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Title: Ligand-Mediated Interactions between Nanoscale Surfaces Depend Sensitively and Nonlinearly on Temperature, Facet Dimensions, and Ligand Coverage

Authors:
 [1];  [2]
  1. School of Chemistry, University of Sydney, Sydney, New South Wales 2006, Australia
  2. Department of Chemistry, University of California Berkeley, Berkeley, California 94720, United States
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1235494
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
ACS Nano
Additional Journal Information:
Journal Name: ACS Nano Journal Volume: 10 Journal Issue: 2; Journal ID: ISSN 1936-0851
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Widmer-Cooper, Asaph, and Geissler, Phillip L. Ligand-Mediated Interactions between Nanoscale Surfaces Depend Sensitively and Nonlinearly on Temperature, Facet Dimensions, and Ligand Coverage. United States: N. p., 2016. Web. https://doi.org/10.1021/acsnano.5b05569.
Widmer-Cooper, Asaph, & Geissler, Phillip L. Ligand-Mediated Interactions between Nanoscale Surfaces Depend Sensitively and Nonlinearly on Temperature, Facet Dimensions, and Ligand Coverage. United States. https://doi.org/10.1021/acsnano.5b05569
Widmer-Cooper, Asaph, and Geissler, Phillip L. Wed . "Ligand-Mediated Interactions between Nanoscale Surfaces Depend Sensitively and Nonlinearly on Temperature, Facet Dimensions, and Ligand Coverage". United States. https://doi.org/10.1021/acsnano.5b05569.
@article{osti_1235494,
title = {Ligand-Mediated Interactions between Nanoscale Surfaces Depend Sensitively and Nonlinearly on Temperature, Facet Dimensions, and Ligand Coverage},
author = {Widmer-Cooper, Asaph and Geissler, Phillip L.},
abstractNote = {},
doi = {10.1021/acsnano.5b05569},
journal = {ACS Nano},
number = 2,
volume = 10,
place = {United States},
year = {2016},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acsnano.5b05569

Citation Metrics:
Cited by: 4 works
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Works referenced in this record:

Molecular dynamics simulation of the effects of temperature on a dense monolayer of long‐chain molecules
journal, November 1990

  • Hautman, Joseph; Klein, Michael L.
  • The Journal of Chemical Physics, Vol. 93, Issue 10
  • DOI: 10.1063/1.459423

Interactions of surfactant monolayers across hydrocarbon liquids
journal, January 1990

  • Gee, Michelle L.; Israelachvili, Jacob N.
  • Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 24
  • DOI: 10.1039/ft9908604049

Self-assembly of uniform polyhedral silver nanocrystals into densest packings and exotic superlattices
journal, November 2011

  • Henzie, Joel; Grünwald, Michael; Widmer-Cooper, Asaph
  • Nature Materials, Vol. 11, Issue 2
  • DOI: 10.1038/nmat3178

Grand Canonical Monte Carlo Simulations of the Hydration Interaction between Oligo(ethylene glycol)-Terminated Alkanethiol Self-Assembled Monolayers
journal, November 2002

  • Pertsin, Alexander J.; Hayashi, Tomohiro; Grunze, Michael
  • The Journal of Physical Chemistry B, Vol. 106, Issue 47
  • DOI: 10.1021/jp025747l

Solvent coarse-graining and the string method applied to the hydrophobic collapse of a hydrated chain
journal, August 2007

  • Miller, T. F.; Vanden-Eijnden, E.; Chandler, D.
  • Proceedings of the National Academy of Sciences, Vol. 104, Issue 37
  • DOI: 10.1073/pnas.0705830104

Controlling Nanocrystal Superlattice Symmetry and Shape-Anisotropic Interactions through Variable Ligand Surface Coverage
journal, March 2011

  • Choi, Joshua J.; Bealing, Clive R.; Bian, Kaifu
  • Journal of the American Chemical Society, Vol. 133, Issue 9
  • DOI: 10.1021/ja110454b

Stability of Crystal Facets in Gold Nanorods
journal, February 2015


Self-Assembled Monolayer Growth of Octadecylphosphonic Acid on Mica
journal, January 1996

  • Woodward, John T.; Ulman, Abraham; Schwartz, Daniel K.
  • Langmuir, Vol. 12, Issue 15
  • DOI: 10.1021/la9510689

Surface-Amplified Ligand Disorder in CdSe Quantum Dots Determined by Electron and Coherent Vibrational Spectroscopies
journal, May 2011

  • Frederick, Matthew T.; Achtyl, Jennifer L.; Knowles, Kathryn E.
  • Journal of the American Chemical Society, Vol. 133, Issue 19
  • DOI: 10.1021/ja200466z

Temperature Antiquenching of the Luminescence from Capped CdSe Quantum Dots
journal, June 2004

  • Wuister, Sander F.; van Houselt, Arie; de Mello Donegá, Celso
  • Angewandte Chemie International Edition, Vol. 43, Issue 23
  • DOI: 10.1002/anie.200353532

Fast Parallel Algorithms for Short-Range Molecular Dynamics
journal, March 1995


Saturated liquid densities of benzene, cyclohexane, and hexane from 298.15 to 473.15 K
journal, July 1993

  • Beg, Shafkat A.; Tukur, Nasiru M.; Al-Harbi, Dulaihan K.
  • Journal of Chemical & Engineering Data, Vol. 38, Issue 3
  • DOI: 10.1021/je00011a035

Adsorption mechanisms, structures, and growth regimes of an archetypal self-assembling system: Decanethiol on Au(111)
journal, May 1998


Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology
journal, April 2005

  • Love, J. Christopher; Estroff, Lara A.; Kriebel, Jennah K.
  • Chemical Reviews, Vol. 105, Issue 4
  • DOI: 10.1021/cr0300789

Alkanethiolate Gold Cluster Molecules with Core Diameters from 1.5 to 5.2 nm:  Core and Monolayer Properties as a Function of Core Size
journal, January 1998

  • Hostetler, Michael J.; Wingate, Julia E.; Zhong, Chuan-Jian
  • Langmuir, Vol. 14, Issue 1
  • DOI: 10.1021/la970588w

Small is different: energetic, structural, thermal, and mechanical properties of passivated nanocluster assemblies
journal, January 2004

  • Landman, Uzi; Luedtke, W. D.
  • Faraday Discussions, Vol. 125
  • DOI: 10.1039/b312640b

Chain-length dependence of the structures and phases of CH 3 ( CH 2 ) n 1 SH self-assembled on Au(111)
journal, April 1993


Self-Assembly of Archimedean Tilings with Enthalpically and Entropically Patchy Polygons
journal, February 2014

  • Millan, Jaime A.; Ortiz, Daniel; van Anders, Greg
  • ACS Nano, Vol. 8, Issue 3
  • DOI: 10.1021/nn500147u

Taylor Dispersion Measurements of Monolayer Protected Clusters:  A Physicochemical Determination of Nanoparticle Size
journal, September 1999

  • Wuelfing, W. Peter; Templeton, Allen C.; Hicks, Jocelyn F.
  • Analytical Chemistry, Vol. 71, Issue 18
  • DOI: 10.1021/ac990429c

Spontaneous Asymmetry of Coated Spherical Nanoparticles in Solution and at Liquid-Vapor Interfaces
journal, June 2010


Epitaxy and chainlength dependent strain in self-assembled monolayers
journal, January 1997

  • Fenter, P.; Eberhardt, A.; Liang, K. S.
  • The Journal of Chemical Physics, Vol. 106, Issue 4
  • DOI: 10.1063/1.473281

Solvent Effects in the Adsorption of Alkyl Thiols on Gold Structures:  A Molecular Simulation Study
journal, July 2007

  • Pool, René; Schapotschnikow, Philipp; Vlugt, Thijs J. H.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 28
  • DOI: 10.1021/jp071491d

On the Characterization of the Surface Chemistry of Quantum Dots
journal, October 2013

  • Knittel, Fabien; Gravel, Edmond; Cassette, Elsa
  • Nano Letters, Vol. 13, Issue 11
  • DOI: 10.1021/nl402192d

Correlating Superlattice Polymorphs to Internanoparticle Distance, Packing Density, and Surface Lattice in Assemblies of PbS Nanoparticles
journal, February 2013

  • Wang, Zhongwu; Schliehe, Constanze; Bian, Kaifu
  • Nano Letters, Vol. 13, Issue 3
  • DOI: 10.1021/nl400084k

Large-scale molecular dynamics simulations of alkanethiol self-assembled monolayers
journal, September 2004

  • Vemparala, Satyavani; Karki, Bijaya B.; Kalia, Rajiv K.
  • The Journal of Chemical Physics, Vol. 121, Issue 9
  • DOI: 10.1063/1.1775779

Anisotropy of building blocks and their assembly into complex structures
journal, August 2007

  • Glotzer, Sharon C.; Solomon, Michael J.
  • Nature Materials, Vol. 6, Issue 8, p. 557-562
  • DOI: 10.1038/nmat1949

Drying-induced hydrophobic polymer collapse
journal, April 2002

  • ten Wolde, P. R.; Chandler, D.
  • Proceedings of the National Academy of Sciences, Vol. 99, Issue 10
  • DOI: 10.1073/pnas.052153299

Orientational Ordering of Passivating Ligands on CdS Nanorods in Solution Generates Strong Rod–Rod Interactions
journal, December 2013

  • Widmer-Cooper, Asaph; Geissler, Phillip
  • Nano Letters, Vol. 14, Issue 1
  • DOI: 10.1021/nl403067p

Explicit all-atom modeling of realistically sized ligand-capped nanocrystals
journal, March 2012

  • Kaushik, Ananth P.; Clancy, Paulette
  • The Journal of Chemical Physics, Vol. 136, Issue 11
  • DOI: 10.1063/1.3689973

An optimized united atom model for simulations of polymethylene melts
journal, July 1995

  • Paul, Wolfgang; Yoon, Do Y.; Smith, Grant D.
  • The Journal of Chemical Physics, Vol. 103, Issue 4
  • DOI: 10.1063/1.469740

Hydrophobicity at Small and Large Length Scales
journal, June 1999

  • Lum, Ka; Chandler, David; Weeks, John D.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 22
  • DOI: 10.1021/jp984327m

Switching Between Crystallization and Amorphous Agglomeration of Alkyl Thiol-Coated Gold Nanoparticles
journal, September 2012


Molecular dynamics simulation of the forces between colloidal nanoparticles in n-decane solvent
journal, October 2007

  • Qin, Yong; Fichthorn, Kristen A.
  • The Journal of Chemical Physics, Vol. 127, Issue 14
  • DOI: 10.1063/1.2776259

Structure and Thermodynamics of Self-Assembled Monolayers on Gold Nanocrystallites
journal, August 1998

  • Luedtke, W. D.; Landman, Uzi
  • The Journal of Physical Chemistry B, Vol. 102, Issue 34
  • DOI: 10.1021/jp981745i

Surface Chemistry of Colloidal PbSe Nanocrystals
journal, November 2008

  • Moreels, Iwan; Fritzinger, Bernd; Martins, José C.
  • Journal of the American Chemical Society, Vol. 130, Issue 45
  • DOI: 10.1021/ja803994m

Chemical, Structural, and Quantitative Analysis of the Ligand Shells of Colloidal Quantum Dots
journal, September 2012

  • Morris-Cohen, Adam J.; Malicki, Michał; Peterson, Mark D.
  • Chemistry of Materials, Vol. 25, Issue 8
  • DOI: 10.1021/cm302108j

Computer simulations of self-assembled monolayers
journal, September 2001

  • Schmid, Friederike; Stadler, Christoph; Düchs, Dominik
  • Journal of Physics: Condensed Matter, Vol. 13, Issue 38
  • DOI: 10.1088/0953-8984/13/38/308

Disorder in Alkylsilane Monolayers Assembled on Surfaces with Nanoscopic Curvature
journal, February 2009

  • Jones, Ryan L.; Pearsall, Nicole C.; Batteas, James D.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 11
  • DOI: 10.1021/jp8081358

Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding
journal, November 2013

  • Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J.
  • Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548
  • DOI: 10.1021/ja4086758

The melting point of ice Ih for common water models calculated from direct coexistence of the solid-liquid interface
journal, April 2006

  • García Fernández, Ramón; Abascal, José L. F.; Vega, Carlos
  • The Journal of Chemical Physics, Vol. 124, Issue 14
  • DOI: 10.1063/1.2183308

Calculation of the melting point of alkali halides by means of computer simulations
journal, September 2012

  • Aragones, J. L.; Sanz, E.; Valeriani, C.
  • The Journal of Chemical Physics, Vol. 137, Issue 10
  • DOI: 10.1063/1.4745205

Shape control of CdSe nanocrystals
journal, March 2000

  • Peng, Xiaogang; Manna, Liberato; Yang, Weidong
  • Nature, Vol. 404, Issue 6773, p. 59-61
  • DOI: 10.1038/35003535

Competition of shape and interaction patchiness for self-assembling nanoplates
journal, May 2013

  • Ye, Xingchen; Chen, Jun; Engel, Michael
  • Nature Chemistry, Vol. 5, Issue 6
  • DOI: 10.1038/nchem.1651

Nonadditivity of nanoparticle interactions
journal, October 2015


Nanoparticle Shape Anisotropy Dictates the Collective Behavior of Surface-Bound Ligands
journal, November 2011

  • Jones, Matthew R.; Macfarlane, Robert J.; Prigodich, Andrew E.
  • Journal of the American Chemical Society, Vol. 133, Issue 46
  • DOI: 10.1021/ja206777k

Structure, Dynamics, and Thermodynamics of Passivated Gold Nanocrystallites and Their Assemblies
journal, January 1996

  • Luedtke, W. D.; Landman, Uzi
  • The Journal of Physical Chemistry, Vol. 100, Issue 32
  • DOI: 10.1021/jp961721g

Frictional Properties of Surfactant-Coated Rod-Shaped Nanoparticles in Dry and Humid Dodecane
journal, August 2008

  • Min, Younjin; Akbulut, Mustafa; Prud’homme, Robert K.
  • The Journal of Physical Chemistry B, Vol. 112, Issue 46
  • DOI: 10.1021/jp802535j

Interaction of hydrocarbon monolayer surfaces across n ‐alkanes: A steric repulsion
journal, May 1989

  • Herder, Christina E.; Ninham, Barry W.; Christenson, Hugo K.
  • The Journal of Chemical Physics, Vol. 90, Issue 10
  • DOI: 10.1063/1.456387

Molecular Dynamics Simulation Study of Self-Assembled Monolayers of Alkanethiol Surfactants on Spherical Gold Nanoparticles
journal, November 2007

  • Ghorai, Pradip Kr.; Glotzer, Sharon C.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 43
  • DOI: 10.1021/jp0746289

Synthesis, surface studies, composition and structural characterization of CdSe, core/shell and biologically active nanocrystals
journal, April 2007


Forces between functionalized silica nanoparticles in solution
journal, May 2009


Structure and Dynamics in Alkanethiolate Monolayers Self-Assembled on Gold Nanoparticles:  A DSC, FT-IR, and Deuterium NMR Study
journal, March 1997

  • Badia, Antonella; Cuccia, Louis; Demers, Linette
  • Journal of the American Chemical Society, Vol. 119, Issue 11
  • DOI: 10.1021/ja963571t

Molecular simulations of structures and solvation free energies of passivated gold nanoparticles in supercritical CO2
journal, September 2010

  • Yang, Zhen; Yang, Xiaoning; Xu, Zhijun
  • The Journal of Chemical Physics, Vol. 133, Issue 9
  • DOI: 10.1063/1.3469774

Molecular Simulations of Interacting Nanocrystals
journal, September 2008

  • Schapotschnikow, Philipp; Pool, René; Vlugt, Thijs J. H.
  • Nano Letters, Vol. 8, Issue 9
  • DOI: 10.1021/nl8017862

Formation and Structure of Self-Assembled Monolayers
journal, January 1996

  • Ulman, Abraham
  • Chemical Reviews, Vol. 96, Issue 4, p. 1533-1554
  • DOI: 10.1021/cr9502357

Self-assembled monolayers: from  simple  model systems to biofunctionalized interfaces
journal, July 2004


The role of collective motion in examples of coarsening and self-assembly
journal, January 2009

  • Whitelam, Stephen; Feng, Edward H.; Hagan, Michael F.
  • Soft Matter, Vol. 5, Issue 6
  • DOI: 10.1039/B810031D