional Journal Information:
Journal Volume: 92; Journal Issue: 18; Journal ID: ISSN 1098-0121
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Ueland, B. G., Saunders, S. M., Bud'ko, S. L., Schmiedeshoff, G. M., Canfield, P. C., Kreyssig, A., and Goldman, A. I. High-resolution x-ray diffraction study of the heavy-fermion compound YbBiPt. United States: N. p., 2015. Web. doi:10.1103/PhysRevB.92.184111.
Ueland, B. G., Saunders, S. M., Bud'ko, S. L., Schmiedeshoff, G. M., Canfield, P. C., Kreyssig, A., & Goldman, A. I. High-resolution x-ray diffraction study of the heavy-fermion compound YbBiPt. United States. https://doi.org/10.1103/PhysRevB.92.184111
Ueland, B. G., Saunders, S. M., Bud'ko, S. L., Schmiedeshoff, G. M., Canfield, P. C., Kreyssig, A., and Goldman, A. I. Mon . "High-resolution x-ray diffraction study of the heavy-fermion compound YbBiPt". United States. https://doi.org/10.1103/PhysRevB.92.184111. https://www.osti.gov/servlets/purl/1235586.
@article{osti_1235586,
title = {High-resolution x-ray diffraction study of the heavy-fermion compound YbBiPt},
author = {Ueland, B. G. and Saunders, S. M. and Bud'ko, S. L. and Schmiedeshoff, G. M. and Canfield, P. C. and Kreyssig, A. and Goldman, A. I.},
abstractNote = {In this study, YbBiPt is a heavy-fermion compound possessing significant short-range antiferromagnetic correlations below a temperature of T*=0.7K, fragile antiferromagnetic order below TN = 0.4K, a Kondo temperature of TK ≈ 1K, and crystalline-electric-field splitting on the order of E/kB = 1 – 10K. Whereas the compound has a face-centered-cubic lattice at ambient temperature, certain experimental data, particularly those from studies aimed at determining its crystalline-electric-field scheme, suggest that the lattice distorts at lower temperature. Here, we present results from high-resolution, high-energy x-ray diffraction experiments which show that, within our experimental resolution of ≈ 6 – 10 × 10–5 Å, no structural phase transition occurs between T = 1.5 and 50 K. In combination with results from dilatometry measurements, we further show that the compound's thermal expansion has a minimum at ≈ 18 K and a region of negative thermal expansion for 9 ≲ T ≲ 18 K. Despite diffraction patterns taken at 1.6 K which indicate that the lattice is face-centered cubic and that the Yb resides on a crystallographic site with cubic point symmetry, we demonstrate that the linear thermal expansion may be modeled using crystalline-electric-field level schemes appropriate for Yb3+ residing on a site with either cubic or less than cubic point symmetry.},
doi = {10.1103/PhysRevB.92.184111},
journal = {Physical Review. B, Condensed Matter and Materials Physics},
number = 18,
volume = 92,
place = {United States},
year = {Mon Nov 30 00:00:00 EST 2015},
month = {Mon Nov 30 00:00:00 EST 2015}
}

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Works referenced in this record:

Magnetism and heavy fermion‐like behavior in the RBiPt series
journal, November 1991

  • Canfield, P. C.; Thompson, J. D.; Beyermann, W. P.
  • Journal of Applied Physics, Vol. 70, Issue 10
  • DOI: 10.1063/1.350141

Massive electron state in YbBiPt
journal, December 1991


Fermi Surface Instability and Symmetry Breaking in Heavy-Fermion Compound YbBiPt
journal, July 1994


Groundstate properties of YbBiPt
journal, March 1994


Magnetic-field-tuned quantum criticality of the heavy-fermion system YbPtBi
journal, February 2013


Fragile antiferromagnetism in the heavy-fermion compound YbBiPt
journal, May 2014


Low-Energy Excitations and the Electronic Specific Heat of YbBiPt
journal, August 1995


Low‐temperature phase diagram of YbBiPt
journal, November 1994

  • Movshovich, R.; Lacerda, A.; Canfield, P. C.
  • Journal of Applied Physics, Vol. 76, Issue 10
  • DOI: 10.1063/1.358326

Crystallography and magnetism of the heavy-fermion compound YbBiPt
journal, October 1994


Low-temperature magnetism in YbBiPt
journal, August 1992


Electron spin resonance of Er 3 + in YBiPt
journal, December 1995


Low-energy excitations, symmetry breaking and specific heat in YbBiPt
journal, January 1999


Versatile and compact capacitive dilatometer
journal, December 2006

  • Schmiedeshoff, G. M.; Lounsbury, A. W.; Luna, D. J.
  • Review of Scientific Instruments, Vol. 77, Issue 12
  • DOI: 10.1063/1.2403088

The raising of angular momentum degeneracy of f-Electron terms by cubic crystal fields
journal, October 1962


Crystal-field study in rare-earth-doped semiconducting YBiPt
journal, August 1999


Crystal field levels in YbBiPt
journal, May 1993


Heavy-fermion systems
journal, October 1984


Magnetic fluctuations in the magnetically ordering heavy-fermion compounds UCu 5 and U 2 Zn 17
journal, August 1987


Transition probabilities for ƒ-electron J-multiplets in cubic crystal fields
journal, January 1972


Crystal-Electric-Field Effects on the Thermal Expansion of TmSb
journal, March 1976


Crystal field effect in the thermal expansion of cubic rare earth compounds
journal, September 1977

  • Ott, H. R.; L�thi, B.
  • Zeitschrift f�r Physik B Condensed Matter and Quanta, Vol. 28, Issue 3
  • DOI: 10.1007/BF01313036

Electronic band structure and structural stability of LaBiPt
journal, March 2001


Local symmetry lowering in the cubic intermetallics YbPdBi and YbNiSb
journal, July 1995


Multipolar interactions in f -electron systems: The paradigm of actinide dioxides
journal, June 2009

  • Santini, Paolo; Carretta, Stefano; Amoretti, Giuseppe
  • Reviews of Modern Physics, Vol. 81, Issue 2
  • DOI: 10.1103/RevModPhys.81.807

Multipole Orders and Fluctuations in Strongly Correlated Electron Systems
journal, July 2009

  • Kuramoto, Yoshio; Kusunose, Hiroaki; Kiss, Annamária
  • Journal of the Physical Society of Japan, Vol. 78, Issue 7
  • DOI: 10.1143/JPSJ.78.072001

Works referencing / citing this record:

Preserved entropy and fragile magnetism
journal, July 2016


Low-temperature elastic properties of YbSbPt probed by ultrasound measurements
journal, March 2018


Preserved entropy and fragile magnetism
text, January 2016


Two-channel conduction in YbPtBi
text, January 2017